WO2016002594A1

WO2016002594A1 - Pesticide composition and application of same

Info

Publication number: WO2016002594A1
Application number: PCT/JP2015/068167
Authority: WO
Inventors: 赤山　敦夫; 将司亀崎
Original assignee: 住友化学株式会社
Priority date: 2014-07-04
Filing date: 2015-06-24
Publication date: 2016-01-07
Also published as: JP2014208695A

Abstract

This pesticide composition contains a compound represented by formula (1) or a compound represented by formula (2), or an N-oxide thereof, and one or more compounds selected from groups A to D below, and has an excellent controlling effect on pests. Group A: bactericide; group B: insecticide/acaricide; group C: safener; group D: plant growth regulator

Description

Pest control composition and use thereof

The present invention relates to a pest control composition and a pest control method.

Conventionally, many compounds are known as active ingredients of pest control compositions (see, for example, Patent Documents 1 to 3 and Non-Patent Document 1).

International Publication No. 2012/086848 International Publication No. 2013/018928 International Publication No. 2014/104404

An object of the present invention is to provide a pest control composition having an excellent control effect against pests.

As a result of studies to find a pest control composition having an excellent control effect against pests, the present inventors have found that the pest control composition contains a compound represented by the following formula (1) or the following formula (2): Has been found to have excellent control effects against pests.
That is, the present invention is as follows.
[1] Formula (1)

[Where:
A ^1a represents —NR ^8a —, an oxygen atom or a sulfur atom,
A ^2a represents a nitrogen atom or ═CR ^9a —,
A ^3a represents a nitrogen atom or ═CR ^10a —,
R ^1a has ^a C1-C6 chain hydrocarbon group which may have one or more atoms or groups selected from group X ^a or one or more atoms or groups selected from group Y ^a Represents a good C3-C6 alicyclic hydrocarbon group,
R ^2a , R ^3a , R ^4a and R ^5a are the same or different and are one or more atoms selected from ^a C1-C6 chain hydrocarbon group which may have one or more halogen atoms and group Za or a phenyl group which may have a group, one or more atoms may be 5-membered heterocyclic group having a group selected from the group Z ^a, or one or more atoms selected from the group Z ^a A 6-membered heterocyclic group optionally having a group, —OR ^11a , —S (O) _m R ^11a , —NR ^11a R ^12a , —CO ₂ R ^11a , —C (O) R ^11a , a cyano group, A nitro group, a halogen atom, —SF ₅ or a hydrogen atom (provided that at least two of R ^2a , R ^3a , R ^4a and R ^5a represent a hydrogen atom);
R ^6a and R ^7a are the same or different, one or more atoms or groups which may have a C1-C6 chain hydrocarbon group selected from the group X ^a, one or more selected from the group Z ^a atoms or a phenyl group which may have a group, one or more atoms may be 5-membered heterocyclic group having a group selected from the group Z ^a, one or more atoms selected from the group Z ^a Alternatively, a 6-membered heterocyclic group optionally having a group, —OR ^11a , —S (O) _m R ^11a , —S (O) ₂ NR ^11a R ^12a , —NR ^11a R ^12a , —NR ^11a CO ₂ R ^12a , —NR ^11a C (O) R ^12a , —CO ₂ R ^11a , —C (O) R ^11a , a cyano group, a nitro group, a halogen atom, —SF ₅ or a hydrogen atom;
R ^8a may have one or more atoms or groups selected from group W ^a, C1-C6 chain hydrocarbon group, —CO ₂ R ^11a , —C (O) R ^11a , group Y ^a Represents a C3-C6 alicyclic hydrocarbon group or a hydrogen atom optionally having one or more selected atoms or groups,
R ^9a and R ^10a are the same or different and are a C1-C6 chain hydrocarbon group which may have one or more halogen atoms, —OR ^11a , —S (O) _m R ^11a , —NR ^11a R ^12a , —CO ₂ R ^11a , —C (O) R ^11a , a cyano group, a nitro group, a halogen atom or a hydrogen atom;
R ^11a and R ^12a are the same or different and each represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms or a hydrogen atom,
m represents 0, 1 or 2, and n represents 0, 1 or 2.
Here, R ^6a and R ^7a do not represent a hydrogen atom at the same time, and in —S (O) _m R ^11a , when m is 1 or 2, R ^11a does not represent a hydrogen atom.
A ^1a is —NH— or —N (CH ₃ ) —, A ^2a and A ^3a are ═CH—, R ^1a is a methyl group, R ^2a , R ^3a , R ^4a and R ^5a are hydrogen atoms. And when n is 0, 1 or 2, R ^6a and R ^7a are the same or different and may have one or more atoms or groups selected from group X ^a C6 chain hydrocarbon group, one or more atoms or phenyl group which may have a group selected from the group Z, may have one or more atoms or groups selected from the group Z ^a 5 A membered heterocyclic group, ^a 6-membered heterocyclic group optionally having one or more atoms or groups selected from the group Za, —OR ^11a , —S (O) _m R ^11a , —S (O) ₂ ^{^{^{NR 11a R 12a, -NR 11a R}}} 12a, -NR 11a CO 2 R 12a, -NR 11a C (O) R 12a, -CO 2 H, -C (O) R 11a, cyano group, nitro It represents group, a bromine atom, an iodine atom, a -SF ₅ or a hydrogen atom. ).
Group X ^a : ^a C1-C6 alkoxy group which may have one or more halogen atoms, a C2-C6 alkenyloxy group which may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms. C2-C6 alkoxycarbonyl group which may have one, C3-C6 cycloalkyl group which may have one or more halogen atoms, cyano group, hydroxy And the group consisting of halogen atoms.
Group Y ^a : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens A group consisting of a C2-C6 alkenyloxy group which may have an atom, a C2-C6 alkynyloxy group which may have one or more halogen atoms, a hydroxy group and a halogen atom.
Group Z ^a : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens C1-C6 alkylsulfanyl group which may have an atom, C1-C6 alkylsulfinyl group which may have one or more halogen atoms, C1-C6 which may have one or more halogen atoms C6 alkylsulfonyl group, C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, one or more halogens A C1-C6 alkylamino group optionally having one atom, a C2-C8 dialkylamino group optionally having one or more halogen atoms, a halogen atom, a cyano group, and Group consisting of nitro group.
Group W ^a : ^a C1-C6 alkoxy group that may have one or more halogen atoms, a C2-C6 alkenyloxy group that may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms. C2-C6 alkoxycarbonyl group which may have one, C3-C6 cycloalkyl group which may have one or more halogen atoms, halogen atom, cyano And the group consisting of hydroxy groups. ]
Or a N-oxide thereof (hereinafter, the condensed heterocyclic compound represented by the formula (1) and its N-oxide may be referred to as the present compound (1));
A pest control composition comprising one or more compounds selected from Group A to Group D.
Group A; fungicide group B; insecticide, acaricide, nematode group C; safener group D; plant growth regulator [2] Formula (2)

[Where:
A ^1b represents —NR ^7b —, an oxygen atom or a sulfur atom,
A ^2b represents a nitrogen atom or ═CR ^8b —,
A ^3b represents a nitrogen atom or ═CR ^9b —,
R ^1b has a C1-C6 chain hydrocarbon group which may have one or more atoms or groups selected from group X ^b or one or more atoms or groups selected from group Y ^b. Represents a good C3-C6 alicyclic hydrocarbon group,
R ^2b , R ^3b and R ^4b are each a C1-C6 chain hydrocarbon group optionally having one or more atoms or groups selected from group ^Xb , and one or more atoms or groups selected from group Z A phenyl group which may have, a 5- or 6-membered heterocyclic group which may have one or more atoms or groups selected from group Z, -OR ^10b , -S (O) _m R ^10b , —S (O) ₂ NR ^10b R ^11b , —NR ^10b R ^11b , —NR ^10b CO ₂ R ^11b , —NR ^10b C (O) R ^11b , —CO ₂ R ^10b , —C (O) R ^10b , — C (O) NR ^10b R ^11b , —SF ₅ , a cyano group, a nitro group, a halogen atom or a hydrogen atom,
R ^5b and R ^6b are the same or different and are each a C1-C6 chain hydrocarbon group optionally having one or more atoms or groups selected from group X ^b , one or more selected from group Z ^b A phenyl group optionally having atoms or groups, a 5- or 6-membered heterocyclic group optionally having one or more atoms or groups selected from group Z ^b , —OR ^10b , —S (O) _m R ^10b , —S (O) ₂ NR ^10b R ^11b , —NR ^10b R ^11b , —NR ^10b CO ₂ R ^11b , —NR ^10b C (O) R ^11b , —CO ₂ R ^10b , —C (O) R ^10b , —C (O) NR ^10b R ^11b , —SF ₅ , a cyano group, a nitro group, a halogen atom or a hydrogen atom (wherein R ^5b and R ^6b do not represent a hydrogen atom at the same time),
R ^7b is a C1-C6 chain hydrocarbon group optionally having one or more atoms or groups selected from the group W ^b , and a C1-C6 chain hydrocarbon group having one phenyl group (wherein The phenyl group may have one or more atoms or groups selected from group Z ^b ), a C1-C6 chain hydrocarbon group having one 5- or 6-membered heterocyclic group (herein And the 5- or 6-membered heterocyclic group may have one or more atoms or groups selected from group Z ^b ), —CO ₂ R ^10b , —C (O) R ^10b , group Y ^a C3-C6 alicyclic hydrocarbon group or a hydrogen atom optionally having one or more atoms or groups selected from ^b ,
R ^8b and R ^9b are the same or different and are a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, —OR ^10b , —S (O) _m R ^10b , —NR ^10b R ^11b , —CO ₂ R ^10b , —C (O) R ^10b , a cyano group, a nitro group, a halogen atom or a hydrogen atom,
R ^10b and R ^11b are the same or different and are each a C1-C6 chain hydrocarbon group optionally having one or more atoms or groups selected from group X ^b , one or more selected from group Z ^b Represents a phenyl group or a hydrogen atom optionally having an atom or group,
m independently represents 0, 1 or 2, and n represents 0, 1 or 2.
Here, in —S (O) _m R ^10b , when m is 1 or 2, R ^10b does not represent a hydrogen atom.
Group X ^b : a C1-C6 alkoxy group which may have one or more halogen atoms, a C2-C6 alkenyloxy group which may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms. A C2-C6 alkoxycarbonyl group which may have one, one or more halogen atoms or one or more C1-C3 alkyl groups which may have one or more C1-C3 alkyl groups. Alkyl group, a cyano group, hydroxy group and the group consisting of halogen atoms.
Group Y ^b : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens A group consisting of a C2-C6 alkenyloxy group optionally having one atom, a C2-C6 alkynyloxy group optionally having one or more halogen atoms, and a halogen atom.
Group Z ^b : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens C1-C6 alkylsulfanyl group which may have an atom, C1-C6 alkylsulfinyl group which may have one or more halogen atoms, C1-C6 which may have one or more halogen atoms C6 alkylsulfonyl group, C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, one or more halogens A C1-C6 alkylamino group optionally having one atom, a C2-C8 dialkylamino group optionally having one or more halogen atoms, a halogen atom, a cyano group, and Group consisting of nitro group.
Group W ^b : a C1-C6 alkoxy group that may have one or more halogen atoms, a C2-C6 alkenyloxy group that may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C2-C6 alkyl which may have one or more halogen atoms A carbonyl group, a C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. C1-C6 alkylsulfinyl group which may have one, C1-C6 alkylsulfonyl group which may have one or more halogen atoms, hydroxy group, halogen The group consisting of atoms and a cyano group. ]
Or an N-oxide thereof (hereinafter, the condensed heterocyclic compound represented by the formula (2) and the N-oxide thereof may be referred to as the present compound (2));
A pest control composition comprising one or more compounds selected from Group A to Group D.
Group A; fungicide group B; insecticidal / acaricidal / nematocidal group C; safener group D; plant growth regulator [3] the present compound (1) or a salt of the present compound (1); The pest control composition according to [1], wherein the content ratio of the compound to one or more compounds selected from Group D is 100: 1 to 1: 100 by weight.
[4] The ratio of the content of the present compound (2) or a salt of the present compound (2) and one or more compounds selected from group A to group D is 100: 1 to 1: 100 by weight. The pest control composition according to [2].
[5] A method for controlling pests, comprising a step of applying an effective amount of the pest control composition according to any one of [1] to [4] to a plant or soil for cultivating the plant.
[6] The pest control method according to [4], wherein the plant is a seed, a bulb, or a seedling.
[7] The pest control method according to [4], wherein the plant is corn, soybean, cotton, wheat, sugar beet, rape or rice.
[8] A plant seed to which an effective amount of the pest control composition according to any one of [1] to [4] is adhered.

According to the present invention, pests can be controlled.

The pest control composition of the present invention comprises the present compound (1) or the present compound (2) (hereinafter, the present compound (1) and the present compound (2) may be referred to as the present compound), groups A to A. And one or more compounds selected from Group D.
Group A; fungicide group B; insecticide / acaricide group C; safener group D; plant growth regulator

As an aspect of the present compound, for example, a compound represented by the formula (1) shown in the following [Table 1] can be mentioned. These compounds are compounds described in International Publication No. 2012/088684, and can be produced by the method described in the specification.

The symbol in Formula (1) represents the combination as described in [Table 1] below. Hereinafter, this compound having the combination of substituents described in [Table 1] is represented by the numbers described in [Table 1]. For example, the compound of No. 1 in [Table 1] is referred to as the present compound 1.

[Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

[Continuation of Table 1]

(In [Table 1] above, Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, iPr represents an isopropyl group, tBu represents a tert-butyl group, and CyPr represents cyclopropyl. CyBu represents a cyclobutyl group, 2-F-Ph represents a 2-fluorophenyl group, 3-F-Ph represents a 3-fluorophenyl group, and 4-F-Ph represents a 4-fluorophenyl group 2-CF ₃ -Ph represents a 2-trifluoromethylphenyl group, 3-CF ₃ -Ph represents a 3-trifluoromethylphenyl group, and 4-CF ₃ -Ph represents 4-trifluoromethylphenyl 2-Cl-Ph represents a 2-chlorophenyl group, 3-Cl-Ph represents a 3-chlorophenyl group, 4-Cl-Ph represents a 4-chlorophenyl group, 2- O ₂ -Ph represents a 2-nitrophenyl group, 3-NO ₂ -Ph represents a 3-nitrophenyl group, 2-CN-Ph represents 2-cyanophenyl group, 3-CN-Ph 3- Represents a cyanophenyl group, 4-CN-Ph represents a 4-cyanophenyl group, 3-Py represents a pyridin-3-yl group, 4-Py represents a pyridin-4-yl group, and 6-Cl- 3-Py represents a 6-chloropyridin-3-yl group, 5-F-3-Py represents a 5-fluoropyridin-3-yl group, and 4-Cl-pyrazole represents 4-chloropyrazol-1-yl 3-Cl-triazole represents a 3-chloro- (1H-1,2,4-triazol) -1-yl group, and 3-CF ₃ -triazole represents 3-trifluoromethyl- (1H-1 , 2,4-triazole) -1 Represents yl _{group, 3-CF 3 -5-Me} -triazole is 3-trifluoromethyl-5-methyl - represents (IH-1,2,4-triazole) -1-yl group, 4-CF ₃ - (Imidazole represents a 4-trifluoromethylimidazol-1-yl group, and 4-CF ₃ -2-Py represents 4-trifluoromethylpyridin-2-yl.)

Moreover, as an aspect of this compound, the compound represented by Formula (2) shown, for example in the following [Table 2] is also mentioned. These compounds are compounds described in International Publication No. 2013/018928, and can be produced by the method described in the specification.

The symbol in Formula (2) represents the combination as described in [Table 2] below. Hereinafter, this compound having the combination of substituents described in [Table 2] is represented by the numbers described in [Table 2]. For example, the compound of No. 449 in [Table 2] is referred to as the present compound 449.

[Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

[Continuation of Table 2]

Here, the description of the number “*” in the present compound in [Table 2] above means N-oxide. Specifically, it is the following compound.
Compound 470

Compound 484

Compound 485

Compound 495

Compound 496

This compound 499

Compound 518

Compound 959

Compound 960

Compound 971

Compound 972

(In the above [Table 2], Me represents a methyl group, Et represents an ethyl group, Pr represents a propyl group, iPr represents an isopropyl group, Bu represents a butyl group, and tBu represents a tert-butyl group. CycPr represents a cyclopropyl group, CycBu represents a cyclobutyl group, CycPen represents a cyclopentyl group, CycHex represents a cyclohexyl group, Ph represents a phenyl group, 2-CF ₃ -Ph represents 2-trifluoro Represents a methylphenyl group, 3-CF ₃ -Ph represents a 3-trifluoromethylphenyl group, 4-CF ₃ -Ph represents a 4-trifluoromethylphenyl group, and 3-CF ₃ -triazolyl represents 3-trimethyl. Represents a fluoromethyl- (1H-1,2,4-triazol) -1-yl group and represents 3-CF ₃ -5-Me-triazo lyl represents a 3-trifluoromethyl-5-methyl- (1H-1,2,4-triazol) -1-yl group, and 4-CF ₃ -imidazolyl represents a 4-trifluoromethylimidazol-1-yl group. To express.)

Moreover, as an aspect of this compound, the compound represented by the formula (2A) to a formula (2D) shown by the following [Table 3A] to [Table 3D], for example is also mentioned. These compounds are compounds described in International Publication No. 2014/104404, and can be produced by the method described in the specification.

A compound represented by formula (2A).

The symbol in a formula represents the combination as described in the following [Table 3A].
Hereinafter, this compound having the combination of substituents described in [Table 3A] is represented by the numbers described in [Table 3A]. For example, the compound of No. 1004 in [Table 3A] is referred to as the present compound 1004.

[Table 3A]

[Continuation of Table 3A]

[Continuation of Table 3A]

A compound represented by formula (2B).

R ¹ and R ² in the formula represent the combinations described in [Table 3B] below.
Hereinafter, this compound having the combination of substituents described in [Table 3B] is represented by the numbers described in [Table 3B]. For example, the compound of No. 1072 in [Table 3B] is referred to as the present compound 1072.

[Table 3B]

A compound represented by formula (2C).

A ¹ , R ¹ and R ² in the formula represent the combinations described in [Table 3C] below.
Hereinafter, this compound having the combination of substituents described in [Table 3C] is represented by the numbers described in [Table 3C]. For example, the compound of No. 1078 in [Table 3C] is referred to as the present compound 1078.

[Table 3C]

A compound represented by formula (2D).

R ¹ and R ² in the formula represent the combinations described in [Table 3D] below.
Hereinafter, this compound having the combination of substituents described in [Table 3D] is represented by the numbers described in [Table 3D]. For example, the compound of number 1090 in [Table 3D] is referred to as the present compound 1090.

[Table 3D]

The present compound may take the form of a salt, and can be produced, for example, by mixing with an acid such as hydrochloric acid, sulfuric acid, methanesulfonic acid and the like.
The present compound or a salt of the present compound can be formulated alone or mixed with other pesticidal active ingredients and applied by the methods described herein. Moreover, the agricultural chemical formulation containing this compound or the salt of this compound and the agricultural chemical formulation containing another agricultural chemical active ingredient can be mixed, and can be applied by the method as described in this specification. Further, the formulated present compound or a salt of the present compound and the formulated other pesticidal active ingredient can also be applied at regular intervals without mixing.
As a salt of this compound,
Hydrochloride of any one compound of the present compounds 1 to 1095;
Sulfuric acid of any one compound of the present compounds 1 to 1095;
Phosphoric acid of any one compound of the present compounds 1 to 1095;
Nitric acid of any one compound of the present compounds 1 to 1095;
Inorganic acid salts, etc.
A methanesulfonate salt of any one compound of the present compounds 1 to 1095;
Paratoluenesulfonate salt of any one compound of the present compounds 1 to 1095;
A benzenesulfonate salt of any one compound of the present compounds 1 to 1095;
Camphorsulfonic acid salt of any one compound of the present compounds 1 to 1095;
And the like, and the like.
The present compound or a salt of the present compound can be formulated into a crystalline or amorphous form and applied by the method described herein.

The combinations described in [Table 4a] to [Table 4f], the present composition a, the present composition b, the present composition c, the present composition d, the present composition e, and the present composition f described below. It describes as this invention composition.
The composition of the present invention may be a simple mixture of the present compound or a salt of the present compound and one or more compounds selected from Group A to Group D. Usually, the present compound or a salt of the present compound and Group A are used. To a mixture with one or more compounds selected from Group D, a solid carrier, a liquid carrier, a surfactant, etc. are mixed, and if necessary, formulation adjuvants such as a fixing agent, a dispersing agent, a stabilizer are added. , Wettable powder, granular wettable powder, aqueous solvent, flowable, granule, fine granule, powder, dry flowable, emulsion, aqueous liquid, oil, microcapsule and the like. These preparations usually contain 0.1 to 99% by weight, preferably 0.2 to 90% by weight in total of the present compound or a salt of the present compound and one or more compounds selected from Group A to Group D. To do.
These preparations may be a combination of two or more preparations composed of a single component, a preparation composed of two or more kinds of components, or a combination thereof.

In the present invention, when two or more kinds of preparations are combined and applied to plants or soil where plants are cultivated, the preparations may be applied separately, or the preparations may be mixed and applied. Moreover, the dosage form of each formulation may be the same or different. When each preparation is applied separately, it may be applied after a certain period, such as several hours to several days. The order of applying each formulation may be arbitrary.

The content ratio of the present compound or a salt of the present compound and one or more compounds selected from Group A to Group D in the composition of the present invention is not particularly limited, but the present compound or the salt of the present compound The total amount of one or more compounds selected from Group A to Group D with respect to 1,000 parts by weight is usually 1 to 100,000 parts by weight, preferably 10 to 10,000 parts by weight.

Examples of the solid support include clays (for example, kaolin, diatomaceous earth, synthetic hydrous silicon oxide, wax clay, bentonite, acid clay), talc, and other inorganic minerals (for example, sericite, quartz powder, sulfur powder, Activated carbon, calcium carbonate, hydrated silica), pumice, calcite, marine stone, dolomite, olivine, pyroxene, feldspar, feldspar, alumina, vermiculite, perlite, etc.), elastomer, plastic, ceramics, metal, sawdust, corn Examples of the liquid carrier include water, alcohols (for example, methanol, ethanol), and ketones (for example, acetone, methyl ethyl ketone). ), Aromatic hydrocarbons (eg, benzene, toluene, xylene, ethylben Methyl naphthalenes), aliphatic hydrocarbons (eg n-hexane, cyclohexanone, kerosene), esters (eg ethyl acetate, butyl acetate), nitriles (eg acetonitrile, isobutyl nitrile), ethers (eg , Dioxane, diisopropyl ether), acid amides (for example, dimethylformamide, dimethylacetamide), and halogenated hydrocarbons (for example, dichloroethane, trichloroethylene, carbon tetrachloride).

Examples of the surfactant include alkyl sulfates, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers and polyoxyethylene compounds thereof, polyoxyethylene glycol ethers, polyhydric alcohol esters, sugar alcohol derivatives. Is mentioned.

Other formulation adjuvants include, for example, fixing agents, dispersants, antifoaming agents, stabilizers, preservatives, specifically casein, gelatin, polysaccharides (eg, starch, arabic gum, cellulose derivatives, alginic acid), Lignin derivatives, bentonite, saccharides, synthetic water-soluble polymers (eg, polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylic acids), PAP (isopropyl acid phosphate), BHT (2,6-di-tert-butyl-4-methylphenol) ), BHA (mixture of 2-tert-butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol), vegetable oil, mineral oil, fatty acid or ester thereof.
Moreover, you may add a coloring agent to a formulation. Examples of the colorant include a red pigment, a blue pigment, a green pigment, and a yellow pigment. Specific examples include monazole red, cyanine green, Prussian blue, and brilliant blue. In particular, in the case of granules and fine granules, it is easy to check the granules and fine granules at the time of application or after application. As will be described later, when the composition of the present invention is treated with plant seeds or bulbs, addition of a colorant is preferred because it is easy to confirm the treatment.
Further, for example, glycerin, ethylene glycol and propylene glycol may be added as antifreeze agents.

When the composition of the present invention is used for pest control, its application rate can vary widely depending on the application time, application location, application method, etc., but the application rate is usually about 10,000 m ² . The total amount of this compound or a salt of this compound and one or more compounds selected from Group A to Group D is 1 to 10,000 g. When the composition of the present invention is formulated into an emulsion, wettable powder, flowable agent, etc., the total of this compound or a salt of this compound and one or more compounds selected from Group A to Group D is usually used. The solution is diluted with water to a concentration of 0.01 to 10,000 ppm, and granules, powders and the like are usually applied as they are.

Examples of pests for which the composition of the present invention is effective include harmful animals such as harmful insects and harmful mites. Specific examples of such harmful animals include the following.

Hemiptera: small brown planthopper (Laodelphax striatellus), brown planthopper (Nilaparvata lugens), Sejirounka (Sogatella furcifera), planthoppers such as corn planthopper (Peregrinus maidis), green rice leafhopper (Nephotettix cincticeps), Taiwan green rice leafhopper (Nephotettix virescens), Rice green leafhopper (Nepotettix nigropictus), Inazuma leafhopper (Recilia dosalis), Chanomidorihimebokoba (Empoaska onukii), Potato leaf hopper (Empoasca fabaye), corn Leaf hopper (Dalbulus maidis), Sugarcane froghopper (Mahanarva posticata), Sugarcane root spittlebug (Mahanarva fimbriolota), white giant leafhopper (Cofana spectra), cross di leafhopper (Nephotettix nigropictus), leafhoppers such as Inazuma leafhopper (Recilia dorsalis), cotton Aphids (Aphis gossypii), peach aphids (Myzus persicae), radish aphids (Brevicorine brassicae), snowy aphids (Aphis spiraecola), tulip mustard Aphids (Macrosiphum euphorbiae), potato aphid (Aulacorthum solani), oat constricted aphid (Rhopalosiphum padi), oranges aphid (Toxoptera citricidus), Momoko butterbur aphid (Hyalopterus pruni), soybean aphid (Aphis glycines Matsumura), corn aphid (Rhopalosiphum Maidis), Black Aphid (Tetraneura nigriab dominalis), Grape Aphid (Viteus vitifoliaie), Grape Phylloxera (Daktospiraira viti) foliae), Pecan phylloxera (Phylloxera devastatrix Pergande), Pecan leaf phylloxera (Phylloxera notabilis pergande), aphids such as Southern pecan leaf phylloxera (Phylloxera russellae Stoetzel), rice black bug (Scotinophara lurida), Malayan rice black bug (Scotinophara coarctata) , Nezara antenata, Togeshiraboshi stink bug (Eysarcoris parvus), Crested stink bug (Halyomorpha m) sta), southern green stink bug (Nezara viridula), Brown stink bug (Euschistus heros), Southern green stink bug (Nezara viridula), Red banded stink bug (Piezodorus guildinii), Burrower brown bug (Scaptocoris castanea), Oebalus pugnax, Dichelops melacanthus Stink bugs such as Reptortus clavetus, Leptocorisa chinensis, Leptocorisa 、 acuta, Lept Coriosa spp., Trichotylus caesestialium, Akasika burrobitatus, Lys lineolula scorpio, Burico ss. White-tailed white-spotted moths such as Trialeurodes vaporariorum, Tobacco whiteflies (Bemisia tabaci), citrus whiteflies (Dialeurodes citri), Akanocaratus spiniferus, etc. lla aurantii), San Jose scale insect (Comstockcaspis perniciosa), Citrus snow scale (Unaspis citri), Ruby leaf beetle (Ceroplastes rubens), Iceria purusi cuco nak Scale insects such as stag beetle (Pseudauracapsis pentagona), tattle-my Lee bug (Brevennia rehi), citrus leaf lice (Diaphorina citri), pear lice (Psylla pyristoga papura) Whales such as Bilecerca cockerelli, Gunby beetles such as Stephanitis nasi, bedbugs such as Cimectularus and Giant Cicada (Quesadagi).

Lepidoptera: rice stem borer (Chilo suppressalis), Darkheaded stm borer (Chilo polychrysus), Sankameiga (Tryporyza incertulas), network Thailand Mei Chu (Chilo polychrysus), Shiromeichuu (Scirpophaga innotata), Yellow stem borer (Scirpophaga incertulas), Pink borer ( Sesamia inferens), Rupela albinella, Cnaphalococcus medinalis, Marasmia paternis, Marasmia exigna, Cotton moth (Notarcha derogata) Madarameiga (Plodia interpunctella), the European corn borer (Ostrinia furnacalis), high Madara Roh moth (Hellula undalis), Shibatsutoga (Pediasia teterrellus), Rice case worm (Nymphula depunctalis), Marasmia genus, Hop vine borer (Hydraecia immanis), European corn borer (Ostrinia nubilalis), Lesser cornstalk borer (Elasmopalpus lignosellus), Bean Shot Borer (Epinotia aporema), Sugarcane borer (Diatraea sacchar) alis), Pyralidae such as Giant Sugarcane borer (Telchin licus), common cutworm (Spodoptera litura), beet armyworm (Spodoptera exigua), armyworm (Pseudaletia separata), cabbage armyworm (Mamestra brassicae), Ineyotou (Sesamia inferens), Shironayotou (Spodoptera mauritia) , Spodoptera frugiperda, Spodoptera exempta, Agrotis ipsilon, Plusia nigrisigna, Soybep lupus udens), Trichopulcia genus, Tobacco moth (Heliothis virescens) and other Heliotis genus; White butterflies, genus Adoxofies, papaver, grapholivita molesta, leguminivola glycinivollella, azukiyamamushiga (Matsumuraeses azukivivora), apple coconut spider x na fasciata), smaller tea tortrix (Adoxophyes honmai. ), Chahamaki (Homona magnanima), Mi someone summer fruit moth (Archips fuscocupreanus), Tortricidae such as codling moth (Cydia pomonella), Chanohosoga (Caloptilia theivora), subfraction such apple leaf miner (Phyllonorycter ringoneella), peach fruit moth (Carposina niponensis), Citrus fruit borer
(Ecdytolopha aurantiana), etc., Coffee Leaf miner (Leucoptera coffela), Anemone genus such as Rionetia genus, Limantria genus, Euproctis genus, etc .; ) Potatoes such as potato moth (Phythromea operculella), and hitorigers such as Hyphantria cunea.

Thysanoptera: western flower thrips (Frankliniella occidentalis), Minami thrips (Thrips parmi), yellow tea thrips (Scirtothrips dorsalis), green onion thrips (Thrips tabaci), Hirazuhanaazamiuma (Frankliniella intonsa), western flower thrips (Frankliniella occidentalis) Inekuda Thrips such as thrips (Haplotrips acculeatus), rice thrips (Stenchaethrips biformis) and the like.

Diptera pests: Drosophila, Delia antiqua, Sugar beet root maggot (Tetenops myopae), Agromyza, Agromyza, Agromyza, Agromyza , Leafworms (Liriomyza trifoliii), leafworms (Chromatomyia horticola), leafworms (Chlorops oryzae), and citrus cuits. a), fruit fly, Hydralia sasakii, and other species of fruit fly, Such as butterflies and black mushrooms. Drosophila such as Hessian fly (Mayetiola destructor) and Inosinia oryzae, Drosophila such as Diopsis macrophtala, Common cranefly (Tipula eurae)

Coleoptera pests: Western Corn Rootworm (Diabrotica virgifera virgifera), southern corn rootworm (Diabrotica undecimpunctata howardi), Northern Corn rootworm (Diabrotica barberi), Mexican Corn Rootworm Diabrotica virgifera zeae), Banded Cucumber Beetle (Diabrotica balteata LeConte) , San Antonio Beetle (Diabrotica speciosa), Cucurbit Beetle (Diabrotica speciosa), Bean Leaf Beetle (Cerotoma trifurcata), Serial Leaf Beet (Oulema melanopus), cucurbit leaf beetle (Aulacophora femoralis), Kisujinomihamushi (Phyllotreta striolata), Colorado potato beetle (Leptinotarsa decemlineata), Inedorooimushi (Oulema oryzae), Grape Korasupisu (Colaspis brunnea), cone-flare Beetle (Chaetocnema pulicaria), potato flare Beetle (Epitrix cucumeris), rice beetle (Dicladispa armigera), Seedhorn beetle (Stenolopus contei), Sender seedcorn beetle (Crivinia impressifrons) leaf beetle such as, cupreous chafer (Anomala cuprea), rufocuprea (Anomala rufocuprea), Japanese beetle (Popillia japonica), European Chafer (Rhizotrogus majalis) carrot beetle (Bothynus gibbosus), Grape Colaspis (Colaspis brunnea), southern Corn leaf beetle ( Mythorous の denticollis), Holotrichia genus, June beetle (Phyllophaga clinita) and other phylums such as Phyllophaga genus, weevil (Sitophilus zea) ais), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), rice weevil such as grass reed weevil (Sphenophorus venatus), boll weevil (Anthonomus grandis), Southern Corn Billbug (Sphenophorus callosus), Soybean stalk weevil (Sternechus subsignatus) and Weevil of the genus Sphenophorus such as Sphenophorus levis, Epilacuna such as Epilachna vigintioctopuncta, Lycidae (Lyc) sbruneus, pine beetle (Tomicus pinipeperda), etc. Aggregates spg., Agriotes ogurae fuscicollis, Mekano click legumes, etc. , Aelous spp. , Anchorus spp. , Melanotus spp. Limonius spp. , Conoderus spp. Ctenicera spp. ), Beetles such as Paederus fuscipes, and Coffee BarryｏｒBorer (Hypothenemus hampei).

Orthoptera pests: locust (Locusta migratoria), mole crickets (Gryllotalpa africana), Morocco Tobi grasshopper (Dociostaurus maroccanus), Australian Plague Locust (Chortoicetes terminifera), Akatobibatta (Nomadacris septemfasciata), Brown Locust (Locustana pardalina), Tree Locust (Anacridium melanorhodon), Italian Locust (Calliptamusａｌitalicus), Differential glasshopper (Melanoplus differentialialis), Twostr ped grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-Legged grasshopper (Melanoplus femurrubrum), Clearwinged grasshopper (Camnula pellucida), desert Watari grasshopper (Schistocerca gregaria), Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris gutulosa), Cobainago (Oxya yezoensis), Hananagainago (Oxya ja onica), Taiwan Tutsi locust (Patanga succincta), house cricket (Acheta domesticus), and Enmakoorogi (Teleogryllus emma), Mormon cricket (Anabrus simplex) or the like crickets acids.

Hymenopteran pests: wasps such as wasp (Athalia rosae) and Japanese bee (Athalia japonica). Fire Ants. Hachiriari such as Brown's leaf-cutting ant (Atta's capiguara).

Nematodes: rice Shin Galle nematode (Aphelenchoides besseyi), strawberry menu nematode (Nothotylenchus acris), sweet potato root-knot nematode (Meloidogyne incognita), northern root-knot nematode (Meloidogyne hapla), Java root-knot nematode (Meloidogyne javanica), soybean cyst nematode (Heterodera glycines), Potato cyst nematode (Globodera rostochiensis), southern nematode nematode (Pratylenchus coffeae), barley nematode nematode (Pratylenchus neglectus), Meloidogyne java ica, Meloidogyne incognita, Rotylenchulus reniformis, Pratylenchus brachyurus and the like.

Termite pests: Reticulites speratus, Termite terminator (Coptoptermes formosanus), American termite terminus (Incitermes minors), Cyptotermes domesticus, Owantosistorus Glypoptermes satsumensis, Glyptotermes nakajimai, Caterpillars (Glypoptermes fuscus), Gyptotermes kodamai, Shimotoshiroari (Glyptotermes kushimensis), giant termite (Hodotermopsis japonica), Kou Shu Ye termite (Coptotermes guangzhoensis), Amami termites (Reticulitermes miyatakei), R. flavipes (Reticulitermes flaviceps amamianus), Kang Mont termites (Reticulitermes sp.), Takasago termite (Nasutitermes takasagoensis ), Termites termites (Pericapritermes nitobei), termites termites (Sinocapriters mushae), Cornitermesｍcumulan s etc.

Acarina pests: two-spotted spider mite (Tetranychus urticae), Kanzawa spider mite (Tetranychus kanzawai), citrus red mite (Panonychus citri), Ringohadani (Panonychus ulmi), Origonikasu genus and Southern Turkey spider mites (Brevipalpus phoenicis) mites such as, tangerine rust mite (Aculops pelekassi) , Ryukyu citrus mite (Phyllocoptruta citri), tomato rust mite (Aculops lycopersici), green rustic mite (Calacarus carinatus), green rusted mite (Acaphylla theavagran), mite riophyes chibaensis), Fushidani such as apple rust mite (Aculus schlechtendali), dust mite such as Chanohokoridani (Polyphagotarsonemus latus), southern Hime Himehadani such as spider mites (Brevipalpus phoenicis), Kenagahadani such, Tyrophagus (Tyrophagus putrescentiae), Tyrophagus (Tyrophagus mites such as Similis, and mites such as Dermatophagoides farinae and Dermatophagoides prenyssnus.
Lip and limb class: Geeu (Thereunema hilgendorfi), Tobizukade (Scorpendra subspinipes) and the like.
Double leg class: Oxidus gracilis, Nedyopus tambanus, etc.
Isopods: Armadillium vulgare, etc.
Gastropoda: Limax marginatus, Limax flavus, etc.

The target harmful insects and harmful ticks may be insects and ticks with reduced drug sensitivity or developed drug resistance to Group B insecticides / acaricides. However, when the drug sensitivity is greatly reduced or the drug resistance is greatly developed, it is desirable to use the composition of the present invention containing an insecticide / acaricide other than the target insecticide / acaricide.

The composition of the present invention can also be used to protect plants from plant diseases when one or more compounds selected from Group A are used.

Examples of plant diseases in which the composition of the present invention has a controlling effect include the following.
Rice diseases: rice blast (Magnaporthe grisea), sesame leaf blight (Cochliobolus miyabeanus), blight (Rhizoctonia solai), idiom ade (infestation) pv.Oryzae), seedling blight (Fusarium avenacerum, F. solani, Pythium arrhenom, P. gramicola, P. spinosum, Rhizopus chinensis, R. oryzae), bacterial disease bur i erh (Burkholderia glum e), brown spot disease (Erwinia herbicola), brown blight (Thanatephorus cucumeris), Helicothomus sigmoideum, Nakataea sigmoidero or spider Disease (Pseudomonas syringae pv. Oryzae), brown stripe disease (Pseudomonas avenae Mannell), leaf sheath browning disease (Pseudomonas marginolus) ntea), scab (Entyloma dactylidis Ciferri), white silkworm (Sclerotium rolfsiii), rice blast (Alternaria oryzaerumus, Pseudocochliolus, Pseudocochliol) Phytoplasma (Mycoplasma organizum)), Brachysporium disease (Curvularia sengalense), Leaf blight (Phaeosphateria oryzae), Gray leaf blight (Hendersonia oryzum), Gray fungus disease ium miyakei), spot disease (Cochliobolus sativus), panicle disease (Epicoccum hyalopes), bacterial blight (Gibberella fujikuroi), brown leaf blight (Metasphaeria albescens) Disease (Watea circinata), brown leaf disease (Khuskia oryzae), yellow blight (Pyrenochaeta oryzae), black spot disease (Cladosporium herbarum), black mold nuclei disease (Helicoceras oryzae rhidium disease) Species rot (Fusarium roseum), rice wilt (Phoma gl) marum), seedling rot (Pythium spp. Achlya spp. , Phytophthora spp. Dictyuchus spp. ), Mouse mold disease (Alternaria oryzae), rust-colored mycorrhizal disease (Sclerotium sp.), Sasara disease (Sphaerulina miyakei), red sclerotia (Waitea arumia disease) , Neocapnodium tanakae, Aureobasidium pullulans, Pseudocochliobolus lunatus, Sphaerulina oryzina leaf, B. scoparium), leaf rot (Acrocylindrium oryzae), leaf brown spot (Pyrenochaeta sp).
Wheat diseases: powdery mildew (Erysiphe graminis), red mold disease (Fusarium gramaminerum, F. avenacerum, F. culmorum, Microdochium nitrid, red rust (Puccinia isp. (Microlectriella nivale), Snow rot microspora nuclear disease (Typhula sp.), Bare smut (Ustylago tritici), Tuna scab (Tilleletia carripe), Pseucercosporella morposis (Pseudocercosporella herposis) Blight (Stagonospo) a nodorum), Kimadarabyo (Pyrenophora tritici-repentis).
Diseases of barley: powdery mildew (Erysiphe graminis), red mold disease (Fusarium gramaminerum, F. avenacerum, F. culmorum, Microdochium nitrifle, black punishment) Ustilago nuda), cloud disease (Rhynchosporium secalis), reticular disease (Pyrenophora teres), spot disease (Cochliobolus sativus), leafy leaf disease (Pyrenophora graminea), and Rhizonia a.
Diseases of corn: smut (Ustilago maydis), sesame leaf blight (Cochliobolus heterostrohus), leprosy (Gloeocercospora sorgi), southern rust (Puccinia polysorii), gray leaf spot disease Rhizoctonia solani due to seedling.

Diseases of Citrus: Black spot disease (Diaporthe citri), common scab (Elsinoe fawceti), fruit rot (Penicillium digitatum, P. italicum), phytophthora paraphysitic or Phytophthora or Phytophthora phytophathoropathy
Diseases of apples: Monilia mary, rot (Valsa ceratosperma), powdery mildew (Podospataera leukotrica), spotted leaf disease (Alternaria altanatal pest disease) , Phytophactora catorum.
Pear diseases: Venturia nashicola, V. pirina, Black spot (Alternaria alternata Japan pearpathotype), Red scab (Gymnosporangium haraeumum), disease
Peach diseases: Monilinia fracticola, black scab (Cladosporium carpophilum), Phomopsis spoilage (Phomopsis sp.).
Grape diseases: black scab (Elsinoe ampelina), late rot (Glomerella cinulata), powdery mildew (Uncinula apelopidais), black rot (Gikonivaladi) .
Oyster diseases: Anthracnose (Gloeosporium kaki), deciduous leaf disease (Cercospora kaki, Mycosphaerella nawae).
Diseases of cucurbits: Anthracnose (Colletotrichum lagenarium), powdery mildew (Sphaerotheca furiginea), vine blight (Mycosphaerella meloniis), vine scab (Fusarium oxysporum), por disease (fusarium oxysporum) ), Seedling blight (Pythium sp.);
Diseases of tomato: Alternaria solani, leaf mold (Cladosporium fulvum), plague (Phytophthora infestans).
Diseases of eggplant: brown spot disease (Phomopsis vexans), powdery mildew (Erysiphe cichoacearum).
Diseases of cruciferous vegetables: black spot disease (Alternaria japonica), white spot disease (Cercosporella brassicae), clubroot (Plasmodiophora brassicae), downy mildew (Peronospora parasitica).
Diseases of leek: rust (Puccinia allii), downy mildew (Peronospora destructor).

Diseases of soybean: Purcosis (Cercospora kikuchii), black scab (Elsinoe glycines), black spot (Diaporthe phasolorum var. Sojae), brown spot (Septoria glycines) Phytophthora sojae, Rhizoctonia solani, Corynespora cassiicola, Sclerotinia sclerotiorum.
Kidney disease: Anthracnose (Colletotrichum lindemthianum).
Peanut disease: black astringency (Cercospora personata), brown spot (Cercospora arachidicola), white silkworm (Sclerotium rolfsii).
Pea disease: powdery mildew (Erysiphe pisi).
Potato diseases: Alternaria solani, Phytophthora infestans, Sputum rot septica, Spongosporia subteranean f.
Strawberry disease: powdery mildew (Sphaerotheca humuli), anthracnose (Glomerella singulata).
Tea diseases: net blast (Exobasidium reticulatum), white scab (Elsinoe leucospila), ring spot disease (Pestarotropis sp.), Anthracnose (Colletotrichum theae-sinensis).
Tobacco disease: Alternaria longipes, powdery mildew (Erysiphe cichoracearum), anthracnose (Colletotrichum tabacum), downy mildew (Peronospora tabacina), epidemic (Phytophyti.
Diseases of oilseed rape: Sclerotinia sclerotiorum, Rhizoctonia solani, Rhizoctonia solani.
Cotton Diseases: Rhizoctonia solani caused by Rhizoctonia spp., Mildew fungus (Mycosphaerella areola), Black rot rot disease (Thielaviopsis basis caused by Thielaviopsis spp.).
Coffee disease: Rust (Hemileia vastatrix).
Diseases of sugarcane: rust (Puccinia melanocephela, Puccinia küehnii), smut (Ustilago scitamine).
Sunflower Disease: Rust (Puccinia helianthi).
Diseases of sugar beet: brown spot disease (Cercospora beticola), leaf rot (Thanatephorus cucumeris), root rot (Thanatephorus cucumeris), black root disease (Aphanomyces cochlioides).
Rose diseases: black spot (Diplocarpon rosae), powdery mildew (Sphaerotheca pannosa), downy mildew (Peronospora sparsa).
Diseases of chrysanthemum and asteraceae vegetables: downy mildew (Bremia lactucae), brown spot disease (Septoria chrysanthemi-indici), white rust (Puccinia horiana).
Diseases of various plants: diseases caused by Pythium spp. (Pythium aphanidermatum, P. debarianum, P. gramicola, P. irregulare, P. ultimum), gray mold (Botrytis cinereum), ro rot.
Radish disease: Alternaria brassicicola.
Diseases of buckwheat: Dollar spot disease (Sclerotinia homeocarpa), Brown patch disease and Large patch disease (Rhizotonia solani).
Banana disease: Sigatoka disease (Mycosphaerella fijiensis, Mycosphaerella musicola).
Sunflower disease: downy mildew (Plasmopara halstedii).
Aspergillus genus, Penicillium genus, Fusarium genus, Gibberella genus, Trichoderma genus, Thielaviopsis genus, Rhizopus genus, Mucor genus, Corticium genus, Poma genus, Rhizoctonia genus Disease.

The pathogenic bacterium or pathogenic bacterium causing the target disease may be a pathogenic bacterium or pathogenic bacterium having reduced drug sensitivity to a group A fungicide or having developed drug resistance. However, when the drug sensitivity is greatly reduced or the drug resistance is greatly developed, it is desirable to use the composition of the present invention containing a bactericide other than the bactericide to be targeted.

The composition of the present invention can also be used to protect plants from plant diseases caused by insect-borne viruses.

Examples of plant diseases caused by insect-borne viruses having the control effect of the composition of the present invention include the following.

Rice dwarf disease (Rice waika virus), Tungue disease (Rice tungro spheroid virus), Rice tungro bacilliform virus, Rice grassy stun disease (Rice gluten virulence) Disease (Rice stripe virus), black stripe strangled dwarf disease, southern rice black-streaked disease (rice leaf disease), rice R Rice hoja blanka virus), white leaf disease of rice (White l af disease of rice), yellow dwarf virus, red disease (Rice penyakit merah virus), rice yellow disease (Rice yellow stunt virus), transition yellowing disease (Rice Yellow Motor Virus), rice necrosis mosaic virus, rice dwarf stunt virus, wheat northern mosaic disease, northern Birth mosaic disease. Virus), wheat yellow leaf disease (W heat yellow dwarf virus), Oat sterile dwarf (Oat sterile dwarf virus), Wheat stream mosaic (Wheat stream mosaic virus)
Maize mosaic (Maize dwarf mosaic virus), Maize stripe disease (maize stripe tenuivirus), Maize chlorotic dwarf (Maize chlorotic dwarf virus), Maize chlorotic mottle (maize chlorotic mottle virus), Maize rayado fino (maize rayado fino marafivirus), Corn stunt (Corn stun spiroplasma), Maize bushy stunt (Maize bushy stunt phytoplasma), sugarcane mosaic disease (Sugarcane mosaic virus),
Soybean mild mosaic virus, Mosaic disease (Alfalfa Mosaic virus, Bean yellow-spot mosaic virus, Soybean mosaic virus, Bean yellowfish) Bean common mosaic virus, Peanut stunt virus, Southern bean mosaic virus, Soybean dwarf luteovirus-, Milk-vetch dwarf lutebird-Birtuo lutus ottle virus), Brazilian bud blight (Tobbaco streak virus), Cowpea chlorotic mottle (Cowpea chlorotic mottle), Mung bean yellow mosaic (Mung bean yellow mosaic virus), Peanut stripe (Peanut stripe mottle), Soybean crinkle leaf (Soybean crinkle leaf viruS ), Soybean Severe Stunt Virus (Soybean Severe Stunt Virus)
Tomato naturalization disease (Tomato chlorosis virus), tomato spotted wilt virus, tomato yellow leaf curl virus, melon yellow wilt cell (Melon yellow wilt cell) Disease (Watermelon mosaic virus), Dwarf disease (Cucumber mosaic virus), Zucchini yellow mosaic virus, Turnip mosaic virus, Bury moss Green spot disease (Capsicum chlorosis virus), Ki Cucumber yellow spot (Bet pseudo yellows virus), chrysanthemum stem necrosis virus, impatiens necrotic spot disease (Iris yellowspot spot), iris yellow spot (Iris yellow spot) Mosaic virus diseases of various plants mediated by Sweet potato internal cork virus, Sweet potato shukuyo mosaic virus, Polymixa genus, Olpidium genus and the like.

Examples of plants that can use the composition of the present invention include the following.
Agricultural crops: corn, rice, wheat, barley, rye, triticale, oat, sorghum, cotton, soybeans, peanuts, peanuts, cypress (green beans), lentils, azuki bean, cowpea, mung bean, safflower beans, bamboo bean, moss bean, tepareen Broad bean, pea, chickpea, lentil, lupine, bean, buckwheat, sugar beet, rape, sunflower, sugar cane, tobacco, etc.
Vegetables: Eggplant vegetables (eggplants, tomatoes, peppers, peppers, bell peppers, potatoes, etc.), Cucurbitaceae vegetables (cucumbers, pumpkins, zucchini, watermelon, melon, squash, etc.), cruciferous vegetables (radish, turnip, horseradish, Kohlrabi, Chinese cabbage, cabbage, mustard, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, garlic, artichoke, lettuce, etc.), Lily family vegetables (eg, leek, onion, garlic, asparagus, etc.), Aceraceae vegetables (carrot, parsley) , Celery, American Bow Fu, etc.), red crustacean vegetables (spinach, chard, etc.), perilla vegetables (perilla, mint, basil, lavender, etc.), strawberry, sweet potato, yam, taro, etc.
Bridegroom,
Foliage plant,
Shiva,
Forage crops; alfalfa, etc.
Fruit trees; pears (apples, pears, Japanese pears, quince, quince, etc.), nuclear fruits (peaches, plums, nectarines, ume, sweet cherry, apricots, prunes, etc.), citrus (satsuma mandarin, orange, lemon, lime, grapefruit) ), Nuts (chestnut, walnut, hazel, almond, pistachio, cashew nut, macadamia nut, etc.), berries (blueberry, cranberry, blackberry, raspberry, etc.), grape, oyster, olive, loquat, banana, coffee, Date palm, coconut palm, etc.
Trees other than fruit trees: Cha, mulberry, flowering trees, street trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, redwood, fu, sycamore, zelkova, black bean, peach tree, Tsuga, rat, pine, Spruce, yew) etc.

The above-mentioned plant may be a plant bred by hybrid technology.

That is, a plant bred by hybrid technology is a first-generation hybrid obtained by crossing two varieties of varieties, and generally has a hybrid strength (generally, yield potential) with a trait superior to that of both parents. Plant with the characteristics of increasing, resistance to biological and abiotic stress factors, etc.).

The above-mentioned plant may be a plant imparted with resistance by genetic recombination technology.

Such varieties of plants include PPO inhibitors such as flumioxazin, 4-hydroxyphenylpyruvate dioxygenase inhibitors such as isoxaflutole, acetolactate synthase such as imazetapyr and thifensulfuron methyl (hereinafter abbreviated as ALS). ) Inhibitors, 5-enolpyruvylshikimate-3-phosphate synthase (hereinafter abbreviated as EPSP) inhibitors such as glyphosate, glutamine synthetase inhibitors such as glufosinate, auxin types such as 2,4-D and dicamba Plants to which tolerance to herbicides such as herbicides and bromoxynil have been imparted by classical breeding methods or genetic engineering techniques are also included.
As an example of a plant to which resistance is imparted by a classic breeding method, corn, rice, wheat, sunflower, canola and the like resistant to an imidazolinone-based ALS-inhibiting herbicide such as imazetapir are trade names of Clearfield (registered trademark). Sold. Examples include sulfonylurea ALS-inhibiting herbicide-resistant STS soybeans such as thifensulfuron methyl. Similarly, SR corn and the like are examples of plants to which tolerance has been imparted to acetyl CoA carboxylase inhibitors such as trion oxime and aryloxyphenoxypropionic acid herbicides by classical breeding methods.
Examples of plants imparted with resistance by genetic recombination techniques include glyphosate-resistant corn, soybean, cotton, sugar beet, rapeseed, alfalfa, etc., RoundUpReady (registered trademark), Agriure (registered trademark) GT, Gly- Already sold under a trade name such as Tol (registered trademark). Similarly, glufosinate-resistant corn, soybean, cotton, rapeseed, and the like obtained by gene recombination techniques are available and are already sold under trade names such as LibertyLink (registered trademark). There are corn and soybean varieties under the trade name Optimum® GAT® which is resistant to both glyphosate and ALS inhibitors. Similarly, there is imidazolinone-type ALS inhibitor-resistant soybean by gene recombination technology, which has been developed under the name of Culture (registered trademark). Similarly, there is bromoxynyl-resistant cotton by genetic recombination technology, which is already sold under the trade name BXN (registered trademark). Similarly, as soybean resistant to both glyphosate and dicamba by genetic recombination technology, there is a soybean variety under the trade name RoundupReady2Yield (registered trademark). Similarly, cotton resistant to both glufosinate and dicamba by genetic engineering has been developed.
A gene encoding allyloxyalkanoate dioxygenase was introduced, and phenoxy acid herbicides such as 2,4-D, MCPA, dicloprop, mecoprop, and quizalofop, haloxyhop, fluazihop, diclohop, phenoxy Plants that are resistant to aryloxyphenoxypropionic acid herbicides such as saprop, metamihop, cihalohop, and clodinahop can be created (Wright et al. 2010: Proceedings of National Academy of Science. 107 (47): ~ 20245).

The “plant” includes a plant that can synthesize, for example, a selective toxin known in the genus Bacillus, using a gene recombination technique.
Toxins expressed in such transgenic plants include insecticidal proteins derived from Bacillus cereus and Bacillus popilliae; Cry1Ab, Cry1Ac, Cry1F derived from Bacillus thuringiensis Δ-endotoxin such as Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1 or Cry9C, insecticidal protein such as VIP1, VIP2, VIP3 or VIP3A; nematicidal insecticidal protein; scorpion toxin, spider toxin, bee toxin or insect-specific neurotoxin Toxins produced by animals; filamentous fungal toxins; plant lectins; agglutinins; trypsin inhibitors, serine protease inhibitors, protease inhibitors such as patatin, cystatin, papain inhibitors; ricin, corn-RIP, abrin, ruffin, saporin, Ribosome inactivating protein (RIP) such as briodin; Steroid metabolic enzymes such as droxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, cholesterol oxidase; ecdysone inhibitor; HMG-COA reductase; ion channel inhibitor such as sodium channel and calcium channel inhibitor; juvenile hormone esterase; Examples include diuretic hormone receptor; stilbene synthase; bibenzyl synthase; chitinase;
In addition, Cry1Ab, Cry1Ac, Cry1A.105, Cry1F, Cry1Fa2, Cry2Ab, Cry2Ab2, Cry2Ae, Cry3A, Cry3Bb1, Cry34Ab1, Cry35AB1, mCry3A, Cry9A, Cry9A, Cry9A, Cry9A and Cry9 Also included are insecticidal protein hybrid toxins such as VIP1, VIP2, VIP3 or VIP3A, partially defective toxins, and modified toxins. Hybrid toxins are produced by new combinations of different domains of these proteins using recombinant techniques. As a toxin lacking a part, Cry1Ab lacking a part of the amino acid sequence is known. In the modified toxin, one or more amino acids of the natural toxin are substituted.
Examples of these toxins and recombinant plants capable of synthesizing these toxins are EP-A-0 374 753, WO 93/07278, WO 95/34656, EP-A-0 427 529, EP-A-0 451 878, WO 03/052073 and the like.
Toxins contained in these recombinant plants particularly confer resistance to Coleoptera and Lepidoptera pests.

Also, genetically modified plants that contain one or more insecticidal pest resistance genes and express one or more toxins are already known, and some are commercially available. Examples of these transgenic plants include YieldGard® (a corn variety expressing Cry1Ab toxin), YieldGard® Rootworm (a corn variety expressing Cry3Bb1 toxin), YieldGard® Plus (Cry1Ab and Cry3Bb1 Corn varieties that express toxins), Herculex® I (corn varieties that express phosphinotricin N-astilyltransferase (PAT) to confer resistance to Cry1Fa2 toxin and glufosinate), NuCOTN33B (Cry1Ac toxin) Cotton varieties), Bollgard (registered trademark) I (cotton varieties expressing Cry1Ac toxin), Bollgard (registered trademark) II (cotton varieties expressing Cry1Ac and Cry2Ab toxin), BollGard (registered trademark) III (Cry1Ac and Cotton varieties expressing Cry2Ab and VIP3A toxin), VIPCOT (registered trademark) (cotton varieties expressing VIP toxin), WideStrike (registered trademark) (Cry1Ac and C Cotton varieties expressing ry1F toxin), NewLeaf (registered trademark) (potato varieties expressing Cry3A toxin), NatureGard (registered trademark) Agrisure (registered trademark) GT Advantage (GA21 glyphosate resistant trait), Agrisure (registered trademark) CB Advantage (Bt11 corn borer (CB) trait), Protecta (registered trademark) and the like. Examples include plants imparted with resistance to aphids such as soybeans introduced with the Rag1 (Resistance Aphid Gene 1) gene. Moreover, the thing to which the tolerance with respect to a nematode was provided using the classic breeding method or the gene recombination technique is also contained. RNAi is an example of a gene recombination technique that provides nematode resistance.

The “plant” includes those imparted with an ability to produce an anti-pathogenic substance having a selective action using a gene recombination technique.
PR proteins and the like are known as examples of anti-pathogenic substances (PRPs, EP-A-0 392 225). Such anti-pathogenic substances and genetically modified plants that produce them are described in EP-A-0 392 225, WO 95/33818, EP-A-0 353 191 and the like.
Examples of anti-pathogenic substances expressed in such genetically modified plants include, for example, sodium channel inhibitors and calcium channel inhibitors (KP1, KP4, KP6 toxins produced by viruses, etc.) are known. Ion channel inhibitors; stilbene synthase; bibenzyl synthase; chitinase; glucanase; PR protein; peptide antibiotics, heterocyclic antibiotics, protein factors involved in plant disease resistance (called plant disease resistance genes, WO No. 03/000906)) and other anti-pathogenic substances produced by microorganisms.
The above plants also include plants imparted with useful traits such as oil component modification and amino acid content enhancing traits using genetic recombination techniques. Examples include VISTIVE® (low linolenic soybean with reduced linolenic content) or high-lysine (high-oil) corn (corn with increased lysine or oil content).

Moreover, the above-mentioned “plant” is a line to which two or more traits relating to herbicide resistance, pest resistance, disease resistance, etc. as described above are imparted using classical breeding techniques or genetic recombination techniques, Also included are strains to which two or more properties of the parent strain are imparted by crossing genetically modified plants having similar or different properties. Examples of such plants include Smart stax (registered trademark).
In addition, the above-mentioned classic herbicide traits or herbicide resistance genes, insecticidal pest resistance genes, anti-pathogenic substance production genes, useful traits such as oil component modification and amino acid content enhancement traits Combined stack varieties are also included. Also included are plants into which RNAi technology has been introduced.

In the present invention, the plant used may be planted or planted with plant seeds, bulbs or seedlings.
Examples of bulbs include bulbs, bulbs, rhizomes, tubers, tuberous roots, root support bodies or stem fragments, and so-called seed pods are included. The seedlings include cuttings in addition to those grown from plant seeds or bulbs.
Plant seeds, bulbs or seedlings are preferably treated with a fungicide, but are not necessary. When treating with a fungicide, it is used after treating plant seeds or bulbs with one or more fungicides. Commercially treated plant seeds or bulbs or the like may be purchased and used, or seedlings grown from the treated plant seeds or bulbs or the like may be purchased and used. As described later, those treated with the present composition containing the present compound or a salt of the present compound and a fungicide compound may be used.

Examples of the method of applying the composition of the present invention to plants include application to plant stems and leaves, flower vases, ears, fruits, trunks, branches or crowns, application to plant seeds or bulbs, and application to seedlings. .

Examples of the application method of the composition of the present invention to plant stems and leaves, flower vases, ears, fruits, tree trunks, branches, or crowns include spraying, coating, and injection. Examples of spraying methods include human sprayers and power sprayers. In addition, ground spraying using a boom sprayer or a crumb sprayer, air spraying using an unmanned helicopter, air spraying, and the like can be given.
The application to the seedling is an application in the seedling raising period of the plant to be transplanted or planted, and examples of the method include spraying, dipping, and irrigation.
Examples of the application method to a place where a plant is cultivated or planned to be cultivated or a place where a pest lives or is expected to live include soil treatment, hydroponic liquid treatment, and the like.
In the present invention, the soil refers to a plant cultivation carrier, particularly a support for growing roots, and the material is not particularly limited, but may be any material that can grow a plant, so-called soil, seedling mat, water. Specific materials may include, for example, sand, pumice, vermiculite, diatomaceous earth, gel material, polymer material, rock wool, glass wool, wood chip, bark and the like.
When applied to the soil, it can be applied to the surface by spraying, irrigation, dripping, etc., or mixed into the soil by covering or plowing after treatment on the surface, and then injected into the soil using an injector It is. These treatments can be performed after mixing with agricultural materials such as paste fertilizer. Specific examples of application sites include holes or grooves when planting seeds, bulbs or seedlings, plant sources, strains, intercostals, the entire surface of plant growth, water surface, nursery beds, and the like.
As a method for applying to a nursery, the composition of the present invention is mixed with the soil before plant seeds, bulbs or seedlings are seeded or planted, or the composition of the present invention is mixed with the plant seeds or bulbs seeded or planted in the soil. It is also preferable to cover with dry soil.

The soil treatment in the present invention refers to, for example, controlling pests directly by applying an active ingredient to the rhizosphere of a plant to be protected from damage such as feeding by pests, or roots inside the plant body. This is a method of controlling the pests by osmotically transferring active ingredients from, etc., specifically, for example, planting treatment (planting hole spraying, planting hole soil mixing), plant source processing (stock source spraying, strain source) Soil admixture, strainer irrigation, seedling treatment in the latter half of the seedling season), grooving treatment (spreading grooving, mixing grooving soil), cropping treatment (spreading, sprinkling soil mixing, sprinkling of growing season), sowing Temporal row treatment (spreading at the time of sowing, mixing with the soil at the time of sowing), full treatment (spreading the whole soil, blending with the whole soil), side treatment, water surface treatment (full water surface application, frame water surface application), other soil spraying Treatment (growth of leaves during growth period, spray under the crown or around the trunk, soil surface Cloth, soil surface mixing, sowing hole spraying, buttocks ground surface spraying, inter-plant spraying), other irrigation treatment (soil irrigation, seedling irrigation, chemical injection, chemical irrigation, chemical drip irrigation, chemigation), nursery box Treatment (spreading of seedling boxes, seedling box irrigation, seedling box chemical solution flooding) seedling treatment (seedbed spraying, seedbed irrigation, water seedling seedling spraying), seedling soaking, seedling culture soil mixing treatment (floor soil mixing, covering soil mixing), seeding covering soil Pre-spreading, sowing after covering soil, stem injection treatment, trunk injection treatment, trunk injection treatment, other treatment (spreading, topsoil mixing, raindrop mixing, planting position processing, granule inflorescence spraying, paste fertilizer mixing) Can be mentioned.
Hydroponic liquid treatment is, for example, by applying an active ingredient to hydroponic liquid etc. in order to infiltrate and transfer from the root etc. into the plant body of the plant to be protected from damage such as feeding by pests, etc. This is a method for protecting plants from damage caused by pests. Specific examples include mixing of hydroponic liquid and mixing of hydroponic liquid.
Further, a plant in which a preparation containing the composition of the present invention is wrapped around a plant by a method such as immersion, impregnation, coating, kneading in a carrier such as sheet, string, tape, net-like resin, paper, cloth, etc. It can also be applied by methods such as stretching over the vicinity, laying on the stock soil, and covering the cultivation area of plants.

Examples of the method of applying the composition of the present invention to plant seeds or bulbs include preparations containing active ingredients in plant seeds or bulbs or methods of coating, smearing or applying diluted solutions thereof, and preparations containing active ingredients. A method of immersing plant seeds or bulbs, a method of spraying a preparation containing an active ingredient or a diluted solution thereof onto plant seeds or bulbs, and a method of coating plant seeds or bulbs with a carrier containing active ingredients (for example, film coating treatment, Pellet coating treatment, etc.). The amount of the compound to be treated is usually 0.2 to 5000 g, preferably 0.5 to 1000 g, per 100 kg of plant seeds or bulbs. Preferred dosage forms are aqueous liquid suspension preparations such as emulsions, wettable powders, flowables, and microcapsules. An aqueous suspension of granule wettable powder and dry flowable powder is also preferable.
Among the plants to be treated, among others, soybeans, corn, cotton, wheat, barley, rye, triticale, oats, rice, sorghum, peanuts, legumes except soybeans and peanuts, sugar beet, rapeseed, sunflower, potato, It is preferably applied to sugarcane and vegetables.

In the case where the composition of the present invention is treated with plant seeds or bulbs, it is particularly preferable to use a composition containing at least one fungicide among the compositions of the present invention. At this time, commercially treated plant seeds or bulbs may be purchased and used.
Moreover, when processing this invention composition to a plant seed or a bulb, you may process manganese, copper, zinc, etc. simultaneously.
Plant seeds or bulbs treated with the composition of the present invention are sown or planted in a field by a usual method.

The composition of the present invention can effectively control a wide range of subjects in a cereal field, a vegetable field, a flower field, an orchard, or a non-agricultural land where normal or non-tillage cultivation is performed.

When the composition of the present invention is applied to sugarcane, in sugarcane cultivation, a sugarcane stem fragment that has been cut so as to have one node may be used, and the size of the sugarcane stem fragment may be 2 cm. One having 15 to 15 cm, preferably 3 to 8 cm may be used. Sugarcane cultivation techniques using such stem fragments are known (WO09 / 000398, WO09 / 000399, WO09 / 000400, WO09 / 000401, WO09 / 000402) and are implemented under the trade name of Prene (registered trademark). The

When the composition of the present invention is applied to rice, it may be applied to a nursery, may be applied to paddy fields, or may be applied to rice seeds.
The nursery includes a nursery box or a rice seedling tray and a nursery.
When applied to a seedling box, the application time of the composition of the present invention is not particularly limited as long as it is a period from the sowing of rice to the time of transplanting, for example, pre-soiling pretreatment at sowing, post-soaking treatment at sowing, greening Phase treatment, transplantation day treatment, and transplantation simultaneous treatment can be mentioned. It may be applied 5 days before transplantation to the day before transplantation, and can be applied at any time during the period from seeding to transplantation.
The period from sowing to transplanting varies depending on young seedlings (seedlings around 2.5 leaf stage), medium seedlings (seedlings around 3.5 leaf stage) or adult seedlings (seedlings around 4.5 leaf stage), and The seedling period varies depending on weather conditions, etc., but it can be applied in any case.
A preparation of the composition of the present invention, for example, a kneaded granule or a sand coating granule may be sprayed on the seedling box, or a solution obtained by diluting the preparation of the composition of the present invention may be irrigated to the seedling box. The composition of the present invention can also be applied by mixing with floor soil or covering soil. The seedling culture medium is not particularly limited as long as it is a soil for rice seedlings, and a seedling mat other than soil may be used. The seedlings to which this compound is applied may be cultivated by pool seedlings.
When applying this invention composition to a paddy field, you may use for the rice of transplant cultivation, and may be used for the rice of direct sowing cultivation. The method of applying to paddy fields is not particularly limited, but the method of applying the composition of the present invention as it is or as a preparation to be applied to rice foliage, the method of applying to paddy soil, and the surface of flooded paddy fields. The method of applying etc. are mentioned. Moreover, it can also be applied labor-saving with the supply of water by processing chemicals such as emulsion and flowable at the source of water flowing into paddy fields such as a water inlet and an irrigation device. The time to apply to the rice stem and leaves may be any time from seedling to harvest. Preparations to be used include preparations to be applied as they are, such as powders and fine granules, and flowables, dry flowables, wettable powders, granule wettable powders, SE drugs, aqueous solvents, granular aqueous solvents, liquids, microscopic products Preparations that are diluted and sprayed, such as emmaffusion agents, EW agents, oil agents, surf agents, or emulsions. The spraying device may be any device that is normally used, and a hand-spreading device, a power spreader, a cruising player, a radio control helicopter, a manned helicopter, and the like can be used. Moreover, you may spray by hand, without using an apparatus.
As a method of applying to paddy soil, a method of treating the whole surface of paddy soil (entire treatment), a method of treating a groove provided when sowing rice (seeding groove treatment), 0-10 cm directly under rice seeds And a method of treating in the vicinity of rice lines or seeds in the form of streaks or dots (side treatment).
When applied to paddy soil, it can be mixed with or simultaneously with agricultural materials such as paste fertilizer and granular fertilizer. The timing of applying the composition of the present invention may be before sowing or transplanting rice, may be simultaneous with sowing or transplanting, or may be immediately after sowing or transplanting.
When applying simultaneously with sowing or transplanting, it may be applied using an attachment attached to the sowing machine or transplanting machine, or by other methods.
Further, in the case of full surface treatment, it may be a period until water injection after sowing or transplanting, an intermediate drying period, or an intermittent irrigation period. When using the composition of the present invention, the soil surface of the paddy field may be dry, or the soil surface may be moist but free of flooding (water depth 0 cm). When it is applied to the surface of a flooded paddy field, it can be applied at any time from sowing or transplanting to harvesting, as long as the water depth is maintained by normal rice management.

When the composition of the present invention is applied to paddy fields and used for direct sowing rice, or when the rice seed applied with the composition of the present invention is used for direct sowing cultivation, the rice seed is composed of iron powder and iron oxide. It may be surface-treated with a coating material such as powder, calcium peroxide, or molybdenum compound. These coating materials can be used alone or in combination at any ratio, and if necessary, additives such as calcined gypsum are added for the purpose of increasing the amount or improving fixation to rice seeds. be able to. Rice seed means rice seed in a state prior to sowing in a paddy field. Rice seeds to which the composition of the present invention has been applied can be cultivated by direct sowing in dry fields, wet fields, and paddy fields, or may be cultivated by sowing seedling boxes. The preparation of the composition of the present invention can be applied to rice seeds by applying it, but before sowing rice seeds are immersed in a solution containing the composition of the present invention, or after germination, a solution containing the composition of the present invention is sprayed. It may be processed. In any treatment method, a safener may be used in combination.
When this composition is applied to rice, sterilized seeds can be used to control seed infectious pests regardless of whether they are applied to seedlings, paddy fields, or seeds. Specifically, chemical pesticides such as prochloraz, triflumizole, pefurazoate, oxolinic acid, ipconazole, fludioxonil, kasugamycin monohydrochloride, cupric hydroxide, basic copper chloride, fenitrothion, cartap hydrochloride, or Trichoderma atrobilide, Seeds that have been soaked, smeared or powdered with agents containing microorganisms such as Talaromyces flavus, Pseudomonas CAB-02, and Bacillus simplex as active ingredients can be used.
When rice is sown or transplanted, or one or more selected from the group consisting of cartap hydrochloride and metaaldehyde is applied to the seeded or transplanted paddy field, it is effective for scallop apple, monoaraga, etc. Can be controlled. Moreover, weeds generated in paddy fields can be controlled by applying a herbicidal active compound. The time when the herbicidal active compound is applied is not particularly limited as long as phytotoxicity to rice by the herbicidal active compound does not cause a problem.

Examples of herbicidally active compounds that can be used in paddy fields include azisulfuron, bensulfuron-methyl, chlorimuron-ethyl, cyclosulfamuron, and ethoxysulfuron. , Flucetosulfuron, halosulfuron-methyl, imazosulfuron, orthosulfamuron, propylsulfuron, propylsulfuron, propylsulfuron Cinosulfuron, metsulfuron-methyl, methazosulfuron, bentiocarb, molinate, esprocarb, piribatecarb (Butachlor), pretilachlor, tenylchlor (theny1ch1or), simethrin, dimethamethrin, methyl-daimuron, propanil, propanil Mefenacet, flufenacet, chromeprop, naproanilide, brombutide, diimuron, enzybone, etizont ), Carfentrazone-ethyl, fenchlorazole-ethyl, isoxadifen-ethyl, fentrazamide, clomazone, maleic acid hydride Razide (maleic hydrazide), pyridate, oxadichromemephone, cinmethylin, benfuresate, oxadiazonp, oxadiargyl ), Caffentrol, ipfencarbazone, pyriminobac-methy1, bibisribac-sodium, pyrimisulfan, triaf Trifamone, pyribenzoxim, pyriftalid, indanophan, ACN, benzobicyclone, tefuryltrione, tefuryltrione, tefuryltrione, tefuryltrione, tefuryltrione dithiopyr, dalapon (da1apon), chlorthiamid (penorthulam), anilofos (anilofos), benzulide (butamifos), phenoxasulfon (fen) nzofenap), pyrazolynate, pyrazoxifene, imazametathabenz, imazametabenz-methyl, imazamoxamimoxam-methyl Imazapic-ammonium, imazapyr, imazaquin, imazethapyr, pendimethalin, fenoxapropethyl, fenopropprop P ethyl (fenoxaprop-P-ethyl), metamihop, pyraclonil, quinclorac, 2,4-D and its salt, MCP and its salt, MCPA and its salt, MCPB and its salt, Examples include piperophos, fluoxypyr, cyclopyrimorate, and the like.

Rice for which the composition of the present invention can be used refers to the cultivated species Oryza sativa, Oryza glaberrima, and hybrids thereof among the annual plants of the genus Oryza, which are any of Japonica, Java, and Indica. Moreover, any of sticky rice, sticky rice, sake rice, and feed rice may be used. Rice varieties are not particularly limited, and may be varieties produced by crossing or cultivars produced by genetic recombination techniques. When applied to varieties imparted with resistance to pests, it can be a particularly labor-saving control method. Examples of such resistant varieties include resistance genes Bph1, bph2, Bph3, bph4, bph5, bph6, bph7, bph8, Bph9, Bph10, bph11, bph12, bph13, Bph14, bph15, Bph16, Bph17, Bph18, bph19, bph20. , Bph21, Bph25, Bph26, Bph27, etc. Qsbph3d, Qsbph4, Qsbph8, Qsbph11, Qsbph11d, Qsbph11e, Qsbph11f, Qsbph 1g, Gypsum leafhopper resistant varieties incorporating Qbph12a, etc., Glh1, Glh2, Glh3, glh4, Glh5, Glh6, Glh7, Glh8, Glh9, glh10, Grh1, Grh2, Grh3, Grh3, Grh2, Grh3, Grh3 Leafhopper resistant varieties incorporating Pi, Pi1, Pi3, Pi5, Pi7, Pi9, Pi11, Pi12, Pi21, Pi36, Pi37, Pia, Pib, Pid, Pid-2, Pid-3, Pif, Pii, Pik , Pik-1, Pik-2, Pik-5, Pik-h, Pik-m, Pik-p, Pik-s, Pish, Pita, Pita-2, Pitq, Piz, Piz-5, Piz-t, Pib List varieties resistant to blast disease in which Pb1 etc. are incorporated It can be. Only one of these genes may be incorporated, or a plurality of these genes may be incorporated simultaneously. Moreover, the multiline which mixes and cultivates several varieties in which different resistance genes were integrated may be sufficient.

Combine the composition of the present invention with application to plants and / or places where plants are or will be grown or where pests and / or pests inhabit or are expected to live One or more herbicidal active compounds may be treated in paddy fields, crop fields, orchards or non-agricultural lands.
The composition of the present invention and the herbicidal active compound may be applied simultaneously or separately. When applying separately, you may apply on the same day or another day.
When treating a herbicidal active compound in paddy fields, crop fields, orchards or non-agricultural lands, the herbicidal active compound is usually mixed with a carrier such as a solid carrier or a liquid carrier, and if necessary, a preparation such as a surfactant. A supplement is added to form a preparation.
Examples of methods for treating herbicidal active compounds in paddy fields, crop fields, orchards, or non-agricultural lands include, for example, a method of spraying herbicidal active compounds on soil in paddy fields, crop fields, orchard fields and after weeding active compounds. The method of spraying on weeds.
The amount of the herbicidal active compound used in the step of treating the herbicidal active compound in paddy fields, crop fields, orchards or non-agricultural lands is usually 5 to 5000 g per 10000 m ² , preferably 10 to 1000 g per 10000 m ² , more preferably 20 to 500 g per 10,000 m ² . In the step of treating the paddy field, crop field, orchard or non-agricultural land with the herbicidal active compound, an adjuvant may be mixed to treat the herbicidal active compound. When two or more herbicidal active compounds are applied, they may be applied simultaneously or separately. When applying separately, you may apply on the same day or another day.
In the present invention, one or more types of safeners can be applied in combination with the herbicide. The method of applying the safener is not particularly limited, but can be applied together with the herbicide. In this case, a preparation containing the herbicide and safener may be used alone, or the herbicide may be used. You may use together the formulation containing and the formulation containing a safener. Alternatively, plant seeds or bulbs treated with a safener can be used. Plant seeds or bulbs may be used after being treated with one or more safeners, or seeds treated with a commercially available safener may be purchased and used.
When treating the herbicidal active compound before sowing or planting plant seeds, bulbs or seedlings, 50 days before sowing or planting to just before sowing or planting, preferably 30 days before sowing or planting to immediately before sowing or planting, more preferably The herbicidal active compound is treated from 20 days before sowing or planting to just before sowing or planting, more preferably from 10 days before sowing or planting to just before sowing or planting.
When the herbicidal active compound is treated after sowing or planting plant seeds, bulbs or seedlings, the herbicidal active compound is preferably treated immediately after sowing or planting to 50 days after sowing or planting, more preferably immediately after sowing to 3 days after sowing. The
The herbicidal active compound can also be treated simultaneously with sowing or planting of plant seeds, bulbs or seedlings.
As a specific treatment time in the case of treating the herbicidal active compound after sowing of soybean seeds, for example, the period from before germination to flowering of soybean can be mentioned. Among the period from before the emergence of soybean to the flowering period, the period is preferably from the period before emergence of soybean to the period of 6 double leaves, and more preferably from the period before emergence of soybean to the period of 3 complex leaves. In the case of treating the herbicidal active compound after sowing of the corn seed, the specific treatment time is from before emergence to the 12th leaf stage, preferably from before emergence to the 8th leaf stage, more preferably from 6 minutes before the emergence. Until the leaf stage. In addition, the leaf age of corn is determined by the leaf color method (Leaf Collar Method).
When the herbicidal active compound is treated before sowing of the cotton seed, the herbicidal active compound is treated 50 days before sowing to immediately before sowing, preferably 30 days before sowing, immediately before sowing, more preferably 20 days before sowing to immediately before sowing. The
When the herbicidal active compound is treated after sowing of the cotton seed, the herbicidal active compound is treated immediately after sowing to 70 days after sowing, preferably 30 days after sowing to 50 days after sowing. The specific treatment time when the herbicidal active compound is treated after sowing of the cotton seed includes, for example, the period before the cotton emergence to the flowering time. Preferably, the period from the start of tree planting to the base of cotton is 20 cm from the base.
When the herbicidal active compound is treated before sugarcane planting, it is 40 days before to just before sowing or planting, preferably 30 days to just before sowing or planting, more preferably the day of sowing or planting. The herbicidally active compound is treated 20 days before to immediately before.
When treating the herbicidal active compound after planting sugarcane, immediately after sowing or planting to 40 days after sowing or planting, preferably immediately after sowing or planting to 20 days after sowing or planting More preferably, the herbicidal active compound is treated immediately after sowing or planting to 10 days after the sowing or planting date.

Examples of the herbicidal active compounds, plant growth regulators and safeners include the following.
Herbicidal active compounds:
Clodinahop, clodinahop-propargyl, cihalohop, cyhalohop-butyl, diclohop, diclopop, dicyclopmethyl , Phenoxaprop-ethyl, phenoxaprop-P, phenoxaprop-P-ethyl, fluazifop, fluazifop-blu P (fluazifop-P), fluazifop Pbutyl (fluazifop-P-butyl), haloxyhop, haloxyhop-methyl, haloxyhop-P, haloxyhop-P-methyl, metamihop, metamihop Quizahopop (di), Quizalohop-diyl, Quizalofop-diyl, Quizalofop-dixy, Quizalofop-dixy, Quizalofop-dixy, Quizalofop-dixy, Quizalofop-dixy Crethodim, cycloxydim (cy loxydim), Puropokishijimu (profoxydim), sethoxydim (sethoxydim), tepraloxydim (tepraloxydim), tralkoxydim (tralkoxydim), pinoxaden (pinoxaden);
Amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, chlorimuron, chlorimuron, chlorsulfuron-ethylsulfuron Cinosulfuron, cyclosulfamuron, ethamethsulfuron, ethamethsulfuron-methyl, ethoxysulfururon, etoxysulfururon ), Flucesulfuron, flupirsulfuron, sodium flupylsulfuron-methyl-sodium, foramsulfuron, halosulfuron, halosulfuron , Imazosulfuron, iodosulfuron, iodosulfuron-methyl-sodium, iofensulfuron, iofensulfuron-sodium um), mesosulfuron, mesosulfuron-methyl, metazosulfuron, metsulfuron, metsulfuron, nicosulfuron, nicosulfuron, nicosulfuron, methulsulfuron, metsulfuron, metsulfuron, metsulfuron Oxasulfuron, primisulfuron, primisulfuron-methyl, propyrisulfuron, prosulfuron, pyrazosulfuron ron), pyrazosulfuron-ethyl, rimsulfuron, sulfometuron, sulfomethuron-methyl, sulfosulfuron, thifensulfuron Ruflonmethyl-thisulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, trifloxysulfuron-trisulfuron-trioxyuron xysulfuron, triflusulfuron, triflusulfuron-methyl, tritosulfuron, imazapic, imazapica salt, imazapicum salt Metabenzmethyl (imazamethabenz-methyl), imazamox (imazamox), imazapyramammonium (imazamimine) Zaquinammonium salt (imazaquin-ammonium), imazetapyr (imazethapyr) ammonium salt (imazethapyr-ammonium), chloranthram, chloranthrammyl, cloranslammethyl , Flumetsulam, flumetsulam, metosulam, penoxsuram, pyroxsulam, bipyribacium bis-pyribacium salt Pyribenzoxim, Pyriphthalide, Pyriminobac, Pyriminobac, Pyrithiobac, Pyrithiobac, Pyrithiobac, Pyrithiobac, Pyrithiobac, Pyrithiobac, Pyrithiobac, Pyrithiobac, Pyrithiobac, Pyrithiobac flucarbazone), flucarbazone sodium salt (flucarbzone-sodium), propoxycarbazone, propoxycarbazone sodium salt (propoxycarbazone-sodium), thienecarbazone (thiencarbazone) iencarbazone-methyl);
Ametrine, atrazine, cyanazine, desmethrin, dimethmetrine, dimethmethine, promethrin, promethine, romethine, promethine, romethine. Terbumeton, terbuthylazine, terbutryne, trietazine, hexazinone, metamitron, metriamizin, methribizone ), Bromacil (Bromacil), lenacil (Lenacil), terbacil (Terbacil), chloridazon (Chloridazon), desmedipham (Desmedipham), phen media Pham (phenmedipham);
Chlorbromuron, chlorotoluuron, chloroxuron, dimeflon, diuron, ethidiuron, fenuron, fluometuron, fluometuron ), Linuron, benzthiazuron, metabenzthiazuron, methobromuron, methoxuron, monolinuron, nebulon on), siduron (siduron), tebuthiuron (tebuthiuron), propanil (propanil), pentanoate crawl (pentanochlor);
Bromophenoxime, Bromoxynil, Bromoxynyl-octanoate, Ioxynil, Ioxynyl-octanoate, Bentazone, Bentazone, Bentazone (Cyclopyromorate), pyridate, pyridafol;
Diquat, diquat-dibromide, paraquat, paraquat-dichloride; acifluorfen, acifluorfen, bisulfen sodium salt Chlomethoxyphen, ethoxyphen-ethyl, fluoroglycofen-ethyl, fomesafen, fomesafen-sodium, fhalofen, halafene offenoxy), oxyfluorfen, fluazolate, fluazolate, pyraflufen-ethyl, cinidon-ethyl, flumicrolac-pentyl, flumioxazin (flumioxazine) (Fluthiacet-methyl), thidazimine, oxadiazon, oxadiaargyl, azaphenidin, bencarbazone, carfentrazone-z, carfentrazone-z sulfentrazone, pentoxazone, benzfendizone, butafenacil, saflufenacil, thiafenolil, pyracloluolful ethyl);
Norflurazon, diflufenican, picocorinafen, beflubutamide, fluridone, flurochloridone, flurutamon (flurtamon)
Fenquinotrione, mesotrione, sulcotrione, tefuryltrione, tembotrione, isoxachlortole, isoxachlortole, xoxachlortole benzofenap, pyrasulfotole, pyrazolynate, pyrazoxifene, topramzone, benzobicyclon, bicyclopyrone; bicyclopyrone;
Amitrole, aclonifen;
Clomazone;
Glyphosate, sulfosate;
Glufosinate, glufosinate-ammonium, glufosinate-P, glufosinate-P sodium salt, bialaphosbialaphos;
Asuram;
Benfluralin, butruralin, dinitramine, ethalfluralin, oryzalin, pendimethalin, trifluralin, phosphine (Butamifos), dithiopyr, thiazopyr, prodiamine, propyzamide, tebutam, DCPA (chulthal dimethyl);
Chlorprofam, propham, carbetamide, flamprop-m;
Acetochlor, alachlor, butachlor, dimethachlor, dimethylenamide, dimethylenamide P (dimethenamide-P), metazachlor methametrochlor Chlor (S-metholachlor), petoxamide, pretilachlor, propachlor, propisochlor, tenylchlor, diphenamide, diphenamide Napropamide-M, naproanilide, flufenacet, mefenacet, fentrazamide, lofencantole, fencarazone, rofenc (Piperophos), pyroxasulfone;
Diclobenil, chlorthiamid, isoxaben, flupoxam, indaziflam, triaziflam;
DNOC, dinoseb, dinoterb;
Butyrate, cycloate, di-allate, dimethylpiperate, EPTC, esprocarb, molinate, olvencarb, bulb, probulu, probul (Bentiocarb), thiocarbazil, tri-allate, vernarate, bensulide, benfurate, etofumesate, Tal, dalapon fl propanate);
Chromeprop, 2,4-D and salts or esters thereof (butyl ester, dimethylammonium salt, diolamine salt, ethylhexyl ester, isoctyl ester, isopropylammonium salt, sodium salt, triisopropanolamine salt, choline salt) 2,4-DB and salts or esters thereof (dimethylammonium salt, isooctyl ester, choline salt), dichloroprop and salts or esters thereof (butyl ester, dimethylammonium salt, 2-ethylhexyl ester, Chill ester, methyl ester, potassium salt, sodium salt, choline salt), dichloroprop-P (dichloroprop-P), dichloroprop-P dimethylammonium salt (dichro) prop-P-dimethylammonium), MCPA and salts or esters thereof (dimethylammonium salt, 2-ethylhexyl ester, isooctyl ester, sodium salt, choline salt), MCPB, mecoprop and salts or esters thereof (dimethylammonium salt, Diolamine salt, etazyl ester, 2-ethylhexyl ester, isooctyl ester, methyl ester, potassium salt, sodium salt, trollamine salt, choline salt), mecoprop P (mecoprop-P) and its salt or ester (dimethylammonium salt) 2-ethylhexyl ester, isobutyl salt, potassium salt, choline salt), chloramben, dicamba and its salts (diglycol) Amine salt, dimethylammonium salt, isopropylammonium salt, potassium salt, sodium salt, choline salt), TBA, aminopyralide and its salt (potassium salt, triisopananol ammonium salt, choline salt), clopyralid and its salt Salt (oramine salt, potassium salt, triethylammonium salt, choline salt), fluroxypyr (fluroxypyr-meptyl), picloram and its salt (potassium salt, triisopanol ammonium salt, choline) Salt), triclopyr and its salt or ester (butyl ester, triethylammonium salt), quinchlora c), quinmerac, benazolin-ethyl;
Naptalam, diflufenzopyr-sodium salt;
Difenzoquat, DSMA, MSMA, bromobutide, flulenol, cinmethylylin, cumyluron, dazomet, daimudron, daimudron ), Fosamine, indanophan, metam, oxadichromemefone, oleic acid, pelargonic acid, pyributicarbozoline; in), phenisopham, swep, aminocyclopyrachlor, aminocyclopyrchlormethyl (amino), dicyclophenol, diaminochlorpyroxyl, trichlorophenol, and aminocyclopyrachlor diphenyl. triphenphane, maleic hydrazide, triafamon, ACN, phenoxasulfone, haluxifen
Plant growth regulators: hymexazole, paclobutrazol, uniconazole, uniconazole-P, inabenfide, prohexadione-cium Propene (1-methylcyclopropene), trinexapac and gibberellins.

Safeners: Benoxacor, cloquintoset, cloquintocet-mexyl, cyometrinil, cyprosulfamide (dipromide), dichlormid (di) Dietholate, fenchlorazole, fenchlorazole-ethyl, fenchlorim, flurazole, fluxofenim, flilazole xadifen), isoxadifen-ethyl (isoxadifen-ethyl), mefenpyr (mefenpyr), mefenpyr-diethyl (mefenpyr-diethyl), Mefeneto (mephenate), naphthalate Rick polyanhydride (naphthalic anhydride) and oxabetrinil (oxabetrinil).

Herbicidal active compounds are in particular flumioxazin, sulfentrazone, saflufenacyl, oxyfluorfen, fomesafen, fomesafen sodium, glufosinate ammonium salt, chlorimuron ethyl, chloransrammethyl, pyroxasulfone, imazetapyram ammonium salt, Metribuzin, 2,4-D, 2,4-D butyl ester, 2,4-D dimethylammonium salt, 2,4-D diolamine salt, 2,4-D ethylhexyl ester, 2,4-D isooctyl Ester, 2,4-D isopropylammonium salt, 2,4-D sodium salt, 2,4-D triisopropanolamine salt, 2,4-D choline salt, dicamba, dicambadiglycolamine salt, dicamba dimethylammonium salt Dicamba isopropyl ammonium salt Dicamba potassium, dicamba sodium salt, Jikanbakorin salts, mesotrione, tembotrione, isoxaflutole and ametryn are preferred.

Examples of weeds that can be controlled include the following.
Nettle weeds: Ultica urens
Polygonaceae weeds: wild buckwheat (Polygonum convolvulus), Sanaetade (Polygonum lapathifolium), the United States smartweed (Polygonum pensylvanicum), Harutade (Polygonum persicaria), knotweed (Polygonum longisetum), Polygonum aviculare (Polygonum aviculare), Haimichiyanagi (Polygonum arenastrum), Japanese knotweed ( Polygonum cuspidatum), Rumex japonicus, Rumex crispus, Rumex obtusifolius, Rumex acetosa
Physalis Weed: Physalis (Portulaca oleracea)
Weeping weeds: Stellaria media, Cerastium holosteoides, Cerastium glomeratum, Spergula arvensis, Silene gallic
Pomegranate family weed: Muluga verticillata
Rubiaceae weeds: Shiroza (Chenopodium album), Carypodium ambrosioides, Kochia scoparaia, Salola kali, Atriple genus (Aspirex)
Amaranthus retroflexus, Amaranthus viridis, Amaranthus vidus, Amaranthus sp., Amaranthus, Amaranthus, Amaranthus, Amaranthus rudis, Amaranthus paturus, Amaranthus tuberculatos, Amaranthus blitoides, Amaranthus deflexus, Amaranthus marthus quitensis), Nagarantera philoxeroides, tsurugateoto (Alternanthera sessilis), sanguinaria (Alternanthera tenella)
Poppy weeds: Papaver rhoea, Argemone mexicana
Brassicaceae weeds: radish (Raphanus raphanistrum), radish (Raphanus sativus), field moth (Sinapis arvensis), napuna (Capsella bursa-pasasis), Brassica rasacea ), Roppa islandica, Rippa sylvestris, Thlaspi arvense, Myagrum rubosum, Lumpa Kusanazuna (Coronopus didymus)
Cleome Affinis (Cleome affinis)
Leguminous weeds: Aeschynomene indica, zigzag joint vetch (Aeschyomene rudis), American horned um (Sesbania exaltata), Ebisu (Cesia obtusifolia), tuna White clover (Trifolium repens), Kudu (Pueraria lobata), Caladium pea (Vicia angustifolia), Raccoon dog (Indigofera hirsuta), Indigofera tolxylene (Indigofera tolxylene) nsis), wild cowpea (Vigna sinensis)
Oxalis family: Oxalis cornicula, Oxalis tricica, Oxalis oxyptera
Auricularia Weeds: American Fluor (Geranium carolinense), Dutch Fluor (Erodium ciculatum)
Euphorbiaceae weeds: spurge (Euphorbia helioscopia), Euphorbia nutans (Euphorbia maculata), Konishikisou (Euphorbia humistrata), Hagikusou (Euphorbia esula), Shaw Zhou Saw (Euphorbia heterophylla), hyssop leaf sand mat (Euphorbia brasiliensis), Enokigusa (Acalypha australis ), Tropic croton (Croton glandulosus), crodo lobato (Croton lobatos), Brazilian citrus (Phyllanthus corcovadensis), licorice (Ricinus communis)
Mallow Weeds: Abtilon theophrasti, Sida rhombiforia, Sida cordifolia, Sida spinosa, Sida gladien (Hibiscus triumum), Nishida mallow (Anoda cristata), Enoki mallow (Malvastrum coromandelianum)
Aegiriaceae weeds: Walteria indica
Violet weeds: Viola arvensis, Wild pansy (Viola tricolor)
Cucurbitaceae weeds: Allium cucumber (Sicios angulatus), Wild cucumber (Echinocystis lobata), Wild bitter gourd (Momodica charantia)
Weeping weeds: Lythum salicaria
Cetaceae weeds: Hydrocotyl sibthopioides
Mudaceae weeds: Cardiosperm halicacabum
Primrose weed: Anagallis arvensis
Species weeds: Asclepias syria, Honeyvine milkweed (Ampelamus albidus)
Rubiaceae weeds: Cullweed bed straw (Galium aparine), Galium spurium var.
Convolvulaceae weeds: morning glory (Ipomoea nil), American morning glory (Ipomoea hederacea), Ipomoea purpurea (Ipomoea purpurea), tall American morning glory (. Ipomoea hederacea var integriuscula), beans morning glory (Ipomoea lacunosa), Hoshiasagao (Ipomoea triloba), Noasagao ( Ipomoea acuminata), Ipomoea hedefifolia, Ibarumou (Ipomoea coccinea), Ipomoea quamoclit, Ipomoea aporia Grandifolia a aristolochiafolia), Maple bus morning glory (Ipomoea cairica), field bindweed (Convolvulus arvensis), Kohirugao (Calystegia hederacea), morning glory (Calystegia japonica), Tsutanohahirugao (Merremia hedeacea), hairy Wood Rose (Merremia aegyptia), roadside Wood Rose (Merremia cissoides), Okinawa morning glory (Jacquemontia tamnifolia)
Purple weeds: Forget-me-nots (Myosotis arvensis)
Labiatae weeds: Lamium purpureum (Lamium purpureum), henbit (Lamium amplexicaule), Tamazakimehajiki (Leonotis nepetaefolia), Nioinigakusa (Hyptis suaveolens), Hiputisu Rofanta (Hyptis lophanta), Mehajiki (Leonurus sibiricus), Yabuchorogi (Stachys arvensis)
Solanum weeds: Datura stramonium, Solanum nigrum, Solanum americanum, Solanum pylori (Solanum ptycanthum), Solanum ptycanum Solanum aculeatissimum), wild tomato (Solanum sisymbriifolium), walnut bean (Solanum carolinense), Physalis angulata, Physalis sublabra sen, smooth ground cherry (Physalis sublabra sen) Li (Nicandra physaloides)
Weeping weeds: Verasica hederaefolia, Veronica persica, Veronica arvensis
Plantain family: Plantago asiatica
Asteraceae weeds: cocklebur (Xanthium pensylvanicum), Ooonamomi (Xanthium occidentale), wild sunflower (Helianthus annuus), chamomile (Matricaria chamomilla), Inukamitsure (Matricaria perforata), corn marigold (Chrysanthemum segetum), Oroshagiku (Matricaria matricarioides), mugwort (Artemisia Princes), Artemisia vulgaris, Chinese mugwort (Artemisia verlotorum), Solidago altissima Po (Taraxacum officinale), galinsoga quadriradiata (Galinsoga ciliata), Kogomegiku (Galinsoga parviflora), Senecio vulgaris (Senecio vulgaris), senecioic brasiliensis emissions cis (Senecio brasiliensis), senecioic Gurisebachi (Senecio grisebachii), Erigeron bonariensis (Conyza bonariensis), Erigeron canadensis (Conyza canadensis ), Ragweed (Ambrosia artemisiae folia), Mulberry (Ambrosia trifida), Bendens piosa, Bidens frontosa, Bidens Subartena (Bidens subalterns), Atlantic thistle (Cirsium arvense), American thistle (Cirsium vulgare), Maria thistle (Sylum marianol), L ), Beach Creeping Oxeye (Wedelia glauca), Perforate Blackfoot (Melampoidium perforiatum), Emilia sonchifolia, Tagetes minuta, Paracriles (Blainville) olia), Kotobukigiku (Tridax procumbens), Yerba Porosa (Porophyllum ruderale), Paraguay star bar (Acanthospermum australe), yellowtail stream Star Bar (Acanthospermum hispidum), Fuusengazura (Cardiospermum halicacabum), cuckoo thistle (Ageratum conyzoides), common bone set ( Eupatium perfoliatum, Eclipta alba, Dandoborogiku (Erchtites hieracifolia), American Everlasting (Gamochaeta spicata), Vortico coxusa (Gna) phalaium spicatum, jageria hirta, sesame (Phenthium hysterophorus), mena fir (Siegesbekkia orientalis), seribean sessilis
Liliaceae weeds: Allium canadense, Wild garlic (Allium vineale)
Weeping weeds: Commelina communis, Camelina bengharensis, Electday flower (Commelina erecta)
Gramineae weeds: Echinochloa crus-galli, Enocologia (Setaria viridis), Aquinoaria diaragula (Setaria fagali), Seneia digrass (Setaria gula) , Jamaican crabgrass (Digitalia horizontalis), Japanese tiger beetle (Digitaria insularis), Hoshishiba (Eleusine indica), Sparrow anemone (Poa annua), Amarine sparrow (Alospecrucus) (Alopecurus myosuroides), oat (Avena fatu), sorghum sorghum (Sorghum halum), shatter cane (Sorghum vumreum), shigum-gi (um) Brown scallinus, Bromus tectorum, Hordeum jubatum, Aegilops cylindrialis, Phararis arundinacea, Mecha r), Silka bentgrass (Apera spica-venti), Prickly pear (Panicum dichomifurorum), Panicum texarum (Panecum maxium), Panicum ichrai (grass) plantainea, Surinamegrass (Brachiaria decumbens), Palisade grass (Brachiaria brizantha), Coloniviagrass (Brachiaria humidicola), Centricius echinatus Cenchrus pauciflorus), Narukobie (Eriochloa villosa), Penisetamu (Pennisetum setosum), Africa beard grass (Chloris gayana), Ooniwahokori (Eragrostis pilosa), Rubigaya (Rhynchelitrum repens), dactyloctenium aegyptium (Dactyloctenium aegyptium), Taiwan Ai reeds (Ischaemum rugosum), wild Rice (Oryza sativa), American spider (Paspalum notatum), Coastal sand paspalm (Paspalum maritimum), Pyrene grass (Penisetum clandestinum), Penicillium pear (Pen nisetum setosum), rotswellia cochinchinensis
Cyperus weeds: Cyperus microria, Cyperus iria, Cyperus odorundus, Cyperus, Cyperus, Cyperus, Cyperus
Cloveraceae weeds: Equisetum arvense, Equisetum palustre, and the like.

By applying the composition of the present invention, depending on the plant species or plant varieties, their growth location and growth conditions (soil, climate, growth season, nutrient), improvement of plant seedling establishment rate, improvement of growth, high temperature or low temperature Improved tolerance or tolerance, drought, over-humidity, increased tolerance to salt in water or soil, improved flowering ability, improved harvestability, accelerated maturation, increased yield, seed or fruit Number, size or weight increase, plant height increase, plant weight increase, leaf green color improvement, healthy leaf number increase, leaf area increase, faster flowering, flowering number or fruit number Increased fruit set rate, improved quality of harvested product and / or increased nutritional value, increased sugar content in fruit, increased gluten strength, improved storage stability of harvested product and / or In some cases, workability can be improved.

Examples of the bactericides included in Group A include the following.
(1) DMI fungicide (demethylation inhibitor)
Azaconazole, bittertanol, bromuconazole, cyproconazole, difenoconazole, dinicoconazole, dinicoconazole, dinicoconazole. (Etaconazole), fenarimol, fenbuconazole, fluquinconazole, flusilazole, flutriazole, hexaconazole (hexaazole) onazole, imazalil, imibenconazole, ipconazole, metconazole, microbutanol, nupomolazole, nupomolazole (Oxpoconazole fumarate), pefrazoate (pefurazolate), penconazole, prochloraz, propiconazole, prothioconazole pilozopyrazole pyrisoxazole, simeconazole, tebuconazole, tetraconazole, triadifoline, triadimol, triflumenol etc;

(2) Amine-based fungicides aldimorph, dodemorph, fenpropidin, fenpropimorph, piperalin, spiroxamine, tridemorph (tri);

(3) Benzimidazole fungicides benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate, thiophanate-methyl, etc .;

(4) Dicarboximide fungicides, clozolinate, iprodione, procymidone, vinclozolin, etc .;

(5) Anilinopyrimidine fungicides cyprodinil, mepanipyrim, pyrimethanil and the like;
(6) Phenylpyrrole fungicide fenpiclonil, fludioxonil and the like;

(7) QoI inhibitors azoxystrobin, cumoxystrobin, dimoxystrobin, enoxastrobin, famoxadone, fenamidone, fenamidone Robin (fenaminestrobin), flufenoxystrobin, fluoxastrobin, cresoxime-methyl, mandestrobin, methinostrobin, metminostrobin Coxystrobin, pyraclostrobin, pyramethostrobin, pyraoxystrobin, pyribencarb, triclopyrtroprinb, triclopyrtrobine -Methyl-2- [2- (2,5-dimethylphenoxy) methyl] phenyl-2-methoxyacetamide (including racemic or enantiomers, mixtures of R and S enantiomers in any proportions) etc;

(8) PA fungicide (phenylamide fungicide)
Benalaxyl, Benalaxyl M or Kiraxyl (furalaxyl), Metalaxyl, Metalaxyl M, Mexoroxyl,

(9) Carboxylic acid amide-based fungicides dimethomorph, flumorph, pyrimorph, benthalicarb, benthibacarb-isopropyl, iprovalib mandipropamid), varifenate, etc .;

(10) SDHI fungicides benodanil, benzovindiflupyr, bixafen, boscalid, carboxin, fenfuram, fluolil, fluopiram Fluxapyroxad, furametopyr, isofetamid, isopyrazam, mepronil, oxycarboxin, pentipyr ne), thifluzamide (thifluzamide), compounds represented by the following formula (a);

(11) Dithiocarbamate fungicides ferbam, mancozeb or manzeb or manzeb, maneb, methylram, propineb, thiram, dineb, zinem )etc;

(12) MBI-R agent phthalide or fthalide, pyroquilone, tricyclazole, etc .;

(13) MBI-D agent carpropamide, diclocymet, phenoxanil and the like;

(14) Microbial materials Agrobacterium radiobactor, strain 84, etc., Bacillus amyloliquefaciens, Bacillus pumilus GF, Baculus pumulus C Strain), Bacillus subtilis synonyms for Bacillus amyloliquefaciens, QST713 strain, FZB24 strain, MBI600 strain, D747 strain, HAI0404 strain, Y1336 strain, varioborx 4526 strain, etc.), Erwinia carotovora (Erwinia carotovora, CGE234M403 strain, etc.), Pseudomonas fluorescens (G7090 strain, etc.), Talaromyces flavus (Talaromyces flavus) Atrobilide (Trichoderma atroviride, SKT-1 strain, etc.) etc .;

(15) Other fungicides acibenzolar-S-methyl, amethoctrazine, amisulbrom, anilazine, biphenyl, blastcidin-S (blasticidin-S) bupirimate, captafol, captan, quinomethionate (chinomethionat or quinomethionate), chloroneb, chlorothalonil, cyamifamide, cyamidofylcylamide oxanil, dichlorfluanid, diclomezine, dichloran, diethofencarb, diflumetorim, dimethimol, dimethimolin, dimethimolin, dimethimolin Echromezole or etridiazole, edifenphos, ethaboxam, ethirimol, fenhexamide, fenpyrazamine acetic acid (fenpyrazamine) Fentin acetate, triphenyltin chloride, triphenyltin hydroxide, ferrimzone, fluazinam, flupicolide, fluorsulfide, fluorsulfide , Flutianil, folpet, fosetyl, guazatine, hymexazole, iminoctaline, iminoctadate triacetate, iminoctadate triacetate Probenfos (iprobenfos), isoprothiolane (isoprothiolane), isothianil (isotianil), kasugamycin (laminarin), meptyldinocap (methulofoncone), metasulfocarb (methathulofoncone) Oxathiapiproline, oxolinic acid, oxytetracycline, pencyclone, polyoxins, probenazole, probenazole Kalb (propamocarb), proquinazid (proquinazid), prothiocarb (prothiocarb), pyrazophos (pyrazophos), pyributicarb (pyributicarb), Piriofenon (pyriofenone), quinoxyfen (quinoxyfen), quintozene (quintozene), streptomycin (streptomycin), Tebufurokin (tebufloquin), Teclophthalam, technazene, thiadinyl, tolclofos-methyl, tolfenpyrad, tolylfluanid, tolpro Lube (tolprocarb), triazoxide (triazoxide), validamycin A (validamycin A), zoxamide (zoxamide),
Basic copper chloride, cupric hydroxide, basic copper sulfate, organic copper, sulfur,
3-chloro-5-phenyl-6-methyl-4- (2,6-difluorophenyl) pyridazine, 3-cyano-5-phenyl-6-methyl-4- (2,6-difluorophenyl) pyridazine, N- (1,1,3-trimethylindan-4-yl) -1-methyl-3-difluoromethylpyrazole-4-carboxylic acid amide (racemic or enantiomer, R-enantiomer and S-enantiomer at any ratio) (Hereinafter, R-form N- (1,1,3-trimethylindan-4-yl) -1-methyl-3-difluoromethylpyrazole-4-carboxylic acid amide is α1, S-form) N- (1,1,3-trimethylindan-4-yl) -1-methyl-3-difluoromethylpyrazole-4-carboxylic acid amide is referred to as compound α2.)
A compound represented by the following formula (b);

A compound represented by the following formula (c);

A compound represented by the following formula (d);

Examples of insecticides, acaricides and nematocides included in Group B include the following.
(1) Organophosphorus compounds Acephate, Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Kazusafos, Chlorethophos, Chlorethofenphos (Chlormephos), chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos (CYAP), demeton-S-methyl, diadione, diazinon (Dichlorvos: DDVP), dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprosm, phanfol , Fenitrothion (MEP), fenthion (MPP), heptenophos, isofenphos, isopropyl = O- (methoxyaminothiophosphoryl) salicylate or isocarboyl-O- (methoxymin) hosphoryl) salicylate or isocarbophos), isoxathion (isoxathion), malathion (malathion), methambam (methamifophos), methidathion (meth) toho (meth), mevinthion (meth) ), Ometoate, oxydemethon-methyl, parathion, parathion methyl or methyl parathion, phentoate PAP), folate, phosalone, phosmet (PMP), phosphamidone, phoxim, pirimiphos-methyl, profenofos, propetosfo ), Pyraclofos, pyridafenthion, quinalphos, sulfotep, tebupyrimfos, temephos, tebufos, terbufos, tebuphos inphos), thiometon (thiometon), triazophos (triazophos), trichlorfon (trichlorfon: DEP), vamidothion (vamidothion) and the like;

(2) Carbamate compounds alaniccarb, aldicarb, bendiocarb, benfuracarb, butocarboxyl, butoxycarbyl, butoxycarbyl, butoxycarbyl, butoxycarboxyl, (Carbofuran), carbosulfan, etiofencarb, fenobucarb (BPMC), formatenate, furothiocarb (isoprocarb), isoprocarb (isoprocarb) rb), methomyl, methocarb, oxamyl, pirimicarb, propoxur (PHC), thiodicarb, thiophanate, thiophanate ), XMC, xylylcarb and the like;

(3) Synthetic pyrethroid compounds acrinathrin, allethrin, bifenthrin, bioallethrin, bioresmethrin, cycloprotolin, fluprothrin -cyfluthrin), cyhalothrin, gamma-cyhalothrin, lambda-cyhalothrin, cypermethrin, alpha-cypermethrin, alpha-methyperthrin ta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empentrin (empentin) etofenprox, fenpropatrin, fenvalerate, flucitrinate, flumethrinate, flumethrin, fluvalinate, tau-fluvalinate, tau-flufenate Halfenprox, heptafluthrin, imiprothrin, kadesthrin, meperfluthrin, monthrothrin, mothofrin (Pyrethrins), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethylfluthrin, tralomethrin (tralomethrin) ethrin), Transfluthrin (transfluthrin) and the like;

(4) Nereistoxin compounds Bensultap, cartap, cartap hydrochloride, thiocyclam, thiosultap-2 sodium salt or thiosultap-disodium salt bis Salt or monosultap or monosultap, etc .;

(5) Neonicotinoid compounds Acetamiprid, clothianidin, dinotefuran, flupyradifurone, thiapyrid (im) cloprid (imi) thiamethoxam) etc .;

(6) Benzoylurea compounds bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexflufluron, hexflufluron (Lufenuron), novaluron, noviflumuron, teflubenzuron, triflumuron, etc .;

(7) Phenylpyrazole compounds Ethiprole, fipronil, flufiprole, etc .;

(8) Hydrazine compounds Chromafenozide, halofenozide, methoxyphenozide, tebufenozide and the like;

(9) Organochlorine compounds Chlordane, endosulfan, alpha-endosulfan and the like;

(10) Diamide-based compounds chlorantraniprole, cyantraniprole, cyclaniliprole, fulbendamide, tetraniliprole, etc.

(11) Natural insecticide machine oil, nicotine-sulfate, rotenone, etc .;

(12) Microbial material Bacillus thuringiensis, var. Aizawai, var. Kurstaki, var. Israrensis, var. ) Derived live spores, produced crystal toxins, and mixtures thereof, Bacillus sphaericus, Beauveria bassiana, GHA strains, etc. , Pekir Myces Relaci Eggplant (Paecilomyces lilacinus), Pecilomyces tenuipes, Trichoderma harzianum, Verticillium lecani, etc .;

(13) Nematicidal active compounds dazomet, fluensulfone, fothiazate, imiciafos, metham, potashsite antifate, tartardite fate Arthrobotrys dactyroides, Bacillus films (Bacilus farmus, I-1582 strain (hereinafter abbreviated as Bf bacterium), etc.), Bacillus megaterium, Hiltella rosirisells Hillstera Mi Nesotensis (Hirsutella minnesotensis), Monacrosporium phymatopagus (Monosporus phymatopagus), Pasteuria nishizawae (hereinafter abbreviated as Pn bacteria) Lithium Chlamydosporium, Harpin protein and the like;

(14) Other acaricidal active compounds acequinocyl, amitraz, benzoximate, bifenazate, bromopropylate, chinomethenotine, chinomethenozine (Cynopyrafen), cyflumethofen, cyhexatin or tricyclohexyltin hydrochloride, dicofol, etoxazole, phenazafen (tin) de), fenpyroximate, fluacrylpyrim, fluazuron, fluphenoxystrobin, phenthiazopy, fluthiazox pyrimidfen, pyriminostrobin, spirodiclofen, spiromesifen, tebufenpyrad, tetradiphon, etc .;

(15) Other insecticides abamectin, emamectin benzoate, lepimectin, milbemectin, spinetoram, spinosad, aphido, aphido (Aluminum phosphide), calcium phosphide, hydrogen phosphine, zinc phosphide, azadirachtin, buprofezin, chlorfenapir picrin, cyromazine, diafenthiuron, DNOC, phenoxycarb, flometoquin, flonicamid, hydramethylhydrone indoxacarb, quinoprene, metaflumizone, methoprene, methoxychlor, methylbromide, methoxadiazine, metoxadiazine yrazophos, pyridalyl, pyrifluquinazone, pyriproxyfen, sodium fluoride, sulfidyl, sulfidyl fluoride, sulfidyl fluoride, sulfidyl fluoride. ), Tolfenpyrad, triflumezopyrim and the like.

Examples of the safeners included in Group C include the following.
Benoxacol, cloquintoset, cloquintocet-mexyl, thiomethrinil, cyprosulfonide, dichlormidol, dichlormidol , Fenchlorazole, fenchlorazole-ethyl, fenchlorim, flurazole, fluxofenim, furilazole, isoxadifen ), Isoxadifen-ethyl (isoxadifen-ethyl), mefenpyr (Mefenpyr), mefenpyr-diethyl (mefenpyr-diethyl), Mefenato (Mephenate), naphthalate Rick polyanhydride (naphthalic anhydride), oxabetrinil (Oxabetrinil) or the like.

Examples of plant growth regulators included in Group D include the following.
Chlormequat-chloride, etephon, gibberellins, gibberellin A3 (gibberellin A3, etc.), hymexazole, i-de-de-methyl-p methylcyclopropylene, paclobutrazol, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, trinexapacol conazole), uniconazole P (uniconazole-P), 4-oxo-4- (2-phenylethyl) aminobutyric acid (4-oxo-4- (2-phenylethyl) aminobutyric acid), 5- (trifluoromethyl) benzo [ b] Methyl thiophene-2-carboxylate and the like.

The composition of the present invention may further contain a compound such as anthraquinone used as a bird repellent.

Each of the above-mentioned compounds included in the above-mentioned group A to group D is a known compound, and is described in, for example, “THE PESTICIDE MANUAL—15th EDITION (published by BCPC) ISBN 978-1-901396-18-8”. Has been. These compounds can be produced by a production method described in a patent document or non-patent document cited in “THE PESTICIDE MANUAL”, or a related document, or can be obtained from a commercially available formulation.

The number of one or more compounds selected from Group A to Group D can be 1 to 6 (eg, 1, 2, 3, 4, 5, 6).

The pest control method of the present invention (hereinafter referred to as the present invention control method) applies an effective amount of the present compound and one or more compounds selected from Group A to Group D to the plant or the soil where the plant is grown. Can be mentioned. Examples of such plants include plant foliage, plant seeds, plant bulbs and plant seedlings.

In the control method of the present invention, the present compound and one or more compounds selected from group A to group D may be applied separately to the plant or soil where the plant is cultivated at the same time. From the viewpoint, it is applied as the composition of the present invention.

In the control method of the present invention, the mixing ratio (weight ratio) between the present compound and one or more compounds selected from Group A to Group D is the type of plant to be protected, the type and occurrence of pests to be controlled. It varies depending on the frequency, formulation, application time, application method, application location, weather conditions and the like.
When applied to the foliage or seeds of plants, or when applied to the soil where plants are grown,
For the compounds included in Group A, regardless of the presence or absence of other components, (this compound or a salt of this compound) / (one or more compounds selected from Group A) = 1/100 to 10,000 / 1,
For the compounds included in Group B, regardless of the presence or absence of other components, (this compound or a salt of this compound) / (one or more compounds selected from Group B) = 1/100 to 100/1,
For the compounds included in Group C, regardless of the presence or absence of other components (this compound or a salt of this compound) / (one or more compounds selected from Group C) = 1/100 to 100/1,
For the compounds included in Group D, regardless of the presence or absence of other components (this compound or a salt of this compound) / (one or more compounds selected from Group D) = 1/100 to 100/1,
For the compounds included in Group E, (this compound or salt of this compound) / (one or more compounds selected from Group E) = 1/100 to 10,000 / 1, regardless of the presence or absence of other components is there.

Hereinafter, the present invention will be described in more detail with formulation examples and test examples, but the present invention is not limited to the following examples. In the following examples, parts represent parts by weight unless otherwise specified.

First, formulation examples are shown.

Specific compositions of the composition of the present invention are described below.
The compositions having the combinations described in [Table 4a] to [Table 4f] are represented by the numbers described in [Table 4a] to [Table 4f]. For example, the composition of No. 1 in [Table 4a] is referred to as the present composition 1.
In [Table 4a] to [Table 4f], * described in the column of component 1 represents any one of the present compounds 1 to 1095, and the numbers described in [] in the column of each component are It means the weight part of each component in the present composition.
The present composition 1 represents the present composition 1-1 to the present composition 1-1095 in which any one of the present compound 1 to the present compound 1095 is 2 parts by weight.

[Table 4a]

[Continuation of Table 4a]

This composition 5, 10, 14, 17, 20, 22, 24 and 26 of [Table 4a] except that a mixture of α1 2.5 parts and α2 0.05 parts was used instead of 2.5 parts α1. Each composition having the same composition as (hereinafter referred to as the present compositions aa1 to aa8).

This composition 1, 7, 8, 9, 10, 11, 18, 19, 20, 21, 22, 25, and [Table 4a] except that 0.75 part of spinosad was used instead of 0.5 part of spinetoram and Each composition having the same composition as that of No. 26 (hereinafter referred to as the present compositions ab1 to ab13).

The present compositions 2, 7, 12, 13, 14, 15, 18, 19, 20, 23, 24, 25 and 26 in [Table 4a] except that 3 parts of pymetrozine was used instead of 1.5 parts of clothianidin Each composition having the same composition (hereinafter referred to as the present compositions ac1 to ac13).

This composition 5, 10, 14, 17, 20, 22, 24 and 26 of [Table 4a] except that a mixture of α1 2.5 parts and α2 0.05 parts was used instead of 2.5 parts α1. Each composition having the same composition as the above (hereinafter referred to as the present compositions ad1 to ad8).

The composition is the same as the present compositions 2, 7, 12, 13, 15, 18, 19, 23 and 26 in [Table 4a] except that 0.75 part of triflumezopyrine was used instead of 1.5 parts of clothianidin. Each composition (hereinafter referred to as the present compositions af1 to af9).

These compositions 1 to 26, aa1 to aa8, ab1 to ab13, ac1 to ac13, ad1 to ad8, af1 to af9, and these compositions except that * 2 parts are changed to * 0.5 parts Any one combination of the respective compositions having the same composition as is referred to as the present composition a.

[Table 4b]

Each composition having the same composition as the present compositions 27, 30, 31, 34, 35 and 37 in [Table 4b] except that 3 parts of fenitrothion was used instead of 0.5 parts of clothianidin (hereinafter referred to as the present composition ba1) ~ Written as ba6).

Each composition having the same composition except for the present compositions 28, 30, 32 and 37 in [Table 4b] using 1 part of tricyclazole instead of 1.5 parts of fusaride (hereinafter referred to as the present compositions bb1 to bb4) .)

Each composition having the same composition except for the present compositions 33, 34, 36 and 37 in [Table 4b] using 0.5 parts of tricyclazole instead of 2 parts of ferrimzone (hereinafter referred to as the present compositions bc1 to bc4) .)

Hereinafter, these compositions 27 to 37, ba1 to ba6, bb1 to bb4, bc1 to bc4, and the same as these compositions except that * 0.1 part of these compositions was changed to * 0.5 part Any one combination of each composition which is a composition is described as this composition b.

[Table 4c]

Each composition having the same composition as the present compositions 38, 41, 43, 44, 45, 46 and 47 in [Table 4c] except that tricyclazole was used in place of the fusalide (hereinafter referred to as the present compositions ca1 to ca7) .)

Hereinafter, any one of the above compositions 38 to 49, ca1 to ca7, and any one of the compositions having the same composition as these compositions except that * 5 parts of these compositions was changed to * 20 parts. The combination is referred to as the present composition c.

[Table 4d]

[Continuation of Table 4d]

[Continuation of Table 4d]

A composition having the same composition as the present composition 80 in [Table 4d] except that a mixture of 2 parts of α1 and 0.05 part of α2 was used instead of 2 parts of α1 of the present composition 80 (hereinafter referred to as the present composition) x80.)
This composition 50, 51 of [Table 4d] except that 10 parts of Bf bacteria (1.5 × 10 11th power CFU / g as the bacterial density) was added to this composition 50, 51, 55 to 84, x80. 55-84, x80 (hereinafter referred to as the present composition da50, da51, da55-da84, xa80).

The same composition as the present compositions 50, 51, 55 to 84 in [Table 4d] except that 10 parts of Pn bacteria were added to the present compositions 50, 51, 55 to 84, and x80 (hereinafter referred to as the present compositions db50 and db51). , Db55 to db84, xb80.)

The same composition as the present compositions 50, 51, 55 to 84 in [Table 4d] except that 10 parts of abamectin was added to the present compositions 50, 51, 55 to 84, and x80 (hereinafter referred to as the present compositions dc50, dc51, (Indicated as dc55 to dc84, xc80)

The compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, xc80, except that 10 parts of clothiazinine was added to the compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, xc80 Same composition (hereinafter referred to as the present compositions daa55 to daa84, xaa80, dba55 to dba84, xba80, dca55 to dca84, xca80)

The compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, except that 10 parts of cyantraniliprole were added to the compositions da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, xc80. The same composition as xc80 (hereinafter referred to as the present compositions dab55 to dab84, xab80, dbb55 to dbb84, xbb80, dcb55 to dcb84, xcb80)

Hereinafter, the present compositions 50 to 84, x80, da55 to da84, xa80, db55 to db84, xb80, dc55 to dc84, xc80, daa55 to daa84, xaa80, dba55 to dba84, xba80, dca55 to dca84, xca80, dab55 ~ Db84, xab80, dbb55 to dbb84, xbb80, dcb55 to dcb84, xcb80, and each composition having the same composition as these compositions, except that * 2 part of these compositions is * 0.5 part Any one combination is referred to as the present composition d.

[Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

[Continuation of Table 4e]

The same composition as the present compositions 85 to 799 in [Table 4e] except that one component in the component 2 row of the present compositions 85 to 799 was omitted (hereinafter referred to as the present compositions ex85 to ex799).
The same composition as the present composition 85 to 799 in [Table 4e] except that one component in the component 3 row of the present composition 85 to 799 was excluded (hereinafter referred to as the present composition ey85 to ey799).
The same composition as the present composition 85 to 799 in [Table 4e] except that one component in the component 4 row of the present composition 85 to 799 was omitted (hereinafter referred to as the present composition ez85 to ez799).

The present compositions 85-799, ex85-ex799, ey85-ey799, ez85-ez799, except that 10 parts of Bf bacteria (bacterial density, 1.5 × 10 11th power CFU / g) were added to the present compositions 85-799 799, ex85 to ex799, ey85 to ey799, ez85 to ez799 (hereinafter referred to as the present composition ea85 to ea799, eax85 to eax799, eay85 to eay799, eaz85 to eaz799)
The same composition as the present composition 85-799, ex85-ex799, ey85-ey799, ez85-ez799 except that 10 parts of Pn bacteria were added to the present composition 85-799 (hereinafter, the present compositions eb85-eb799, ebx85- (Indicated as ebx799, eby85 to eby799, and ebz85 to ebz799)
The same composition as the present composition 85-799, ex85-ex799, ey85-ey799, ez85-ez799 except that 10 parts of abamectin was added to the present composition 85-799, ex85-ex799, ey85-ey799, ez85-ez799 ( Hereinafter, the present compositions ec85 to ec799, ecx85 to ecx799, ecy85 to ecy799, and ecz85 to ecz799 are described.)

This composition ex85 to ex799, ey85 to ey799, ez85 to ez799, ea85 to ea799, eax85 to eax799, ea85 to eee799, eaz85 to eaz799, eb85 to eb799, ebx85 to ebx799, eby7 e7 to e99e, , Ecx85 to ecx799, ecy85 to ecy799, ecz85 to ecz799, except that 10 parts of clothiazinine was added to this composition ex85 to ex799, ey85 to ey799, ez85 to ez799, ea85 to ea799, eax85 to e99799, eaz799, eb85 to eb799, ebx85 to ebx799, eby85 to eby799, ebz85 to ebz 799, ec85 to ec799, ecx85 to ecx799, ecy85 to ecy799, ecz85 to ecz799 (hereinafter referred to as this composition exa85 to exa799, eya85 to eya799, eza85 to eaa7, ea85 to eaa7, Eza85 to eaza799, eba85 to eba799, ebxa85 to ebxa799, ebya85 to ebya799, ebza85 to ebza799, eca85 to eca799, ecxa85 to ecxa799, eza85 to eyz7

This composition ex85 to ex799, ey85 to ey799, ez85 to ez799, ea85 to ea799, eax85 to eax799, ea85 to eee799, eaz85 to eaz799, eb85 to eb799, ebx85 to ebx799, eby7 e7 to e99e, Ex85 to ex799, ey85 to ey799, ez85 to ez799, ea85 to ea799, ea85 to ea799a, e85 to ea99799, exy85 to ea99799, ec85 to ea799, , Eaz85 to eaz799, eb85 to eb799, ebx85 to ebx799, eby85 to eby799, ebz85 -Ebz799, ec85-ec799, ecx85-ecx799, ec85-ecy799, ecz85-ecz799 (hereinafter referred to as this composition exb85-exb799, ebb85-eyb799, ezb85-eb799, eab85-eb7- eyb799, eazb85 to eazb799, ebb85 to ebb799, ebxb85 to ebxb799, ebyb85 to ebyb799, ebzb85 to ebbz799, ecb85 to ecb799, ecxb85 to ecxb85, ec

Hereinafter, the present compositions 85 to 834, ex85 to ex834, ey85 to ey834, ez85 to ez834, ea85 to ea799, eax85 to eax799, ea85 to eee799, ez85 to eaz799, eb85 to eb799, ebx85 to eb7, eb99 , Ebz85 to ebz799, ec85 to ec799, ecx85 to ecx799, ecy85 to ecy799, ecz85 to ecaz799, exa85 to eaa799, ea85 to eaa7, ea85 to ea7, ea85 to ea7, ~ Eba799, ebxa85 ~ ebxa799, ebya85 ~ ebya79 9, ebza85 to ebza799, eca85 to eca799, ecxa85 to ecxa799, ecya85 to ecya799, ecza85 to ecza799, exb85 to exb799, eyb85 to yeb799, ezb85 to ebb7, ezb85 to ebb7 ebb 85 to ebb 799, ebxb 85 to ebxb 799, ebyb 85 to ebyb 799, ebzb 85 to ebbz 799, ecb 85 to ecb 799, ecxb 85 to ecxb 799, ecyb 85 to ecyb 799, eczb99 to ecb7 Each composition is the same as these compositions except for Referred to as the present composition ex Te.
In each of the present compositions ex including α1 in the present composition ex, each composition using a mixture of α1 2 parts and α2 0.05 parts instead of α1 2 parts is collectively referred to as present composition ey. Any one combination of each composition contained in this composition ex and each composition contained in this composition ey is described as this composition e.

[Table 4f]

[Continuation of Table 4f]

[Continuation of Table 4f]

[Continuation of Table 4f]

[Continuation of Table 4f]

The same composition as the present composition 800 to 864 in [Table 4f] (except for the two components in the row of component 4 and component 5 of the present composition 800 to 864) (hereinafter referred to as the present composition fx800 to fx864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of tifluzamide (hereinafter referred to as the present compositions fa800 to fa864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of penflufen (hereinafter referred to as the present compositions fb800 to fb864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of sedaxane (hereinafter referred to as the present compositions fc800 to fc864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of floxapyroxide (hereinafter referred to as the present compositions fd800 to fd864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of tolcrofosmethyl is changed to 2 parts of fluopyram (hereinafter referred to as the present compositions fe800 to fe864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts ethaboxam is a mixture of 2 parts ethaboxam and 2 parts metalaxyl (hereinafter referred to as the present compositions ff800 to ff864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of metalaxyl (hereinafter referred to as the present compositions fg800 to fg864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of metalaxyl M (hereinafter referred to as the present compositions fh800 to fh864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of fluorpicolide (hereinafter referred to as the present compositions fj800 to fj864).

Each composition which is the same composition as the present compositions 800 to 864 in [Table 4f] except that 2 parts of ethaboxam was changed to 2 parts of oxathiapiproline (hereinafter referred to as the present compositions fk800 to fk864).

This composition 800-864, fx800-fx864, fa800-fa864, fb800-fb864, fc800-fc864, fd800-fd864, fe800-fe864, ff800-ff864, fg800-fg864, fh800-fh864, fj800-fj864, fj864-64 The composition 800-864, fx800-fx864, fa800-fa864, fb800-fb864, fc800-fc864, except that 10 parts of Bf bacteria (1.5 × 10 11th power CFU / g) was added to , Fd800 to fd864, fe800 to fe864, ff800 to ff864, fg800 to fg864, fh800 to fh864, fj800 to fj864, fk800 to fk864 Hereinafter, the present compositions 800a to 864a, fxa800 to fxa864, faa800 to faa864, fba800 to fba864, fca800 to fca864, fda800 to fda864, fea800 to fea864, ffa800 to ffa864, fga800 to fga8h, fga800 to fga8 ˜ fka864.)

This composition 800-864, fx800-fx864, fa800-fa864, fb800-fb864, fc800-fc864, fd800-fd864, fe800-fe864, ff800-ff864, fg800-fg864, fh800-fh864, fj800-fj864, fj864-64 In addition, the composition 800-864, fx800-fx864, fa800-fa864, fb800-fb864, fc800-fc864, fd800-fd864, fe800-fe864, ff800-ff864, fg800-fg864, except that 10 parts of Pn bacteria were added. The same composition as fh800 to fh864, fj800 to fj864, fk800 to fk864 (hereinafter, the present compositions 800b to 864b, fxb800 fxb864, referred to as fab800 ~ fab864, fbb800 ~ fbb864, fcb800 ~ fcb864, fdb800 ~ fdb864, feb800 ~ feb864, ffb800 ~ ffb864, fgb800 ~ fgb864, fhb800 ~ fhb864, fjb800 ~ fjb864, fkb800 ~ fkb864.)

This composition 800-864, fx800-fx864, fa800-fa864, fb800-fb864, fc800-fc864, fd800-fd864, fe800-fe864, ff800-ff864, fg800-fg864, fh800-fh864, fj800-fj864, fj864-64 In addition, except that 10 parts of abamectin was added, the present compositions 800-864, fx800-fx864, fa800-fa864, fb800-fb864, fc800-fc864, fd800-fd864, fe800-fe864, ff800-ff864, fg800-fg864, fh800 To fh864, fj800 to fj864 and fk800 to fk864 (hereinafter referred to as the present compositions 800c to 864c, fxc8) 0 referred to as ~ fxc864, fac800 ~ fac864, fbc800 ~ fbc864, fcc800 ~ fcc864, fdc800 ~ fdc864, fec800 ~ fec864, ffc800 ~ ffc864, fgc800 ~ fgc864, fhc800 ~ fhc864, fjc800 ~ fjc864, fkc800 ~ fkc864.)

The present compositions 800a to 864a, fxa800 to fxa864, faa800 to faa864, fba800 to fba864, fca800 to fca864, fda800 to fda864, fea800 to fea864, ffa800 to ffa864, hga864f, hga864f, hga864f 800b to 864b, fxb800 to fxb864, fab800 to fab864, fbb800 to fbb864, fcb800 to fcb864, fdb800 to fdb864, feb800 to feb864, ffb800 to ffb864, fbb8 to fbb8, fhb8 to fbb8 0c to 864c, fxc800 to fxc864, fac800 to fac864, fbc800 to fbc864, fcc800 to fcc864, fdc800 to fdc864, fec800 to fec864, ffc800 to ffc864, fgc800 to fgc864, fhc64 to c8, fhc64 to fh8 Except for the addition of 10 parts, the compositions 800a to 864a, fxa800 to fxa864, faa800 to faa864, fba800 to fba864, fca800 to fca864, fda800 to fda864, fea800 to fea864, ffa800 to ffa864h, fga864h, gga8h fja800 to fja86 , Fka800 to fka864, 800b to 864b, fxb800 to fxb864, fab800 to fab864, fbb800 to fbb864, fcb800 to fcb864, fdb800 to fdb864, feb800 to feb864, fb864 to fb864h, fb864 to fb864h ~ Fkb864, 800c ~ 864c, fxc800 ~ fxc864, fac800 ~ fac864, fbc800 ~ fbc864, fcc800 ~ fcc864, fdc800 ~ fdc864, fec800 ~ fec864, ffc800 ~ ffc864j, fgc800f, c8f, 8c The same composition as 00 to fkc864 (hereinafter referred to as the present composition 800aa to 864aa, fxaa800 to fxaa864, faaa800 to faaa864, fbaa800 to fbaa864, fca800800 to fca800g, fda800h to fda864, ~ Fhaa864, fjaa800 ~ fjaa864, fkaa800 ~ fkaa864, 800ba ~ 864ba, fxba800 ~ fxba864, faba800 ~ faba864, fbba800 ~ fbba864, fbaba800 ~ fdb8800, fdb8800, fdb8800, fdb8800 , Fgba800 ~ fgba864, fhba800 ~ fhba864, fjba800 ~ fjba864, fkba800 ~ fkba864,800ca ~ 864ca, fxca800 ~ fxca864, faca800 ~ faca864, fbca800 ~ fbca864, fcca800 ~ fcca864, fdca800 ~ fdca864, feca800 ~ feca864, ffca800 ~ ffca864, fgca800 To fgca864, fhca800 to fhca864, fjca800 to fjca864, and fkca800 to fkca864. )

This composition 800a to 864a, faa800 to faa864, fba800 to fba864, fca800 to fca864, fda800 to fda864, fea800 to fea864, ffa800 to ffa864, fga800 to fga864a, fha800 to 800ha, 8f to 8ha , Fab800 to fab864, fbb800 to fbb864, fcb800 to fcb864, fdb800 to fdb864, feb800 to feb864, ffb800 to ffb864, fgb800 to fgb864, fhb800 to fhb864, fjb800c, fjb864c, fjb864c ~ Fbc864, fcc800 ~ fcc864, fdc800 ~ fdc864, fec800 ~ fec864, ffc800 ~ ffc864, fgc800 ~ fgc864, fhc800 ~ fhc864, fjc800 ~ fjc864, fkc800 ~ fkc864
The compositions 800a to 864a, fxa800 to fxa864, faa800 to faa864, fba800 to fba864, fca800 to fca864, fda800 to fda864, fea800 to fea864, fga864, fha800 to fha864, fja800 to fja864, fka800 to fka864, 800b to 864b, fxb800 to fxb864, fab800 to fab864, fbb800 to fbb864, fcb800 to fcb864, fdb64 to 800b, fb64 to fb8, fhb800 to fhb864, fjb800 fjb864, fkb800 to fkb864, 800c to 864c, fxc800 to fxc864, fac800 to fac864, fbc800 to fbc864, fcc800 to fcc864, fdc800 to fdc864, fec800 to fec864f, cfc to 800c, 8c The same composition as fkc800 to fkc864 (hereinafter, this composition 800ab to 864ab, fxab800 to fxab864, faab800 to faab864, fbab800 to fbab864, fcab800 to fcab864, fdb800 to fdb864, fab864 to fffab800, ffab800 to fabfab864, ffab800 to fabfab864, b864, fhab800 to fhab864, fjab800 to fjab864, fkab800 to fkab864, 800bb to 864bb, fxbb800 to fxbb864, fabbb800 to fabbb864, fbbbb, fcbbbb, ffcb800b fhbb800 to fhbb864, fjbb800 to fjbb864, fkbb800 to fkbb864, 800cb to 864cb, fxcb800 to fxcb864, facb800 to facb864, fbcb800 to fbcb864, fccb800d to fccb864d, fccb864d These are indicated as fecb800 to fecb864, ffcb800 to ffcb864, fgcb800 to fgcb864, fhcb800 to fhcb864, fjcb800 to fjcb864, and fkcb800 to fkcb864. )

Hereinafter, the present compositions 800-864, fx800-fx864, fa800-fa864, fb800-fb864, fc800-fc864, fd800-fd864, fe800-fe864, ff800-ff864, fg800-fg864, fh800-fh864, fj800-fj864 , Fk800 to fk864, 800a to 864a, fxa800 to fxa864, faa800 to faa864, fba800 to fba864, fca800 to fca864, fda800 to fda864, fea800 to fea864, ffa800 to ffa864, fga864, fga864h ~ Fka864, 800b ~ 864b, fxb800 ~ fx 864, fab800 to fab864, fbb800 to fbb864, fcb800 to fcb864, fdb800 to fdb864, feb800 to feb864, ffb800 to ffb864, fgb800 to fgb864, fhb800 to fhb864, fjb800 to fj64, fjb800 to fb864 fac800 to fac864, fbc800 to fbc864, fcc800 to fcc864, fdc800 to fdc864, fec800 to fec864, ffc800 to ffc864, fgc800 to fgc864, fhc800 to fhc864, fjc800 to f8864, f8c64 to 800 64, faaa800 ~ faaa864, fbaa800 ~ fbaa864, fcaa800 ~ fcaa864, fdaa800 ~ fdaa864, feaa800 ~ feaa864, ffaa800 ~ ffaa864, fgaa800 ~ fgaa864, fhaa800 ~ fhaa864, fjaa800 ~ fjaa864, fkaa800 ~ fkaa864,800ba ~ 864ba, fxba800 ~ fxba864, faba800 to faba864, fbba800 to fbba864, fcba800 to fcba864, fdba800 to fdba864, feba800 to feba864, ffba800 to ffba864, fgba800 to fgba864, fhba800 to fhjj 4, fkba800 ~ fkba864,800ca ~ 864ca, fxca800 ~ fxca864, faca800 ~ faca864, fbca800 ~ fbca864, fcca800 ~ fcca864, fdca800 ~ fdca864, feca800 ~ feca864, ffca800 ~ ffca864, fgca800 ~ fgca864, fhca800 ~ fhca864, fjca800 ~ fjca864, fkca800 to fkca864, 800ab to 864ab, fxab800 to fxab864, faab800 to faab864, fbab800 to fbab864, fcab800 to fcab864, fdab800 to fdab864, feb800 to feb864, ffab800 to ffab864, fab800 800 to fgab864, fhab800 to fhab864, fjab800 to fjab864, fkab800 to fkab864, 800bb to 864bb, fxbb800 to fxbbb864, fabbb800 to fabbb864, fbbbb800 to fbbb864, fcbb864 to fbbb864 fgbb864, fhbb800 to fhbb864, fjbb800 to fjbb864, fkbb800 to fxbb864, 800cb to 864cb, fxcb800 to fxcb864, facb800 to facb864, fbcb800 to fbcb800, fccb800 to fccb800 dcb864, fecb800-fecb864, ffcb800-ffcb864, fgcb800-fgcb864, fhcb800-fhcb864, fjcb800-fjcb864, fkcb800-fkcb864, and the composition * 2 parts of these compositions Each composition having the same composition as is collectively referred to as the present composition fx.
In each of the present compositions fx containing α1, each composition using a mixture of α1 2 parts and α2 0.05 parts instead of α1 2 parts is collectively referred to as the present composition fy. Any one combination of each composition contained in this composition fx and each composition contained in this composition fy is described as this composition f.

Formulation Example 1
Any one of the present composition c, the present composition d, the present composition e, and the present composition f is described in the above [Table 4c], [Table 4d], [Table 4e], or [Table 4f]. Parts by weight, 35 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and water were mixed to make a total amount of 100 parts. Obtain a flowable formulation.

Formulation Example 2
Any one of the present composition c, the present composition d, the present composition e, and the present composition f is described in the above [Table 4c], [Table 4d], [Table 4e], or [Table 4f]. Of water, 1.5 parts of sorbitan trioleate, and 28 parts of an aqueous solution containing 2 parts of polyvinyl alcohol were mixed and finely pulverized by a wet pulverization method, and then 0.05 parts of xanthan gum and aluminum magnesium silicate 0.1 An aqueous solution containing parts is added to make the total amount 90 parts, and further 10 parts of propylene glycol is added and mixed by stirring to obtain each flowable preparation.

Formulation Example 3
Any one of the present composition c, the present composition d, the present composition e, and the present composition f is described in the above [Table 4c], [Table 4d], [Table 4e], or [Table 4f]. The total weight is 100 parts by adding 1 part by weight, 3 parts of calcium lignin sulfonate, 2 parts of sodium lauryl sulfate, and the remainder of the synthetic silicon hydrated silicon, and pulverize and mix well to obtain each wettable powder.

Formulation Example 4
Add any one of the present composition a by weight, the synthetic silicon hydroxide fine powder 1 part, 2 parts calcium lignin sulfonate, 30 parts bentonite and the balance of kaolin clay as described in [Table 4a]. To 100 parts and mix. Next, an appropriate amount of water is added to the mixture, and the mixture is further stirred, granulated by a granulator, and dried by ventilation to obtain each granule.

Formulation Example 5
A powder is obtained by mixing any one of the present compositions b with 100 parts by weight, adding 10 parts by weight of talc and 10 parts of talc and the remainder of kaolin clay as described in [Table 4b] etc.

Formulation Example 6
Any one of the present composition c, the present composition d, the present composition e, and the present composition f is described in the above [Table 4c], [Table 4d], [Table 4e], or [Table 4f]. 1 part by weight, 15 parts of a mixture of white carbon and polyoxyethylene alkyl ether sulfate ammonium salt (weight ratio 1: 1) and water are mixed to make a total amount of 100 parts. Obtain a flowable formulation.

Next, application examples of the composition of the present invention to plant seeds will be shown.
Application example 1
By applying 200 ml of each flowable preparation prepared in Preparation Example 1 or 2 to 100 kg of dried sorghum seeds using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), each treated seed is treated. obtain.
Further, each treated seed can also be obtained by adding 180 grams of oxabetrinyl to 200 ml of each flowable preparation prepared in Preparation Example 1 or 2 and performing a similar smearing treatment.

Application example 2
By applying 200 ml of each flowable preparation prepared in Preparation Example 1 or 2 to 100 kg of dried sorghum seeds using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), each treated seed is treated. obtain.
Alternatively, each treated seed can be obtained by adding 40 grams of fluxofenim to 200 ml of each flowable preparation prepared in Formulation Example 1 or 2, followed by a smear treatment.

Application example 3
Each treated seed is treated by smearing 10 ml of each flowable formulation prepared in Formulation Example 1 or 2 on 10 kg of dried corn seed using a rotary seed processing machine (seed dresser, Hans-Ulrich Hege GmbH). obtain. The corn may be a genetically modified corn containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application example 4
40 kg of each flowable preparation prepared in Formulation Example 1 or 2 is smeared on 10 kg of dried corn seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), thereby treating each treated seed. obtain.

Application example 5
100 kg of each flowable preparation prepared in Formulation Example 1 or 2 is smeared on 10 kg of dried corn seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), thereby treating each treated seed. obtain.

Application Example 6
Treated seeds are obtained by applying 50 g of each wettable powder prepared in Formulation Example 3 to 10 kg of dried corn seeds.

Application example 7
By applying 20 ml of each flowable preparation prepared in Preparation Example 1 or 2 to 10 kg of dried soybean seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), each treated seed is treated. obtain. The soybean may be a genetically modified soybean containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application example 8
By subjecting 10 kg of dried soybean seeds to 100 ml of each flowable preparation prepared in Formulation Example 1 or 2, using a rotary seed treatment machine (seed dresser, manufactured by Hans-Ulrich Hege GmbH), each treated seed is treated. obtain.

Application example 9
By applying 50 ml of each flowable formulation prepared in Formulation Example 1 or 2 to 10 kg of dry cotton seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), each treated seed is treated. obtain. The cotton may be a genetically modified cotton containing a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application Example 10
50 ml of each flowable preparation prepared in Formulation Example 1 or 2 is applied to 10 kg of dried oilseed rape seeds using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), and each treated seed is then smeared. Get. The oilseed rape may be a genetically modified oilseed rape including a glyphosate resistance gene or a Bt crystal toxin protein gene.

Application Example 11
10 kg of dried oilseed rape seeds are smeared with 10 ml of each flowable preparation prepared in Formulation Example 1 or 2 using a rotary seed treatment machine (seed dresser, Hans-Ulrich Hege GmbH), thereby treating each treated seed. Get.

Application Example 12
50 kg of each dry seed prepared in Formulation Example 1 or 2 is smeared on 10 kg of dried wheat seeds using a rotary seed processing machine (seed dresser, Hans-Ulrich Hege GmbH), thereby treating each treated seed. obtain

Hereinafter, the effects of the present invention will be shown by test examples.

Test example 1
The corn seeds obtained in Application Example 3 are sown at 15 cm intervals to a depth of 5 cm using a seeder. A high control effect can be obtained against diabrotica pests such as Western corn rootworm, and larvae of the clicks typified by the genus Agriotes and Melanotus (collectively referred to as wire worms). When the preparation treated with corn seeds contains a fungicide, the fungicide can have a high control effect against diseases with a control effect.

Test example 2
By sowing the soybean seeds obtained in Application Example 7, it is possible to obtain a high control effect against the fly larvae. When the preparation treated with soybean contains a bactericidal agent, a high controlling effect can be obtained against diseases for which the bactericidal agent has a controlling effect. When nematode control agent is contained, a high control effect can be acquired with respect to sweet potato nematode.

Test example 3
By sowing the oilseed rape seeds obtained in Application Example 10, it is possible to obtain a high control effect against flea beetle larvae. When a fungicide is contained in the preparation treated with oilseed rape seeds, it is possible to obtain a high control effect against diseases for which the fungicide has a control effect.

Test example 4
During the seedling period such as seeding or transplanting, the granules obtained in Formulation Example 4 are sprayed on a seedling box at the same time as rice seeding, and the seedling is covered with soil and grown. The seed pods used are seed sterilized with a mixture of ipconazole and cupric hydroxide before sowing. 2.5 Rice seedlings grown in the leaf stage are transplanted to paddy fields using a rice planting machine. After transplanting, spray paddy rice herbicide. A high control effect can be obtained for rice weevil, rice beetle, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper leafhopper, white-tailed beetle, wing-bellied moth, yellow-tailed moth, locust. When the preparation contains a bactericidal agent, it is possible to obtain a high control effect for diseases in which the bactericidal agent has a control effect, such as rice blast and blight.

Test Example 5
In Test Example 4, instead of the granule obtained in Formulation Example 4, a solution obtained by diluting the flowable obtained in Formulation Example 1 or 2 was applied to a rice seedling grown at the 3.5 leaf stage as a watering device. Irrigated using, and transplanted to paddy field with rice planting machine. A high control effect can be obtained for rice weevil, rice beetle, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper leafhopper, white-tailed beetle, wing-bellied moth, yellow-tailed moth, locust.

Test Example 6
Rice seed cake obtained by applying the diluted solution of the flowable agent obtained in Formulation Example 1 is sown in a paddy field. A high control effect can be obtained for rice weevil, rice beetle, white planthopper, white-tailed planthopper, white-bellied planthopper, leafhopper leafhopper, white-tailed beetle, wing-bellied moth, yellow-tailed moth, locust. When the preparation contains a bactericidal agent, it is possible to obtain a high control effect for diseases in which the bactericidal agent has a control effect, such as rice blast and blight.

Claims

Formula (1)

[In Formula (1),
A 1a represents —NR 8a —, an oxygen atom or a sulfur atom,
A 2a represents a nitrogen atom or ═CR 9a —,
A 3a represents a nitrogen atom or ═CR 10a —,
R 1a has a C1-C6 chain hydrocarbon group which may have one or more atoms or groups selected from group X a or one or more atoms or groups selected from group Y a Represents a good C3-C6 alicyclic hydrocarbon group,
R 2a , R 3a , R 4a and R 5a are the same or different and are one or more atoms selected from a C1-C6 chain hydrocarbon group which may have one or more halogen atoms and group Za or a phenyl group which may have a group, one or more atoms may be 5-membered heterocyclic group having a group selected from the group Z a, or one or more atoms selected from the group Z a A 6-membered heterocyclic group optionally having a group, —OR 11a , —S (O) m R 11a , —NR 11a R 12a , —CO 2 R 11a , —C (O) R 11a , a cyano group, Represents a nitro group, a halogen atom, —SF 5 or a hydrogen atom (provided that at least two of R 2a , R 3a , R 4a and R 5a represent a hydrogen atom);
R 6a and R 7a are the same or different, one or more atoms or groups which may have a C1-C6 chain hydrocarbon group selected from the group X a, one or more selected from the group Z a atoms or a phenyl group which may have a group, one or more atoms may be 5-membered heterocyclic group having a group selected from the group Z a, one or more atoms selected from the group Z a Alternatively, a 6-membered heterocyclic group optionally having a group, —OR 11a , —S (O) m R 11a , —S (O) 2 NR 11a R 12a , —NR 11a R 12a , —NR 11a CO 2 R 12a , —NR 11a C (O) R 12a , —CO 2 R 11a , —C (O) R 11a , a cyano group, a nitro group, a halogen atom, —SF 5 or a hydrogen atom;
R 8a may have one or more atoms or groups selected from group W a, C1-C6 chain hydrocarbon group, —CO 2 R 11a , —C (O) R 11a , group Y a Represents a C3-C6 alicyclic hydrocarbon group or a hydrogen atom optionally having one or more selected atoms or groups,
R 9a and R 10a are the same or different and are a C1-C6 chain hydrocarbon group which may have one or more halogen atoms, —OR 11a , —S (O) m R 11a , —NR 11a R 12a , —CO 2 R 11a , —C (O) R 11a , a cyano group, a nitro group, a halogen atom or a hydrogen atom;
R 11a and R 12a are the same or different and each represents a C1-C6 chain hydrocarbon group which may have one or more halogen atoms or a hydrogen atom,
m represents 0, 1 or 2, and n represents 0, 1 or 2.
Here, R 6a and R 7a do not represent a hydrogen atom at the same time, and in —S (O) m R 11a , when m is 1 or 2, R 11a does not represent a hydrogen atom.
A 1a is —NH— or —N (CH 3 ) —, A 2a and A 3a are ═CH—, R 1a is a methyl group, and R 2a , R 3a , R 4a and R 5a are hydrogen atoms. And when n is 0, 1 or 2, R 6a and R 7a are the same or different and may have one or more atoms or groups selected from group X a C6 chain hydrocarbon group, one or more atoms or phenyl group which may have a group selected from the group Z, may have one or more atoms or groups selected from the group Z a 5 A membered heterocyclic group, a 6-membered heterocyclic group optionally having one or more atoms or groups selected from the group Za, —OR 11a , —S (O) m R 11a , —S (O) 2 NR 11a R 12a, -NR 11a R 12a, -NR 11a CO 2 R 12a, -NR 11a C (O) R 12a, -CO 2 H, -C (O) R 11a, cyano Represents a nitro group, a bromine atom, an iodine atom, -SF 5, or a hydrogen atom. ).
Group X a : a C1-C6 alkoxy group which may have one or more halogen atoms, a C2-C6 alkenyloxy group which may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms. C2-C6 alkoxycarbonyl group which may have one, C3-C6 cycloalkyl group which may have one or more halogen atoms, cyano group, hydroxy And the group consisting of halogen atoms.
Group Y a : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens A group consisting of a C2-C6 alkenyloxy group which may have an atom, a C2-C6 alkynyloxy group which may have one or more halogen atoms, a hydroxy group and a halogen atom.
Group Z a : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens C1-C6 alkylsulfanyl group which may have an atom, C1-C6 alkylsulfinyl group which may have one or more halogen atoms, C1-C6 which may have one or more halogen atoms C6 alkylsulfonyl group, C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, one or more halogens A C1-C6 alkylamino group optionally having one atom, a C2-C8 dialkylamino group optionally having one or more halogen atoms, a halogen atom, a cyano group, and Group consisting of nitro group.
Group W a : a C1-C6 alkoxy group that may have one or more halogen atoms, a C2-C6 alkenyloxy group that may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms. C2-C6 alkoxycarbonyl group which may have one, C3-C6 cycloalkyl group which may have one or more halogen atoms, halogen atom, cyano And the group consisting of hydroxy groups. ]
A condensed heterocyclic compound represented by the formula:
A pest control composition comprising one or more compounds selected from Group A to Group D.
Group A; fungicide group B; insecticide / acaricide group C; safener group D; plant growth regulator
Formula (2)

[In Formula (2),
A 1b represents —NR 7b —, an oxygen atom or a sulfur atom,
A 2b represents a nitrogen atom or ═CR 8b —,
A 3b represents a nitrogen atom or ═CR 9b —,
R 1b has a C1-C6 chain hydrocarbon group which may have one or more atoms or groups selected from group X b or one or more atoms or groups selected from group Y b. Represents a good C3-C6 alicyclic hydrocarbon group,
R 2b , R 3b and R 4b are each a C1-C6 chain hydrocarbon group which may have one or more atoms or groups selected from group Xb , and one or more atoms or groups selected from group Z A phenyl group which may have, a 5- or 6-membered heterocyclic group which may have one or more atoms or groups selected from group Z, -OR 10b , -S (O) m R 10b , -S (O) 2 NR 10b R 11b , -NR 10b R 11b , -NR 10b CO 2 R 11b , -NR 10b C (O) R 11b , -CO 2 R 10b , -C (O) R 10b ,- C (O) NR 10b R 11b , —SF 5 , a cyano group, a nitro group, a halogen atom or a hydrogen atom,
R 5b and R 6b are the same or different and are each a C1-C6 chain hydrocarbon group optionally having one or more atoms or groups selected from group X b , one or more selected from group Z b A phenyl group optionally having an atom or group, a 5- or 6-membered heterocyclic group optionally having one or more atoms or groups selected from the group Z b , —OR 10b , —S (O) mR 10b , —S (O) 2 NR 10b R 11b , —NR 10b R 11b , —NR 10b CO 2 R 11b , —NR 10b C (O) R 11b , —CO 2 R 10b , —C (O) R 10b , —C (O) NR 10b R 11b , —SF 5 , a cyano group, a nitro group, a halogen atom or a hydrogen atom (wherein R 5b and R 6b do not represent a hydrogen atom at the same time),
R 7b is one or more atoms or groups which may have a C1-C6 chain hydrocarbon group selected from the group W b, C1-C6 chain hydrocarbon group having one phenyl group (wherein The phenyl group may have one or more atoms or groups selected from group Z b ), a C1-C6 chain hydrocarbon group having one 5- or 6-membered heterocyclic group (herein The 5- or 6-membered heterocyclic group may have one or more atoms or groups selected from group Z b ), —CO 2 R 10b , —C (O) R 10b , group Y a C3-C6 alicyclic hydrocarbon group or a hydrogen atom optionally having one or more atoms or groups selected from b ,
R 8b and R 9b are the same or different and are a C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, —OR 10b , —S (O) m R 10b , —NR 10b R 11b , -CO 2 R 10b , -C (O) R 10b , a cyano group, a nitro group, a halogen atom or a hydrogen atom,
R 10b and R 11b are the same or different and are each a C1-C6 chain hydrocarbon group optionally having one or more atoms or groups selected from group X b , one or more selected from group Z b Represents a phenyl group or a hydrogen atom optionally having an atom or group,
m independently represents 0, 1 or 2, and n represents 0, 1 or 2.
Here, in —S (O) m R 10b , when m is 1 or 2, R 10b does not represent a hydrogen atom.
Group X b : a C1-C6 alkoxy group which may have one or more halogen atoms, a C2-C6 alkenyloxy group which may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C1-C6 alkyl which may have one or more halogen atoms A sulfinyl group, a C1-C6 alkylsulfonyl group optionally having one or more halogen atoms, a C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, and one or more halogen atoms. A C2-C6 alkoxycarbonyl group which may have one, one or more halogen atoms or one or more C1-C3 alkyl groups which may have one or more C1-C3 alkyl groups. Alkyl group, a cyano group, hydroxy group and the group consisting of halogen atoms.
Group Y b : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens A group consisting of a C2-C6 alkenyloxy group optionally having one atom, a C2-C6 alkynyloxy group optionally having one or more halogen atoms, and a halogen atom.
Group Z b : C1-C6 chain hydrocarbon group optionally having one or more halogen atoms, C1-C6 alkoxy group optionally having one or more halogen atoms, one or more halogens C1-C6 alkylsulfanyl group which may have an atom, C1-C6 alkylsulfinyl group which may have one or more halogen atoms, C1-C6 which may have one or more halogen atoms C6 alkylsulfonyl group, C2-C6 alkylcarbonyl group optionally having one or more halogen atoms, C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, one or more halogens A C1-C6 alkylamino group optionally having one atom, a C2-C8 dialkylamino group optionally having one or more halogen atoms, a halogen atom, a cyano group, and Group consisting of nitro group.
Group W b : a C1-C6 alkoxy group that may have one or more halogen atoms, a C2-C6 alkenyloxy group that may have one or more halogen atoms, and one or more halogen atoms C2-C6 alkynyloxy group which may have one, C1-C6 alkylsulfanyl group which may have one or more halogen atoms, C2-C6 alkyl which may have one or more halogen atoms A carbonyl group, a C2-C6 alkoxycarbonyl group optionally having one or more halogen atoms, a C3-C6 cycloalkyl group optionally having one or more halogen atoms, and one or more halogen atoms. C1-C6 alkylsulfinyl group which may have one, C1-C6 alkylsulfonyl group which may have one or more halogen atoms, hydroxy group, halogen The group consisting of atoms and a cyano group. ]
A condensed heterocyclic compound represented by the formula:
A pest control composition comprising one or more compounds selected from Group A to Group D.
Group A; fungicide group B; insecticide / acaricide group C; safener group D; plant growth regulator
The ratio of the content of the compound (1) or a salt of the compound (1) and one or more compounds selected from group A to group D is 100: 1 to 1: 100 by weight. 2. The pest control composition according to 1.
The weight ratio of the compound (2) or a salt of the compound (2) to one or more compounds selected from group A to group D is 100: 1 to 1: 100 by weight. 2. The pest control composition according to 2.
A method for controlling pests, comprising a step of applying an effective amount of the pest control composition according to any one of claims 1 to 4 to a plant or soil for cultivating the plant.
The pest control method according to claim 4, wherein the plant is a seed, a bulb, or a seedling.
5. The method for controlling pests according to claim 4, wherein the plant is corn, soybean, cotton, wheat, sugar beet, rape or rice.
Plant seeds to which an effective amount of the pest control composition according to any one of claims 1 to 4 is adhered.