WO2016142456A1 - Pesticidal mixture comprising a carboxamide compound and a biopesticide - Google Patents
Pesticidal mixture comprising a carboxamide compound and a biopesticide Download PDFInfo
- Publication number
- WO2016142456A1 WO2016142456A1 PCT/EP2016/055105 EP2016055105W WO2016142456A1 WO 2016142456 A1 WO2016142456 A1 WO 2016142456A1 EP 2016055105 W EP2016055105 W EP 2016055105W WO 2016142456 A1 WO2016142456 A1 WO 2016142456A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- lllb
- lla
- llla
- spp
- mixtures
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/20—Bacteria; Substances produced thereby or obtained therefrom
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/30—Microbial fungi; Substances produced thereby or obtained therefrom
Definitions
- Pesticidal mixture comprising a carboxamide compound and a biopesticide
- the present invention relates to mixtures of pesticidal active compounds having synergistically enhanced action and to methods and uses comprising applying said mixtures.
- Another problem encountered concerns the need to have available pest control agents which are effective against a broad spectrum of pests.
- seed vitality - improving vitality of plant propagation material, also termed seed vitality
- the present invention relates to pesticidal mixtures comprising as active components
- Microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. megaterium, B. mojavensis, B. mycoides, B. pumilus,
- activator activity harpin protein, Reynoutria sachalinensis extract; L3) Microbial pesticides with insecticidal, acaricidal, molluscidal and/or nematicidal activity: Agrobacterium radiobacter, Bacillus cereus, B. firm us, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp.
- Flavobacterium sp. Helicoverpa armigera nucleopolyhedrovirus (HearNPV), Helicoverpa zea nucleopolyhedrovirus (HzNPV), Helicoverpa zea single capsid nucleopolyhedrovirus (HzSNPV), Heterorhabditis bacteriophora, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium, Metarhizium anisopliae, Metarhizium anisopliae var. anisopliae, M. anisopliae var.
- compound I is compound i) of formula (I).
- biopesticide(s) II allows enhanced control of pests compared to the control rates that are possible with the individual compounds. Therefore, the term "mixture” as used herein is intended to include also combinations.
- the present invention also relates to a seed treatment composition
- a seed treatment composition comprising a mixture of the active carboxamide compound I and at least one biopesticide II as defined above as well as at least one auxiliary.
- the present invention also relates to the use of the mixture of the active carboxamide compound I and at least one biopesticide II for protecting a plant, plant propagation material, or soil or water, in which the plants are growing, against the attack or infestation by invertebrate pests.
- the present invention relates to the use of the mixture of the active carboxamide compound I and at least one biopesticide II for protecting plant propagation material, preferably seeds, from soil insects and the seedlings' roots and shoots from soil and foliar insects, wherein the plant progagation material as e.g. the seeds are contacted with a pesticidally effective amount of the mixture before sowing and/or after pregermination.
- the present invention further relates to a method for controlling invertebrate pests, which method comprises contacting the plant or the plant propagation material or the soil; the pests or their food supply, habitat or breeding grounds, with a pesticidally effective amount of the mixture of the active carboxamide compound I and at least one biopesticide II.
- the present invention further relates to a method for controlling nematodes, which method comprises contacting the plant or the plant propagation material, such as the seeds, or the soil; the pests or their food supply, habitat or breeding grounds, with a pesticidally effective amount of the mixture of the active carboxamide compound I and at least one biopesticide II with nematicidal activity.
- the invention also provides seeds comprising the mixture of at least one active compound I and at least one biopesticide II.
- mixture(s) of at least one active compound selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii) with at least one biopesticide II are herein referred to as "mixture(s) according to the invention” or “mixture(s) of the invention", wherein the compounds selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii) are understood to include their stereoisomers, salts, tautomers or N-oxides, or a polymorphic crystalline form, a co-crystal or a solvate of a compound or a stereoisomer, salt, tautomer or N-oxide thereof.
- the mixture according to the invention is a mixture of one active compound selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii), preferably compound i) of formula I with one biopesticide II (binary mixture).
- the mixture according to the invention is a mixture of one active compound selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii), preferably compound i) of formula I with at least one biopesticide II.
- the mixture according to the invention is a mixture of one active compound selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii), preferably compound i) of formula I with one biopesticide II and another insecticidal active compound III (ternary mixture).
- the mixture according to the invention is a mixture of one active compound selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii), preferably compound i) of formula I with one biopesticide II and one fungicidal active compound III (ternary mixture).
- composition(s) according to the invention or “composition(s) of the present invention” encompasses composition(s) comprising the mixtures of the invention, i.e. mixtures of the compounds selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii), preferably compound i) of formula I with at least one biopesticide II for being used and/or applied in methods according to the invention as defined herein, wherein the compounds selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii), preferably compound i) of formula I are understood to include their stereoisomers, salts, tautomers or N-oxides, or a polymorphic crystalline form, a co-crystal or a solvate of a compound or a stereoisomer, salt, tautomer or N-oxide thereof.
- Carboxamide derivatives showing generally pesticidal activity have been described previously.
- WO200573165 and WO2010018714 describe carboxamide compounds, their preparation and their use as pest control agents.
- WO2007013150, JP201 1-157294, JP201 1- 157295 and JP201 1 -157296 describe mixtures of carboxamides with other active ingredients.
- Preparation of the carboxamide compound of formula I can further be accomplished according to standard methods of organic chemistry, e.g. by the methods or working examples described in WO 2010/018857 without being limited to the routes given therein.
- carboxamide compound ii of formula la which is also known under the name desmethyl-broflanilide, and/or similar compounds has been described in US8686044 (inter alia columns 75 to 76) and EP1714958A1 .
- the compound selected from compound i) of formula I, compound ii) of formula la or mixtures comprising i) and ii), preferably compound i) of formula I includes its tautomers, racemic mixtures, individual pure enantiomers and diasteroemers and the optically active mixtures.
- compound of formula I or “compound I according to the invention” or “component 1” comprises the compound as defined herein as well as a stereoisomer, salt, tautomer or N- oxide thereof.
- compound of the present invention is to be understood as equivalent to the term “compound according to the invention”, therefore also comprising a stereoisomer, salt, tautomer or possibly N-oxide thereof.
- Biopesticides have been defined as a form of pesticides based on micro-organisms (bacteria, fungi, viruses, nematodes, etc.) or natural products (compounds, such as metabolites, proteins, or extracts from biological or other natural sources) (U.S. Environmental Protection Agency: http://www.epa.gov/pesticides/biopesticides/). Biopesticides fall into two major classes, microbial and biochemical pesticides:
- Microbial pesticides consist of bacteria, fungi or viruses (and often include the metabolites that bacteria and fungi produce). Entomopathogenic nematodes are also classified as microbial pesticides, even though they are multi-cellular.
- Biochemical pesticides are naturally occurring substances or or structurally-similar and functionally identical to a naturally-occurring substance and extracts from biological sources that control pests or provide other crop protection uses as defined below, but have non-toxic mode of actions (such as growth or developmental regulation, attractents, repellents or defence activators (e.g. induced resistance) and are relatively non-toxic to mammals.
- biopesticides from group L1 ) and/or L2) may also have insecticidal, acaricidal,
- the biopesticides from group L3) and/or L4) may also have fungicidal, bactericidal, viricidal, plant defense activator, plant stress reducing, plant growth regulator, plant growth promoting and/or yield enhancing activity.
- the biopesticides from group L5) may also have fungicidal, bactericidal, viricidal, plant defense activator, insecticidal, acaricidal, molluscidal, pheromone and/or nematicidal activity.
- CNCM 1-1582 a variant of parental strain EIP-N1 (CNCM 1-1556) isolated from soil of central plain area of Israel (WO 2009/126473, US 6,406,690; e. g. Votivo® from Bayer CropScience LP, USA), B. pumilus GHA 180 isolated from apple tree rhizosphere in Mexico (IDAC 260707-01 ; e. g. PRO- MIX® BX from Premier Horticulture, Quebec, Canada), B. pumilus INR-7 otherwise referred to as BU-F22 and BU-F33 isolated at least before 1993 from cucumber infested by Erwinia tracheiphila (NRRL B-50185, NRRL B-50153; US 8,445,255), B. pumilus KFP9F isolated from the rhizosphere of grasses in South Africa at least before 2008 (NRRL B-50754;
- B. pumilus OBJ 2808 was isolated from soil collected in Pohnpei, Federated States of Micronesia, in 1998 (NRRL B-30087; e. g. Sonata® or Ballad® Plus from Bayer Crop Science LP, USA), B. simplex ABU 288 (NRRL B-50304; US 8,445,255), B. subtilis FB17 also called UD 1022 or UD10-22 isolated from red beet roots in North America (ATCC PTA-1 1857; System. Appl. Microbiol.
- B. t. ssp. kurstakiS A isolated from E saccharina larval cadavers (NRRL B-50753; e. g. Beta Pro® from BASF Agricultural Specialities (Pty) Ltd., South Africa), B. t. ssp. tenebrionis NB-M6A , a mutant of strain NB-125, a wild type strain isolated in 1982 from a dead pupa of the beetle Tenebrio molitor (DSM 5480; EP 585 215 B1 ; e. g.
- HSSNPV single capsid nucleopolyhedrovirus
- ABA-NPV-U e. g. Heligen® from AgBiTech Pty Ltd., Queensland, Australia
- Heterorhabditis bacteriophora e. g.
- Paecilomyces ilacinus 2 ⁇ isolated from infected nematode eggs in the Philippines (AGAL 89/030550; W01991/02051 ; Crop Protection 27, 352- 361 , 2008; e. g. BioAct®from Bayer CropScience AG, Germany and MeloCon® from Certis, USA), Paenibacillus alvei NAS6G6 isolated from the rhizosphere of grasses in South Africa at least before 2008 (WO 2014/029697; NRRL B-50755; e.g.
- T. harzianum l-22 also called KRL-AG2 (ATCC 20847; BioControl 57, 687-696, 2012; e. g. Plantshield® from BioWorks Inc., USA or SabrExTM from Advanced Biological Marketing Inc., Van Wert, OH, USA).
- Preferred biopesticides which have been deposited under deposition numbers mentioned herein (the prefices such as ATCC or DSM refer to the acronym of the respective culture collection, for details see e. g. here: http://www.
- wfcc.info/ccinfo/collection/by_acronym/ are referred to in literature, registered and/or are commercially available: mixtures of Aureobasidium pu/lu/ans DSM 14940 and DSM 14941 isolated in 1989 in Konstanz, Germany (e. g.
- plantarum QST-713 isolated from peach orchard in 1995 in California, U.S.A. (NRRL B-21661 ; e. g. Serenade® MAX from Bayer Crop Science LP, USA), B. amyloliquefaciens spp. plantarum TJ1000 isolated in 1992 in South Dakoda, U.S.A. (also called 1 BE; ATCC BAA-390; CA
- pumilus INR-7 otherwise referred to as BU-F22 and BU-F33 isolated at least before 1993 from cucumber infested by Erwinia tracheiphila (NRRL B-50185, NRRL B-50153; US 8,445,255), B. pumilus QST 2808 was isolated from soil collected in Pohnpei, Federated States of Micronesia, in 1998 (NRRL B-50185, NRRL B-50153; US 8,445,255), B. pumilus QST 2808 was isolated from soil collected in Pohnpei, Federated States of Micronesia, in 1998 (NRRL
- B-30087 B-30087; e. g. Sonata® or Ballad® Plus from Bayer Crop Science LP, USA
- B. simplex ABU 288 NRRL B-50304; US 8,445,255
- B. subtilis FB17 also called UD 1022 or UD10-22 isolated from red beet roots in North America (ATCC PTA-1 1857; System. Appl. Microbiol. 27, 372-379, 2004; US 2010/0260735; WO 201 1/109395);
- B. t. ssp. tenebrionis NB-176-1 B. t. ssp. tenebrionis NB-176-1 , a mutant of strain NB-125, a wild type strain isolated in 1982 from a dead pupa of the beetle Tenebrio molitor (DSM 5480; EP 585 215 B1 ; e. g.
- Contans® WG, Intercept® WG from Bayer CropScience AG, Germany Contans® WG, Intercept® WG from Bayer CropScience AG, Germany
- harpin (alpha- beta) protein Science 257, 85-88, 1992; e. g. MessengerTM or HARP-N-Tek from Plant Health Care pic, U.K.
- HearNPV Helicoverpa armigera nucleopolyhedrovirus
- HSSNPV capsid nucleopolyhedrovirus
- Helicoverpa zea nucleopolyhedrovirus ABA-NPV-U (e. g. Heligen® from AgBiTech Pty Ltd., Queensland, Australia), Heterorhabditis bacteriophora (e. g. Nemasys® G from BASF
- ClarivaTM PN from Syngenta Crop Protection, LLC, USA
- Penicillium bilaiae also called P. bilaii
- ATCC 18309 ATCC 74319
- ATCC 20851 and/or ATCC 22348 ATCC 743148
- ATCC 743178 ATCC 743178
- T. harzianum -22 also called KRL-AG2 (ATCC 20847; BioControl 57, 687-696, 2012; e. g. Plantshield® from BioWorks Inc., USA or SabrExTM from Advanced Biological Marketing Inc., Van Wert, OH, USA).
- Preferred biopesticides on strain level are selected from the following groups L1 ) to L5):
- L1 Microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity: Aureobasidium pu/iu/ans DSM 14940 and DSM 14941 (L1 .1 ), Bacillus amyloliquefaciens AP-188 (L.1 .2), B. amylolique faciens ssp. plantarum ⁇ 41 (L.1.3), B. amyloliquefaciens ssp. plantarum FZB24 (L.1 .4), B. amyloliquefaciens ssp. plantarum
- FZB42 (L.1.5), B. amyloliquefaciens ssp. plantarum MBI600 (L.1.6), B.
- amyloliquefaciens ssp. plantarum OB -l ⁇ (L.1.7), B. amyloliquefaciens ssp. plantarum TJ1000 (L.1 .8), B. pumi/us GB34 (L.1.9), B. pumi/us GHA 180 (L.1.10), B. pumi/us ⁇ NR-7 (L.1.1 1 ), B. pumilus KFP9F (L.1 .12), B. pumi/us QST 2808 (L.1 .13), B. simp/exABU 288 (L.1.14), B. subti/is FBM (L.1 .15), Coniothyrium minitans CON/M/91-08 (L.1.16),
- Metschnikowia fruct/co/a NRRL Y-30752 (L.1.17), Paenibacillus #/i/e/NAS6G6 (L.1.18), Penicillium bilaiae ATCC 22348 (L.1.19), P. bilaiae ATCC 20851 (L.1.20), Penicillium bilaiae ATCC 18309 (L.1.21 ), Streptomyces microflavus NRRL B-50550 (L.1 .22), Trichoderma asperelloides JM41 R (L.1.23), T. harzianum T-22 (L.1 .24);
- harpin protein L.2.1
- Reynoutria sachalinensis extract L.2.2
- Bacillus firmus ⁇ 582 (L.3.1 ); B. thuringiensis ssp. aizawai AB S- ⁇ 51 (L.3.2), B. t. ssp. (L.3.3), B. t. ssp. kurstaki SB4 (L.3.4), B. t. ssp. tenebr/on/s NB-176-1 (L.3.5), Beauveria bass/ana GHA (L.3.6), B. bass/ana JW-1 (L.3.7), B. bass/ana PPRI
- Metarhizium anisopliae var. anisopliae F52 (L.3.15), Paecilomyces ///acinus 251 (L.3.16),
- Pasteur/a nishizawae Vx ⁇ L.3.17), Steinernema carpocapsae (L.3.18), S. feltiae (L.3.19);
- nematicidal activity cis-jasmone (L.4.1 ), methyl jasmonate (L.4.2), Quillay extract (L.4.3);
- L1 Microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity: Aureobasidium pu/lu/ans DSM 14940 and DSM 14941 (L1 .1 ), Bacillus amyloliquefaciens AP-188 (L.1 .2), B. amylolique faciens ssp. plantarum ⁇ 41 (L.1.3), B. amyloliquefaciens ssp. plantarum FZB24 (L.1 .4), B. amyloliquefaciens ssp. plantarum FZB42 (L.1.5), z5. amyloliquefaciens ⁇ . plantarum MBI600 (L.1.6), z5.
- TJ1000 (L.1 .8), £. pumi/us GB34 (L.1.9), R pumi/us GHA 180 (L.1.10), /?. /3 ⁇ 4y/77/7iys INR-7 (L.1.1 1 ), /?. pumi/us QST 2808 (L.1.13), /?. s//77 ?/e ⁇ ABU 288 (L.1.14), /?.
- subti/is FBM (L.1.15), Coniothyrium minitans COWM -08 (L.1.16), Metschnikowia fructicola NRRL Y-30752 (L.1.17), Penicillium bilaiae AT CC 22348 (L.1.19), . bi/aiae AJCC 20851 (L.1.20), Penicillium bilaiae ATCC 18309 (L.1.21 ), Streptomyces m/crof/avus NRRl B-
- harpin protein L.2.1
- Reynoutria sachalinensis extract L.2.2
- Bacillus firmus 1-1582 (L.3.1 ); z5. thuringiensis ssp. ⁇ /z ⁇ w ⁇ /ABTS-1857 (L.3.2), z5. t. ssp. (L.3.3), z5. /. ssp. tenebrionis NB-176-1 (L.3.5), Beauveria bass/ana GHA (L.3.6), /?. bass/ana JW-1 (L.3.7), Burkho/deria sp. A396 (L.3.9), Helicoverpa armigera nucleopolyhedrovirus (HearNPV) (L.3.10), Helicoverpa zea
- HzNPV nucleopolyhedrovirus
- HzSNPV Helicoverpa zea single capsid nucleopolyhedrovirus
- L.3.13 Heterohabditis bacteriophora
- L.3.14 Metarhizium anisopliae anisopliae F52
- L.3.16 Paecilomyces Iilacinus ⁇
- L.3.17 Pasteur/a nishizawae Vx ⁇
- Steinernema carpocapsae L.3.18), 5. /fe/_ / .?e (L3.19);
- nematicidal activity cis-jasmone (L.4.1 ), methyl jasmonate (L.4.2), Quillay extract
- mixtures comprising as pesticide II (component 2) a biopesticide selected from the groups L1 ), L3) and L5), preferably selected from strains denoted above as (L.1.2), (L.1.3), (L.1.4), (L.1.5), (L.1.6), (L.1.7), (L.1.8), (L.1.10), (L.1.1 1 ), (L.1 .12), (L.1.13), (L.1.14), (L.1 .15), (L.1.17), (L.1 .18), (L.1.19), (L.1 .20), (L.1.21 ), (L.3.1 ); (L.3.9), (L.3.16), (L.3.17), (L.5.1 ), (L.5.2), (L.5.3), (L.5.4), (L.5.5), (L.5.6), (L.5.7), (L.5.8); (L.4.2), and (L.4.1 ); even more preferably selected from (L.1.2), (L.1.6), (L.1.3), (L
- mixtures comprising as pesticide II (component 2) a biopesticide selected from the groups L1 ), L3) and L5), preferably selected from strains denoted above as (L1 .1 ), (L.1 .2), (L.1 .3), (L.1 .6), (L.1 .7), (L.1.9), (L.1.1 1 ), (L.1.12), (L.1.13), (L.1 .14), (L.1.15), (L.1.17), (L.1 .18), (L.1.22), (L.1 .23), (L.1.24), (L.2.2); (L.3.2), (L.3.3), (L.3.4), (L.3.5), (L.3.6), (L.3.7), (L.3.8), (L.3.10), (L.3.1 1 ), (L.3.12), (L.3.13), (L.3.14), (L.3.15), (L.3.18), (L.3.19); (L.4.2),
- the mixtures of the invention embrace not only the isolated, pure cultures of the respective microorganisms as defined herein, but also its cell-free extract having pesticidal activity, preferably a ketone-based extract, its suspensions in a whole broth culture or as a metabolite-containing supernatant or a purified metabolite obtained from a whole broth culture of the microorganism or microorganism strain.
- Whole broth culture refers to a liquid culture containing both cells and media.
- Supernatant or “culture medium” refers to the liquid broth remaining when cells grown in broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art.
- metabolite refers to any compound, substance or byproduct (including but not limited to small molecule secondary metabolites, polyketides, fatty acid synthase products, non- ribosomal peptides, ribosomal peptides, proteins and enzymes) produced by a microorganism (such as fungi and bacteria) that has pesticidal activity or improves plant growth, water use efficiency of the plant, plant health, plant appearance, or the population of beneficial microorganisms in the soil around the plant activity.
- a microorganism such as fungi and bacteria
- mutant refers to a microorganism, obtained by direct mutant selection but also includes microorganisms that have been further mutagenized or otherwise manipulated (e. g., via the introduction of a plasmid). Accordingly, embodiments include mutants, variants, and or derivatives of the respective microorganism, both naturally occurring and artificially induced mutants. For example, mutants may be induced by subjecting the microorganism to known mutagens, such as N-methyl-nitrosoguanidine, using conventional methods. Preferably such mutants retain the pesticidal activity of the respective microorganism.
- the pesticidal mixtures of the invention comprise a component 2), which is a biopesticide II, which is selected from the groups L1 to L5 as defined above.
- a biopesticide II which is selected from the groups L1 to L5 as defined above. Preferred biopesticides II are defined hereinafter.
- biopesticides II which may be selected as component 2) of the mixtures of the invention, are to be understood as preferred on their own as well as preferably in combination with the preferred embodiments of the compounds of formula I, i.e. component 1 ) of the mixture of the invention, and, where applicable, as well as concerning the uses and methods according to the invention and the compositions according to the invention.
- biopesticide II component 2
- a biopesticide selected from group L1 preferably selected from Bacillus amyloliquefaciens herein even more preferably from strains AP-136, AP-188, AP-218, AP-219, AP-295, IN937a, IT-45; B.
- amyloliquefaciens ssp. plan tarum (formerly called B. subtilis or B. subtilis spp.
- amyloliquefaciens herein even more preferably from strains MBI600, D747, FZB24, FZB42, GB03, QST-713 and TJ1000; B. mojavensis AP-209; B. pumilus herein even more preferably from strains GHA 180, INR-7, KFP9F and QST 2808; B. simp/exhereln more preferably strain ABU 288; B. so/isa/si erein more preferably strain AP-217; B.
- subtilis herein even more preferably selected from strains CX-9060, FB17 and GB07; Muscodor albus herein more preferably strains QST 20799 and SA-13; Paenibacillus alveihereln more preferably strain NAS6G6, Paenibacillus polymyxa herein more preferably strain PKB1 , Penicillium bilaiae herein more preferably strains ATCC 22348, ATCC 20581 and ATCC 18309; Pseudomonas fluorescens herein more preferably strain A506; Sphaerodes mycoparasitica herein more preferably strain SMCD2220; Trichoderma fertile - herein more preferably strain JM41 R; Tricho- derma harzianum herein more preferably strain T-22; Trichoderma virens herein more preferably strais GI-3 and G-41.
- biopesticide II component 2
- a biopesticide selected from group L1 even more preferably selected from B. amyloliquefaciens AP-188, B. amyloliquefaciens ssp. plantarum MBI600, B. amyloliquefaciens ssp. plantarum QST-l 13, B. pumilus INR-7, B. pumilus QST 2808, B. simplex ABU 288, B. subtilis FB17, Paenibacillus alvei NAS6G6 and Trichoderma fertile JM41 R.
- the at least one biopesticide II is Bacillus amyloliquefaciens ssp. plantarum MBI600. These mixtures are particularly suitable in soybean.
- the at least one biopesticide II is B. pumilus INR-7. These mixtures are particularly suitable in soybean and corn.
- the at least one biopesticide II is Bacillus simplex, preferably B. simplex ABU 288. These mixtures are particularly suitable in soybean and corn.
- the at least one biopesticide II is Bacillus subtilis, preferably B. subtilis strain FB17.
- the at least one biopesticide II is selected from Bacillus amyloliquefaciens AP-136, B. amyloliquefaciens AP-188, B.
- amyloliquefaciens ssp. plantarum OOO B. amyloliquefaciens ssp. plantarum D747, B.
- amyloliquefaciens ssp. plantarum MBI600 B. amyloliquefaciens spp. plantarum GB03, B. amyloliquefaciens spp. plantarum QB -l ⁇ , B. mojavensis AP-209, B. pumilus GB34, B.
- pumilus ⁇ UR-7 B. pumilus KFP9F, B. pumilus QST 2808, B. pumilus GHA 180, B. simplex ABU 288, B. solisalsi AP-217 ' , /?. subt/i/s CX-9060, B. subti/is FBM and /?. subt/i/s GB07.
- These mixtures are particularly suitable in soybean and corn, in particular for seed treatment.
- the at least one pesticide II is selected from Streptomyces spp., preferably from S. griseoviridis, S. lydicus and S. violaceusniger, in particular from strains S. griseoviridis S. iydicus ⁇ NYEC 108, S. v/o/aceusn/gerXL-2 and S. v/o/aceusn/gerYCED- 9.
- the at least one biopesticide II is selected from the following fungi Coniothyrium minitans CON/M/91 -08, Trichoderma fertile
- the at least one biopesticide II is selected from Pseudo- monas spp., preferably selected from P. chloraphis herein more preferably strain MA 342 and Pseudomonas sp. DSM 13134; P. fluorescens herein more preferably selected from strains A506, WCS 374 and Pf-5; and P. put/da herein more preferably strain ATCC 202153.
- the present invention also relates to mixtures wherein the at least one biopesticide II is selected from the fungal genus Trichoderma, preferably from the strains T. aspere/lum ⁇ 34, T. asperellum SKT-1 , T. aspere/lum ICC 012, T. asperellum ⁇ W , T. a troviride LC52, T. atroviride CNCM 1-1237, T. fertile JM41 R, T. gamsii ⁇ CC 080, T. harmatum JH 382, T. harzianum T-22, T. harzianum T ' -35, T. harzianum T ' -39, T.
- T harzianum T ' -315 mixture of T. harzianum ICC012 and T. gams/I ⁇ CC080; mixture of T. polysporum and T. harzianum; T. stromaticum, T. virens GI-3, T. virens GL-21 , T. virens G-41 and; in particular T. fertile JM41 R.
- the present invention also relates to mixtures wherein the at least one biopesticide II is selected from the fungal species Muscodor a/bus preferably from the strains SA-13 and QST 20799, which are particularly suiable for soil and seed treatment against soil-borne pathogens and/or nematodes.
- biopesticide II component 2
- component 2 a biopesticide selected from group L3
- Bacillus firmus herein preferably strain 1-1582
- Beau veria bass/ana herein preferably selected from strains GHA, H123, DSM 12256 and PPRI 5339
- Burkho/deria sp. and herein preferably strain A396, Metarhizium anisop/iae var. acridum herein preferably strain IMI 330189, M.
- anisopliae herein preferably selected from strains Fl- 985, FI-1045, F52 and ICIPE 69; Paecilomyces ///acinus herein preferably selected from strains 251 , DSM 15169 and BCP2, Paenibacillus popilliae herein preferably selected from strains Dutky-1940, KLN 3 and Dutky 1 ; Pasteur/a nishazawa and herein preferably strain Pn1.
- biopesticide II component 2 a biopesticide selected from group L3, even more preferably from B. bass/ana DSM 12256, B. bass/ana PPRI 5339, Metarhizium anisop/iae var. acridum IMI 330189, M. anisopliae FI-985, M. anisopliae ⁇ - 1045, Paecilomyces ///acinus DSM 15169, P. lilacinus BCP2, P. lilacinus 251 , Paenibacillus popilliae Dutky-1940, P. popilliae KLN 3 and P. popilliae Dutky 1.
- the at least one biopesticide II is Beauveria brongniartii. According to a further embodiment, the at least one biopesticide II is Metarhizium anisopliae or M. anisopliae var. acridium, preferably selected from M. anisopliae FI-1045, M. anisopliae F52, M. anisop/iae var. acridum strains FI-985 and IMI 330189; in particular strain IMI 330189. These mixtures are particularly suitable for control of arthropod pests in soybean and corn.
- the at least one biopesticide II is Paecilomyces fumoso- roseus, preferably strain FE 9901 especially for white fly control.
- the at least one biopesticide II is selected from Nomuraea rileyi, preferably strains SA86101 , GU87401 , SR86151 , CG128 and VA9101 ; and P. lilacinus, preferably strains 251 , DSM 15169 or BCP2, in particular BCP2, which strains especially control the growth of plant-pathogenic nematodes.
- the at least one biopesticide II is Bacillus firmus, preferably spores of strain CNCM 1-1582, preferably useful for seed treatment of cereals, soybean, cotton, sugarbeets and corn against nematodes and insects.
- the at least one biopesticide II is Pasteuria nishizawae, preferably spores of strain Pn1 , preferably useful for seed treatment of cereals, soybean, cotton, sugarbeets and corn against nematodes and insects.
- the at least one biopesticide II is Flavobacterium sp., preferably spores of strain H492, preferably useful for seed treatment of cereals, soybean, cotton, sugarbeets and corn against nematodes and insects.
- the at least one biopesticide II is Bacillus cereus, preferably spores of CNCM 1-1562, preferably useful for seed treatment of soybean, cotton, cereals, and corn against nematodes and insects.
- the at least one biopesticide II is Burkho/deria sp., preferably strain A396, preferably useful for seed treatment of soybean, cotton, cereals, and corn.
- the at least one biopesticide II is Paecilomyces lilacinus 251 , preferably useful for seed treatment of soybean, cotton, cereals, and corn.
- the at least one biopesticide II is a mixture of spores of B. firmus and B. cereus, preferably mixtures spores of above mentioned strains CNCM 1-1582 and CNCM 1-1562, preferably useful for seed treatment of soybean, cotton, cereals, and corn against nematodes and insects.
- the at least one pesticide II is selected from Bacillus firmus CNCM 1-1582, Paecilomyces lilacinus 251 , Pasteuria nishizawa Pn1 and Burkholderia sp. A396 having nematicidal, acaricidal and/or insecticidal activity. These mixtures are particularly suitable in soybean, cotton, cereals, and corn, in particular for seed treatment.
- biopesticide II component 2
- component 2 a biopesticide selected from group L4
- methyl jasmonate preferably methyl jasmonate
- biopesticide II component 2
- a biopesticide selected from group L5 preferably selected from A. lipoferum, A. irakense, A. halopraeferens, Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseoli, R. I. bv. trifolii, R. I. bv. viciae, and Sinorhizobium meliloti.
- biopesticide II component 2
- a biopesticide selected from group L5 selected from B. Japonicum l " A-1 1 , Paenibacillus alvei NAS6G6, Peniciillium bilaiae strains ATCC 18309, ATCC 20851 and ATCC 22348; Rhizobium leguminosarum by . phaseoli ' RG-B10, R. I. bv. viciae PM ⁇ P3Cst, R. I. bv. viciae R G -P2, R. I. bv. trifolii RP 1 13-7, R. I. bv. w ' c/ae SU303, R. I.
- the present invention also relates to mixtures, wherein the at least one biopesticide II is selected from A. lipoferum, A. irakense and A. halopraeferens, These mixtures are particularly suitable in soybean, especially as seed treatment.
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from Azospirillum lipoferum, Azospirillum irakense, Azospirillum halopraeferens, Bradyrhizobium spp., Bradyrhizobium sp. (Arachis), Bradyrhizobium sp. (Vigna),
- Bradyrhizobium liaoningense Bradyrhizobium lupini, Dei ft/a acidovorans, Glomus intraradices, Mesorhizobium sp., Mesorhizobium ciceri, Mesorhizobium huakii, Mesorhizobium lot/,
- Rhizobium leguminosarum bv. phaseoli Rhizobium leguminosarum bv. trifolii
- Rhizobium leguminosarum bv. viciae Rhizobium leguminosarum bv. viciae
- Sinorhizobium meliloti Bacillus altitudinis, Bacillus
- amyloliquefaciens Bacillus amyloliquefaciens ssp. plantarum, Bacillus firmus, Bacillus megaterium, Bacillus mojavensis, Bacillus mycoides, Bacillus pumilus, Bacillus simplex, Bacillus solisalsi, Bacillus subtilis, Burkho/der/a sp., Coniothyrium minitans, Paecilomyces niacin us, Paenibacillus alvei, Paenibacillus polymyxa, Paenibacillus popilliae, Pasteur/a nishizawae, Pasteur/a usgae, Penicillium bilaiae, Pseudomonas chloraphis, Pseudomonas fluorescens, Pseudomonas put/da, abscisic acid, harpin protein (alpha-beta), jasmonic acid or salts
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from Bradyrhizobium sp. (Arachis) CB1015, Bradyrhizobium sp. (Arachis) SEMIA 6144, Bradyrhizobium sp. (Arachis) SEMIA 6462, Bradyrhizobium sp. (Arachis) SEMIA 6464, Bradyrhizobium sp. (Vigna) PNL1 , Mesorhizobium sp. WSM1497, Rhizobium
- Rhizobium leguminosarum by. phaseoli ' RG-B10 Rhizobium leguminosarum by. trifolii ⁇ 95, Rhizobium leguminosarum bv. trifolii CB782, Rhizobium leguminosarum bv. trifolii ' CC1099, Rhizobium leguminosarum bv. trifolii CC275e, Rhizobium leguminosarum bv. trifolii CC283b, Rhizobium leguminosarum bv. trifolii RP1 13-7, Rhizobium leguminosarum bv. trifolii PA , Rhizobium leguminosarum bv. /frfo//// WSM1325, Rhizobium leguminosarum bv. / ⁇ /%?//// WSM2304,
- Rhizobium leguminosarum bv. P1 NP3Cst also referred to as 1435, Rhizobium
- leguminosarum bv. i /c?/#e RG-P2 also called P2
- Rhizobium leguminosarum bv. i /c?/#e SU303 Rhizobium leguminosarum bv. WSM1455, Sinorhizobium meliloti NRG185,
- Sinorhizobium meliloti also called 201 1 or SU47, Sinorhizobium meliloti, RRI 128, Bacillus altitudinis 41 KF2b, Bacillus amyloliquefaciens AP-136, Bacillus amyloliquefaciens AP- 188 , Bacillus amyloliquefaciens AP-218 , Bacillus amyloliquefaciens AP-219 , Bacillus amyloliquefaciens AP-295, Bacillus amyloliquefaciens ssp. plantarum D747, Bacillus amyloliquefaciens ssp.
- plantarum FZB24 also called SB3651 , Bacillus amyloliquefaciens ssp. plantarum FZB42, Bacillus amyloliquefaciens ssp. plantarum GB03 also called GB03 formerly z5. subtilis, Bacillus amyloliquefaciens ssp. plantarum MBI600 also referred to as 1430, formerly z5. subtilis, Bacillus amyloliquefaciens ssp. plantarum QST " -713, formerly z5. subtilis, Bacillus amyloliquefaciens ssp.
- plantarum OOO also called 1 BE
- Bacillus firmus CNCM 1-1582 Bacillus megaterium H491 , Bacillus megaterium J 142, Bacillus megaterium M018, Bacillus mojavensis AP-209, Bacillus mojavensis SR1 1 , Bacillus mycoides AQ726, Bacillus mycoides J also called BmJ, Bacillus pumilus GB34, Bacillus pumilus GHA 180, Bacillus pumilus ⁇ NR-7 otherwise referred to as BU F22 and BU-F33, Bacillus pumilus KFP9F, Bacillus pumilus OB 2808, Bacillus simplex ABU 288, Bacillus subtilis CX-9060, Bacillus subtilis FB17 ' , Bacillus subtilis GB07 , Burkho/der/a sp.
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from
- Microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. megaterium, B. mojavensis, B. mycoides, B. pumilus,
- activator activity harpin protein, Reynoutria sachalinensis extract
- Agrobacterium radiobacter Bacillus cereus, B. firm us, Burkho/der/a sp.,
- Chromobacter/um subtsugae Flavobacterium sp., Paecilomyces fumosoroseus, P.
- nematicidal activity cis-jasmone, methyl jasmonate, jasmonic acid or salts or derivatives thereof;
- Microbial pesticides with plant stress reducing, plant growth regulator, plant growth promoting and/or yield enhancing activity A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp., B. liaoningense, B. lupini, Delftia acidovorans, Glomus intraradices, Mesorhizobium sp., Rhizobium leguminosarum bv. phaseoli, R. I. bv. trifolii, R. I. bv. viciae, Sinorhizobium meliloti.
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from the group L1 , i.e. microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyioiiquefaciens, B. megaterium, B.
- group L1 i.e. microbial pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyioiiquefaciens, B. megaterium, B.
- amyioiiquefaciens Candida oleophila, C saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum, C/onostachys rosea catenulate (also named Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L.
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from Bacillus amyioiiquefaciens, Bacillus pumilus, Bacillus simplex, and Bacillus subtilis, in particular from the strains Bacillus amyioiiquefaciens MBI600, B.
- the biopesticide II of the mixtures of the invention is Bacillus pumilus, preferably spores of strain INR-7.
- the biopesticide II of the mixtures of the invention is Bacillus simplex, preferably spores of strain ABU 288.
- the biopesticide II of the mixtures of the invention is Bacillus subtilis, preferably spores of strain FB17.
- component 2) i.e. the biopesticide II, of the mixture of the invention is Penicillium steckii, preferably Penicillium steckii strain IBWF104-06 as deposited with DSMZ under the deposit number DSM 27859. Strain IBWF104-06 was determined to have potent antifungal activity, in particular, against infestion with plant pathogens including
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from the group L2, i.e. biochemical pesticides with fungicidal, bactericidal, viricidal and/or plant defense activator activity: harpin protein, Reynoutria sachalinensis extract.
- the biopesticide II of the mixture of the invention is harpin protein (alpha-beta).
- component 2), i.e. the biopesticide II, of the mixtures of the invention is selected from the group L4, i.e. biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and/or nematicidal activity: cis-jasmone, methyl jasmonate, jasmonic acid or salts or derivatives thereof.
- the biopesticide II of the mixtures of the invention is cis-jasmone.
- the biopesticide II of the mixture of the invention is methyl jasmonate.
- the biopesticide II of the mixture of the invention is jasmonic acid or a salt or derivative thereof.
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from the group L3, i.e. microbial pesticides with insecticidal, acaricidal, molluscidal and/or nematicidal activity: Agrobacterium radiobacter, Bacillus cereus, B. firmus, Burkholderia sp., Chromobacterium subtsugae, Flavobacterium sp., Paeciiomyces
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from Bacillus firmus, Pasteur/a nishazawa sp. , Flavobacterium sp., Paeciiomyces Iiiacinus, and Burkholderia sp, in particular from the strains Burkholderia sp. A396, Paeciiomyces Iiiacinus 251 , Bacillus firmus CNCM 1-1582, Pasteur/a nishizawae - Pn1 , and Flavobacterium sp. H492.
- component 2) i.e. the biopesticide II, of the mixtures of the invention is selected from Bacillus firmus, Pasteur/a nishizawa, and Flavobacterium sp., in particular from the strains Bacillus firmus CNCM 1-1582, Pasteur/a nishizawae - Pn1 , and Flavobacterium sp. H492.
- the biopesticide II of the mixtures of the invention is Bacillus cereus, preferably spores of strain CNCM 1-1562.
- the biopesticide II of the mixtures of the invention is Burkholderia sp., preferably strain A396.
- the biopesticide II of the mixtures of the invention is Paeciiomyces Iiiacinus, preferably strain 251 , DSM 15169 or BCP2, particularly preferably strain 251.
- the compound I is preferably combined with biopesticides II having a nematicidal activity.
- the biopesticide II of the mixtures of the invention is Bacillus firmus, preferably spores of strain CNCM 1-1582; e.g. VOTiVO® from Bayer CropScience LP, USA, which is suitable for nematode control.
- the biopesticide II of the mixtures of the invention is Pasteur/a nishizawae, preferably spores of strain Pn1 , e.g. Clariva® PN from Syngenta Crop Protection, LLC, USA, which is suitable for nematode control.
- the biopesticide II of the mixtures of the invention is Flavobacterium sp., preferably spores of strain H492, e.g. MBI-302 from Marrone Bio Innovations, USA, which is suitable for nematode control.
- biopesticides II may be selected from the following biopesticides 11-1 to 11-14 in accordance with each row of table II, of which biopesticides 11-12, Ills, and 11-14 are particularly preferred.
- particularly preferred strains of biopesticides II may be selected from the following biopesticide strains lla-1 to lla-1 1 in accordance with each row of table lla, of which the biopesticide strains lla-9, lla-10, and lla-1 1 are particularly preferred.
- the mixtures A-1 to A-14 as presented in table A represents binary mixtures according to the present invention.
- the mixtures B-1 to B-1 1 as presented in table B represents binary mixtures according to the present invention.
- the solid material (dry matter) of the biopesticides (with the exception of oils such as Neem oil) are considered as active components (e. g. to be obtained after drying or evaporation of the extraction or suspension medium in case of liquid formulations of the microbial pesticides).
- the weight ratios and percentages used herein for a biological extract such as Quillay extract are based on the total weight of the dry content (solid material) of the respective extract(s).
- the total weight ratios of compositions comprising at least one microbial pesticide in the form of viable microbial cells including dormant forms can be determined using the amount of CFU of the respective microorganism to calclulate the total weight of the respective active component with the following equation that 1 x 10 10 CFU equals one gram of total weight of the respective active component.
- Colony forming unit is measure of viable microbial cells, in particular fungal and bacterial cells.
- CFU may also be understood as the number of (juvenile) individual nematodes in case of (entomopathogenic) nematode biopesticides, such as
- component 1 preferably compound i of formula I, and component 2) of the mixtures of the invention are present in synergistically effective amounts.
- component 1 preferably compound i of formula I, and component 2) of the mixtures of the invention are present in a total weight ratio of from 100:1 to 1 :100, wherein the total weight of component 2) is based on the amount of the solid material (dry mater) of component 2).
- the weight ratio of the component 1 generally depends from the properties of the active components used, usually it is in the range of from 1 :10,000 to 10,000:1 , often it is in the range of from 1 :100 to 100:1 , regularly in the range of from 1 :50 to 50:1, preferably in the range of from 1:20 to 20:1, more preferably in the range of from 1:10 to 10:1, even more preferably in the range of from 1:4 to 4:1 and in particular in the range of from 1:2 to 2:1.
- the weight ratio of the component 1), preferably compound i of formula I, and the component 2) usually is in the range of from 1000:1 to 1:1, often in the range of from 100: 1 to 1:1, regularly in the range of from 50:1 to 1:1, preferably in the range of from 20:1 to 1:1, more preferably in the range of from 10:1 to 1:1, even more preferably in the range of from 4:1 to 1:1 and in particular in the range of from 2:1 to 1:1.
- the weight ratio of the component 1) preferably compound i of formula I, and the component 2) usually is in the range of from 20,000:1 to 1:10, often in the range of from 10,000:1 to 1:1, regularly in the range of from 5,000:1 to 5:1, preferably in the range of from 5,000:1 to 10:1, more preferably in the range of from 2,000:1 to 30:1, even more preferably in the range of from 2,000:1 to 100:1 and in particular in the range of from 1,000:1 to 100:1.
- the weight ratio of the component 1) preferably compound i of formula I, and the component 2) usually is in the range of from 1:1 to 1:1000, often in the range of from 1:1 to 1:100, regularly in the range of from 1:1 to 1:50, preferably in the range of from 1:1 to 1:20, more preferably in the range of from 1:1 to 1:10, even more preferably in the range of from 1:1 to 1:4 and in particular in the range of from 1:1 to 1:2.
- the weight ratio of the component 1) usually is in the range of from 10:1 to 1:20,000, often in the range of from 1:1 to 1:10,000, regularly in the range of from 1:5 to 1:5,000, preferably in the range of from 1:10 to 1:5,000, more preferably in the range of from 1:30 to 1:2,000, even more preferably in the range of from 1:100 to 1:2,000 to and in particular in the range of from 1:100 to 1:1,000.
- the weight ratio of component 1) , preferably compound i of formula I, and component 2) depends from the properties of the active substances used, usually it is in the range of from 1:100 to 100:1, regularly in the range of from 1:50 to 50:1, preferably in the range of from 1:20 to 20:1, more preferably in the range of from 1:10 to 10:1 and in particular in the range of from 1 :4 to 4:1 , and the weight ratio of component 1) , preferably compound i of formula I, and component 3) usually it is in the range of from 1:100 to 100:1, regularly in the range of from 1:50 to 50:1, preferably in the range of from 1:20 to 20:1, more preferably in the range of from 1:10 to 10:1 and in particular in the range of from 1:4 to 4:1.
- any further active components are, if desired, added in a ratio of from 20:1 to 1 :20 to the component 1) , preferably compound i of formula I.
- the application rates preferably range from about 1 x 10 6 to 5 x 10 15 (or more) CFU/ha, preferably from about 1 x 10 8 to about 1 x 10 13 CFU/ha, and even more preferably from about 1 x 10 9 to about 1 x 10 12 CFU/ha.
- the application rates preferably range inform about 1 x 10 5 to 1 x 10 12 (or more), more preferably from 1 x 10 8 to 1 x 10 11 , even more preferably from 5 x 10 8 to 1 x 10 10 individuals (e. g. in the form of eggs, juvenile or any other live stages, preferably in an infetive juvenile stage) per ha.
- the application rates with respect to plant propagation material preferably range from about 1 x 10 6 to 1 x 10 12 (or more) CFU/seed.
- the concentration is about 1 x 10 6 to about 1 x 10 9 CFU/seed.
- the application rates with respect to plant propagation material also preferably range from about 1 x 10 7 to 1 x 10 14 (or more) CFU per 100 kg of seed, preferably from 1 x 10 9 to about 1 x 10 12 CFU per 100 kg of seed.
- the mixtures of the invention in particular the mixtures A-1 to A-14 or B-1 to B-1 1 , further comprise as active component 3) a further active compound III, which is selected from insecticides or fungicides.
- the insecticides which are hereinafter described by common names, are commercially available and may be found in The Pesticide Manual, 16th Edition, C. MacBean, British Crop Protection Council (2013) among other publications.
- the online Pesticide Manual is updated regularly and is accessible through http://bcpcdata.com/pesticide-manual.html.
- Another online data base for pesticides providing the ISO common names is
- fungicides which are hereinafter described by common names, are commercially available and may be found in the database http://www.alanwood.net/pesticides.
- the mixtures of the invention further comprise as active component 3) a further active compound III, which is an insecticide, wherein said insecticide is selected from the group consisting of fipronil, clothianidin, thiamethoxam, acetamiprid, dinotefuran, imidacloprid, thiacloprid, sulfoxaflor, methiocarb, tefluthrin, bifenthrin, cypermethrin, alphacypermethrin, spinosad, cyantraniliprole, chlorantraniliprole, triflumezopyrim, flupyradifurone, abamectin, thiodicarb, tetraniliprole and tioxazafen.
- insecticide is selected from the group consisting of fipronil, clothianidin, thiamethoxam, acetamiprid, dinotefuran, imidacloprid, thi
- the mixtures of the invention further comprise as active component 3) a further active compound III, which is a fungicide, wherein said fungicide is selected from the group consisting of azoxstrobin, trifloxystrobin, picoxystrobin, pyraclostrobin, sedaxane, penthiopyrad, penflufen, fluopyram, fluxapyroxad, boscalid, oxathiapiprolin, metalaxyl, metalaxyl-M, ethaboxam, dimethomorph, cyproconazole, difenoconazole, prothioconazole, flutriafol, thiabendazole, ipconazole, tebuconazole, triadimenol, prochloraz, fluquinconazole, triticonazole, fludioxonil, carboxin, silthiofarm, ziram, thiram, carbendazim,
- the active compound III is an insecticide
- said insecticide is preferably selected from the insecticides as defined in the following table Ilia.
- the insecticides as listed in table Ilia are in the following referred to as insecticides llla-1 to llla-22.
- the active compound III is a fungicide
- said fungicide is preferably selected from the fungicides as defined in the following table 1Mb.
- the fungicides as listed in table 1Mb are in the following referred to as fungicides lllb-1 to lllb-36.
- the present invention relates to ternary mixtures, which comprise at least the carboxamide compound of formula I as component 1 ) , preferably compound i of formula I, and at least one biopesticide II, which is preferably selected from the biopesticides II-
- At least one further active compound III which may be preferably selected from the insecticides llla-1 to llla-22 or the fungicides lllb-1 to lllb-36.
- Such mixtures are preferably ternary mixture comprising the carboxamide compound of formula I as component 1 ) , preferably compound i of formula I,, and one biopesticide II, which is selected from the biopesticides 11-1 to 11-14, in particular from the biopesticide strains lla-1 to lla-1 1 , and one further active compound III, which may be selected from the insecticides llla-1 to llla-22.
- Such mixtures are preferably ternary mixture comprising the carboxamide compound of formula I as component 1 ) , preferably compound i of formula I, and one biopesticide II, which is selected from the biopesticides 11-1 to 11-14, in particular from the biopesticide strains lla-1 to lla- 1 1 , and one further active compound III, which may be selected from the fungicides lllb-1 to lllb- 36.
- the present invention relates to ternary mixtures, which comprise at least the carboxamide compound of formula I as component 1 ) , preferably compound i of formula I, and
- At least one further nematicidal active compound III preferably selected from abamectin or tioxazafen.
- the nematicidal mixtures may comprise the carboxamide compound of formula I as component 1 ) , preferably compound i of formula I, combined with one biopesticide II with nematicidal activity or, alternatively, with a non-biopesticide with nematicidal activity, such as abamectin or tioxazafen.
- the carboxamide compound of formula I may be combined with abamectin, independently of the presence of a biopestide.
- the carboxamide compound of formula I may be combined with tioxazafen, independently of the presence of a biopestide.
- the binary nematicidal mixture may comprise the carboxamide compound of formula I and tioxazafen.
- binary nematicidal mixture may comprise the carboxamide compound of formula I and abamectin.
- Pesticidal mixtures which comprise carboxamide compound of formual I as component 1 ) , preferably compound i of formula I, and in which the combination of components 2) and 3) corresponds in each case to the combination of a biopesticide I I or biopesticide strain lla with an active compound III according to one row of Table M said pesticidal mixtures being referred to as pesticidal mixtures l-M-1 to l-M-1453
- Agricultural compositions in a further embodiment, relates to agricultural compositions comprising a mixture of the invention, in particular any one of the mixtures A-1 to A-14 or B-1 to B-1 1 or I- M-1 to l-M-1453.
- the user applies the composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
- the agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
- 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
- individual components of the composition according to the invention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank or any other kind of vessel used for applications (e. g. seed treater drums, seed pelleting machinery, knapsack sprayer) and further auxiliaries may be added, if appropriate.
- a spray tank or any other kind of vessel used for applications e. g. seed treater drums, seed pelleting machinery, knapsack sprayer
- auxiliaries e.g. seed treater drums, seed pelleting machinery, knapsack sprayer
- one embodiment of the invention is a kit for preparing a usable pesticidal composition, the kit comprising a) a composition comprising component 1 ) , preferably compound i of formula I as defined herein and at least one auxiliary; and b) a composition comprising component 2) as defined herein and at least one auxiliary; and optionally c) a composition comprising at least one auxiliary and optionally a further active component 3) as defined herein.
- the present invention relates to a seed treatment composition
- a seed treatment composition comprising an auxiliary and a mixture of the invention, preferably any one of the mixtures A-1 to A-14 or B-1 to B-1 1 or l-M-1 to l-M-1453, wherein the auxiliary is preferably selected from the group consisting of surfactants, antifreezing agents, binders, and pigments, and is particularly preferably a surfactant or a binder.
- the seed treatment composition is in the form of a flowable concentrate FS, a solution LS, a powder for dry treatment DS, a water dispersible powder for slurry treatment WS, a water-soluble powder SS, an emulsion ES or EC, or a gel formulation, and is preferably in the form of a flowable concentrate.
- the present invention relates to the use of a mixture of the invention, in particular a mixture selected from the mixtures A-1 to A-14 or B-1 to B-1 1 or l-M-1 to l-M-1453, or a seed treatment composition as defined above, for protecting a plant, plant propagation material, or soil or water, in which the plants are growing, against the attack or infestation by invertebrate pests.
- the present invention relates to a method for controlling invertebrate pests, which method comprises contacting the plant or the plant propagation material or the soil; the pests or their food supply, habitat or breeding grounds, with a pesticidally effective amount of a mixture of the invention, in particular a mixture selected from the mixtures A-1 to A-14 or B- 1 to B-1 1 , or a seed treatment composition as defined above.
- the present invention relates to seeds comprising the mixture of the invention, in particular a mixture selected from the mixtures A-1 to A-14 or B-1 to B-1 1 or l-M-1 to l-M-1453, or a seed treatment composition as defined above in an amount of from 0.01 g to 10000 g per 100 kg of seeds.
- the amount per 100 kg seeds is based on the weight of the pesticidal mixture irrespective of whether it is referred to the mixture as such or the seed treatment composition thereof.
- Preferred seeds are seeds selected from wheat, maize, barley, oat, rye, rice, soybean, cotton, sugarbeet, rapeseed, and potato. With regard to all the mixtures of the invention as defined herein, the following embodiments are additionally preferred. Additional mixing partners
- the mixtures of the present invention may be combined and applied in agriculture in mixture with other active ingredients, for example with other pesticides, insecticides, nematicides, fungicides, herbicides, safeners, fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators.
- active ingredients for example with other pesticides, insecticides, nematicides, fungicides, herbicides, safeners, fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators.
- the invention also relates to agrochemical compositions comprising an auxiliary and at least one mixture of the present invention.
- An agrochemical composition comprises a pesticidally effective amount of a mixture of the present invention.
- the term "pesticidally effective amount" is defined below.
- compositions of the present invention can be converted into customary types of agro-chemical compositions, e. g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof.
- composition types are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wettable powders or dusts (e.g. WP, SP, WS, DP, DS), pressings (e.g.
- compositions types are defined in the "Catalogue of pesticide formulation types and international coding system", Technical Mono-graph No. 2, 6th Ed. May 2008, CropLife International.
- compositions are prepared in a known manner, such as described by Mollet and Grube- mann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.
- auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protec- tive colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifi- ers and binders.
- suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protec- tive colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifi- ers and binders.
- Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions of medium to high boiling point, e.g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g. ethanol, propanol, butanol, benzylalcohol, cyclo-'hexanol; glycols; DMSO; ketones, e.g. cyclohexanone; esters, e.g.
- mineral oil fractions of medium to high boiling point e.g. kerosene, diesel oil
- oils of vegetable or animal origin oils of vegetable or animal origin
- aliphatic, cyclic and aromatic hydrocarbons e. g. toluene, paraffin, tetrahydronaphthalene, alky
- lactates carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.
- Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharide powders, e.g. cellulose, starch;
- fertilizers e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas
- products of vegetable origin e.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.
- Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emusifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon's, Vol.1 : Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).
- Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof.
- sulfonates are alkylaryl- sulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkyhnaphthalenes, sulfosuccinates or sulfosuccinamates.
- Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethox- ylated alcohols, or of fatty acid esters.
- Examples of phosphates are phosphate esters.
- Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol eth- oxylates.
- Suitable nonionic surfactants are alkoxylates, N-subsituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof.
- alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents.
- Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide.
- N-subsititued fatty acid amides are fatty acid glucamides or fatty acid alkanolamides.
- esters are fatty acid esters, glycerol esters or monoglycerides.
- sugar- based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkylpolyglucosides.
- polymeric surfactants are homo- or copolymers of
- Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.
- Suitable amphoteric surfactants are alkylbetains and imidazolines.
- Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide.
- Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.
- Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the mixtures of the present invention on the target.
- examples are surfactants, mineral or vegetable oils, and other auxilaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.
- Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), anorganic clays (organically modified or unmodified), polycarboxylates, and silicates.
- Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazoli- nones and benzisothiazolinones.
- Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
- Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.
- Suitable colorants are pigments of low water solubility and water- soluble dyes.
- examples are inorganic colorants (e.g. iron oxide, titan oxide, iron hexacyanofer- rate) and organic colorants (e.g. alizarin-, azo- and phthalocyanine colorants).
- Suitable tackifiers or binders are polyvinylpyrrolidone, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers. Examples for composition types and their preparation are:
- 10-60 wt% of the mixture according to the invention and 5-15 wt% wetting agent e.g. alcohol alkoxylates
- a wetting agent e.g. alcohol alkoxylates
- the active substance dissolves upon dilution with water.
- dispersant e.g. polyvinylpyrrolidone
- organic solvent e.g. cyclohexanone
- Emulsions (EW, EO, ES)
- emulsifiers e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate
- 20-40 wt% water-insoluble organic solvent e.g. aromatic hydrocarbon
- 20-60 wt% of the mixture according to the invention are comminuted with addition of 2-10 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate), 0,1 -2 wt% thickener (e.g. xanthan gum) and up to 100 wt% water to give a fine active substance suspension. Dilution with water gives a stable suspension of the active sub-stance.
- dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
- 0,1 -2 wt% thickener e.g. xanthan gum
- 50-80 wt% of the mixture according to the invention are ground finely with addition of up to 100 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate) and prepared as water-dispersible or water-soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.
- dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
- 50-80 wt% of the mixture according to the invention are ground in a rotor-stator mill with addition of 1-5 wt% dispersants (e.g. sodium lignosulfonate), 1 -3 wt% wetting agents (e.g. alcohol ethoxylate) and up to 100 wt% solid carrier, e.g. silica gel. Dilution with water gives a stable dispersion or solution of the active substance.
- dispersants e.g. sodium lignosulfonate
- 1 -3 wt% wetting agents e.g. alcohol ethoxylate
- solid carrier e.g. silica gel
- wt% of the mixture according to the invention are comminuted with addition of 3-10 wt% dispersants (e.g. sodium lignosulfonate), 1 -5 wt% thickener (e.g. car- boxymethylcellulose) and up to 100 wt% water to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance.
- dispersants e.g. sodium lignosulfonate
- 1 -5 wt% thickener e.g. car- boxymethylcellulose
- 5-20 wt% of the mixture according to the invention are added to 5-30 wt% organic solvent blend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt% surfactant blend (e.g. alkohol ethoxylate and arylphenol ethoxylate), and water up to 100 %.
- organic solvent blend e.g. fatty acid dimethylamide and cyclohexanone
- surfactant blend e.g. alkohol ethoxylate and arylphenol ethoxylate
- An oil phase comprising 5-50 wt% of the mixture according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), 2-15 wt% acrylic monomers (e.g.
- methylmethacrylate, methacrylic acid and a di- or triacrylate are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.
- a protective colloid e.g. polyvinyl alcohol
- an oil phase comprising 5-50 wt% of the mixture according to the invention, 0-40 wt% water insolu-ble organic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer (e.g. diphenylme- thene-4,4'-diisocyanatae) are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol).
- a polyamine e.g. hexamethylenediamine
- the monomers amount to 1-10 wt%.
- Dustable powders (DP, DS)
- 1-10 wt% of a the mixture according to the invention are ground finely and mixed intimately with up to 100 wt% solid carrier, e.g. finely divided kaolin.
- 0.5-30 wt% of the mixture according to the invention is ground finely and associated with up to 100 wt% solid carrier (e.g. silicate).
- Granulation is achieved by extrusion, spray-drying or the fluidized bed.
- compositions types i) to xi) may optionally comprise further auxiliaries, such as 0.1-1 wt% bactericides, 5-15 wt% anti-freezing agents, 0.1 -1 wt% anti-foaming agents, and 0.1 -1 wt% colorants.
- the agrochemical compositions generally comprise between 0.01 and 95%, preferably be- tween 0.1 and 90%, and most preferably between 0.5 and 75%, by weight of active substance.
- the active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
- oils, wetters, adjuvants, fertilizer, or micronutrients, and other pesticides may be added to the active substances or the compositions cormprising them as premix or, if appropriate not until immediately prior to use (tank mix).
- pesticides e.g. herbicides, insecticides, fungicides, growth regulators, safeners
- These agents can be admixed with the compositions according to the invention in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.
- the user applies the composition according to the invention usually from a predosage de-vice, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
- the agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
- 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
- composition according to the invention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate.
- either individual components of the composition according to the invention or partially premixed components, e.g. components comprising mixtures of the present invention, may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate.
- either individual components of the composition according to the invention or partially premixed components, e. g. components comprising mixtures of the present invention, can be applied jointly (e.g. after tank mix) or consecutively.
- the mixtures of the present invention are suitable for use in protecting crops, plants, plant propagation materials, such as seeds, or soil or water, in which the plants are growing, from attack or infestation by animal pests. Therefore, the present invention also relates to a plant protection method, which comprises contacting crops, plants, plant propagation materials, such as seeds, or soil or water, in which the plants are growing, to be protected from attack or infestation by animal pests, with a pesticidally effective amount of a mixture of the present invention.
- the mixtures of the present invention are also suitable for use in combating or controlling animal pests. Therefore, the present invention also relates to a method of combating or controlling animal pests, which comprises contacting the animal pests, their habitat, breeding ground, or food supply, or the crops, plants, plant propagation materials, such as seeds, or soil, or the area, material or environment in which the animal pests are growing or may grow, with a pesticidally effective amount of a mixture of the present invention.
- the mixtures of the present invention are effective through both contact and ingestion.
- mixtures of the present invention can be applied to any and all developmental stages, such as egg, larva, pupa, and adult.
- mixtures of the present invention can be applied as such or in form of compositions comprising them as defined above. Furthermore, the mixtures of the present invention can be applied together with a mixing partner as defined above or in form of compositions comprising said mixtures as defined above. The components of said mixture can be applied
- the application can be carried out both before and after the infestation of the crops, plants, plant propagation materials, such as seeds, soil, or the area, material or environment by the pests.
- Suitable application methods include inter alia soil treatment, seed treatment, in furrow application, and foliar application.
- Soil treatment methods include drenching the soil, drip irrigation (drip application onto the soil), dipping roots, tubers or bulbs, or soil injection.
- Seed treatment techniques include seed dressing, seed coating, seed dusting, seed soaking, and seed pelleting.
- furrow applications typically include the steps of making a furrow in cultivated land, seeding the furrow with seeds, applying the pesticidally active mixture to the furrow, and closing the furrow.
- Foliar application refers to the application of the pesticidally active mixture to plant foliage, e.g. through spray equipment.
- pheromones for specific crops and pests are known to a skilled person and publicly available from databases of pheromones and semiochemicals, such as http://www.pherobase.com.
- contacting includes both direct contact (applying the
- mixtures/compositions directly on the animal pest or plant typically to the foliage, stem or roots of the plant
- indirect contact applying the mixtures/compositions to the locus, i.e. habitat, breeding ground, plant, seed, soil, area, material or environment in which a pest is growing or may grow, of the animal pest or plant).
- animal pest includes arthropods, gastropods, and nematodes.
- Preferred animal pests according to the invention are arthropods, preferably insects and arachnids, in particular insects.
- Insects, which are of particular relevance for crops, are typically referred to as crop insect pests.
- crop refers to both, growing and harvested crops.
- plant includes cereals, e.g. durum and other wheat, rye, barley, triticale, oats, rice, or maize (fodder maize and sugar maize / sweet and field corn); beet, e.g. sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, e.g.
- iceberg lettuce chicory, cabbage, asparagus, cabbages, carrots, onions, garlic, leeks, tomatoes, potatoes, cucurbits or sweet peppers; lauraceous plants, such as avocados, cinnamon or camphor; energy and raw material plants, such as corn, soybean, rapeseed, sugar cane or oil palm; tobacco; nuts, e.g. walnuts; pistachios; coffee; tea; bananas; vines (table grapes and grape juice grape vines); hop; sweet leaf (also called Stevia); natural rubber plants or ornamental and forestry plants, such as flowers (e.g. carnation, petunias,
- geranium/pelargoniums pansies and impatiens
- shrubs broad-leaved trees (e.g. poplar) or evergreens, e.g. conifers; eucalyptus; turf; lawn; grass such as grass for animal feed or ornamental uses.
- Preferred plants include potatoes sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rapeseed, legumes, sunflowers, coffee or sugar cane; fruits; vines; ornamentals; or vegetables, such as cucumbers, tomatoes, beans or squashes.
- plant is to be understood as including wild type plants and plants, which have been modified by either conventional breeding, or mutagenesis or genetic engineering, or by a combination thereof.
- Plants which have been modified by mutagenesis or genetic engineering, and are of particular commercial importance, include alfalfa, rapeseed (e.g. oilseed rape), bean, carnation, chicory, cotton, eggplant, eucalyptus, flax, lentil, maize, melon, papaya, petunia, plum, poplar, potato, rice, soybean, squash, sugar beet, sugarcane, sunflower, sweet pepper, tobacco, tomato, and cereals (e.g. wheat), in particular maize, soybean, cotton, wheat, and rice.
- rapeseed e.g. oilseed rape
- the one or more mutagenized or integrated genes are preferably selected from pat, epsps, crylAb, bar, cryl Fa2, cry1 Ac, cry34Ab1 , cry35AB1 , cry3A, cryF, cry1 F, mcry3a, cry2Ab2, cry3Bb1 , cry1A.105, dfr, barnase, vip3Aa20, barstar, als, bxn, bp40, asnl , and ppo5.
- the mutagenesis or integration of the one or more genes is performed in order to improve certain properties of the plant.
- Such properties include abiotic stress tolerance, altered growth/yield, disease resistance, herbicide tolerance, insect resistance, modified product quality, and pollination control.
- herbicide tolerance e.g. imidazolinone tolerance, glyphosate tolerance, or glufosinate tolerance
- mutagenesis Several plants have been rendered tolerant to herbicides by mutagenesis, for example Clearfield® oilseed rape being tolerant to
- imidazolinones e.g. imazamox.
- genetic engineering methods have been used to render plants, such as soybean, cotton, corn, beets and oil seed rape, tolerant to herbicides, such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady® (glyphosate) and LibertyLink® (glufosinate).
- herbicides such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady® (glyphosate) and LibertyLink® (glufosinate).
- glyphosate and glufosinate some of which are commercially available under the trade names RoundupReady® (glyphosate) and LibertyLink® (glufosinate).
- insect resistance is of importance, in particular lepidopteran insect resistance and coleopteran insect resistance.
- Insect resistance is typically achieved by modifying plants by integrating cry and/or vip genes, which were
- Plants may be modified by mutagenesis or genetic engineering either in terms of one property (singular traits) or in terms of a combination of properties (stacked traits). Stacked traits, e.g. the combination of herbicide tolerance and insect resistance, are of increasing importance.
- plant propagation material refers to all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e.g. potatoes), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants. Seedlings and young plants, which are to be transplanted after germination or after emergence from soil, may also be included. These plant propagation materials may be treated prophylactically with a plant protection mixture either at or before planting or transplanting.
- seed embraces seeds and plant propagules of all kinds including but not limited to true seeds, seed pieces, suckers, corms, bulbs, fruit, tubers, grains, cuttings, cut shoots and the like, and means in a preferred embodiment true seeds.
- pesticidally effective amount means the amount of active ingredient needed to achieve an observable effect on growth, including the effects of necrosis, death, retardation, prevention, and removal, destruction, or otherwise diminishing the occurrence and activity of the target organism.
- the pesticidally effective amount can vary for the various combinations
- a pesticidally effective amount of the compositions will also vary according to the prevailing conditions such as desired pesticidal effect and duration, weather, target species, locus, mode of application, and the like.
- the quantity of active ingredient ranges from 0.0001 to 500 g per 100 m 2 , preferably from 0.001 to 20 g per 100 m 2 .
- the rate of application of the active ingredients of this invention may be in the range of 0.0001 g to 4000 g per hectare, e.g. from 1 g to 2 kg per hectare or from 1 g to 750 g per hectare, desirably from 1 g to 100 g per hectare, more desirably from 10 g to 50 g per hectare, e.g., 10 to 20 g per hectare, 20 to 30 g per hectare, 30 to 40 g per hectare, or 40 to 50 g per hectare.
- the mixtures of the present invention are particularly suitable for use in the treatment of seeds in order to protect the seeds from insect pests, in particular from soil-living insect pests, and the resulting seedling's roots and shoots against soil pests and foliar insects.
- the present invention therefore also relates to a method for the protection of seeds from insects, in particular from soil insects, and of the seedling's roots and shoots from insects, in particular from soil and foliar insects, said method comprising treating the seeds before sowing and/or after pregermination with a mixture of the present invention.
- the protection of the seedling's roots and shoots is preferred. More preferred is the protection of seedling's shoots from piercing and sucking insects, chewing insects and nematodes.
- seed treatment comprises all suitable seed treatment techniques known in the art, such as seed dressing, seed coating, seed dusting, seed soaking, seed pelleting, and in-furrow application methods.
- seed treatment application of the active mixture is carried out by spraying or by dusting the seeds before sowing of the plants and before emergence of the plants.
- the present invention also comprises seeds coated with or containing the active mixture.
- coated with and/or containing generally signifies that the active ingredient is for the most part on the surface of the propagation product at the time of application, although a greater or lesser part of the ingredient may penetrate into the propagation product, depending on the method of application. When the said propagation product is (re)planted, it may absorb the active ingredient.
- Suitable seed is for example seed of cereals, root crops, oil crops, vegetables, spices, ornamentals, for example seed of durum and other wheat, barley, oats, rye, maize (fodder maize and sugar maize / sweet and field corn), soybeans, oil crops, crucifers, cotton, sunflowers, bananas, rice, oilseed rape, turnip rape, sugarbeet, fodder beet, eggplants, potatoes, grass, lawn, turf, fodder grass, tomatoes, leeks, pumpkin/squash, cabbage, iceberg lettuce, pepper, cucumbers, melons, Brassica species, melons, beans, peas, garlic, onions, carrots, tuberous plants such as potatoes, sugar cane, tobacco, grapes, petunias,
- the active mixture may also be used for the treatment of seeds from plants, which have been modified by mutagenisis or genetic engineering, and which e.g. tolerate the action of herbicides or fungicides or insecticides. Such modified plants have been described in detail above.
- Conventional seed treatment formulations include for example flowable concentrates FS, solutions LS, suspoemulsions (SE), powders for dry treatment DS, water dispersible powders for slurry treatment WS, water-soluble powders SS and emulsion ES and EC and gel formulation GF. These formulations can be applied to the seed diluted or undiluted. Application to the seeds is carried out before sowing, either directly on the seeds or after having
- the formulations are applied such that germination is not included.
- the active substance concentrations in ready-to-use formulations are preferably from 0.01 to 60% by weight, more preferably from 0.1 to 40 % by weight.
- a FS formulation is used for seed treatment.
- a FS formulation may comprise 1 -800 g/l of active ingredient, 1-200 g/l Surfactant, 0 to 200 g/l antifreezing agent, 0 to 400 g/l of binder, 0 to 200 g/l of a pigment and up to 1 liter of a solvent, preferably water.
- Especially preferred FS formulations of the mixtures of the present invention for seed treatment usually comprise from 0.1 to 80% by weight (1 to 800 g/l) of the active ingredient, from 0.1 to 20 % by weight (1 to 200 g/l) of at least one surfactant, e.g. 0.05 to 5 % by weight of a wetter and from 0.5 to 15 % by weight of a dispersing agent, up to 20 % by weight, e.g. from 5 to 20 % of an anti-freeze agent, from 0 to 15 % by weight, e.g. 1 to 15 % by weight of a pigment and/or a dye, from 0 to 40 % by weight, e.g.
- a binder (sticker /adhesion agent), optionally up to 5 % by weight, e.g. from 0.1 to 5 % by weight of a thickener, optionally from 0.1 to 2 % of an anti-foam agent, and optionally a preservative such as a biocide, antioxidant or the like, e.g. in an amount from 0.01 to 1 % by weight and a filler/vehicle up to 100 % by weight.
- a binder sticker /adhesion agent
- a preservative such as a biocide, antioxidant or the like
- the application rates of the mixtures of the invention are generally from 0.1 g to 10 kg per 100 kg of seed, preferably from 1 g to 5 kg per 100 kg of seed, more preferably from 1 g to 1000 g per 100 kg of seed and in particular from 1 g to 200 g per 100 kg of seed, e.g. from 1 g to 100 g or from 5 g to 100 g per 100 kg of seed.
- the invention therefore also relates to seed comprising a mixture of the present invention, or an agriculturally useful salt thereof, as defined herein.
- the amount of the mixture of the present invention or the agriculturally useful salt thereof will in general vary from 0.1 g to 10 kg per 100 kg of seed, preferably from 1 g to 5 kg per 100 kg of seed, in particular from 1 g to 1000 g per 100 kg of seed. For specific crops such as lettuce the rate can be higher.
- the mixtures of the present invention may also be used for improving the health of a plant. Therefore, the present invention also relates to a method for improving plant health by treating a plant, plant propagation material and/or the locus where the plant is growing or is to grow with an effective and non-phytotoxic amount of a mixture of the present invention.
- an effective and non-phytotoxic amount means that the mixture is used in a quantity which allows to obtain the desired effect but which does not give rise to any phytotoxic symptom on the treated plant or on the plant grown from the treated propagule or treated soil.
- plant and “plant propagation material” are defined above.
- Plant health is defined as a condition of the plant and/or its products which is determined by several aspects alone or in combination with each other such as yield (for example increased biomass and/or increased content of valuable ingredients), quality (for example improved content or composition of certain ingredients or shelf life), plant vigour (for example improved plant growth and/or greener leaves ("greening effect"), tolerance to abiotic (for example drought) and/or biotic stress (for example disease) and production efficiency (for example, harvesting efficiency, processability).
- yield for example increased biomass and/or increased content of valuable ingredients
- quality for example improved content or composition of certain ingredients or shelf life
- plant vigour for example improved plant growth and/or greener leaves ("greening effect")
- tolerance to abiotic for example drought
- biotic stress for example disease
- production efficiency for example, harvesting efficiency, processability
- the above identified indicators for the health condition of a plant may be interdependent and may result from each other.
- Each indicator is defined in the art and can be determined by methods known to a skilled person.
- the mixtures of the invention are also suitable for use against non-crop insect pests.
- mixtures of the present invention can be used as bait composition, gel, general insect spray, aerosol, as ultra-low volume application and bed net (impregnated or surface applied).
- drenching and rodding methods can be used.
- non-crop insect pest refers to pests, which are particularly relevant for non-crop targets, such as ants, termites, wasps, flies, ticks, mosquitos, crickets, or cockroaches.
- the bait can be a liquid, a solid or a semisolid preparation (e.g. a gel).
- the bait employed in the composition is a product, which is sufficiently attractive to incite insects such as ants, termites, wasps, flies, mosquitos, crickets etc. or cockroaches to eat it.
- the attractiveness can be manipulated by using feeding stimulants or sex pheromones.
- Food stimulants are chosen, for example, but not exclusively, from animal and/or plant proteins (meat-, fish- or blood meal, insect parts, egg yolk), from fats and oils of animal and/or plant origin, or mono-, oligo- or polyorganosaccharides, especially from sucrose, lactose, fructose, dextrose, glucose, starch, pectin or even molasses or honey.
- Fresh or decaying parts of fruits, crops, plants, animals, insects or specific parts thereof can also serve as a feeding stimulant.
- Sex pheromones are known to be more insect specific. Specific pheromones are described in the literature (e.g.
- the typical content of active ingredient is from 0.001 weight % to 15 weight %, desirably from 0.001 weight % to 5% weight % of active mixture.
- Formulations of the mixtures of the present invention as aerosols are highly suitable for the non-professional user for controlling pests such as flies, fleas, ticks, mosquitos or cockroaches.
- Aerosol recipes are preferably composed of the active mixture, solvents, furthermore auxiliaries such as emulsifiers, perfume oils, if appropriate stabilizers, and, if required, propellants.
- the oil spray formulations differ from the aerosol recipes in that no propellants are used.
- the content of active ingredient is from 0.001 to 80 weights %, preferably from 0.01 to 50 weight % and most preferably from 0.01 to 15 weight %.
- mixtures of the present invention and its respective compositions can also be used in mosquito and fumigating coils, smoke cartridges, vaporizer plates or long-term vaporizers and also in moth papers, moth pads or other heat-independent vaporizer systems.
- Methods to control infectious diseases transmitted by insects with mixtures of the present invention and its respective compositions also comprise treating surfaces of huts and houses, air spraying and impregnation of curtains, tents, clothing items, bed nets, tsetse-fly trap or the like.
- Insecticidal compositions for application to fibers, fabric, knitgoods, nonwovens, netting material or foils and tarpaulins preferably comprise a mixture including the insecticide, optionally a repellent and at least one binder.
- the mixtures of the present invention and its compositions can be used for protecting wooden materials such as trees, board fences, sleepers, frames, artistic artifacts, etc. and buildings, but also construction materials, furniture, leathers, fibers, vinyl articles, electric wires and cables etc. from ants and/or termites, and for controlling ants and termites from doing harm to crops or human being (e.g. when the pests invade into houses and public facilities).
- Customary application rates in the protection of materials are, for example, from 0.001 g to 2000 g or from 0.01 g to 1000 g of active mixture per m 2 treated material, desirably from 0.1 g to 50 g per m 2 .
- Insecticidal compositions for use in the impregnation of materials typically contain from 0.001 to 95 weight %, preferably from 0.1 to 45 weight %, and more preferably from 1 to 25 weight % of at least one repellent and/or insecticide.
- the mixtures of the present invention are especially suitable for efficiently combating animal pests such as arthropods, gastropods and nematodes including but not limited to:
- insects from the order of Lepidoptera for example Achroia grisella, Acleris spp. such as A. fimbriana, A. gloverana, A. variana; Acrolepiopsis assectella, Acronicta major, Adoxophyes spp. such as A. cyrtosema, A. orana; Aedia leucomelas, Agrotis spp. such as A. exclamationis, A. fucosa, A. ipsiion, A. orthogoma, A. segetum, A.
- Argyresthia conjugella Argyroploce spp., Argyrotaenia spp.
- A. velutinana Athetis mindara, Austroasca viridigrisea, Autographa gamma, Autographa nigrisigna, Barathra brassicae, Bedellia spp., Bonagota salubricola, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp. such as C. murinana, C.
- Cactoblastis cactorum Cadra cautella, Calingo braziliensis, Caloptilis theivora, Capua reticulana, Carposina spp. such as C. niponensis, C. sasakii; Cephus spp., Chaetocnema aridula, Cheimatobia brumata, Ch/io spp. such as C. Indicus, C. suppressalis, C. partellus; Choreutis pariana, Choristoneura spp. such as C. conflictana, C. fumiferana, C. longicellana, C. murinana, C. occidentalis, C.
- kuehniella kuehniella; Epinotia aporema, Epiphyas postvittana, Erannis tiliaria, Erionota thrax, Etiella spp., Eulia spp., Eupoecilia ambiguella, Euproctis chrysorrhoea, Euxoa spp., Evetria bouliana, Faronta albilinea, Feltia spp. such as F. subterranean; Galleria mellonella, Gracillaria spp., Grapholita spp. such as G. funebrana, G. molesta, G.
- H. armigera Heliothis armigera
- H. zea Heliothis zea
- Heliothis spp. such as H. assulta, H. subflexa, H. virescens
- Hellula spp. such as H. undalis, H.
- Mamestra spp. such as M. brassicae, M. configurata; Mamstra brassicae, Manduca spp. such as M. quinquemaculata, M. sexta; Marasmia spp, Marmara spp., Maruca testulalis, Megalopyge lanata, Melanchra picta, Melanitis leda, Mods spp. such as M. lapites, M.
- operculella Phyllocnistis citrella, Phyllonorycter spp. such as P. blancardella, P. crataegella, P. issikii, P. ringoniella; Pieris spp. such as P. brassicae, P. rapae, P. napi; PHocrocis tripunctata, Plathypena scabra, Platynota spp. such as P. flavedana, P. idaeusalis, P.
- Udea spp. such as U. rubigalis, U. rubigalis
- Virachola spp. Yponomeuta padella, and Zeiraphera canadensis
- insects from the order of Coleoptera for example Acalymma vittatum, Acanthoscehdes obtectus, Adoretus spp., Agelastica alni, Agrilus spp. such as A. anxius, A. planipennis, A. sinuatus; Agriotes spp. such as A. fuscicollis, A. lineatus, A. obscurus; Alphitobius diaperinus, Amphimallus soistitiaiis, Anisandrus dispar, Anisopiia austriaca, Anobium punctatum, Anomala diverenta, Anomala rufocuprea, Anoplophora spp. such as A.
- Anthonomus spp. such as A. eugenii, A. grandis, A. pomorum; Anthrenus spp., Aphthona euphoridae, Apion spp., Apogonia spp., Athous haemorrhoidalis, Atomaria spp. such as A. linearis; Attagenus spp., Aulacophora femora/is, Blastophagus piniperda, Blitophaga undata, Bruchidius obtectus, Bruchus spp. such as B. lentis, B. pisorum, B.
- vespertinus Conotrachelus nenuphar, Cosmopolites spp., Costelytra zealandica, Crioceris asparagi, Cryptolestes ferrugineus, Cryptorhynchus lapathi, Ctenicera spp. such as C. destructor; Curculio spp., Cylindrocopturus spp., Cyclocephala spp., Dactylispa balyi, Dectes texanus, Dermestes spp., Diabrotica spp. such as D. undecimpunctata, D. speciosa, D. longicornis, D. semipunctata,
- Diaprepes abbreviates, Dichocrocis spp., Dicladispa armigera, Diloboderus abderus, Diocalandra frumenti (Diocalandra stigmaticollis), Enaphalodes rufulus, Epilachna spp. such as
- hypomeces squamosus Hypothenemus spp., Ips typographus, Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp. such as L. bilineata, L. melanopus; Leptinotarsa spp. such as L. decemlineata; Leptispa pygmaea, Limonius californicus, Lissorhoptrus oryzophilus, Lixus spp., Luperodes spp., Lyctus spp. such as L.
- aiternatus Naupactus xanthographus, Niptus hoioieucus, Oberia brevis, Oemona hirta, Oryctes rhinoceros, Oryzaephilus surinamensis, Oryzaphagus oryzae, Otiorrhynchus sulcatus, Otiorrhynchus ovatus, Otiorrhynchus sulcatus, Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon spp. such as P. brassicae, P.
- Saperda Candida Scolytus schevyrewi, Scyphophorus acupunctatus, Sitona lineatus, Sitophilus spp. such as S. granaria, S. oryzae, S. zeamais; Sphenophorus spp. such as S. levis; Stegobium paniceum, Sternechus spp. such as S. subsignatus; Strophomorphus ctenotus, Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp. such as T.
- Trogoderma spp. Tychius spp.
- Xylotrech vs spp. such as X. pyrrhoderus
- Zabrus spp. such as Z. tenebrioides
- insects from the order of Diptera for example Aedes spp. such as A. aegypti, A. albopictus, A. vexans; Anastrepha ludens, Anopheles spp. such as A. albimanus, A. crucians, A. freeborni, A. gambiae, A. leucosphyrus, A. maculipennis, A. minimus, A. quadrimaculatus, A. sinensis; Bactrocera invadens, Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis capitata, Chrysomyia spp. such as C. bezziana, C.
- quinquefasciatus C tarsalis, C tritaeniorhynchus
- Culicoides furens Culiseta inornata, Culiseta melanura, Cuterebra spp., Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Dasineura oxycoccana, Delia spp. such as D. antique, D. coarctata, D. platura, D. radicum; Dermatobia hominis, Drosophila spp. such as D. suzukii, Fannia spp. such as F. canicularis; Gastraphilus spp. such as G.
- Geomyza tipunctata, Glossina spp. such as G. fuscipes, G. morsitans, G. pa/pa/is, G. tach/noides; Haematobia irritans, Haplodiplosis equestris, Hippelates spp., Hylemyia spp. such as H. platura; Hypoderma spp. such as H. lineata; Hyppobosca spp., Hydrellia philippina, Leptoconops torrens, Liriomyza spp. such as L. sativae, L. trifoiii; Luciiia spp. such as L. caprina, L.
- insects from the order of Thysanoptera for example, Basothrips biformis, Dichromothrips corbetti, Dichromothrips ssp., Echinothrips americanus, Enneothrips Havens, Frankliniella spp. such as F. fusca, F. occidentalis, F. tritici; Heliothrips spp., Hercinothrips femora/is, Kakothrips spp., Microcephalothrips abdominalis, Neohydatothrips samayunkur, Pezothrips kellyanus, Rhipiphorothrips cruentatus, Scirtothrips spp. such as S.
- insects from the order of Hemiptera for example, Acizzia jamatonica, Acrosternum spp. such as A. hilare; Acyrthosipon spp. such as A. onobrychis, A. pisum; Adelges laricis, Adelges tsugae, Adelphocoris spp., such as A. rapidus, A.
- Diaspis spp. such as D. bromeliae; Dichelops furcatus, Diconocoris hewetti, Dora/is spp., Dreyfus/a nordmann/anae, Dreyfus/a piceae, Drosicha spp., Dysaphis spp. such as D. plantaginea, D. pyri, D. radicola; Dysaulacorthum pseudosolani, Dysdercus spp. such as D. cingulatus, D. in termed/us; Dysmicoccus spp., Edessa spp., Geocoris spp., Empoascaspp. such as E.
- Idiocerus spp. Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lecanoideus floccissimus, Lepidosaphes spp. such as L. ulmi; Leptocorisa spp., Leptoglossus phyllopus, Lipaphis erysimi, Lygus spp. such as L. hesperus, L. lineolaris, L.
- Macrosiphum spp. such as M. rosae, M. a venae, M.
- P. corn/, P. persicae such as P. corn/, P. persicae; Pemphigus spp. such as P. bursar/us, P. populivenae; Peregrin us maidis, Perkinsiella saccharic/da, Phenacoccus spp. such as P. aceris, P. gossypii; Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp. such as P. devastatrix, Piesma quadrata, Piezodorus spp. such as P. guiidinii; Pinnaspis aspidistrae, Planococcus spp. such as P. citri, P.
- Prosapia bicincta Protopulvinaria pyriformis, Psallus seriatus, Pseudacysta persea, Pseudaulacaspis pentagona, Pseudococcus spp. such as P. comstocki; Psylla spp. such as P. mali; Pteromalus spp., Pulvinaria amygdali, Pyrilla spp., Quadraspidiotus spp., such as Q.
- T. accerra, T. perditor Tibraca spp., Tomaspis spp., Toxoptera spp. such as T. aurantii; Trialeurodes spp. such as T. abutilonea, T. ricini, T. vaporariorum; Triatoma spp., Trioza spp., Typhlocyba spp., Unaspis spp. such as U. citri, U. yanonensis; and Viteus vitifolii,
- geminata S.invicta, S. molesta, S. richteri, S. xyloni, Sphecius speciosus, Sphexspp., Tapinoma spp. such as T. melanocephalum, T. sessile; Tetramorium spp. such as T. caespitum, T. bicarinatum, Vespa spp. such as V. crabro; Vespula spp. such as V. squamosal; Wasmannia auropunctata, Xylocopa sp;
- Insects from the order Orthoptera for example Acheta domesticus, Calliptamus italicus, Chortoicetes terminifera, Ceuthophilus spp., Diastrammena asynamora, Dociostaurus maroccanus, Gryllotalpa spp. such as G. africana, G. gryllotalpa; Gryllus spp., Hieroglyphus daganensis, Kraussaria angulifera, Locusta spp. such as L. migratoria, L. pardalina; Melanoplus spp. such as M. bivittatus, M. femurrubrum, M. mexicanus, M. sanguinipes, M.
- Pests from the Class Arachnida for example Acari,e.g. of the families Argasidae, Ixodidae and Sarcoptidae, such as Amblyomma spp. (e.g. A. americanum, A. variegatum, A. maculatum), Argas spp. such as A. persicu), Booph/ius spp. such as B. annulatus, B. decoloratus, B. microplus, Dermacentor spp. such as D.silvarum, D. andersoni, D. variabilis, Hyalomma spp. such as H. truncatum, Ixodes spp. such as /. ricinus, I.
- Amblyomma spp. e.g. A. americanum, A. variegatum, A. maculatum
- Argas spp. such as A. persicu
- Booph/ius spp. such
- rubicundus I. scapularis, I. holocyclus, I. pacificus, Rhipicephalus sanguineus, Ornithodorus spp. such as O. moubata, O. hermsi, O. turicata, Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae, Psoroptes spp. such as P. ovis, Rhipicephalus spp. such as R. sanguineus, R. appendiculatus, Rhipicephalus everts/, Rhizoglyphus spp., Sarcoptes spp. such asS.
- Scabiei, and Family Eriophyidae including Acer/a spp. such as A. sheldoni, A. anthocoptes, Acallitus spp., Aculops spp. such as A. lycopersici, A. peiekassr, Aculus spp. such as A. schiechtendali; Coiomerus vitis, Epitrimerus pyri, Phyllocoptruta oleivora; Eriophytes ribis and Eriophyes spp.
- T. cinnabarinus such as Eriophyes sheldoni, Family Tarsonemidae including Hemitarsonemus spp., Phytonemus pallidus and Polyphagotarsonemus latus, Stenotarsonemus spp. Steneotarsonemus spinki, Family Tenuipalpidae including Brevipalpus spp. such as B. phoenicis; Family Tetranychidae including Eotetranychus spp., Eutetranychus spp., O/igonych us spp., Petrobia latens, Tetranych us spp. such as T. cinnabarinus, T. evansi, T. kanzawai, T, pacificus, T.
- Halotydeus destructor Family Demodicidae with species such as Demodex spp.; Family Trombicidea including Trombicula spp.; Family Cellyssidae including Ornothonyssus spp.; Family Pyemotidae including Pyemotes tritici, Tyrophagus putrescentiae, Family Acaridae including Acarus siro; Family Araneida including Latrodectus mactans, Tegenaria agrestis, Chiracanthium sp, Lycosa sp Achaearanea tepidariorum and Loxosceles rec/usa;
- Pests from the Phylum Nematoda for example, plant parasitic nematodes such as root-knot nematodes, Meloidogyne spp. such as M. hapla, M. incognita, M. javanica; cyst-forming nematodes, Globodera spp. such as G. rostochiensis; Heterodera spp. such as H. avenae, H. glycines, H. schachtii, H. trifolii; Seed gall nematodes, Anguina spp.; Stem and foliar
- nematodes Aphelenchoides spp. such as A. besseyi; Sting nematodes, Belonolaimus spp. such as B. longicaudatus; Pine nematodes, Bursaphelenchus spp. such as B. lignicolus, B. xylophilus; Ring nematodes, Criconema spp., Criconemella spp. such as C. xenop/axand C. ornata; and, Criconemoides spp. such as Criconemoides in formis; Mesocriconema spp.; Stem and bulb nematodes, Ditylench us spp.
- D. destructor such as D. destructor, D. dipsaci;Aw ⁇ nematodes, Dolichodorus spp.; Spiral nematodes, Heliocotylenchus multicinctus; Sheath and sheathoid nematodes, Hemicycliophora spp. and Hemicriconemoides spp.; Hirshmanniella spp.; Lance nematodes, Hoploaimus spp.; False rootknot nematodes, Nacobbus spp.; Needle nematodes, Longidorus spp. such as Z.. elongatus; Lesion nematodes, Pratylenchus spp. such as .
- brachyurus P. neglectus, P. penetrans, P. curvitatus, P. goodeyi; Burrowing nematodes, Radopholus spp. such as R. similis; Rhadopholus spp.; Rhodopholus spp.; Reniform nematodes, Roty/ench us spp. such as R. robustus, R. reniformis; Scutellonema spp.; Stubby- root nematode, Trichodorus spp. such as T. obtusus, T. primitivus; Paratrichodorus spp. such as P.
- Stunt nematodes Tylenchorhynchus spp. such as 7! claytoni, T. dub/us
- Citrus nematodes Ty/enchu/us spp. such as 7! semipenetrans
- Dagger nematodes Xiphinema spp.
- other plant parasitic nematode species include Stunt nematodes, Tylenchorhynchus spp. such as 7! claytoni, T. dub/us;
- Citrus nematodes Ty/enchu/us spp.
- Dagger nematodes Xiphinema spp.; and other plant parasitic nematode species;
- Neotermes spp. Procornitermes spp., Zootermopsis spp. such as Z. angusticollis, Z. nevadensis, Reticulitermes spp. such as R. hesperus, R. tibialis, R. speratus, R. flavipes, R. grassei, R. lucifugus, R. santonensis, R. virginicus; Termes natalensis,
- Insects from the order Blattaria for example Blattaspp. such as B. orientalis, B. lateralis; Blattella spp. such as B. asahinae, B. germanica; Leucophaea maderae, Panchlora nivea, Periplaneta spp. such as P. americana, P. australasiae, P. brunnea, P. fuligginosa, P. japonica; Supella longipalpa, Parcoblatta pennsylvanica, Eurycotis floridana, Pycnoscelus surinamensis,
- Insects from the order Siphonoptera for example Cediopsylla simples, Ceratophyllus spp., Ctenocephalides spp. such as C. felis, C. cam ' s, Xenopsylla cheopis, Pulex irritans, Trichodectes cam ' s, Tunga penetrans, and Nosopsyllus fasciatus,
- Thysanura for example Lepisma saccharina , Ctenolepisma urbana, and Thermobia domestica
- Pests from the class Chilopoda for example Geophilus spp., Scutigera spp. such as Scutigera co/eoptrata;
- Pests from the class Diplopoda for example B/an/ ' u/us guttu/atus, Julus spp., Narceus spp., Pests from the class Symphyla for example Scutigerella immaculata,
- Insects from the order Collembola for example Onychiurus spp., such as Onychiurus armatus, Pests from the order Isopoda for example, Armadillidium vulgare, Oniscus asellus, Porcellio scaber,
- Insects from the order Phthiraptera for example Damalinia spp., Pediculus spp. such as Pediculus humanus capitis, Pediculus humanus corporis, Pediculus humanus humanus; Pthirus pubis, Haematopinus spp. such as Haematopinus eurysternus, Haematopinus suis; Linognathus spp. such as Linognathus vituli; Bovicola bovis, Menopon gallinae, Menacanthus stramineus and Solenopotes capillatus, Trichodectes spp.,
- Examples of further pest species which may be controlled by mixtures of the invention include: from the Phylum Mollusca, class Bivalvia, for example, Dreissena spp.; class Gastropoda, for example, Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Ga/ba spp., Lymnaea spp., Oncomelania spp., Pomacea canaliclata, Succinea spp.; from the class of the helminths, for example, Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis,
- Ancylostoma spp. Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., C Ion orchis spp., Cooperia spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp.
- Haemonchus contortus such as Haemonchus contortus; Heterakis soo., Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus soo., Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp.,
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/557,334 US11219211B2 (en) | 2015-03-11 | 2016-03-10 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
CA2978029A CA2978029C (en) | 2015-03-11 | 2016-03-10 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
AU2016231152A AU2016231152A1 (en) | 2015-03-11 | 2016-03-10 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
BR112017019208-0A BR112017019208B1 (en) | 2015-03-11 | 2016-03-10 | Pesticides mixtures, seed treatment composition, use of a mixture, use of a seed treatment composition and methods for controlling invertebrate and nematode pests |
MX2017011682A MX2017011682A (en) | 2015-03-11 | 2016-03-10 | Pesticidal mixture comprising a carboxamide compound and a biopesticide. |
CR20170464A CR20170464A (en) | 2015-03-11 | 2016-03-10 | PESTICIDE MIXTURE THAT INCLUDES A CARBOXAMIDE COMPOUND AND A BIOPLAGUICIDE |
CN201680027163.6A CN107592790B (en) | 2015-03-11 | 2016-03-10 | Pesticidal mixtures comprising carboxamide compounds and biopesticides |
AU2020256413A AU2020256413B2 (en) | 2015-03-11 | 2020-10-15 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
US17/553,097 US11882830B2 (en) | 2015-03-11 | 2021-12-16 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201562131291P | 2015-03-11 | 2015-03-11 | |
US62/131,291 | 2015-03-11 | ||
EP15201359.5 | 2015-12-18 | ||
EP15201359 | 2015-12-18 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15/557,334 A-371-Of-International US11219211B2 (en) | 2015-03-11 | 2016-03-10 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
US17/553,097 Continuation US11882830B2 (en) | 2015-03-11 | 2021-12-16 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2016142456A1 true WO2016142456A1 (en) | 2016-09-15 |
Family
ID=54979487
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2016/055105 WO2016142456A1 (en) | 2015-03-11 | 2016-03-10 | Pesticidal mixture comprising a carboxamide compound and a biopesticide |
Country Status (6)
Country | Link |
---|---|
AU (2) | AU2016231152A1 (en) |
BR (1) | BR112017019208B1 (en) |
CA (1) | CA2978029C (en) |
CR (1) | CR20170464A (en) |
MX (1) | MX2017011682A (en) |
WO (1) | WO2016142456A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018152411A1 (en) * | 2017-02-17 | 2018-08-23 | Bayer Cropscience Lp | Compositions comprising recombinant bacillus cells and an insecticide |
WO2019170690A1 (en) * | 2018-03-07 | 2019-09-12 | Basf Agrochemical Products B.V. | Method for increasing the resistance of a cereal plant |
US10512267B2 (en) | 2013-07-08 | 2019-12-24 | BASF Agro, B.V. | Compositions comprising a triazole compound and a biopesticide |
US10519122B2 (en) | 2013-01-09 | 2019-12-31 | BASF Agro B.V. | Process for the preparation of substituted oxiranes and triazoles |
US11064696B2 (en) | 2015-04-07 | 2021-07-20 | Basf Agrochemical Products B.V. | Use of an insecticidal carboxamide compound against pests on cultivated plants |
CN113699048A (en) * | 2021-08-25 | 2021-11-26 | 云南省烟草公司昆明市公司 | Microbial compound bacterium agent for preventing and treating black shank and bacterial wilt of solanaceae plants and application thereof |
US11234436B2 (en) | 2015-04-17 | 2022-02-01 | Basf Agrochemical Products B.V. | Method for controlling non-crop pests |
WO2022128812A1 (en) | 2020-12-17 | 2022-06-23 | Basf Se | Spore compositions, production and uses thereof |
RU2798880C2 (en) * | 2018-03-07 | 2023-06-28 | Басф Агрокемикл Продактс Б.В. | Method for increasing resistance of grain plant |
Citations (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0307510B1 (en) | 1987-09-17 | 1991-02-06 | BASF Aktiengesellschaft | Process for combating fungicides |
WO1991002051A1 (en) | 1989-08-03 | 1991-02-21 | The Australian Technological Innovation Corporation | Myconematicide |
US5026417A (en) | 1987-03-17 | 1991-06-25 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Agriculture | Methods and compositions for increasing the amounts of phosphorus and/or micronutrients available for plant uptake from soils |
WO1995017806A1 (en) | 1993-12-29 | 1995-07-06 | Philom Bios Inc. | Methods and compositions for increasing the benefits of rhizobium inoculation to legume crop productivity |
WO1996021358A1 (en) | 1995-01-14 | 1996-07-18 | Prophyta Biologischer Pflanzenschutz Gmbh | Fungus isolate, preparation for combatting plant-pathogenic fungi, process for producing it and its use |
EP0585215B1 (en) | 1989-11-17 | 1999-09-15 | Abbott Laboratories | Mutants or variants of bacillus thuringiensis producing high yields of delta endotoxin |
US6406690B1 (en) | 1995-04-17 | 2002-06-18 | Minrav Industries Ltd. | Bacillus firmus CNCM I-1582 or Bacillus cereus CNCM I-1562 for controlling nematodes |
WO2005073165A1 (en) | 2004-01-28 | 2005-08-11 | Mitsui Chemicals, Inc. | Amide derivatives, process for production of the same, and method for application thereof as insecticide |
CA2471555A1 (en) | 2004-06-18 | 2005-12-18 | Thomas D. Johnson | Controlling plant pathogens with fungal/bacterial antagonist combinations comprising trichoderma virens and bacillus amyloliquefaciens |
US6994849B2 (en) | 2001-03-14 | 2006-02-07 | State Of Israel, Ministry Of Agriculture, Agricultural Research Organization | Yeast Metschnikowia fructicola NRRL Y-30752 for inhibiting deleterious microorganisms on plants |
WO2007013150A1 (en) | 2005-07-27 | 2007-02-01 | Mitsui Chemicals, Inc. | Pest control composition |
WO2009126473A1 (en) | 2008-04-07 | 2009-10-15 | Bayer Cropscience Lp | Stable aqueous spore-containing formulation |
WO2010018857A1 (en) | 2008-08-13 | 2010-02-18 | 三井化学アグロ株式会社 | Method for producing amide derivative |
WO2010018714A1 (en) | 2008-08-13 | 2010-02-18 | 三井化学アグロ株式会社 | Amide derivative, pest control agent containing the amide derivative and use of the pest control agent |
US20100260735A1 (en) | 2009-04-13 | 2010-10-14 | University of Delawre | Methods for promoting plant health |
JP2011157296A (en) | 2010-01-29 | 2011-08-18 | Mitsui Chemicals Agro Inc | Pest-controlling composition |
JP2011157294A (en) | 2010-01-29 | 2011-08-18 | Mitsui Chemicals Agro Inc | Pest-controlling composition |
JP2011157295A (en) | 2010-01-29 | 2011-08-18 | Mitsui Chemicals Agro Inc | Insect damage-controlling composition for plant seed, and method for preventing insect damage |
WO2011109395A2 (en) | 2010-03-01 | 2011-09-09 | University Of Delaware | Compositions and methods for increasing biomass, iron concentration, and tolerance to pathogens in plants |
US20120149571A1 (en) | 2010-12-10 | 2012-06-14 | Auburn University | Inoculants Including Bacillus Bacteria for Inducing Production of Volatile Organic Compounds in Plants |
WO2013032693A2 (en) | 2011-08-27 | 2013-03-07 | Marrone Bio Innovations, Inc. | Isolated bacterial strain of the genus burkholderia and pesticidal metabolites therefrom-formulations and uses |
US20130236522A1 (en) | 2010-11-10 | 2013-09-12 | Kumiai Chemical Industry Co., Ltd. | Microbial pesticidal composition |
WO2014029697A1 (en) | 2012-08-22 | 2014-02-27 | Basf Se | Fungicidal ternary mixtures comprising fluazinam |
US8686044B2 (en) | 2008-08-13 | 2014-04-01 | Mitsui Chemicals Agro, Inc. | Amide derivative, pest control agent containing the amide derivative, and use of the amide derivative |
WO2014124369A1 (en) | 2013-02-11 | 2014-08-14 | Bayer Cropscience Lp | Compositions comprising a streptomyces-based biological control agent and a fungicide |
WO2015055752A1 (en) * | 2013-10-18 | 2015-04-23 | Basf Se | Insecticidal active mixtures comprising carboxamide compound |
WO2015055757A1 (en) * | 2013-10-18 | 2015-04-23 | Basf Se | Use of pesticidal active carboxamide derivative in soil and seed application and treatment methods |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2891207C (en) * | 2012-11-22 | 2023-08-22 | Basf Corporation | A pesticidal composition comprising beauveria bassiana |
-
2016
- 2016-03-10 CR CR20170464A patent/CR20170464A/en unknown
- 2016-03-10 AU AU2016231152A patent/AU2016231152A1/en not_active Abandoned
- 2016-03-10 CA CA2978029A patent/CA2978029C/en active Active
- 2016-03-10 MX MX2017011682A patent/MX2017011682A/en unknown
- 2016-03-10 BR BR112017019208-0A patent/BR112017019208B1/en active IP Right Grant
- 2016-03-10 WO PCT/EP2016/055105 patent/WO2016142456A1/en active Application Filing
-
2020
- 2020-10-15 AU AU2020256413A patent/AU2020256413B2/en active Active
Patent Citations (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5026417A (en) | 1987-03-17 | 1991-06-25 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of Agriculture | Methods and compositions for increasing the amounts of phosphorus and/or micronutrients available for plant uptake from soils |
EP0307510B1 (en) | 1987-09-17 | 1991-02-06 | BASF Aktiengesellschaft | Process for combating fungicides |
WO1991002051A1 (en) | 1989-08-03 | 1991-02-21 | The Australian Technological Innovation Corporation | Myconematicide |
EP0585215B1 (en) | 1989-11-17 | 1999-09-15 | Abbott Laboratories | Mutants or variants of bacillus thuringiensis producing high yields of delta endotoxin |
WO1995017806A1 (en) | 1993-12-29 | 1995-07-06 | Philom Bios Inc. | Methods and compositions for increasing the benefits of rhizobium inoculation to legume crop productivity |
WO1996021358A1 (en) | 1995-01-14 | 1996-07-18 | Prophyta Biologischer Pflanzenschutz Gmbh | Fungus isolate, preparation for combatting plant-pathogenic fungi, process for producing it and its use |
US6406690B1 (en) | 1995-04-17 | 2002-06-18 | Minrav Industries Ltd. | Bacillus firmus CNCM I-1582 or Bacillus cereus CNCM I-1562 for controlling nematodes |
US6994849B2 (en) | 2001-03-14 | 2006-02-07 | State Of Israel, Ministry Of Agriculture, Agricultural Research Organization | Yeast Metschnikowia fructicola NRRL Y-30752 for inhibiting deleterious microorganisms on plants |
WO2005073165A1 (en) | 2004-01-28 | 2005-08-11 | Mitsui Chemicals, Inc. | Amide derivatives, process for production of the same, and method for application thereof as insecticide |
EP1714958A1 (en) | 2004-01-28 | 2006-10-25 | Mitsui Chemicals, Inc. | Amide derivatives, process for production of the same, and method for application thereof as insecticide |
CA2471555A1 (en) | 2004-06-18 | 2005-12-18 | Thomas D. Johnson | Controlling plant pathogens with fungal/bacterial antagonist combinations comprising trichoderma virens and bacillus amyloliquefaciens |
WO2007013150A1 (en) | 2005-07-27 | 2007-02-01 | Mitsui Chemicals, Inc. | Pest control composition |
WO2009126473A1 (en) | 2008-04-07 | 2009-10-15 | Bayer Cropscience Lp | Stable aqueous spore-containing formulation |
WO2010018714A1 (en) | 2008-08-13 | 2010-02-18 | 三井化学アグロ株式会社 | Amide derivative, pest control agent containing the amide derivative and use of the pest control agent |
WO2010018857A1 (en) | 2008-08-13 | 2010-02-18 | 三井化学アグロ株式会社 | Method for producing amide derivative |
US8686044B2 (en) | 2008-08-13 | 2014-04-01 | Mitsui Chemicals Agro, Inc. | Amide derivative, pest control agent containing the amide derivative, and use of the amide derivative |
US20100260735A1 (en) | 2009-04-13 | 2010-10-14 | University of Delawre | Methods for promoting plant health |
JP2011157296A (en) | 2010-01-29 | 2011-08-18 | Mitsui Chemicals Agro Inc | Pest-controlling composition |
JP2011157294A (en) | 2010-01-29 | 2011-08-18 | Mitsui Chemicals Agro Inc | Pest-controlling composition |
JP2011157295A (en) | 2010-01-29 | 2011-08-18 | Mitsui Chemicals Agro Inc | Insect damage-controlling composition for plant seed, and method for preventing insect damage |
WO2011109395A2 (en) | 2010-03-01 | 2011-09-09 | University Of Delaware | Compositions and methods for increasing biomass, iron concentration, and tolerance to pathogens in plants |
US20130236522A1 (en) | 2010-11-10 | 2013-09-12 | Kumiai Chemical Industry Co., Ltd. | Microbial pesticidal composition |
US8445255B2 (en) | 2010-12-10 | 2013-05-21 | Auburn University | Inoculants including Bacillus bacteria for inducing production of volatile organic compounds in plants |
US20120149571A1 (en) | 2010-12-10 | 2012-06-14 | Auburn University | Inoculants Including Bacillus Bacteria for Inducing Production of Volatile Organic Compounds in Plants |
WO2013032693A2 (en) | 2011-08-27 | 2013-03-07 | Marrone Bio Innovations, Inc. | Isolated bacterial strain of the genus burkholderia and pesticidal metabolites therefrom-formulations and uses |
WO2014029697A1 (en) | 2012-08-22 | 2014-02-27 | Basf Se | Fungicidal ternary mixtures comprising fluazinam |
WO2014124369A1 (en) | 2013-02-11 | 2014-08-14 | Bayer Cropscience Lp | Compositions comprising a streptomyces-based biological control agent and a fungicide |
WO2015055752A1 (en) * | 2013-10-18 | 2015-04-23 | Basf Se | Insecticidal active mixtures comprising carboxamide compound |
WO2015055757A1 (en) * | 2013-10-18 | 2015-04-23 | Basf Se | Use of pesticidal active carboxamide derivative in soil and seed application and treatment methods |
Non-Patent Citations (17)
Title |
---|
"Technical Mono-graph No. 2", May 2008, CROPLIFE INTERNATIONAL, article "Catalogue of pesticide formulation types and international coding system" |
BIOCONTROL SCIENCE TECHNOL., vol. 22, no. 7, 2012, pages 747 - 761 |
BIOCONTROL, vol. 57, 2012, pages 687 - 696 |
C. MACBEAN: "The Pesticide Manual", 2013, BRITISH CROP PROTECTION COUNCIL |
CAN. J. PLANT SCI., vol. 78, no. 1, 1998, pages 91 - 102 |
COLBY, S. R.: "Calculating Synergistic and Antagonistic Responses in Herbicide Combinations", WEEDS, vol. 15, 1967, pages 21 - 22 |
CROP PROTECTION, vol. 27, 2008, pages 352 - 361 |
FEDERAL REGISTER, vol. 76, no. 22, 2 February 2011 (2011-02-02), pages 5808 |
FERTILIZER RES., vol. 39, 1994, pages 97 - 103 |
J. INVERTEBRATE PATHOL., vol. 107, 2011, pages 112 - 126 |
J. PLANT DIS. PROT., vol. 105, 1998, pages 181 - 197 |
KNOWLES: "Agrow Reports DS243", 2005, T&F INFORMA, article "New developments in crop protection product formulation" |
KNOWLES: "Agrow Reports DS256", 2006, T&F INFORMA, article "Adjuvants and additives" |
MCCUTCHEON'S: "Emulsifiers & Detergents, McCutcheon's Directories", vol. 1, 2008, INTERNATIONAL ED. OR NORTH AMERICAN ED. |
MOLLET; GRUBE-MANN: "Formulation technology", 2001, WILEY VCH |
SCIENCE, vol. 257, 1992, pages 85 - 88 |
SYSTEM. APPL. MICROBIOL., vol. 27, 2004, pages 372 - 379 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10519122B2 (en) | 2013-01-09 | 2019-12-31 | BASF Agro B.V. | Process for the preparation of substituted oxiranes and triazoles |
US10981883B2 (en) | 2013-01-09 | 2021-04-20 | BASF Agro B.V. | Process for the preparation of substituted oxiranes and triazoles |
US10512267B2 (en) | 2013-07-08 | 2019-12-24 | BASF Agro, B.V. | Compositions comprising a triazole compound and a biopesticide |
US11064696B2 (en) | 2015-04-07 | 2021-07-20 | Basf Agrochemical Products B.V. | Use of an insecticidal carboxamide compound against pests on cultivated plants |
US11234436B2 (en) | 2015-04-17 | 2022-02-01 | Basf Agrochemical Products B.V. | Method for controlling non-crop pests |
WO2018152411A1 (en) * | 2017-02-17 | 2018-08-23 | Bayer Cropscience Lp | Compositions comprising recombinant bacillus cells and an insecticide |
WO2019170690A1 (en) * | 2018-03-07 | 2019-09-12 | Basf Agrochemical Products B.V. | Method for increasing the resistance of a cereal plant |
RU2798880C2 (en) * | 2018-03-07 | 2023-06-28 | Басф Агрокемикл Продактс Б.В. | Method for increasing resistance of grain plant |
WO2022128812A1 (en) | 2020-12-17 | 2022-06-23 | Basf Se | Spore compositions, production and uses thereof |
CN113699048A (en) * | 2021-08-25 | 2021-11-26 | 云南省烟草公司昆明市公司 | Microbial compound bacterium agent for preventing and treating black shank and bacterial wilt of solanaceae plants and application thereof |
Also Published As
Publication number | Publication date |
---|---|
AU2020256413B2 (en) | 2022-10-27 |
BR112017019208B1 (en) | 2022-06-21 |
CA2978029A1 (en) | 2016-09-15 |
AU2016231152A1 (en) | 2017-09-28 |
AU2020256413A1 (en) | 2020-11-12 |
MX2017011682A (en) | 2018-02-09 |
CA2978029C (en) | 2023-08-22 |
BR112017019208A2 (en) | 2018-04-24 |
CR20170464A (en) | 2018-03-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US11882830B2 (en) | Pesticidal mixture comprising a carboxamide compound and a biopesticide | |
AU2014336138B2 (en) | Agricultural mixtures comprising carboxamide compound | |
EP3255990B1 (en) | Pesticidal mixture comprising a pyrazole compound, an insecticide and a fungicide | |
CA2989253C (en) | Pesticidal compositions comprising a triazole compound | |
CA2978029C (en) | Pesticidal mixture comprising a carboxamide compound and a biopesticide | |
WO2016128239A1 (en) | Pesticidal mixture comprising a pyrazole compound and a biopesticide | |
EP3329777A1 (en) | Pesticidal mixtures | |
KR20190028764A (en) | Insecticidal active compound | |
EP3522714B1 (en) | Pesticidal mixtures | |
US20190307127A1 (en) | Pesticidal Mixtures | |
EP3111763A1 (en) | Pesticidal compositions comprising a triazole compound | |
WO2018069110A1 (en) | Pesticidal mixtures | |
US20200045970A1 (en) | Pesticidal mixture | |
EP3269246A1 (en) | Pesticidal mixtures | |
EP3202267A1 (en) | Pesticidal mixtures | |
WO2019007719A1 (en) | Pesticidal mixtures | |
EP3518676A1 (en) | Pesticidal mixtures | |
EA044712B1 (en) | AGRICULTURAL MIXTURES THAT CONTAIN CARBOXAMIDE COMPOUNDS | |
BR122021013250B1 (en) | AGRICULTURAL MIXTURES, METHODS FOR THE PROTECTION OF VEGETABLES FROM ATTACK OR INFESTATION, METHOD FOR THE CONTROL OF INSECTS, METHOD FOR THE PROTECTION OF VEGETABLES PROPAGATION MATERIAL, METHOD FOR THE CONTROL OF HARMFUL PHYTOPATOGENIC FUNGI, METHOD FOR THE PROTECTION OF VEGETABLES FROM PHYTOPATOGENIC FUNGI HARMFUL, USES OF AN AGRICULTURAL MIXTURE AND COMPOSITION |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 16709065 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2978029 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 15557334 Country of ref document: US Ref document number: MX/A/2017/011682 Country of ref document: MX |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112017019208 Country of ref document: BR |
|
ENP | Entry into the national phase |
Ref document number: 2016231152 Country of ref document: AU Date of ref document: 20160310 Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: CR2017-000464 Country of ref document: CR |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 16709065 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 112017019208 Country of ref document: BR Kind code of ref document: A2 Effective date: 20170908 |