VOL. 27, NO. 2 Summer 2018
IN THIS ISSUE 3 From the Editor: A Double-Edged Plastic Sword
7 From the President:
116 Years of Continuous Success Is a Sign of a Great Future
17 Seattle, Washington
ECS Meeting Highlights
47 Looking at Patent Law 53 Tech Highlights 55 UPD, SLRR, SEBALD: Abbreviations with Many Connotations
Electrodeposition
For the
57 Fundamentals of Metal
Future with
37 Years Roque Calvo Page 9
Deposition via Surface Limited Redox Replacement of UnderpotentiallyDeposited Monolayer
65 Palladium Ultrathin Film
Growth by Surface-Limited Redox Replacement of Cu and H UPD Monolayers: Approaches, Pros, Cons, and Comparison
71 Electrodeposition of Pt-
Bimetallic Model Systems for Electrocatalysis and Electrochemical Surface Science
77 Selective Electrodesorption-
Based Atomic Layer Deposition (SEBALD) of Bismuth under Morphological Control
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FROM THE Editor Published by: The Electrochemical Society (ECS) 65 South Main Street Pennington, NJ 08534-2839, USA Tel 609.737.1902, Fax 609.737.2743 www.electrochem.org Editor: Krishnan Rajeshwar, Rajeshwar@uta.edu
A Double-Edged Plastic Sword
T
he graduation season is just ending in schools and colleges as I compose this editorial. And I wonder what the neighbor Mr. McGuire would have now said after buttonholing the newly minted graduate Benjamin Braddock (played by Dustin Hoffman) in the movie The Graduate with the famous quote, “One word: plastics.” As human civilization progressed from one era to the next, the future loomed bright with every new type of material, be it iron, steel, silicon, or now, carbon. Plastics were no exception. I was astounded to read (National Geographic, June 2018) that fully half the amount of plastic ever made was produced only during the past 15 years! While the average service life of a plastic bag is a few minutes, plastics require forever to assimilate into our ecosystem after use. For an ecosystem to be completely sustainable, the fluxes have to be delicately poised such that the input into the system (materials or energy) balances the output. When this is not the case, the consequences may be unpredictable, or worse, catastrophic. We do not have to look beyond the global climate situation in which man-made emissions of greenhouse gases (e.g., CO2) are overwhelming the rates at which they can be assimilated by natural sinks (e.g., plants). In a similar vein, the production of plastics has far outrun the rate at which they can be safely or permanently disposed, especially in the most populous parts of the globe. It is sociologically interesting that most innovations are double-edged. For example, malaria was largely eradicated with the discovery of the chemical DDT. However, its wanton and irresponsible use also resulted in long-lasting health effects, such as cancer and so on, importantly unforeseen at the time of its widespread use—so much so that agricultural use of this chemical has been banned in the U.S. for the past 40 years. (The DDT story has been highlighted by Rachel Carson’s best seller Silent Spring, within the broader context of the overuse of pesticides.) There is no debate that plastics revolutionized our way of life on this planet in myriad ways. They even save lives in terms of use as airbags, safety helmets, and water containers. However, our dependence on plastics has grown to such proportions that landfills cannot handle them anymore, and we have to haul huge amounts on ships to other countries for disposal or recycling. Plastic wastes that do not make it to these disposal routes are transported by river streams from densely populated areas and ultimately end up in our oceans as microplastics with disastrous consequences on marine life. In tackling this challenge, the answer clearly does not lie solely with cutting back the use of technological materials such as plastics. Albeit at smaller scales, we have been able to refine recycling into a fine art with the use of lead (as a battery material), and previously silver (as an analog photography material). There is no reason to believe that plastics recycling cannot be just as efficient. At the same time, human ingenuity has to be put to work in the discovery of biodegradable alternatives to plastics as we know them today. In this respect, we can take a cue from the use, in many rural parts of the world (or even posh resorts!), of thatched huts for living or banana leaves for eating needs; these materials are completely biodegradable. In this regard, the recent, serendipitous discovery of a mutant enzyme that eats plastics is worthy of note. (See www.theguardian.com/environment/2018/apr/16/scientists-accidentally-createmutant-enzyme-that-eats-plastic-bottles.) Can we possibly engineer synthetic analogs of such natural materials using clever chemistries? And better still, can we add value to disposable plastics by converting them into useful chemicals (e.g., liquid fuel)? Stay tuned.
Krishnan Rajeshwar Editor https://orcid.org/0000-0003-4917-7790
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Guest Editor: Stanko R. Brankovic, SRBrankovic@uh.edu Contributing Editors: Donald Pile, donald.pile@gmail. com; Alice Suroviec, asuroviec@berry.edu Managing Editor: Annie Goedkoop, Annie.Goedkoop@electrochem.org Production Manager: Dinia Agrawala, interface@electrochem.org Advertising Manager: Ashley Moran, Ashley.Moran@electrochem.org Advisory Board: Christopher Johnson (Battery), Masayuki Itagaki (Corrosion), Durga Misra (Dielectric Science and Technology), Philippe Vereecken (Electrodeposition), Jennifer Hite (Electronics and Photonics), A. Manivannan (Energy Technology), Paul Gannon (High Temperature Materials), John Weidner (Industrial Electrochemistry and Electrochemical Engineering), Uwe Happek (Luminescence and Display Materials), Slava Rotkin (Nanocarbons), Jim Burgess (Organic and Biological Electrochemistry), Andrew Hillier (Physical and Analytical Electrochemistry), Nianqiang (Nick) Wu (Sensor) Publisher: Mary Yess, mary.yess@electrochem.org Publications Subcommittee Chair: Stefan De Gendt Society Officers: : Yue Kuo, President; Christina Bock, Senior Vice President; Stefan De Gendt, 2nd Vice President; Eric Wachsman, 3rd Vice President; James Fenton, Secretary; Gessie Brisard, Treasurer; Roque J. Calvo, Executive Director Statements and opinions given in The Electrochemical Society Interface are those of the contributors, and ECS assumes no responsibility for them. Authorization to photocopy any article for internal or personal use beyond the fair use provisions of the Copyright Act of 1976 is granted by The Electrochemical Society to libraries and other users registered with the Copyright Clearance Center (CCC). Copying for other than internal or personal use without express permission of ECS is prohibited. The CCC Code for The Electrochemical Society Interface is 1064-8208/92. Canada Post: Publications Mail Agreement #40612608 Canada Returns to be sent to: Pitney Bowes International, P.O. Box 25542, London, ON N6C 6B2 ISSN : Print: 1064-8208
Online: 1944-8783
The Electrochemical Society Interface is published quarterly by The Electrochemical Society (ECS), at 65 South Main Street, Pennington, NJ 08534-2839 USA. Subscription to members as part of membership service; subscription to nonmembers is available; see the ECS website. Single copies $10.00 to members; $19.00 to nonmembers. © Copyright 2018 by The Electrochemical Society. Periodicals postage paid at Pennington, New Jersey, and at additional mailing offices. POSTMASTER: Send address changes to The Electrochemical Society, 65 South Main Street, Pennington, NJ 08534-2839. The Electrochemical Society is an educational, nonprofit 501(c)(3) organization with more than 8,500 scientists and engineers in over 75 countries worldwide who hold individual membership. Founded in 1902, the Society has a long tradition in advancing the theory and practice of electrochemical and solid state science by dissemination of information through its publications and international meetings. 3 All recycled paper. Printed in USA.
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55 57 65 71 77
UPD, SLRR, SEBALD: Abbreviations with Many Connotations by Stanko R. Brankovic Fundamentals of Metal Deposition via Surface Limited Redox Replacement of UnderpotentiallyDeposited Monolayer by Stanko R. Brankovic Palladium Ultrathin Film Growth by Surface-Limited Redox Replacement of Cu and H UPD Monolayers: Approaches, Pros, Cons, and Comparison by Nikolay Dimitrov, Innocent Achari, and Stephen Ambrozik Electrodeposition of Pt-Bimetallic Model Systems for Electrocatalysis and Electrochemical Surface Science by Natasa Vasiljevic Selective Electrodesorption-Based Atomic Layer Deposition (SEBALD) of Bismuth under Morphological Control by Walter Giurlani, Andrea Giaccherini, Emanuele Salvietti, Maurizio Passaponti, Andrea Comparini, Vittorio Morandi, Fabiola Liscio, Massimiliano Cavallini, and Massimo Innocenti
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Vol. 27, No. 2 Summer 2018
the Editor: 3 From A Double-Edged Plastic Sword
the President: 7 From 116 Years of Continuous Success Is a Sign of a Great Future
9 37 Years With Roque Calvo Washington 17 Seattle, ECS Meeting Highlights The New 25 ECSarXiv: ECS Preprint Service
28 Society News Chalkboard: 42 The C Rating of Batteries:
A Misleading Concept C Flux Rather than C Rate
44 People News 47 Looking at Patent Law 53 Tech Highlights 82 Section News 84 Awards Program 88 New Members 92 Student News Texas 103 Dallas, Call for Papers 107 2017 Annual Report On the Cover: Electrodeposition via Surface Limited Redox Replacement: Schematics and Deposit Morphology. Cover design by Dinia Agrawala.
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From The President Past Performance Is No Guarantee of Future Results But
116 Years of Continuous Success Is a Sign of a Great Future
W
Numbers
numerous breakthroughs in ECS journals and conferences, hen one inquires for which established the foundation of today’s electrochemical an investment service, and solid state industries. One example is the first disclosure no matter how well the of Moore’s law on the IC development trend in an ECS San company, fund, or stock is performing, Francisco conference by ECS life member Gordon E. Moore. the following statement always appears in the brochure or In addition, among many ECS-affiliated Nobel Prize winners,1 comes out of the advisor’s mouth: “Past performance is no ECS life member Isamu Akasaki, who received the prestigious guarantee of future results.” Obviously, it is a cautious warning ECS Gordon E. Moore Medal, has published papers in ECS on making one’s intelligent decision. It is also wise advice journals since 1966. He presented the first blue LED at the for anyone making important professional decisions, such 175th ECS Meeting in Los Angeles in 1989.2 as in what field to devote efforts or with which professional The figure below shows numbers of ECS members as society to be involved. Indeed, The Electrochemical Society well as meeting attendees and journal articles in the past 116 is a dynamic society with things changing constantly and at years. It is clear that all major factors, such as membership, a moment’s notice. Scientifically and philosophically, no meeting attendees, and publications, increased throughout the one can predict the future unless he or she can time-travel. time in spite of two world wars and many serious disturbances In scientific terms, it is dangerous to extrapolate data out of in the world during the period. The short time variations of range. However, experience has taught us that the possibility of these numbers are unavoidable due to the fluctuation of many future success could be high if the data range is very large and society factors. ECS is truly a global society with members the measurement method is accurate. ECS and its 116-year-old coming from academia, industry, and governments in about history is a prime example for this statement. 80 countries. ECS contains The quantum jump of balanced core subjects the modern human history 10,000 including traditional topics to a great extent started that progressed continuously from the demonstration for over 100 years with the of the existence and 8,000 strong industry base and practical applications of Members new hot research areas electrons, including their of which the knowledge generation, transferring, and 6,000 becomes available due to storage through scientific recent science or technology methods. The fields of Meeting breakthroughs. electrochemical and solid 4,000 Attendees In summary, ECS state science and technology activities have closely rose to prominence near 2,000 contributed to the advancethe end of the 19th century. ment of science and Shortly after that, exactly Journal industry. In many ways, new 1902, ECS was founded. Articles 0 directions in electrochemical The impact ECS has had on 1900 1920 1940 1960 1980 2000 2020 and solid state science and the advancement of science technology are derived Year and industry is extensive, from these works. The deep, and continuous. In Statistics of ECS members, meeting attendees, and journal articles. (Data distinguished record of the fact, ECS founders and Statistics ofbyECS members, meeting attendees, and journal articles. provided ECS staff.) evolvement of ECS for over early members were mostly one century can guarantee— distinguished scientists, or be a strong indication of—continuous success in the future. engineers, and inventors, such as Herbert H. Dow, who Of course, this requires collaborative efforts of all current founded the largest American chemical company: Dow and new-generation members as well as the strong support of Chemical; Edward G. Acheson, who first synthesized ECS staff. graphite and artificial diamonds; Charles M. Hall, who invented the low-cost aluminum manufacturing process; Edward Winston, whose Weston cell became the international standard for EMF; and Thomas Edison, who invented the first commercially viable incandescent light bulb, among many Yue Kuo others. In the past century, eminent members have reported ECS President president@electrochem.org
https://orcid.org/0000-0003-2757-1842 1. www.electrochem.org/history-ecs/. 2. Electrochem. Soc. Interface, 26(1), 9 (2017).
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
7
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The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
with
37 Years
Roque Calvo ECS Executive Director Roque Calvo has served as a steward of The Electrochemical Society for over 37 years, guiding the Society through tremendous changes while remaining dedicated to the Society’s mission to advance electrochemical and solid state science and technology. Now, as Calvo comes to the end of his tenure and begins transitioning out of his role at ECS, we are looking back at some of the Society’s greatest accomplishments during his time.
C
alvo joined ECS in 1980 as the accounting supervisor, managing the financial operations for the headquarters office. After two years, he was promoted to assistant executive secretary. In 1990, as then executive secretary V. H. (Bud) Branneky prepared for retirement, a search committee was established to find the individual who would fill that role and lead the Society into the future. “Roque just impressed us with his energy and ability,” said past ECS president Larry Faulkner, who was a member of the committee that would recommend the hiring of Calvo. “We had high confidence in him and I don’t think anyone who was involved in his hiring would have done it differently. Every one of us shared the view that it all turned out even better than we hoped.” Calvo took the role of executive secretary in 1991, just the fourth person to hold that title in the Society’s then 88-year history. The title was changed to executive director in 1994. “The Society was interested in self-renewal and I think we had the leadership and energy at that time with Roque inheriting the agenda,” Faulkner said. “Of course, he didn’t just inherit that agenda, he shaped it and turned it into something real.” His position would prove over the next three decades to hold significant importance in guiding the Society through a technological shift, which changed the landscape for many nonprofit organizations.
Publishing paradigm One of the first initiatives Calvo took on as the Society’s new leader was to establish ECS’s quarterly membership magazine, Interface. In a 1989 report, the ECS Long Range Planning Committee recommended creating a news-oriented publication to foster and implement ideas and achieve greater access for members to information on matters affecting the Society. Along with Paul Kohl, then a (continued on next page) The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
9
(continued from previous page)
“Roque was bringing energy and vitality to the Society,” said Kohl, who served as editor of the Journal of The Electrochemical Society from 1995 to 2007, seeing the journal through its transition from an exclusively paper model to an online publication. “For so many people, if it’s not their concern and requires some work, they just pass the buck somewhere. But Roque would stand and try to address these issues.” That positivity and forward thinking would help propel the Society into the digital age. Not only did Calvo undertake the immense project of overseeing electronic submission and the digitization of the publications, he also spearheaded the Society’s first website. In such a trying time with many unknowns and dozens of technological challenges, Calvo’s vision and hallmark positivity kept everyone engaged and focused on accomplishing the task at hand.
The group that put together the first Interface magazine in 1992 including the editor Paul Kohl (seated) and Roque Calvo (far right).
member of the ECS Publications Committee, and Barry Miller, who had recently become editor of the Journal of The Electrochemical Society, a team started meeting at ECS’s headquarters in Pennington, NJ, to brainstorm how to pull the magazine together. However, not all parties involved were on board, citing the potential for financial loss that could hurt the Society.
In Calvo’s 26 years as executive director, net assets increased from $3.9M to $19.4M. “Roque stepped forward and faced the financial consequences and he backed it,” said Kohl, who would serve as the first editor of Interface. “He was the right person at the right time to get it going and if he wasn’t there, it never would have happened.” The ECS Board of Directors approved the new publication at the 1992 spring meeting, and the publication continues to see success to this day, having recently celebrated its 25th anniversary. The next key initiative Calvo undertook in his new role was the digitization of ECS publications. As new technologies began to emerge and publishers started shifting their business model, Calvo led an aggressive effort to establish what would become the ECS Digital Library, using technology to advance the Society’s mission. A venture into unknown territory, much of this process was initially trial and error.
Roque Calvo in 2008 at the 228th ECS Meeting in Phoenix, AZ.
“Roque never said we couldn’t do something,” Kohl said. “It would always be, ‘Is there a way to do this? Let’s figure it out.’ That attitude was absolutely critical because every time we came to a stumbling block, Roque would find a new way to accomplish our goal.” The ECS Digital Library was launched in 2006, and ECS chose the American Institute of Physics’ Scitation platform to be the host for its library. In addition to hosting all the newly published journal manuscripts, the effort also included work to archive past papers, dating back to 1930. The continued expansion of the ECS Digital Library also led to the inclusion of ECS Transactions, which the Society began publishing in 2005 as a replacement for ECS Proceedings Volumes. Through it all, Calvo’s business sense allowed him to control overall budgets and successfully navigate the publications entry into the digital world. The paradigm shift represented great opportunity for ECS, but as a small nonprofit publisher, the Society faced significant challenges, particularly in generating the necessary financial resources. Calvo’s ability to drive technological advancements and effectively manage the budget is one of the main reasons for the financial security and programmatic success that ECS is experiencing today.
International expansion
Roque Calvo and Dale Hall (ECS president 1999-2000) in Japan planning PRiME 2004 with ECSJ. 10
When ECS was founded in 1902, there were nine countries represented on the charter membership roster. As a result of Calvo’s guidance, the Society currently has members and involvement in more than 75 countries, having created a dynamic international community of electrochemists and solid state scientists and engineers. Before Calvo became executive director, ECS ran its first joint international meeting in Honolulu, HI, in 1987. As assistant executive secretary during that time, Calvo was able to gain hands-on experience and establish relationships with Japanese partners. Due to the increased interest and engagement at this meeting, Calvo knew it would be an enduring opportunity for the Society. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
In 2017, 55% of meeting abstracts and 75% of journal manuscripts were from international authors. Upon gaining the executive director title, Calvo began to tackle new ventures in joint international meetings, overseeing strategy and relationship-building with organizations around the world. It wasn’t until 1993 when the chips fell into place again, marking the Society’s return to Hawaii for its second joint international meeting. Seeing the potential, Calvo began initiatives in branding this meeting, resulting in what we know today as PRiME. Global partnerships with The Electrochemical Society of Japan and later the Korean Electrochemical Society acted as the catalyst for the development of this highly successful meeting, with additional sponsorship from five other organizations from Australia, China, Korea, and Japan. PRiME has grown into the largest, most significant research conference in electrochemical and solid state science and technology. “PRiME helped to significantly raise the prominence of ECS,” said Fernando Garzon, ECS president during the PRiME 2012 meeting. “The meeting set a precedent that was then copied by other scientific societies. They saw the success of our meeting and that Hawaii was an excellent venue to bring together our Asian partners within the Society.”
Roque Calvo planting a tree at the Central Electro Chemical Research Institute in Karaikudi, India, to commemorate his visit.
Through international partnership efforts, Calvo led ECS to continue fulfilling its mission by advancing the science on an international scale, building relationships with over a dozen professional societies, including the Chinese Society of Electrochemistry, the Society for Advancement of Electrochemical Science and Technology (India), the International Society of Electrochemistry, the International Conference on Solid State Ionics, the Institute of Electrical and Electronics Engineers, and others already mentioned in this article.
Meetings, meetings, meetings
Roque Calvo at PRiME 2008 with ECSJ members.
PRiME now occurs every four years in the very same venue in which the inaugural meeting took place, its level of attendance having grown from approximately 2,500 participants to now nearly 4,000 researchers from all corners of the world. The eighth PRiME meeting is scheduled for October 2020 and is expected to surpass existing benchmarks. Calvo continued the joint meeting branding strategy through the creation of the Americas International Meeting on Electrochemical and Solid State Science, which this year will be held in October. This global partnership strategy was extended to the Sociedad Mexicana de Electroquímica in 2006 when the two organizations held the first of a continuing series of joint international meetings in Cancun, Mexico. After another successful joint meeting in 2014, the conference took on its own, unique identity. AiMES 2018 will include sponsorship from the Sociedade Brasileira de Eletroquímica e Eletroanalítica and the Sociedad Iberoamericana de Electroquímica, with high expectations of AiMES being the most important meeting in our field ever convened in the Americas. Under Calvo’s guidance, ECS has also held joint partnership meetings in China and Europe, and Calvo has established both sponsored and satellite meetings, opening the door to integrate such significant meetings as the International Meeting on Lithium Batteries, the International Symposium on Solid Oxide Fuel Cells, and the China Semiconductor Technology International Conference.
In addition to international expansion, Calvo piloted ECS to significant growth through the implementation of new programs at its biannual meetings. He guided the development of the Electrochemical Energy Summit, with the first summit taking place in 2011 during the 220th ECS Meeting in Boston, MA. Since the inaugural event, the energy summit has taken place every year during the fall biannual meeting, bringing together policy makers and researchers to discuss the critical issues of energy needs and the pivotal research in electrochemical energy. He also shepherded the first Science for Solving Society’s Problems Challenge in 2014, which was created in partnership with the Bill & Melinda Gates Foundation and awarded a grand total of $360,000 in funding to innovative researchers working to address world sanitation issues. Calvo’s leadership has also significantly impacted symposia planning at ECS biannual meetings, leading to larger and more diverse meetings and a steady increase in attendance. In 1995, utilizing new technologies, ECS began accepting electronic abstract submissions, which has led to major improvements in program development. In the same year, ECS introduced technical exhibits at biannual meetings, which have led to long-term success in providing a venue for exhibitors to interact with world-renowned researchers. But technological shifts were not always easily embraced within the Society. From his oversight of the implementation of electronic abstract submission to the development of a comprehensive constituent database, Calvo consistently used his managerial and business sense to back decisions and deliver clear, concise communications on the importance of these moves to a diverse scientific community. (continued on next page)
In 37 years, Calvo has championed the success of 75 consecutive ECS biannual meetings.
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
11
(continued from previous page)
“Implementing these changes really took the skill of an international diplomat,” Garzon said. “We joke at the university that trying to organize scientists and engineers is like herding cats. Roque is very good at herding cats.” His work with U.S. funding agencies also allowed the various ECS symposia to grow and expand, with Calvo communicating the importance of the work of the Society’s scientists to major institutions. “Roque was very good at working with divisional leadership to make sure that the symposia we have in the Society reflect the national research interests,” Garzon said. “He made people understand that ECS was the place for their program managers to discuss the major research in areas like battery technology, fuel cells, and photovoltaics. And one of the greatest values that ECS provides its membership and meeting attendees, is that the Society has very high credibility with the folks who fund science.”
Roque Calvo and Esther S. Takeuchi (ECS president 2011-2012) at the 227th ECS Meeting in Chicago, IL.
Christina Bock (ECS treasurer 2010-2014) with Roque Calvo in 2013 at the 223rd ECS Meeting in Toronto, Canada.
Student investments Prior to Calvo’s tenure as executive director, the Society’s student activities relied heavily on university faculty networks to seed the new generation of scientists. Knowing that the Society’s future success depends on that, Calvo began investing in and expanding student programs. One way student opportunities started to grow was through increased support and recognition of young researchers. Currently, ECS has 13 student awards, 9 of which were established during Calvo’s tenure, including the biannual meeting student poster session awards, which are among the now robust portfolio of student awards. Shortly after Calvo became executive director, he and the ECS Education Committee realized that a poster session could function as an ideal platform for students to present their work, network with the top researchers in the field, and be recognized for their accomplishments. The first General Student Poster Session was held in 1993 at the 184th ECS Meeting in New Orleans with a successful showing for the inaugural event, which featured a few dozen student posters. By now, this event has grown into an enormously effective program, highlighting young researchers from around the world, with 102 posters presented at the 233rd ECS Meeting in Seattle in 2018. The objective was to enable an easier, more accessible opportunity for students to attend ECS meetings and create more interaction once they got there. Calvo directed the implementation of the ECS Student Mixer, creating a unique opportunity at the time for students to network with senior scientists and engineers, fellow students from around the world, and like-minded thinkers. And, working with the ECS divisions, he has enabled the awarding of around $75,000 in student travel grants annually to assist students with attending ECS biannual meetings. 12
The development of ECS student chapters allowed for students to continue exploring new opportunities outside of meeting settings. Student chapters were established under Calvo’s leadership in the late ‘90s through the ECS Council of Sections. During that time, a group of students from Penn State came to the Society looking for official recognition from a professional society to gain full access to university resources as a student affiliation. Upon this request, Calvo and Daniel Schwartz, then chair of the Council of Sections, worked together to draft the guidelines for what would become ECS student chapters.
In Calvo’s 26 years as executive director, student participation in ECS programs has more than doubled. “The student chapters have become one of the more vibrant membership-oriented activities over the years,” Schwartz said. “Roque shepherded this program through leadership so that we were actually able to have the chapters. ECS is a good organization for students, and the chapters provided one more opportunity and kicked off a whole student program that would be built around this.” The creation of student chapters allowed young researchers new opportunities to network with the Society’s constituents, gain funding to support chapter activities, get access to career resources, and partner with local sections. Student chapters have become wildly successful, with over 70 having been established around the world, providing students the opportunity to pursue new opportunities and ECS the ability to establish communication with this vital group of researchers.
Membership and constituent programs With Calvo’s tenure came a more robust honors and awards program. Changes were implemented and new awards were established, leading to a total today of 53 Society, student, division, and section awards. The development of new awards allowed for researchers to be recognized for their accomplishments, giving those individuals stature in the field as well as the potential to get more funding for the programs due to this increased recognition. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Free the Science
Roque Calvo interviewing John B. Goodenough for the ECS Masters series in 2016 at PRiME in Honolulu, HI.
ECS’s membership now stands at over 8,000 constituents, with the Society consistently developing new opportunities for members to advance their professional careers and access innovative grant programs. These include several new summer fellowships and the addition of the ECS Toyota Young Investigator Fellowship in 2014, which provides yet another resource for early researchers to connect with a major industrial organization and receive funding to pursue innovative work.
In Calvo’s 26 years as executive director, 29 new awards were established. With committee and staff assistance, Calvo managed the creation of a professional development program in 1997. This program consists of workshops, professional panels, and career resources that help both early-career researchers and experienced professionals learn integral information about the field and propel their careers in the right direction. These programs were added to the already established short courses to offer members opportunities to learn about some of the hottest topics in the field from academic and industry experts. Finally, in 2014, Calvo started the process of expanding member recognition beyond the honors and awards program by establishing the Society’s first marketing department. Again, Calvo looked to harness new technological advances and promote the Society and its members by creating a digital media library with videos, podcast, and other new media initiatives.
Roque Calvo interviewing Gordon E. Moore in 2016 in Hawaii.
Throughout his career with the Society, Calvo watched as the amount of research published grew exponentially. With the increased amount of content out there, accessibility started to become an even more important issue, especially in light of the rising subscription costs of large, for-profit publishers. When Calvo started with the Society in 1980, the scholarly publishing model was vastly different, with only paper journals and subscription prices that were affordable to most universities and institutions. As for-profit publishers began dominating the scholarly publishing field and smaller, nonprofit publishers struggled to compete, the entire publishing model started on a drastic evolution, bringing into question price barriers and access to information. In a 2010 Interface article, “Chasing the Great White Whale,” Calvo described this issue and emphasized the need for the free, open dissemination of research. “ECS is the steward of electrochemical and solid state science and technology, which is an increasingly important role now that commercial enterprises dominate scientific publishing and stymie the advancement of our science,” he said in the article. “The reality in the new millennium is that scientific publishing can, but should not be, a money-making proposition.” This new publishing reality had significant implications on the Society’s mission to disseminate research to advance the science, and this was not lost on Calvo, whose strategic compass was based on the mandate of the ECS mission. This threat compelled Calvo to study and diagnose the issues and changes in research publishing long before the Society’s initiative known as Free the Science would gain its name. “High prices represent an obstacle in the dissemination of information and we cannot accept a situation where multibillion dollar corporations, who set high prices to generate large profits, determine what scientific research will cost and what results are publishable,” Calvo continued in the 2011 Interface article. “Our ultimate goal is to create open access to the ECS Digital Library, which means ECS is planning to eliminate the cost obstacles for the scientific research that we publish.”
In 37 years, Calvo has served for 336 ECS board members while attending 89 consecutive board meetings. The elimination of the price barrier would be Calvo’s great white whale, a reference to Herman Melville’s Moby Dick, a story about one captain’s passionate chase around the globe. Calvo continued pursuing this mission-based imperative, finally putting a name to the vision in 2013. “Our goal is to provide open access to all the content in the ECS Digital Library and literally free the science for researchers in electrochemistry and solid state science all over the world,” Calvo said in a 2013 Interface article. “This is truly a risky walk across the high wire, but the possibilities of open access have made it an organizational imperative.” That same year, he put together the Committee on Free Dissemination of Research, calling on Larry Faulkner to chair this committee made up of such prolific scientists as Allen Bard, Esther Takeuchi, Mark Wrighton, Tetsuya Osaka, and Martin Winter. The committee was charged with “evaluating the future of open access for ECS and its impact on scientific advancements in our field” and “making recommendations concerning ECS’s organizational structure, funding options, and advocacy requirements necessary for an open access model that will lead to successful and uninhibited scientific advancement.”
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“Roque was central to our discussion and the work of that committee,” Faulkner said. “In fact, the Society’s ability to prepare for that committee and gather resources that could get us started toward making the changes we were discussing was heroic.” In March 2014, the committee came to the conclusion that in addition to maintaining the high standards and rigorous peer review associated with ECS journals, the Society should pursue complete open access to keep the publications relevant and sustainable. The initiative kicked off by launching a hybrid open access program for ECS journals called Author Choice Open Access. To gain momentum, ECS began publishing open access manuscripts while providing a generous introductory waiver program for article processing charges. The ECS Board of Directors approved the launch of the Free the Science campaign in 2015 with the long-term goal to help make the entire ECS Digital Library open access, eventually eliminating subscription costs while continuing to allow authors to publish their work for free. “For me, this is the most important initiative in all my years of service and it is also the most daunting,” Calvo said during the plenary at the 229th ECS Meeting. “Undoubtedly, Free the Science is a bold vision and just as I have been supported by so many of you over the years, I ask for your support again now so we can advance this critical science at a pace I could never have imagined when this journey started.”
In honor of 37 years of service from Executive Director and CEO Roque Calvo, The Electrochemical Society has created the Roque Calvo Next Generation Scholarship Fund.
Purpose Ensure the participation of students and young investigators at ECS meetings through travel grants.
Goal
During the 229th ECS Meeting in 2016 in San Diego, Roque Calvo launched the Free the Science campaign at the plenary session.
The Free the Science initiative has continued to expand over the past two years, incorporating ideas and values from the open science and open data movements. Through initiatives such as the launch of ECSarXiv, a preprint service developed through a partnership with the Center for Open Science, enhanced research dissemination with Research4Life, the Society’s first OpenCon event in 2017, and the start of the ECS Data Sciences Hack programming, ECS continues to move toward a future that embraces open science to further advance research in the fields of electrochemical and solid state science and technology. Since 2014, over 35% of the manuscripts published in ECS journals have been open access, and most importantly, ECS has experienced phenomenal progress in achieving the mission by increasing dissemination from the ECS Digital Library by 220% to over 3.5M downloads last year. “If you are anywhere for over 37 years, like I have been at ECS things are going to happen,” said Calvo recently. “But to truly accomplish anything, it’s all about building relationships. As executive director, it has been my pleasure and honor to serve as the staff leader of a great international institution. Success in my position has required partnerships that have lasted for decades and generated ideas and support from volunteer leaders who serve on the board, committees, divisions, and as editors and symposium organizers. And, of course, the staff support has been essential. The many years of meetings and activities blend after a while, the journey is what I’ll remember and all the extraordinary people who have shared it with me.”
Raise $500,000 which will fund an additional 50 students per year to attend ECS biannual meetings.
Donate Learn more and make a donation at www.electrochem.org/next-gen.
If you are interested in other ECS giving opportunities, please contact Ngoc Le at Development@electrochem.org or call 609.737.1902 ext. 102. 14
Roque Calvo and his wife Marianne Calvo at the presidential reception at the meeting in Seattle, WA, in spring 2018.
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Thanks Roque ... for your insights, guidance and support of the International Symposium on Solid Oxide Fuel Cells for the last thirty years. - Subhash C. Singhal, Founding Chair
Sixteenth International Symposium on Solid Oxide Fuel Cells (SOFC-XVI) September 8-13, 2019 Kyoto Terssa, Kyoto, Japan Subhash Singhal
Chairs: Subhash Singhal and Koichi Eguchi
Koichi Eguchi
Sponsors: SOFC Society of Japan The Electrochemical Society, Inc.
AIP & AIP Publishing
CONGRATULATE ROQUE CALVO ef on his years of service and dedication to THE ELECTROCHEMICAL SOCIETY
Dear Roque
We express sincere congratulations on your retirement, and our deep gratitude for your excellent achievements in building good relations between the ECS and the ECSJ, especially for the successful establishment of the joint meetings and PRiME! - on behalf of all ECSJ members
The Electrochemical Society of Japan
Korean (KECS) deeply KoreanElectrochemistry ElectrochemicalSociety Society (KECS) deeply appreciates service appreciates Roque Roque Calvo Calvo for for his his 37 37 years years of of service and to to Thethe Electrochemical Society anddedication dedication Electrochemical Society (ECS) andand contributions to to (ECS) and andconstant constantsupport supports contributions establish establish KECS-ECS KECS-ECS collaborations. collaborations.
s
37
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Y Roque, Thank you for your leadership, guidance, and passion for ECS!
16
-ECS Staff The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
233rd ECS Meeting
Seattl e, WA
May 13-17, 2018
Seattle Sheraton and Washington State Convention Center
O
Highlights from the 233rd ECS Meeting ver 2,600 people from 53 countries attended the 233rd ECS Meeting in Seattle, WA, May 13-17, 2018— the largest spring meeting in the Society’s history! Participants could choose from 46 symposia, with over 2,000 oral talks and nearly 600 posters, of which almost 700 were student presentations.
Attendees networked while enjoying refreshments at the meeting’s opening reception.
Opening Reception A new and improved opening reception kicked off the meeting. Held in a spacious atrium in the Washington State Convention Center, the well-attended Sunday evening social event featured light snacks and an open bar. Visit Seattle personnel were in attendance to provide attendees information on the city and things to do during their stay. The lively event offered attendees ample opportunity to network.
Plenary Session
ECS Senior Vice President Yue Kuo presented the opening remarks at the 233rd ECS Meeting.
ECS Senior Vice President Yue Kuo welcomed attendees to the meeting during Monday evening’s plenary session, an event that wrapped up the day’s technical sessions, honored award winners, and featured the meeting’s ECS Lecture. “It’s your attendance at our meetings, being a member of ECS, advocating with your libraries to subscribe to ECS publications, and publishing your work with ECS that allows us to continue to Free the Science,” Kuo said. “You should be proud as we continue to build a
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of the Walk Again Project, an international consortium of scientists and engineers dedicated to the development of exoskeleton devices to assist severely paralyzed patients in regaining full bodily mobility. After recounting his early career in John K. Chapin’s laboratory, Nicolelis began his fascinating talk with how brain encodes sensory and motor skills in animals and human beings. Some 86 billion brain cells are involved and an understanding of how signals are processed and propagated may have implications in the treatment of many neurological diseases. He showed action potential experiments from surgically implantable devices in the rhesus monkey brain cortex; these electrodes could be left in the brain for years for continued experiments. Such brain/machine interfaces (BMIs) form the basis for discovering a series of key physiological principles that govern the operation of mammalian brain circuits. Even more intriguing with these BMIs was the demonstration by Nicolelis and coworkers that animals and human subjects can utilize their electrical brain activity to directly control neuroprosthetic devices. He showed videos of monkeys and rats triggering robotic limbs to perform a variety of tasks, although a paraplegic human subject kicking a soccer ball was perhaps the most vivid demonstration of all. This reporter has covered many plenary talks at ECS meetings and it is no exaggeration to say that this was one of the most compelling and inspirational talks that he had heard in years. This talk provided a fitting start to the technical sessions that followed during the weeklong meeting.
ECS Executive Director and CEO Roque Calvo was granted ECS honorary membership in recognition of all he has done for the Society throughout over 37 years of service.
rich tradition of open science while supporting the next generation of scientists, ECS meetings, and each other.” During the plenary, Kuo announced the launch of ECSarXiv, the Society’s new preprint service, as well as the Amazon Catalyst at ECS program, a new opportunity for ECS members to receive financial support to pursue solutions in health and sustainability. Before introducing the meeting’s ECS Lecture, Kuo took an opportunity to honor the legacy of ECS Executive Director and CEO Roque Calvo, who—after over 37 years of service to the Society—is stepping down from his position. “Roque has served as a steward of the Society for over 37 years,” Kuo said, “guiding the Society through tremendous changes while remaining dedicated to its mission to advance electrochemical and solid state science and technology.” Kuo then highlighted some of the most significant accomplishments of Calvo’s tenure. “Roque took the Society from print to digital, created an international audience for our programs and meetings, expanded the ECS Honors & Awards program, and encouraged student participation by instituting student chapters and adding more travel grants and fellowships,” Kuo said. Kuo concluded by announcing the establishment of a new Society travel grant fund for students and early-career scientists and researchers—the Roque Calvo Next Generation Scholarship Fund— and by granting Calvo honorary membership with ECS in recognition of his long-standing devotion to the Society.
The ECS Lecture Miguel Nicolelis, MD, PhD, delivered the ECS Lecture, “Linking Brains to Machines: From Basic Science to Neurological Neurorehabilitation,” to a packed audience Monday evening. Nicolelis is a distinguished professor of neuroscience at Duke University and is the founder of Duke’s Center for Neuroengineering. He is founder and scientific director of the Edmond and Lily Safra International Institute for Neuroscience in Natal, Brazil. Nicolelis is also founder 18
Miguel Nicolelis, the Duke School of Medicine Distinguished Professor of Neuroscience, delivered the ECS Lecture during the plenary session.
ECS Data Sciences Hack Week Building on the success of the first ECS Data Sciences Hack Day (October 2017), the Society offered an expanded program at its Seattle meeting. The ECS Data Sciences Hack Week kicked off on Monday and consisted of all-day sessions Wednesday through Friday, as well as optional software training tutorials during the week. These activities culminated with project presentations and an optional clamming expedition—a traditional activity in the Puget Sound area—on Saturday. Like Hack Day, Hack Week was organized by Daniel Schwartz, David Beck, and Matthew Murbach of the University of Washington. Daniel Schwartz is the Boeing-Sutter Professor of Chemical Engineering and director of the Clean Energy Institute at the University of Washington. He brings electrochemistry and modeling expertise to the team. David Beck is a senior data scientist with the eSciences Institute at the University of Washington who leads regular The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Participants of the ECS Data Sciences Hack Week.
hackathons. He is also the associate director of the NSF Data Intensive Research Enabling CleanTech PhD training program. Matthew Murbach is a past president of the ECS University of Washington Student Chapter and an advanced data sciences PhD trainee. He has been leading student section software development sessions on the UW campus and has practical experience coaching electrochemical scientists and engineers in software development. The goal of the event was to increase the awareness and impact of data science tools, open source software, and shared datasets in electrochemistry and solid state science and technology by bringing together people from different backgrounds to collaborate.
David Danielson, managing director of Breakthrough Energy Ventures, gave a talk during the Annual Society Business Meeting and Luncheon.
Following the reports, Kuo introduced a speaker—a new addition to the annual event. The speaker was David Danielson, managing director of Breakthrough Energy Ventures, who presented a talk titled “Electrochemistry & the Electrification of Everything in the Era of Low Cost Renewable Energy.”
Trip to Microsoft SOFC Powered Data Center On Thursday a limited number of meeting attendees took part in an excursion to Microsoft’s state-of-the-art data center powered by solid oxide fuel cells. Participants took a tour of the facility and had the opportunity to ask questions about the test center and the SOFC technology involved. Tickets for this high-demand event sold out quickly.
Award Highlights
Participants at work during a Hack Week session.
Annual Society Business Meeting and Luncheon During the Annual Society Business Meeting and Luncheon held on Tuesday, ECS leadership reported on the Society’s 2017 successes with a focus on the organization’s future. “Now more than ever,” said ECS Senior Vice President Yue Kuo, “you’ll want to support ECS by making a donation, renewing your membership, and publishing with us—ideally, open access. These simple contributions allow you to support the next generation of scientists, our meetings, and ECS’s initiative to Free the Science that aims to make science more open.”
Two Society awards were presented during the plenary session. The ECS Vittorio de Nora Award was presented to Hariklia (Lili) Deligianni. Deligianni is a research scientist in IBM’s Thomas J. Watson Research Center. Her current research interests include materials and devices for power electronics, bioelectronics, biosensors, and brain-inspired computing. Deligianni has played a key role developing the solder bump technology that became the standard for the joining of silicon chips to packages. She coinvented copper electrodeposition for on-chip interconnects and was a corecipient of the 2006 Inventor of the Year Award from the New York Intellectual Property Law Association. For these technologies, IBM was recognized with the U.S. National Medal of Technology and Innovation. She has developed an electrodeposition route for the synthesis of solar thin film semiconductors and earth abundant solar materials and has been instrumental in the scale-up of thin film solar energy conversion technologies. Deligianni holds PhD and MS degrees in chemical engineering from the University of Illinois at Urbana-Champaign and a BS in chemical engineering from Aristotelion University in Thessaloniki, Greece. She has coauthored 58 manuscripts and has 187 patents, with more than 30 patents pending with the United States Patent and Trademark Office. Deligianni is a member of the IBM Academy of Technology and an ECS fellow. In 2012, Deligianni was the first female recipient of the ECS Electrodeposition Division Research Award. She is a past secretary of ECS (2012-2016) and has served as chair of the ECS Education Committee, the ECS Ways and Means
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Hariklia (Lili) Deligianni (right) received the ECS Vittorio de Nora Award from ECS Senior Vice President Yue Kuo (left).
Committee, and the ECS Electrodeposition Division. She is a senior member of the Institute of Electrical and Electronics Engineers and the American Institute of Chemical Engineers and a member of the International Society of Electrochemistry, the American Chemical Society, the Association for Computing Machinery, and the American Association for the Advancement of Science. The Vittorio de Nora Award was established in 1971 to recognize distinguished contributions to the field of electrochemical engineering and technology. The ECS Henry B. Linford Award for Distinguished Teaching was presented to Ralph E. White. White is a professor of chemical engineering and a distinguished scientist at the University of South Carolina. He graduated from the University of South Carolina with a BS in chemical engineering in 1971. He then attended the University of California at Berkeley and completed his PhD in 1977 under the direction of John Newman. White began his teaching career at Texas A&M University in 1977. In 1993 he moved to the University of South Carolina, where he served as the chair of the Department of Chemical Engineering for seven years and then as the dean of the College of Engineering and Computing for five years. In 1995 he founded the Center for Electrochemical Engineering. White has published 338 peer-reviewed journal articles and has graduated 50 PhD and 39 MS students. He is a past treasurer of ECS (1990-1994) and a fellow of ECS, the American Institute of Chemical
Ralph E. White (left), recipient of the ECS Henry B. Linford Award for Distinguished Teaching, with his wife, Marjorie Nicholson (right). 20
Engineers, and the American Association for the Advancement of Science. White has received several international awards, including the American Electroplaters and Surface Finishers Society Scientific Achievement Award (2000) for mathematical modeling of the electrodeposition of alloys, the ECS Olin Palladium Award (2013) for contributions to the science of electrochemistry, and the ECS Vittorio de Nora Award (2016) for contributions to the field of electrochemical engineering and technology. He has served as a consultant to several major companies, including Energizer and General Electric. The Henry B. Linford Award for Distinguished Teaching was established in 1981 to recognize excellence in teaching in subject areas of interest to the Society. Eight division awards were presented over the course of the meeting. • The ECS Electronics and Photonics Division Award was presented to Tae-Yeon Seong of Korea University. • The ECS Energy Technology Division Research Award was presented to Yushan Yan of the University of Delaware. • The ECS Energy Technology Division Supramaniam Srinivasan Young Investigator Award was presented to Marίa Escudero Escribano of the University of Copenhagen. • The ECS Energy Technology Division Graduate Student Award sponsored by Bio-Logic was presented to Deijun Xiong of Shenzhen Capchem Technology Co., Ltd. (continued on page 22)
Tae-Yeon Seong, winner of the ECS Electronics and Photonics Division Award.
ECS Energy Technology Division Chair Andrew Herring (right) presented Yushan Yan (left) with the ECS Energy Technology Division Research Award. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
ECS Energy Technology Division Chair Andrew Herring (left) presented Marίa Escudero Escribano (right) with the ECS Energy Technology Division Supramaniam Srinivasan Young Investigator Award.
ECS Industrial Electrochemistry and Electrochemical Engineering Division Chair Douglas Riemer (middle) and division member Elizabeth Biddinger (left) presented Yasser Ashraf Gandomi (right) with the ECS Industrial Electrochemistry and Electrochemical Engineering Division Student Achievement Award.
ECS Energy Technology Division Chair Andrew Herring (middle) and Bio-Logic owner Bill Eggers (left) presented Deijun Xiong (right) with the ECS Energy Technology Division Graduate Student Award sponsored by Bio-Logic.
ECS Nanocarbons Division Chair Slava V. Rotkin (right) presented Michael S. Arnold (left) with the ECS Nanocarbons Division SES Young Investigator Award.
Flavio Maran, winner of the ECS Organic and Biological Electrochemistry Division Manuel M. Baizer Award.
Soo Kim, winner of the ECS Industrial Electrochemistry and Electrochemical Engineering Division H. H. Dow Memorial Student Achievement Award.
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(continued from page 20) • The ECS Industrial Electrochemistry and Electrochemical Engineering Division H. H. Dow Memorial Student Achievement Award was presented to Soo Kim of the Massachusetts Institute of Technology. • The ECS Industrial Electrochemistry and Electrochemical Engineering Division Student Achievement Award was presented to Yasser Ashraf Gandomi of the University of Tennessee, Knoxville.
• The ECS Nanocarbons Division SES Young Investigator Award was presented to Michael S. Arnold of the University of Wisconsin-Madison. • The ECS Organic and Biological Electrochemistry Division Manuel M. Baizer Award was presented to Flavio Maran of the University of Padova.
General Student Poster Session There were 103 posters presented in the General Student Poster Session. The session’s award winners are listed below. • Mario Cedano, San Diego State University, “RedoxResponsive Dimerization in a Ferrocene-Ureidopyrimidinone Supramolecular Assembly” • Hao Wang, Beijing University of Chemical Technology, “Metal-Organic Framework Supported on Food Waste-Derived Carbon as an Efficient Bifunctional Catalyst for Oxygen Electrocatalysis” • David Reber, École Polytechnique Fédérale de Lausanne, “High-Voltage Aqueous Electrolytes for Sodium-Ion Supercapacitors and Batteries”
• Jae Young Yoo, Korea Advanced Institute of Science and Technology, “Comprehensive Analysis of a Tubular, Reversible Solid Oxide Fuel Cell by Using a 3-D Computational Fluid Dynamics Model” • Tammy Pham, San Diego State University, “Evaluating the Roles of Proton Transfer and H-Bonding in the Electron Transfer Reactions of Organic Redox Couples in Non-Aqueous Solvents: Oxidation of Phenylenediamines in the Presence of Pyridine Bases in Acetonitrile”
Winners of the General Student Poster Session (left to right): Jae Young Yoo, Hao Wang, Tammy Pham, Mario Cedano, and David Reber.
The following ECS division members served as student poster judges. • Battery, Industrial Electrochemistry and Electrochemical Engineering, and Sensor Divisions: Tissaphern Mirfakhrai, Joshua Gallaway, and Roseanne Warren • Dielectric Science and Technology and Electronics and Photonics Divisions: Nikolay Dimitrov, Douglas Riemer, Jan Froitzheim, and Paul Gannon • Energy Technology Division: Andrea Bourke, Douglas Kushner, and Miomir Vukmirovic
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• Corrosion, Electrodeposition, and Physical and Analytical Electrochemistry Divisions: Iwona Rutkowska, Eiji Tada, and Sadagopan Krishnan • High Temperature Materials, Luminescence and Display Materials, Nanocarbons, and Organic and Biological Electrochemistry Divisions: Wilson Chiu, Mark Allendorf, Jeffrey Halpern, and Graham Cheek ECS thanks the sponsors of the 233rd ECS Meeting, the faculty advisors, and the division members who served as judges for their support of the session.
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Sponsors and Exhibitors Special thanks to the meeting’s sponsors and exhibitors, whose support and participation directly contributed to the success of the meeting. Thank you for developing the tools and equipment driving scientific advancement and for sharing your innovations with the ECS community.
Gold
Silver
Bronze
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societ PEOPLE y ne ws
a free preprint service for electrochemistry and solid state science and technology
Visit www.electrochem.org/ecsarxiv to learn more!
powered by OSF Preprints
Questions? Contact ecsarxiv@electrochem.org. 24
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
The New ECS Preprint Service by Mary Yess
What is a preprint anyway? That has been a recurring question since ECS announced its plans to open a preprint service to support the technical community we serve. Simply put, a preprint is a version of a scholarly or scientific document or other preliminary communication not yet published in a peer-reviewed outlet. In May, the Society launched the service, called ECSarXiv, and pronounced “ECS archive.” At the ECS’s spring meeting in Seattle—in the booth, at the info session, and in the halls—the question of what is a preprint was prevalent, and there were many other questions on topics such as discoverability, use, quality, and scooping. Preprints do not replace a journal paper, they precede it. Preprints and journal publication work in parallel as a communication system for scientific research. Preprints allow researchers to directly control the dissemination of their work to the community world-wide. Preprints are not formally peer reviewed; so when reusing or citing them, this status should be clearly indicated. In many cases, preprints and journal manuscripts are the same in their basic content. Typically, a A preprint is a version preprint is submitted before of a scholarly or the manuscript is scientific document submitted to a or other preliminary journal.
“
“
communication not yet published in a peerreviewed outlet.
Are preprints a new phenomenon?
Submissions
hile ECS would love to take credit for the idea of preprints as an innovative way to share content, the idea has been around since 1991. Researchers at the Los Alamos National Laboratory began emailing physics preprints to each other around 1990. Paul Ginsparg then created a central repository that could be accessed from any computer. Today, arXiv.org is a highly-automated electronic archive and distribution system for research articles, home to nearly 1.4 million preprints, and maintained and operated by the Cornell University Library. To date, there are approximately 25 known preprint services across the globe, serving a wide variety of disciplines.1 The nature of this first open sharing platform was one of the factors that has led to the open access movement, and since then, many preprint services have been born. ECSarXiv joins 18 other services on a platform developed and hosted by the Center for Open Science (COS).2
A very important rule for ECSarXiv submissions is that they may not be articles that have already been published in a peer-reviewed journal. All ECSarXiv preprints undergo a screening process to reject content not relevant to the fields ECS covers and/or offensive and/or nonscientific content.3 A preprint can offer more freedom of expression. As just one example, for many journals, the short communication article type has strict guidelines for length and formatting. In a preprint, you can extend the introduction, conclusion, and references to provide more context for your work. Information that is currently difficult to publish (e.g., negative results, results in slide decks, explanations of datasets, etc.) can be submitted. Based upon feedback and/or new data, new versions of a preprint can be presented. While the scholarly communications ecosystem is rapidly progressing to allow freer communication, some journals are lagging behind in what authors want and need. For example, some journals do not allow a new version to be submitted to a preprint service after that content has been submitted to the journal; and some journals do not allow upload of the copyedited, formatted article. It is very important to always check the policies of individual journals before posting your preprint. ECS does allow preprints to be submitted to our journals, once the preprint has been shaped into a full journal article.4
W
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A sample preprint.
Enhancing visibility The fact that most preprints are open access enhances visibility, especially for early-career researchers; and the rapid publication of preprints provides evidence of productivity and accomplishment. Authors can make use of preprint services to develop new collaborations earlier. There also have been instances of journal editors scanning preprint services, seeing posts, and then contacting the authors to submit to their journals. After a quick moderation process (2-3 business days), preprints are immediately available, allowing funding agencies an early look at research where a journal article might not be ready for months. The US National Institutes of Health encourages investigators to “use interim research products, such as preprints, to speed the dissemination and enhance the rigor of their work.”5 Other agencies are encouraging researchers to submit preprints, for example the UK Wellcome Trust6 and the US National Science Foundation.
To submit or not submit (patent and scooping considerations)
Posting a preprint can help to establish the priority of discoveries because they are date-stamped. In addition, preprints can aid in reproducibility, because preprints can show new, confirmatory, or even contradictory results. If you plan to file a patent, it’s important to understand that patent law is complex as related to publications and public availability. Consequently, authors should always seek legal advice about publishing (in any form), any description of the invention the author desires to patent. That being said, note that authors have complete control over the timing of a preprint release.7 Another concern is that a preprint could release information that could have adverse effects on the public at large. In fact, when misinformation is published in a journal, it can be more damaging because journals carry an implied seal of approval from the scientific community. This is a growing issue, not only in preprints, but in Discoverability and citability journal publishing; and many organizations have measures in place to manage this concern. Nevertheless, preprint services, as well as Preprints afford citable documentation of preliminary results of peer-reviewed journals, will require continued attention from our research because they carry a digital object identifier (DOI), which scientific community. provides a persistent and interoperable link. ECSarXiv provides a “Scooping” is another issue, and one that gets a great deal of choice of citation styles. Most styles (Chicago, MLA, etc.) call for attention in discussions about preprints. Researchers worry that their citing the authors(s)’ names, the date, the title of the preprint, and the ideas and work will be published by others and that they will not DOI. Be sure to check with the journal where you want to submit receive proper recognition. Postings in most preprint services, for its specific style for citing preprints. like ECSarXiv, however, are date-stamped priority claims, All preprints submitted through the OSF Preprints and can actually counter scooping practices. Paul Ginsparg, platform are indexed by Google Scholar (which takes the founder of arXiv, has contributed to an excellent 7-10 days) and SHARE (which only takes minutes). discussion on scooping.8 To search Google Scholar for ECSarXiv preprints, The current journal system already is challenged enter “https://osf.io/preprints/ecsarxiv *” into the by issues of poor quality, irreproducibility, and search box. You can replace the * with other gaps in peer review; but there is no current search text such as “fuel cells” to refine the evidence that the situation will worsen with search. preprints. In some cases, preprints can help draw attention to errors, enabling the author to correct them before Advisory Board submitting to a journal. Authors should be aware that a pre• Jeff Fergus, Editor, ECS Transactions print can be flawed, just as • Dennis Hess, Editor, ECS Journal of Solid State Science and a journal paper can be. Researchers work Technology hard to build and • Robert G. Kelly, Editor, Interface maintain excel-
• Robert Mantz, United States Army Research Office • Slava Rotkin, Pennsylvania State University
• Robert Savinell, Editor, Journal of The Electrochemical Society • Mary Yess, ECS Chief Content Officer & Publisher • Beth Craanen, ECS Director of Publications
Submit Meeting Content Beginning with AiMES (fall 2018), ECS Transactions (ECST) will discontinue publishing umbrella term standard issues (or “after meeting” content) for ECS biannual meetings. Instead, that supports lent reputations ECS encourages presenters to submit this content to ECSarXiv. Although a broad spectrum in their fields, and enhanced issues (or “before meeting” content) of ECST will remain of practicing science they continue these unchanged, authors submitting to these issues will also be able to to enable researchers practices when publishsubmit other types of content from their meeting presentation to collaborate, so that data ing in preprint services. (such as slideshows, posters, or data) to ECSarXiv. and other research processes Meeting presenters should check the meeting’s are freely available, and so that Choosing a license call for papers to find out more information others may share and reproduce the about which symposia are publishing research.”11 Choosing a license can be ECSarXiv helps us to better serve content in ECS Transactions. particularly daunting in the open access environment in which we now live. The appropriate license communicates to others how you will allow others to use your work. ECSarXiv currently allows for a wide variety of licenses, from Creative Commons open access licenses to open source licenses. When submitting a preprint in ECSarXiv, clicking on the “show full text” link (under “choosing a license”) will show you the actual license terms of any particular license. Authors typically choose a Creative Commons (CC) license for preprints, and the CC site has excellent information about these licenses in general, and help in choosing a license.9 For those considering attaching software code to their preprint, there are resources that can help with license selection. Check the Free Software Foundation or check the licenses listed as “open source” from the Open Source Initiative. Researchers looking for the policies of specific journals or funding agencies can make use of two excellent resources. The first is SHERPA Romeo, which can help researchers to find a summary of permissions that are normally given as part of each publisher’s copyright transfer agreement. The second is SHERPA Juliet, which enables researchers and librarians to see funders’ conditions for open access publication.
Looking ahead COS develops features and functionality on an ongoing basis for all the preprint services they host. One example of a feature that is coming soon is the integration of hypothes.is. This will allow commenting, providing valuable feedback that can help researchers build a robust article for journal submission. Other development goals include working with technical providers to build additional ways to ensure the discoverability of preprints. ECS’s collaboration with COS to create ECSarXiv helped ECS to take another step in our Free the Science10 initiatives by providing a fast, cost-effective way to provide services and tools for our members to embrace an “open science” way of working. Open science is an
A sample preprint.
the community of those working in electrochemistry and solid state science and technology, and ECS will continue to take those kinds of steps to improve the culture of communication within the scholarly community, now and in the future.
References 1. A list of current preprint services (not comprehensive) may be found by starting at Wikipedia, https://en.wikipedia.org/wiki/ Preprint#Servers_by_field, downloaded May 22, 2018. 2. A full list of all the preprint services on the COS site: https:// osf.io/preprints/. 3. The ECSarXiv posting policy: www.electrochem.org/ ecsarxiv/#posting. 4. Author instructions for ECS journals, and preprint submissions: https://ecsjournals.msubmit.net/cgi-bin/main.plex. 5. “Reporting Preprints and other Interim Research Products,” US National Institutes of Health, https://grants.nih.gov/ grants/guide/notice-files/NOT-OD-17-050.html, release date: March 24, 2017. 6. The Wellcome Trust stated, “This change will help us (and those reviewing grant applications) to get a more up-to-date picture of researchers’ work.” https://wellcome.ac.uk/news/ we-now-accept-preprints-grant-applications, release date: January 10, 2017. 7. For more information on patent law, be sure to read the ongoing series published in Interface: http://interface.ecsdl.org/content/26/1/41.full.pdf+html, http://interface.ecsdl.org/content/26/2/45.full.pdf+html, http://interface.ecsdl.org/content/26/3/39.full.pdf+html, http://interface.ecsdl.org/content/26/4/57.full.pdf+html, http://interface.ecsdl.org/content/27/1/37.full.pdf+html, and the article in this issue on page 47. 8. “ArXiv founder Paul Ginsparg’s thoughts on scooping,” http://asapbio.org/preprint-info/preprint-faq#qe-faq-922, downloaded May 22, 2018. 9. The Creative Commons website provides help in selecting a license: https://creativecommons.org/share-your-work/. 10. The Free the Science initiative is a broad mission-based initiative launched by ECS in 2014. The goals include working toward full open access for our journals and introducing open science tools and services in support of our constituents, all the while maintaining programmatic and financial sustainability, www.electrochem.org/free-the-science. 11. A diagram of open science and all its branches can be found on the FOSTER e-learning platform, www.fosteropenscience.eu/ foster-taxonomy/open-science-definition, downloaded May 22, 2018. Mary Yess is the Society’s Chief Content Officer and Publisher. http://orcid.org/0000-0003-3909-6524 @maryyess https://osf.io/eznd3/
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New Interface Editor: Robert G. Kelly Robert G. Kelly has been appointed by the ECS Board of Directors as the new editor of Interface for a four-year term. Kelly has demonstrated tremendous commitment to the Society over the years—as a division chair, a symposium organizer, and a prominent member of several standing committees. ECS is extremely pleased to welcome him to the position. Kelly has been conducting research in electrochemical science and engineering for the past 35 years. After completing his PhD studies at Johns Hopkins University (1989), he spent 2 years at the Corrosion and Protection Centre at the University of Manchester (UK) as a Fulbright Scholar and an NSF/NATO postdoctoral fellow. He joined the faculty of the University of Virginia in 1990. His past work has included studies of lithium/iodine batteries, the corrosion of metals and alloys in marine environments, nonaqueous and mixed solvents, as well as stress-corrosion cracking and other
forms of localized corrosion. His present work includes studies of the electrochemical and chemical conditions inside localized corrosion sites in various alloy systems, corrosion in aging aircraft, development of embeddable corrosion microinstruments, microfabrication methods to probe the fundamentals of localized corrosion, and multiscale modeling of corrosion processes. Kelly is the codirector of the Center for Electrochemical Science and Engineering at UVA. He was the 2001 recipient of the Robert T. Foley Award from the ECS National Capital Section. In 2010 Kelly was named an ECS fellow, and in 2016 he was awarded the H. H. Uhlig Award of the ECS Corrosion Division. He is also a fellow of NACE International. In 2013 he was awarded the AT&T Professorship. Kelly has won several teaching awards while at UVA, including an All-University Teaching Award in 2004. He has rendered technical assistance to the NRC and DOE concerning the Yucca Mountain Project, the USAF Aging Aircraft Program, the NASA Safety and Engineering Center, and the 9/11 Pentagon Memorial design team.
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Five Questions with Interface Editor Robert G. Kelly What excites you about taking on the role of Interface editor? I still remember the pride I felt at the founding of Interface when I was a student member. On one hand, it was like a Christmas catalog with the advertisements showing the latest and greatest toys. On the other, it filled an important gap that I did not realize existed: a need to allow members to learn across and outside their technical divisions, whereas the Journal of The Electrochemical Society kept everyone at the forefront of their field. I found that the selection of topics and the outstanding authors in Interface provided me with enough education about a technical area that I could envision its connections to my own work. Its charter to encourage member participation in the entire range of ECS activities, from conference attendance to student chapters, to award nominations, to publications opened up a range of possibilities. Its focus on reaching across the technical divisions to spur collaborative thinking has been ahead of its time, as has its drawing in of highlights from areas of science outside the standard electrochemical ones. In addition, the older I get, the more history means to me, so I believe Interface’s role as the official record of the Society needs to be preserved. Finally, I have long been an advocate of the Society increasing its outreach to the wider scientific community as well as the general public. I am excited to be a part of the exploration of that opportunity. What role has ECS played in your career up until this point in time? I joined ECS in 1982 while an undergraduate working for Pat Moran. Since that time, ECS has been my technical home. My first technical interactions with ECS were through the Battery Division, in whose symposia I gave my first technical presentations. I migrated to the Corrosion Division during my PhD work. Since that time, I have attended an ECS meeting virtually every year, helping to organize symposia, chairing numerous sessions, as well as giving talks. The majority of my publications are in ECS vehicles, from the Journal of The Electrochemical Society to ECS Proceedings Volumes, to ECS Transactions, and even Interface. I also served in all of the offices of the Corrosion Division Executive Committee and several other ECS committees (e.g., Audit, Finance, Meetings, Honors and Awards). I look forward to every ECS meeting not only for the technical interactions, but also as a place where I can catch up with friends and colleagues from all over the world. In trying to pass on the wonderful experiences that I have had with ECS, I assisted students in founding the ECS University of Virginia Student Chapter, which has allowed them to participate in a range of career-enhancing activities. How might Interface play a role in promoting open science? One of the main objectives of ECS is the dissemination of knowledge. Free the Science is the flagship initiative of ECS for dissemination of technical information via the journals. I believe that Interface can be the megaphone for Free the Science to ECS members, in particular in explaining its
motivation, the progress being made, and the outlook for the future. In addition, Interface can expand its role as a means for broad dissemination of electrochemistry and solid state science information in a very accessible format to scientists and engineers in other fields as well as the general public. At a time when the value and reliability of science is under siege, Interface can be a means of connecting the general public to the important work ECS members do and how that work has impacted them, does impact them, and will impact them in the future. What do you see as the untapped opportunities of Interface? Interface has been a great ambassador for ECS, but there is potential for much more. The use of Interface for more aggressive outreach to other fields/societies, students, and the general public appears to be an example of a largely untapped opportunity. In addition, I think there is potential to use the magazine more aggressively within ECS to make connections across technical divisions. Outreach to leadership of professional societies of high school physics and chemistry teachers may be a means to accomplish the former, whereas the Interface Advisory Board and ECS student chapters are two obvious mechanisms by which to accomplish the latter. Last, but certainly not least, the explosion in the capabilities to deliver information electronically via a staggering range of routes represents an incredible opportunity for Interface. Exploiting the ever-increasing power of the Internet will allow us to extend the reach of the society dramatically and provide a forum for informal, but important, interactions among people by knocking down barriers of access. What do you feel is most important for Interface readers to know about you? Most importantly, I understand the jewel that previous editors, ECS staff, and authors have created, and I am committed to doing all I can to make Interface a publication that members even more immediately want to open. I also view this opportunity as a fantastic chance to serve ECS, its members, and the wider audience by facilitating connections. Making connections among people is something that gives me a great deal of joy. I will be attentive to my obligation to make sure that the sum of the articles and other entries in Interface has balance—among technical divisions, among outreach to ECS members, sponsors, other scientists, as well as the general public. In the spirit of full disclosure, the position will also serve as a means to sneakily address my curiosity about the breadth of the field of electrochemistry. Although I have published in the areas of corrosion, batteries, and electrochemical sensors, there are many times I wish there could be many of me to allow the exploration of all of the technical divisions (I will stipulate that very few people would support the existence of many of me). I feel like the proverbial kid in the candy store. I will have the chance to learn about each of the divisions from the foremost experts in their fields, which sure beats working for a living. Robert G. Kelly may be reached at rgk6y@virginia.edu.
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Free the Science Week 2018 ECS hosted its second Free the Science Week April 2-8, 2018, enabling free, uninhibited access to the entire ECS Digital Library, which by now contains over 141,000 articles and abstracts spanning critical areas of electrochemical and solid state science and technology. The week was characterized by substantial increases— both in digital library visitors and in full-text downloads across all ECS publications. ECS launched the first Free the Science Week in April 2017 in commemoration of the Society’s 115th anniversary and in support of its Free the Science initiative, a long-term drive toward transformative change in the traditional models of scholarly communication and a future that embraces open science as a means of advancing research and accelerating the development of new solutions in sustainability. The inaugural week saw huge surges in digital library visits and ECS content access. Free the Science Week 2018 elicited a similar response that in some ways even surpassed the success of the first Free the Science Week. This year’s Free the Science Week attracted over 800 more digital library visitors than Free the Science Week 2017, as well as a higher percentage of visitors who had never before visited the digital library (2018: 62%, 2017: 49%).
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Nearly all ECS publications saw steeper increases in usage (over their first-quarter monthly averages) in April 2018 than they did in April 2017. The ECS Journal of Solid State Science and Technology, which saw a 15% increase in full-text downloads in April 2017, saw a 33% increase in April 2018. ECS Transactions, which saw a 47% increase in full-text downloads in April 2017, saw a 64% increase in April 2018—the sharpest increase of any ECS publication during the month. This year’s Free the Science Week established April 2018 as the highest usage month of the year to date for ECS publications, both individually and collectively. From a broader perspective, the month marked the second-highest month of April usage, and the fifth-highest month of total usage, since January 2013. These surges in usage are testaments to the value of open science initiatives and the critical needs in the research sphere they seek to address. Free the Science Week, after all, is much more than a week of free paper downloads; it is a celebration of open science and a commitment to the changing of a culture that bars far too many from the keys to innovation.
Associate Editor Venkat Srinivasan Reappointed Venkat Srinivasan has recently been reappointed as an associate editor of the Journal of The Electrochemical Society (JES) for a three-year term. Srinivasan is the director of the Argonne Collaborative Center for Energy Storage Science and the deputy director of the Joint Center for Energy Storage Research. His research focuses upon the development of next-generation batteries for various uses, including vehicle and grid applications. Srinivasan has a strong interest in the design and commercialization of new technologies within the energy storage sector. Srinivasan has served on the JES Editorial Board since 2013 and specializes in the batteries and energy storage topical interest area.
www.koslow.com “Fine electrochemical probes since 1966”
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Focus on Focus Issues ECS publishes focus issues of the Journal of The Electrochemical Society and the ECS Journal of Solid State Science and Technology that highlight scientific and technological areas of current interest and future promise. These issues are handled by a prestigious group of ECS technical editors and guest editors, and all submissions undergo the same rigorous peer review as papers in the regular issues. As begun in 2017, all focus issue papers are open access at no cost to the authors. ECS waives the article processing charge for all authors of focus issue papers as part of the Society’s ongoing Free the Science initiative. The following focus issues are currently in production with many papers already published in the ECS Digital Library (http://ecsdl.org): • JES Focus Issue on Proton Exchange Membrane Fuel Cell Durability. [JES 165(6) 2018] Thomas Fuller, JES technical editor; Jean St-Pierre, Deborah Myers, and Rodney Borup, guest editors. • JES Focus Issue on Ubiquitious Sensors and Systems for IoT. [JES 165(8) 2018] Rangachary Mukundan, JES technical editor; Ajit Kholsa, Praveen Kuman Sekhar, Peter Hesketh, Charles Henry, and Luca Magagnin, guest editors. • JES Focus Issue on the Brain and Electrochemistry Honoring R. Mark Wightman and Christian Amatore. [JES 165(12) 2018] Janine Mauzeroll, JES technical editor; Lili Deligianni, Michael Wolfson, Nick Langhals and Mekki Bayachou, guest editors.
The following focus issues are open for submissions. Manuscripts may be submitted at http://ecsjournals.msubmit.net: • JES Focus Issue on Electrocatalysis—In Honor of Radoslav Adzic. [JES 165(15) 2018] David Cliffel and Thomas Fuller, JES technical editors; Minhua Shao, guest editor. • JES Focus Issue on Advances in Electrochemical Processes for Interconnect Fabrication in Integrated Circuits. [JES 166(1) 2019] Charles Hussey, JES technical editor; Rohan Akolkar and Peter Broekmann, guest editors.
• JSS Focus Issue on Semiconductor-Based Sensors for Application to Vapors, Chemicals, Biological Species, and Medical Diagnosis. [JSS 7(7) 2018] Fan Ren, JSS technical editor; Yu-Lin Wang, Ajit Khosla, Rangachary Mukundan, and Toshiya Sakata, guest editors.
To see the calls for papers for upcoming focus issues, for links to the published issues, or if you would like to propose a future focus issue, visit
www.electrochem.org/focusissues
Results of the 2018 Election of Officers and Slate of Officers for 2019 The ECS Tellers of Election have announced the results of the 2018 society election with the following persons elected: president—Yue Kuo, Texas A&M University; vice president—Eric Wachsman, University of Maryland; and treasurer— Gessie Brisard, Universite de Sherbrooke. The terms of Christina Bock (vice president), Stefan De Gendt (vice president), and James Fenton (secretary) were unaffected by this election. At the board of directors meeting in Seattle, WA, on May 17, 2018, members voted to approve the slate of candidates recommended by the ECS Nominating Committee. The slate of candidates for the next election of ECS officers, to be held from January to March 2019, include: for president—Christina Bock, and for vice president (one to be elected)—Turgut Gür and Durga Misra. Full biographies and candidate statements will appear in the winter 2018 issue of Interface.
Yue Kuo President
Eric Wachsman Vice President
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2018–2019 ECS Committees Executive Committee of the Board of Directors
Yue Kuo, Chair.............................................................................................................. President, Spring 2019 Christina Bock........................................................................................... Senior Vice President, Spring 2019 Stefan De Gendt........................................................................................Second Vice President, Spring 2019 Eric Wachsman............................................................................................ Third Vice President, Spring 2019 James Fenton................................................................................................................ Secretary, Spring 2020 Gessie Brisard............................................................................................................... Treasurer, Spring 2022 Roque Calvo............................................................................................................Term as Executive Director
Audit Committee
Johna Leddy, Chair.............................................................................. Immediate Past President, Spring 2019 Yue Kuo........................................................................................................................ President, Spring 2019 Christina Bock........................................................................................... Senior Vice President, Spring 2019 Gessie Brisard................................................................................................................Treasurer, Spring 2022 Stuart Swirson.......................................................................... Nonprofit Financial Professional, Spring 2019
Education Committee
James Nöel, Chair..........................................................................................................................Spring 2021 Anne Co.........................................................................................................................................Spring 2019 Enn Lust.........................................................................................................................................Spring 2019 Kalpathy Sundaram........................................................................................................................Spring 2020 Alice Suroviec................................................................................................................................Spring 2020 Keryn Lian......................................................................................................................................Spring 2021 David Hall......................................................................................................................................Spring 2021 Vimal Chaitanya.............................................................................................................................Spring 2022 Takayuki Homma............................................................................................................................Spring 2022 Daniel Parr.....................................................................................................................................Spring 2019 Margaret Calhoun..........................................................................................................................Spring 2020 James Fenton................................................................................................................ Secretary, Spring 2020 William Mustain.......................................................... Chair, Individual Membership Committee, Spring 2020
Ethical Standards Committee
Johna Leddy, Chair.............................................................................. Immediate Past President, Spring 2019 Dennis Hess...............................................................................................................Past Officer, Spring 2019 D. Noel Buckley.........................................................................................................Past Officer, Spring 2020 James Fenton................................................................................................................ Secretary, Spring 2020 Gessie Brisard............................................................................................................... Treasurer, Spring 2022
Finance Committee
Gessie Brisard, Chair.................................................................................................... Treasurer, Spring 2022 Robert Mantz..................................................................................................................................Spring 2019 Mark Verbrugge.............................................................................................................................Spring 2019 Robert Kostecki..............................................................................................................................Spring 2020 Boryann Liaw.................................................................................................................................Spring 2020 James Fenton................................................................................................................ Secretary, Spring 2020 Tim Gamberzky....................................................................................... Chief Operating Officer, Term as COO
Honors and Awards Committee
Peter Fedkiw, Chair........................................................................................................................Spring 2019 Joseph Stetter................................................................................................................................Spring 2019 Rohan Akolkar................................................................................................................................Spring 2019 R. Bruce Weisman..........................................................................................................................Spring 2019 Vimal Chaitanya.............................................................................................................................Spring 2020 Thomas Moffat...............................................................................................................................Spring 2020 Jean St-Pierre................................................................................................................................Spring 2020 Viola Birss.....................................................................................................................................Spring 2021 Shelley Minteer..............................................................................................................................Spring 2021 Scott Calabrese Barton...................................................................................................................Spring 2021 Junichi Murota...............................................................................................................................Spring 2022 Dev Chidambaram.........................................................................................................................Spring 2022 Wei Tong........................................................................................................................................Spring 2022 Yue Kuo........................................................................................................................ President, Spring 2019
Individual Membership Committee
William Mustain, Chair..................................................................................................................Spring 2020 Steven Policastro...........................................................................................................................Spring 2019 M. Neal Golovin.............................................................................................................................Spring 2019 R. Bruce Weisman..........................................................................................................................Spring 2020 Timothy Paschkewitz......................................................................................................................Spring 2020 Toshiyuki Nohira............................................................................................................................Spring 2021 Chi-Chang Hu................................................................................................................................Spring 2021 Beatriz Molero Sanchez..................................................................................................................Spring 2019 Jeffrey Henderson..........................................................................................................................Spring 2020 Marion Jones...............................................................................Chair, Sponsorship Committee, Spring 2019 James Fenton................................................................................................................ Secretary, Spring 2020
Nominating Committee
Johna Leddy, Chair.............................................................................. Immediate Past President, Spring 2019 Alice Suroviec................................................................................................................................Spring 2019 Hariklia Deligianni.........................................................................................................................Spring 2019 Dennis Hess...................................................................................................................................Spring 2019 Eric Wacshman............................................................................................ Third Vice President, Spring 2019
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Sponsorship Committee
Marion Jones, Chair......................................................................................................................Spring 2019 Robert Mantz..................................................................................................................................Spring 2019 Khalil Amine..................................................................................................................................Spring 2019 Mindy Zhang..................................................................................................................................Spring 2019 Chuck Hussey................................................................................................................................Spring 2020 Peter Fedkiw..................................................................................................................................Spring 2020 Xiaoping Jiang...............................................................................................................................Spring 2020 Jie Xiao..........................................................................................................................................Spring 2021 Christopher Beasley.......................................................................................................................Spring 2021 Mark Glick.....................................................................................................................................Spring 2021 William Mustain.......................................................... Chair, Individual Membership Committee, Spring 2020 Gessie Brisard............................................................................................................... Treasurer, Spring 2022
Technical Affairs Committee
Christina Bock, Chair................................................................................. Senior Vice President, Spring 2019 Yue Kuo........................................................................................................................ President, Spring 2019 Johna Leddy........................................................................................ Immediate Past President, Spring 2019 Krishnan Rajeshwar................................................................ Second Immediate Past President, Spring 2019 Eric Wachsman............................................................................Chair, Meetings Subcommittee, Spring 2019 Stefan De Gendt......................................................................Chair, Publications Subcommittee, Spring 2019 E. Jennings Taylor.................................................................................Chair, IST Subcommittee, Spring 2019 Roque Calvo..................................................................................................... Executive Director, Term as ED
Symposium Planning Advisory Board of the Technical Affairs Committee
Eric Wachsman, Chair.................................................................................. Third Vice President, Spring 2019 Christopher Johnson.................................................................................... Chair, Battery Division, Fall 2018 Sannakaisa Virtanen................................................................................. Chair, Corrosion Division, Fall 2018 Nianqiang Wu............................................................................................... Chair, Sensor Division, Fall 2018 Colm O’Dwyer.............................................................Chair, Electronics and Photonics Division, Spring 2019 Andy Herring..........................................................................Chair, Energy Technology Division, Spring 2019 Graham Cheek......................................Chair, Organic and Biological Electrochemistry Division, Spring 2019 Alice Suroviec...................................... Chair, Physical and Analytical Electrochemistry Division, Spring 2019 Stanko Brankovic..........................................................................Chair, Electrodeposition Division, Fall 2019 Greg Jackson................................................................Chair, High Temperature Materials Division, Fall 2019 Mikhail Brik....................................................Chair, Luminescence and Display Materials Division, Fall 2019 Vimal Chaitanya.............................................Chair, Dielectric Science and Technology Division, Spring 2020 Slava Rotkin....................................................................................Chair, Nanocarbons Division, Spring 2020 John Staser............Chair, Industrial Electrochemistry and Electrochemical Engineering Division, Spring 2020 E. Jennings Taylor......................Chair, Interdisciplinary Science and Technology Subcommittee, Spring 2019
Publications Subcommittee of the Technical Affairs Committee
Stefan De Gendt, Chair..............................................................................Second Vice President, Spring 2019 Eric Wachsman, Vice Chair.......................................................................... Third Vice President, Spring 2019 Dennis Hess................................................................................................................. JSS Editor, 12/31/2018 Robert Savinell................................................................................................................JES Editor, 5/17/2020 Jeffrey Fergus......................................................................................... ECS Transactions Editor, 12/31/2020 Robert Kelly.......................................................................................................... Interface Editor, 12/31/2022 D. Noel Buckley.............................................................................................................................Spring 2019 Scott Calabrese Barton...................................................................................................................Spring 2020 Elizabeth Biddinger........................................................................................................................Spring 2020 Christina Roth................................................................................................................................Spring 2021 Mary Yess..................................................................................................................... Publisher, Term as Pub
Meetings Subcommittee of the Technical Affairs Committee
Eric Wachsman, Chair.................................................................................. Third Vice President, Spring 2019 Stefan De Gendt, Vice Chair......................................................................Second Vice President, Spring 2019 Boryann Liaw.................................................................................................................................Spring 2019 Thomas Moffat...............................................................................................................................Spring 2020 Thomas Schmidt............................................................................................................................Spring 2021 Mary Yess..................................................................................................................... Publisher, Term as Pub
Ways and Means Committee
James Fenton, Chair..................................................................................................... Secretary, Spring 2020 Nianqianq Wu................................................................................................................................Spring 2019 John Weidner.................................................................................................................................Spring 2019 Durga Misra...................................................................................................................................Spring 2020 Yaw Obeng ....................................................................................................................................Spring 2020 Stefan De Gendt........................................................................................Second Vice President, Spring 2019 Christina Bock........................................................................................... Senior Vice President, Spring 2019
Other Representatives
Society Historian Zoltan Nagy...............................................................................................................................Spring 2019 American Association for the Advancement of Science Roque J. Calvo....................................................................................................Term as Executive Director Chemical Heritage Foundation Yury Gogotsi.............................................................................................. Heritage Councilor, Spring 2019 External Relations Representative Mark Orazem.............................................................................................................................Spring 2019 National Inventors Hall of Fame Peter Fedkiw....................................................................Chair, Honors & Awards Committee, Spring 2019
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ECS Division Contacts High Temperature Materials
Battery
Christopher Johnson, Chair Argonne National Laboratory johnsoncs@cmt.anl.gov • 630.252.4787 (US) Marca Doeff, Vice Chair Shirley Meng, Secretary Brett Lucht, Treasurer Doron Aurbach, Journals Editorial Board Representative Corrosion
Sannakaisa Virtanen, Chair Friedrich-Alexander-Universität Erlangen-Nürnberg virtanen@ww.uni-erlangen.de • +49 09131/85-27577 (DE) Masayuki Itagaki, Vice Chair James Nöel, Secretary/Treasurer Gerald Frankel, Journals Editorial Board Representative Dielectric Science and Technology
Vimal Chaitanya, Chair New Mexico State University vimalc@nmsu.edu • 575.635.1406 (US) Peter Mascher, Vice Chair Uros Cvelbar, Secretary Zhi David Chen, Treasurer Peter Mascher, Journals Editorial Board Representative Electrodeposition
Stanko Brankovic, Chair University of Houston srbrankovic@uh.edu • 713.743.4409 (US) Philippe Vereecken, Vice Chair Natasa Vasiljevic, Secretary Luca Magagnin, Treasurer Charles Hussey, Journals Editorial Board Representative Electronics and Photonics
Colm O’Dwyer, Chair University College Cork c.odwyer@ucc.ie • +353 863.958373 (IE) Junichi Murota, Vice Chair Robert Lynch, 2nd Vice Chair Soohwan Jang, Secretary Yu-Lin Wang, Treasurer Fan Ren, Journals Editorial Board Representative Energy Technology
Andy Herring, Chair Colorado School of Mines aherring@mines.edu • 303.384.2082 (US) Vaidyanathan Subramanian, Vice Chair William Mustain, Secretary Katherine Ayers, Treasurer Thomas Fuller, Journals Editorial Board Representative
Greg Jackson, Chair Colorado School of Mines gsjackso@mines.edu • 303.273.3609 (US) Paul Gannon, Sr. Vice Chair Sean Bishop, Jr. Vice Chair Cortney Kreller, Secretary/Treasurer Raymond Gorte, Journals Editorial Board Representative
Industrial Electrochemistry and Electrochemical Engineering
John Staser, Chair Ohio University staser@ohio.edu • 740.593.1443 (US) Shrisudersan Jayaraman, Vice Chair Maria Inman, Secretary/Treasurer Venkat Subramanian, Journals Editorial Board Representative Luminescence and Display Materials
Mikhail Brik, Chair University of Tartu brik@fi.tartu.ee • + 372 737.4751 (EE) Jakoah Brgoch, Vice Chair Rong-Jun Xie, Secretary/Treasurer Kailash Mishra, Journals Editorial Board Representative Nanocarbons
Slava Rotkin Pennsylvania State University rotkin@psu.edu • 814.863.3087 (US) Hiroshi Imahori, Vice Chair Olga Boltalina, Secretary R. Bruce Weisman, Treasurer Francis D’Souza, Journals Editorial Board Representative Organic and Biological Electrochemistry
Graham Cheek, Chair United States Naval Academy cheek@usna.edu • 410.293.6625 (US) Diane Smith, Vice Chair Sadagopan Krishnan, Secretary/Treasurer Janine Mauzeroll, Journals Editorial Board Representative Physical and Analytical Electrochemistry
Alice Suroviec Berry College asuroviec@berry.edu • 706.238.5869 (US) Petr Vanýsek, Vice Chair Andrew Hillier, Secretary Stephen Paddison, Treasurer David Cliffel, Journals Editorial Board Representative Sensor
Nianqiang (Nick) Wu, Chair West Virginia University nick.wu@mail.wvu.edu • 304.293.3111 (US) Ajit Khosla, Vice Chair Jessica Koehne, Secretary Larry Nagahara, Treasurer Rangachary Mukundan, Journals Editorial Board Representative 34
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New Division Officers New officers for the spring 2018–spring 2020 term have been elected for the following divisions:
Dielectric Science and Technology Division
Chair Vimal Chaitanya, New Mexico State University Vice Chair Peter Mascher, McMaster University Secretary Uros Cvelbar, Jozef Stefan Institute Treasurer Zhi David Chen, University of Electronic Science and Technology of China Members-at-Large Gautam Banerjee, Versum Materials, LLC Daniel Bauza, IMEP-LaHC, University of Grenoble Alpes France Stefan De Gendt, IMEC John Flake, Louisiana State University Dennis Hess, Georgia Institute of Technology Zia Karim, Eugenus, Inc Paul Kohl, Georgia Institute of Technology Dolf Landheer, G-Camria Co Durga Misra, New Jersey Institute of Technology Hazara Rathore, IBM Corporation Research Center Kalpathy Sundaram, University of Central Florida Mahendra Sunkara, University of Louisville John Susko Robin Susko Industrial Electrochemistry and Electrochemical Engineering Division
Chair John Staser, Ohio University Vice-Chair Shrisudersan Jayaraman, Corning Inc. Secretary/Treasurer Maria Inman, Faraday Technology, Inc. Members-at-Large Elizabeth Biddinger, The City College of New York (CUNY) Gerardine Botte, Ohio University James Fenton, University of Central Florida
Trung Nguyen, University of Kansas Mark Orazem, University of Florida Robert Savinell, Case Western Reserve University Venkat Subramanian, University of Washington E. Jennings Taylor, Faraday Technology, Inc. John Weidner, University of South Carolina Nanocarbons Division
Chair Slava Rotkin, Pennsylvania State University Vice-Chair Hiroshi Imahori, Kyoto University Secretary Olga Boltalina, Colorado State University Treasurer R. Bruce Weisman, Rice University Members-at-Large Michael Arnold, University of Wisconsin-Madison Jeff Blackburn , National Renewable Energy Laboratory Tatiana Da Ros, Universita degli Studi di Trieste Francis D’Souza, University of North Texas Stephen Doorn, Los Alamos National Laboratory Shunichi Fukuzumi, Osaka University Yury Gogotsi, Drexel University Dirk Guldi, Universitat Erlangen-Nurnberg Daniel Heller, Memorial Sloan Kettering Andreas Hirsch, Universitat Erlangen-Nurnberg Karl Kadish, University of Houston Fernando Langa, University of Castilla la Mancha Richard Martel, Universite de Montreal Nazario Martin, Universidad Complutense de Madrid Shigeo Maruyama, University of Tokyo Maurizio Prato, Universita degli Studi di Trieste Roberto Paolesse, Universita di Roma Tor Vergata Tomas Torres, Universidad Autonoma de Madrid Shangfeng Yang, University of Science and Technology China Ming Zheng, National Institute of Standards and Technology
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2018 Leadership Circle Awards This year ECS is pleased to honor the following organizations with the Leadership Circle Award to demonstrate gratitude for their continued partnership with and commitment to the Society.
Gold Level – 25 Years of Membership • Central Electrochemical Research Institute. CSIR-CECRI is a publicly funded organization that strives for scientific excellence and societal benefits. The organization’s vision is to become a global R&D platform for innovation in electrochemical science and technology, leading to inclusive development. Its scientists and engineers blend their passion for excellence in science with societal commitments to develop globally competitive and ecologically benign technologies in energy generation and storage, health diagnostics, corrosion mitigation, and material conservation. www.cecri.res.in
• DLR-Institut fuer Vernetzte Energiesysteme e. V. The DLR Institute of Networked Energy Systems in Oldenburg, Germany, develops technologies and concepts for future energy supply based on renewable energy sources. The institute’s major challenge is how to form stable and efficient energy systems from weather-dependent decentralized production units. The research for this transformation process follows a D3 approach (D3 = decarbonization, decentralization, and digitalization). www.next-energy.de.
Creating Powerful Partnerships
Silver Level – 10 Years of Membership • Bio-Logic USA/Bio-Logic SAS. Founded in 1983, Bio-Logic Science Instruments is an international company that designs, manufactures, and distributes a broad range of high performance measurement instruments for electrochemistry, battery testing, fuel cell materials testing, rapid kinetics, and photosynthesis all around the world. Drawing on experience, innovative ideas, core values, and a commitment to quality and reliability, Bio-Logic continues to develop new products with applications and customer usage in mind. www.bio-logic.info
Institutional membership provides organizations in academia, government, and industry the opportunity to support and advance the dissemination of electrochemical and solid state science research. Member organizations are awarded discounts on ECS subscriptions and marketing opportunities, along with access and ECS membership for their employees. ECS welcomes its newest institutional member, Microsoft Corporation.
Contact Shannon.Reed@electrochem.org to learn more about institutional membership benefits.
Upcoming ECS Sponsored Meetings In addition to the ECS biannual meetings and ECS satellite conferences, ECS, its divisions, and sections, sponsor meetings and symposia of interest to the technical audience ECS serves. The following is a partial list of upcoming sponsored meetings. Please visit the ECS website (www.electrochem.org/upcoming-meetings/) for a list of all sponsored meetings.
2018 • 1st Conference on 4D Materials and Systems; August 26-30, 2018; Yamagata, Japan; https://ecs.confex.com/ecs/4dms18/cfp.cgi • 69th Meeting of the International Society of Electrochemistry; September 2-7, 2018; Bologna, Italy; http://annual69.ise-online.org/; ECS–ISE Joint Symposium: “Theory: From Understanding to Optimization and Prediction” • International Conference on Solid State Devices and Materials (SSDM); September 9-13, 2018; Tokyo, Japan; www.ssdm.jp/index.html • III Colombian Congress of Electrochemistry; October 2-5, 2018; Cali, Colombia; https://sites.google.com/view/cceq2018/ • 7th Baltic Electrochemistry Conference: Finding New Inspiration (BEChem 2018); November 4-7, 2018; Tartu, Estonia; http://BEChem2018.ut.ee/ To learn more about what an ECS sponsorship could do for your meeting, including information on publishing proceeding volumes for sponsored meetings, or to request an ECS sponsorship of your technical event, please contact ecs@electrochem.org.
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ECS-CSE Joint Symposium on Electrochemical Energy & the Environment (ECEE 2017) Continuing on a partnership begun in 2014, the ECS-CSE Joint Symposium on Electrochemical Energy & the Environment (ECEE 2017) was held in conjunction with the 19th National Meeting of the Chinese Society of Electrochemistry (CSE) at the Shanghai International Convention Center on December 14, 2017. This focus of this national meeting was “Electrochemistry and Sustainable Development” and covered most essential topics of electrochemistry, with more than 2,800 participants attending multiple parallel sessions during the three-day event. The ECS Organizing Committee assembled 40 internationally renowned experts to speak on the topics of batteries, fuel cells, and CO2 reduction, all of whom were well received. The ECEE symposium was well attended; especially during the battery-related talks, with many of the sessions drawing standing room crowds. The overall experience was indicative of the success and potential that this joint meeting has to attract a significant portion of the National Meeting participants.
ECS recognizes and thanks all the invited speakers and members of the organizing committee for their efforts to make this symposium a great success. The Society looks forward to continuing this partnership with CSE for many years to come. ECS Organizing Committee; Boryann Liaw (Chair), Jun Liu (Battery Division), Minhua Shao (Energy Technology Division), and Xingbo Liu (High Temperature Division). Invited Speakers; Srikanth Gopalan, Jeffrey Fergus, Ting He, S.P. Jiang, Meilin Liu, Xinbo Liu, Yue Qi, Prabhakar Singh, Xin Sun, Shanwen Tao, Enrico Traversa, Xiao-Dong Zhou, Bryan Pivovar, Deryn Chu, Peter Pintauro, Adam Weber, Yushan Yan, Vojislav Stamenkovic, Hui Xu, Mike Perry, Keith Stevenson, Piotr Zelaney, Jean St. Pierre, Thomas F. Fuller, Liming Dai, Sanjeev Mukherjee, Michael Guiver, Kang Xu, Manthiram Arumugam, Xiao-Qing Yang, Gao Liu, Jiguang (Jason) Zhang, Jie Xiao, Daniel T. Schwartz, Jihui Yang, Boryann Liaw, Shirley Meng, Mei Cai, and Donghai Wang.
Pictured are officers of the Chinese Society of Electrochemistry (CSE), recipients of the CSE awards, members of the Chinese Academy of Science and Engineering, and other assorted VIPs.
ECS Collections of Interface Articles Visit the ECS Digital Library (DL) now to access recently created collections of articles from the following recurring columns in Interface: • From the Editor • From the President • Pennington Corner
• ECS Classics • Currents • The Chalkboard
• Websites of Note • Tech Highlights • Looking at Patent Law
More collections will be created and more articles will be added as new issues are published and more back issues are put online.
http://interface.ecsdl.org/cgi/collection The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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XXXII National Congress of the Mexican Society of Electrochemistry and 10th Meeting of the ECS Mexico Section The XXXII National Congress of the Mexican Society of Electrochemistry (SMEQ) and 10th Meeting of the ECS Mexico Section was held June 5-8, 2017, in Guanajuato, Mexico. The hosts were academics from the University of Guanajuato led by Jose Luis Nava Montes de Oca, president of the organizing committee. From an attendance perspective, the congress was a success because it elicited the participation of more than 300 attendees— mostly undergraduate, master’s, and doctoral students. But it was also successful in regard to the quality of the papers in the oral and poster sessions, which ECS organized by topic. The session topics encompassed all the major areas of electrochemistry. There were more than 400 works in total, as can be seen in the reports, which can be found at www.smeq.org.mx by searching for ISSN 24486191, volume 2, number 1. No less important was the publication of a special issue of ECS Transactions (volume 84, issue 1, 2018), to which attendants were able to submit their contributions for publication, expanding and complementing the papers they presented at the congress. The inaugural ceremony was attended by authorities of the University of Guanajuato, the state government, Francisco Javier Rodríguez Gómez, SMEQ president (2015-2017), and Krishnan Rajeshwar from ECS (University of Texas at Arlington), who also gave the inaugural lecture. There were four other international speakers who gave keynote addresses: Lorenzo Fedrizzi, Robert F. Savinell, Enric Brillas, and Guy Denuault. SMEQ is also a forum for new professionals in electrochemistry who have recently finished their PhDs. Based on their academic achievements, some were selected to give plenary lectures. In 2017, this honor was granted to Juan Edgar Carrera Crespo, Andy Alán Melo López, Andrea Quetzalli Cerdán Pasarán, Raciel Jaimes López, and Gabriela Coria Rodríguez. On Tuesday, June 6, 2017, a unique activity was carried out—the electrochemical hand in hand— with the participation of Norberto Casillas Santana, Jorge G. Ibáñez Cornejo, and Bernardo Frontana Uribe. In front of a fully filled auditorium, in the manner of a bullfight, the researchers challenged themselves with electrochemical experiments. Then they explained basic concepts as well as more complex concepts. The event served as a very funny, original, and entertaining way to bring electrochemistry to students. This successful session was moderated by Francisco Javier Rodríguez. On Wednesday, June 7, 2017, attendees and guests were able to make a half-day visit to the archaeological zone Cañada de la Virgen, which is located near the city of Guanajuato. This archaeological zone
is outside the traditional tourist circuit and is less frequently explored despite its abundance of pyramidal buildings. The last day of the congress, Thursday, June 8, 2017, was very intensive in terms of academic activities. In addition to the lectures and plenary sessions, the poster session was held, featuring the traditional contest organized by SMEQ, which awards prizes by degree (master’s/doctorate). The main prize for the best doctorate poster also wins the possibility of being presented at an ECS event thanks to the sponsorship of ECS. This year the winning work was by Miriam Franco Guzmán. It was titled “Study of the Influence on the Electroactive Area of the Nature of the Working Electrode and the Transformed REDOX Molecule.” Its coauthors were G. A. Alvarez Romero, L. H. Mendoza Huizar, C. A. Galán Vidal, and G. Roa Morales. To conclude the congress, the annual assembly of SMEQ was held, in which Francisco Javier Rodríguez passed the title of president of SMEQ to Ricardo Orozco Cruz (Universidad Veracruzana) for the 2017-2019 term. René Antaño López (CIDETEQ) was elected as the new vice president of SMEQ for the 2017-2019 term in accordance with the bylaws. An emotional moment was the presentation of the 2017 National Electrochemistry Award to Jorge Uruchurtu Chavarín. Uruchurtu was president of SMEQ from 1988 to 1990, as well as president of the organizing committee of the V National Congress of the Mexican Society of Electrochemistry, held in Cuernavaca, Mexico, in 1990. His contributions in the area of corrosion and electrochemical techniques, especially in the use of electrochemical noise, supplement his extensive academic and industrial career of many years. Uruchurtu was part of the team that carried out the Ibero-American Map of Atmospheric Corrosivity (MICAT) project along with other great Ibero-American researchers. Finally, the training of high-level human resources has been one of the most important for the quality of the people who have trained inside and outside the country. Uruchurtu’s ever-friendly and cooperative character won him the sympathy of his colleagues, who gave him a standing ovation during the ceremony. He especially thanked his wife and family for the support he has always had. With the good taste of Uruchurtu’s speech of gratitude, the congress closed, inviting the attendees to participate in 2018 in AiMES, an ECS and SMEQ joint international meeting that will be held September 30-October 4, 2018, in Cancun, Mexico.
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Advancement News Longtime ECS Member Paying It Forward Lili Deligianni was recently awarded the 2018 ECS Vittorio de Nora Award for distinguished contributions to the field of electrochemical engineering and technology. Upon receiving this news, she began thinking of ways the $7,500 cash prize could be used to support the larger scientific community. After speaking with the ECS development team, she has chosen to give back the prize money to the ECS Education Fund. Deligianni had served as chair on the ECS Lili Education Committee in 2008 and again in Deligianni 2009. Through that experience, she knew that the Education Fund could use the extra support. “I’d like to pay it forward to the new generation of scientists at our Society,” Deligianni explains. “As a Society, we have a great number of new and young scientists and I’d like to encourage and help them participate in our community.”
Education Committee initiatives include holding student poster awards, creating professional development workshops and short courses at the biannual meetings, and coordinating the summer fellowships. It is also exploring other ways to enhance opportunities for ECS members, especially students and early-career researchers. As a member of ECS for over 32 years, Deligianni has been invested in the work that the Society has been doing. She has not only volunteered her time and talents to the many activities of ECS, she has served as board secretary (2012-2016), chair of ECS Education and Ways and Means Committees, and chair of the Electrodeposition Division. She began her involvement with ECS as a student and says she has developed lifelong friendships and professional relationships. With her contribution, she will now be able to support similar students throughout their careers, as they build their network within the ECS community. The Education Fund enables ECS to support emerging scientists through summer fellowships, student programs, and educational programming at biannual meetings. Listen to Deligianni talk about her career here.
Sponsored Collection to Honor Jan Talbot ECS is excited to announce a new sponsored collection to honor past ECS president Jan Talbot. Talbot retired on July 1 and the development team would like to honor ECS’s mission by fundraising to open her collection in the ECS Digital Library so that all researchers have access to her papers. ECS sponsored collections are generously supported by the family, friends, students, and colleagues of ECS authors. Compiling all of an author’s articles published in ECS journals, Jan Talbot these collections honor the author’s significant contributions to their particular field, the Society, and the wider scientific community by aiming to make their research freely accessible. There are currently two other sponsored collections honoring Hugh Isaacs and Glenn Stoner. Talbot was the chair of the UC San Diego Academic Senate in 2003-2004. She was awarded a UCSD Distinguished Teaching Award for 2010. Talbot has been the director of the Jacobs School’s chemical engineering program since 2000 and was associate dean of the Jacobs School of Engineering from 2014-2016. From 1975 to 1981, she
worked as a development engineer at Oak Ridge National Laboratory in Tennessee. Talbot has been a longtime ECS member, served as board vice president (1998-2001), president (2001-2002), and became a fellow in 2004. She was also the editor of Interface from 1995 to 1998. “It amazes me that ECS, its journals, and its meetings were the main venue for my research interests over 30 years, which has spanned applications of corrosion, magnetic recording, semiconductor processing, and solid state lighting,” Talbot reflects. Throughout her career she has published a total of 44 papers in ECS journals. “It has truly been my professional home.” Talbot’s work includes 38 Journal of The Electrochemical Society papers and 6 ECS Journal of Solid State Science and Technology papers. Her body of work is focused on electrophoretic deposition, electrodeposition, chemical mechanical polishing, display screen processing, solid state lightning materials, materials science, and electrochemical transport phenomena and engineering. If you are interested in making a donation to free this collection or getting involved in any way, please contact Development@ electrochem.org.
ECS Proceedings Volumes Between 1967 and 2005, ECS published over 600 proceedings volumes, all of which are out of print and had been unavailable in digital format—until now. Over 450 historic proceedings volumes have been added to the archival content available through the ECS Digital Library.
Visit www.ecsdl.org to learn more. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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websites of note by Alice H. Suroviec
Power Electronics Tutorial • Tutorialspoint.com is dedicated to providing quality online education in the domains of computer science, information technology, programming languages, and other engineering as well as management subjects. The tutorials are designed for novice readers with a basic knowledge of electronics. www.tutorialspoint.com/power_electronics/index.htm
Rotating Disk Theory • Pine Research provides a detailed theory on rotating disk electrochemistry. The use of forced convection influences the current measured. Proper interpretation of the current signal must accurately account for any contributions from solution convection. Hydrodynamic methods are well suited for steady-state experiments. This website provides an excellent starting place to learn more about these methods. www.pineresearch.com/dev/shop/knowledgebase/pine-rotating-electrode-theory/
research
Memristors • The development of memristors, the fourth passive component type after resistors, capacitors, and inductors, along with other solid state memory devices, takes us one step further to creating cheap, powerful, distributed solutions for sensing and processing. This website provides a site for those looking for the news, articles, and tutorials on memristors. www.memristor.org
About the Author
Alice Suroviec is an associate professor of bioanalytical chemistry and chair of the Department of Chemistry and Biochemistry at Berry College. She earned a BS in chemistry from Allegheny College in 2000. She received her PhD from Virginia Tech in 2005 under the direction of Mark R. Anderson. Her research focuses on enzymatically modified electrodes for use as biosensors. She is currently the chair of the ECS Physical and Analytical Electrochemistry Division and an associate editor for the physical and analytical electrochemistry, electrocatalysis, and photoelectrochemistry topical interest area of the Journal of The Electrochemical Society. She may be reached at asuroviec@berry.edu. https://orcid.org/0000-0002-9252-2468
In the
• The fall 2018 issue of Interface will be a special issue focused on the theme of Sonoelectrochemistry. Guest edited by Bruno G. Pollet of the Norwegian University of Science and Technology, the issue will feature the following technical articles (titles are tentative): “Sonoelectrochemistry: A ‘Sound’ and Promising Technology,” by Bruno G. Pollet; “Introduction to Ultrasound and Sonochemistry,” by Wu Li and Muthupandian Ashokkumar; “Sonoelectrochemistry: Both a Tool for Investigating Mechanisms and for Accelerating Processes,” by Jean-Yves Hihn, Marie-Laure Doche, Loic Hallez, Abdeslam Et Taouil, and Bruno G. Pollet; “Ultrasonic Agitation for Emerging Electrodeposition Systems,” by S. Roy and S. J. Coleman; and “In Situ Ultrasonic Dispersion in Multiphase Electrolysis Systems,” by Mahito Watanabe and Frank Marken . 40
issue of • A preview of the AiMES 2018 meeting including interviews with its leaders and technical cosponsors. • The next installment of the guest column by E. J. Taylor and Maria Inman that covers intellectual property and patent issues. • Recognition of the newest class of ECS fellows, as well as winners of these Society awards: the Charles W. Tobias Young Investigator Award; the Edward Goodrich Acheson Award; the Norman Hackerman Young Author Award; and the Bruce Deal & Andy Grove Young Author Award. Several ECS division award winners and a section award winner will be included as well.
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New Content Discovery Feature in the ECS Digital Library ECS has integrated a new feature into the ECS Digital Library (http://ecsdl.org/) to facilitate the discovery of scholarly content—both within the scope of the Society’s publications and beyond it.
How It Works
The new content discovery feature uses collaborative filtering and evolving algorithms to identify and recommend scholarly content of potential interest to readers of ECS articles. The twist? Recommended articles are not limited to those published in ECS publications. The feature also recommends content from the world’s leading peer-reviewed journals and research news outlets across a wide breadth of academic disciplines, making it easier than ever for readers to locate the information they need to advance their research.
How It Looks
To use the feature, scroll to the end of an abstract or full-text article in the ECS Digital Library. Beneath the words “May be of interest,” you will see a two-column listing of recommended content. The left-hand
column displays content from internal sources—ECS publications. The right-hand column displays content from external sources—any of the hundreds of other premium scholarly sites in the service’s network.
Why It Matters
For readers: The service connects you with relevant articles and developments in your area of study and across academic disciplines, enabling you to expand your knowledge base and further your research. For authors: The feature promotes ECS content across the hundreds of other scholarly sites in the service’s network, exposing your ECS publications to a wider audience and increasing your readership. For the Society: The service drives the organic expansion of the ECS community. The promotion of ECS content across external platforms will introduce more scholars than ever before to the rigorous, influential work being conducted by the Society’s members and constituents. In sum, ECS’s new content discovery feature will profoundly enhance the way leading research in electrochemical and solid state science and technology is discovered and shared across disciplines.
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C Rating of Batteries: A Misleading Concept C Flux Rather than C Rate by Jacob Jorne
I
n 1908 Thomas Edison said about batteries: “When a man gets on to accumulators (rechargeable batteries) his inherent capacity for lying comes out.” A few battery concepts and definitions have been shown to be misleading. The C rating of batteries is such a concept. The C stands for the capacity of a battery usually measured in ampere hours (AH) indicating the amount of active material within the battery available for discharge. Ampere is the measure of a current and gives the number of coulombs per unit time, so current times time gives essentially the amount of charge in coulombs stored within the battery. The C rate measures the rate at which the battery is charged or discharged. If a battery capacity is 10 AH, then if the C rate is 1C, it means that the battery can be charged or discharged at 10 A for 1 hr. C rate of 10C means that the current is 100 A and theoretically can last for 0.1 hr, or 6 minutes. C rate of C/10 means that the current is 1 A and should theoretically last for 10 hours. Thus the C rate indicates the current rather than the current density, which is the current per unit area, usually in A/ cm2. Thus the C rate alone cannot indicate the flux or the current density unless the projected area of the specific battery is given. Electrochemical processes are heterogeneous and must be reported per unit area. Consider for example the schematics of two batteries with the same C as indicated by the volume or mass of active material. Figure 1 schematically shows two batteries where the volume of each box represents the amount of active material in each electrode, usually expressed in AH. However the two batteries have significantly different cross-sectional area. Battery B has 1/5 the projected front area of battery A. Therefore when both batteries are charged or discharged at the same C rate, the total current is the same, yet the current density of battery B is 5 times larger. Therefore, while battery A operates below its limiting current density, battery B might significantly exceed its limiting current density. Furthermore the internal resistance of each battery is different, and the measured capacity as measured by the time could be significantly different. Historically the C rate was developed and adopted to compare and evaluate similar batteries, and it is a useful concept for the battery industry, yet it can be manipulated to lead to wrong and sometimes absurd claims. For example, recent publications claim that the lithium-ion battery can be charged at a very high C rate. The implication is that the battery can be charged in a few minutes rather than in hours. The practical claim is that electric cars with lithiumion batteries can be charged in a service station to near full capacity in a matter of a few minutes. First principles calculations show that the amount of power in watts is enormous and certainly can lead to meltdown. For example, a 10 AH battery charged at 10C will be operated at 100 A for 6 minutes. If the overvoltage is 1 V, then the power is 100 W and cannot be dissipated. Furthermore the current, for example, will exceed the limiting current if the projected area of the battery is 100 cm2. The reason for these outrageous claims is that the high C rate was applied to batteries with very small capacity per unit area; therefore high current density was maintained for short times and was most likely maintained by the active materials within the electrode where the internal area is high. However in order to maintain the current for longer times, Li+ ions must be transferred from the cathode to the anode, and this transport is limited by the diffusivity and the available cross-sectional area of the battery. 42
It is therefore proposed to change the measuring of capacity from C (in AH) to specific C in AH/cm2. This way the C rate will be changed to C flux, which will indicate the current density rather than the total current. Going back to the first example, if the 10 AH battery has a 100 cm2 cross-sectional area, then the specific capacity is 0.1 AH/cm2. Thus charging the battery at 10C means that the current density is 1 A/cm2 and is definitely exceeding the limiting current density. On the other hand, charging at 0.1C means that the current density is 0.01 A/cm2, which might be well below the limiting current density. The need to normalize per unit area is demonstrated below by two practical examples: Example 1: Commercially available rechargeable Li-ion coin batteries are listed at a capacity of 70 mAH and 110 mAH. For the 70 mAh coin battery, the recommended charge current is 35 mA, and the maximum discharge current is 140 mA. The projected area of these coin batteries is about 3 cm2; therefore the recommended charge current density is about 10 mA/cm2. For a battery with C = 70 mAH, at 35 mA, the theoretical charging time is therefore 2 hours. To cut the charging time to let’s say 6 minutes, the charge current at 20C should be 1.4 A, corresponding to a current density of 470 mA/cm2, substantially above the expected diffusional limiting current density. Example 2: Tesla, the electric car company, claims to charge its Li-ion batteries at a rate of up to 4C. The battery module, which contains 7104 single Li-ion cells, exhibits 310 KW power and 85 KWH energy. Therefore, each single cell has a capacity of about 3 AH. The cross-sectional area of each single cell is estimated to be around 100 cm2. The claimed charge rate of 4C corresponds therefore to a current of 12 A, or roughly to 0.12 A/cm2, above the expected diffusional limiting current. Increasing the charge rate to 10C will correspond to 0.3 A/cm2, well above the expected limiting current density. Therefore, with the existing technology, the claims for very high charging rates, on the order of 5 minutes, are questionable, as it might significantly exceed the limiting current density. Diffusional limiting current can be avoided using an electrolyte where the transference number for Li+ ion is 1.0. Under this condition, electrical drift satisfies the electrochemical consumption of Li+ ions. tLi+ = 1 can be achieved in an electrolyte where the anions are immobile and the Li+ ions carry 100% of the current. The transference number of the reactive ion should approach unity to avoid diffusion limitation. Fast charging requires high current densities, 10-100 times that of normal discharge operation. Several battery and automobile companies have recently claimed that fast and ultrafast charging can be achieved within minutes for batteries where the discharge period is 6 hours or more. These claims are debatable, and a way to overcome these limitations is proposed. There are two limitations to how fast a battery can be charged— thermal heating and mass transfer limitation. Thermal heating occurs because the internal resistance of the battery generates excessive heat, which must be dissipated to the environment. When charging occurs at very high currents, the heat generated within the battery cannot be removed fast enough, and the temperature quickly rises. Mass transfer of Li+ ions during fast charge results in diffusion limiting current even if the electrodes are made of nanoparticles with high surface area. While the high surface area allows sufficient rate of lithiation or de-lithiation, the Li+ diffusion through the crosssectional area of the electrolyte within the separator is limited. It is quite possible to fast-charge for a limited time restricted to the Li+ ions already presented in the electrolyte within the electrode. This The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
electrode; thus depletion of Li+ occurs near the anode, resulting in diffusion limiting current. Any attempt to surpass the limiting current results in solvent decomposition, heating and deterioration of the battery. Since convection is absent within the cell gap, one can overcome diffusion limitation by designing an electrolyte where Li+ is the only charge carrier, and consequently the transference number of Li+ is equal to 1. Solid electrolyte where the anions are anchored to the solid matrix is a possibility, like in the case of Nafion solid electrolyte where the sulfate ions are attached to the fluorinated polymer. Yet finding such a solid electrolyte for nonaqueous organic solvent remains a challenge. © The Electrochemical Society. DOI: 10.1149/2.F01182if.
About the Author
Fig. 1. Schematic comparison of two batteries, A and B, with the same capacity C but with two different cross-sectional areas A: CA = CB, AA > AB.
unsteady state diffusion can last until the Li+ ions are depleted and their supply is limited by the cross-sectional area of the battery. This mass transfer limitation occurs because the transference number of Li+ is smaller than 1. While Li+ ions carry a fraction of the current in the electrolyte, they carry 100% of the current at the
Jacob Jorne’s research deals with electrochemical energy conversion and storage, hydrogen fuel cells, flow batteries, and lithiumair batteries. Green energy and energy conservation are the themes of his current research and interests. His PhD thesis (University of California Berkeley 1972), entitled “The Electrochemical Behavior of the Alkali Metals in Propylene Carbonate,” led to the development of lithium and lithium-ion batteries. He taught at Wayne State University from 1972 to 1982 and joined the University of Rochester in 1982. His group collaborated with General Motors on the development of hydrogen PEM fuel cells for electric vehicles. His group also worked on the research and development of zinc-chlorine flow batteries for the storage of electrical energy. In 1993 he received the Carl Wagner Memorial Award from The Electrochemical Society. He has taught courses in transport phenomena, separation processes, thermodynamics, semiconductors and microelectronics, and electrochemical engineering of batteries and fuel cells. He may be reached at jacob.jorne@rochester.edu.
Chung Chiun Liu Leadership Collection
Journal of The Electrochemical Society 2018 Volume Honor an ECS leader by creating a new leadership collection Learn more at electrochem.org/liu-collection The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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In Memoriam memoriam Theodore Richard Beck
Glenn Wherry Cullen
(1926 – 2017)
(1931 – 2018)
T
heodore Richard Beck passed away at the age of 91 on May 28, 2017. Beck served as the president of the Society from 1975 to 1976. He was also an ECS fellow and honorary member, who spent over 60 years actively involved in Society affairs. Beck earned his BS, MS, and PhD degrees in chemical engineering from the University of Washington in 1949, 1950, and 1952, respectively. In 1952 he joined the Jackson Laboratory of DuPont in Deepwater, NJ, as a research engineer in process development. There he conducted pilot plant studies on the manufacture of isocyanates. In 1954 Beck became the group leader of the 10,000A experimental aluminum cell program with the Kaiser Aluminum and Chemical Corporation in Permanente, CA. In 1959 he joined the American Potash and Chemical Corporation in Henderson, NV, as head of the Electrochemical Research Section. Beck joined Boeing’s Aerospace Division in 1961 as a research specialist responsible for research in batteries and fuel cells. After he transferred to the Boeing Scientific Research Laboratories in 1965, his research shifted to mechanisms of stress corrosion cracking of metals and streaming current phenomena. Beck began his work with Flow Research, Inc. in 1972, conducting research on pitting, stress corrosion and double layers, the development of electrochemical processes and devices, and consulting. He continued contract research and development within his own company, Electrochemical Technology Corp., from 1975 until 1996, when he closed his laboratory and went into semiretirement. He authored 77 technical papers and received 11 patents. Throughout his prolific history with ECS, which began in 1954, Beck served as vice chair of the ECS San Francisco Section, chair of the Society’s now-defunct Pacific Northwest Section, and secretary, vice chair, and chair of the ECS Council of Sections. He also served as secretary, vice chair, and chair of the ECS Industrial Electrochemistry and Electrochemical Engineering Division and as a Corrosion Division editor for the Journal of The Electrochemical Society back when the publication had divisional editors. Beck became the Society’s vice president in 1972 and was elected ECS president in 1975. In 1981 Beck received the Outstanding Achievement Award of the ECS Corrosion Division. The next year, he was named an honorary member of the Society. Beck was awarded the ECS Edward Goodrich Acheson Award in 1990 and became an ECS fellow in 1991. Beck was active in other societies as well, having served as chair of the Southern Nevada Section of AIChE and the Puget Sound Section of ACS. He was also a fellow of the AIChE, a member of AAAS, ISE, Sigma XI, NACE, and AIC, and a registered professional engineer in the state of Washington. Beyond the technical domain, Beck served on the boards of the North Cascades Conservation Council, the Seattle Youth Symphony, the Icelandic Club of Greater Seattle, the Nordic Heritage Museum, and the advisory board for the University of Washington’s Scandinavian Department. A 50-year member of the Seattle Mountaineers, he enjoyed traversing the mountains and trails of the Pacific Northwest with his family and friends. Beck is survived by his wife, Ruth, two daughters, and two grandsons. 44
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lenn Wherry Cullen passed away on January 23, 2018, at the age of 86. Cullen was an honorary member of the Society, an ECS fellow, and a former chair of the ECS Electronics and Photonics Division. In 1982 he received the ECS Electronics and Photonics Division Award. Cullen earned his PhD in inorganic chemistry from the University of Illinois in 1956. He served as a captain in the U.S. Army, where he also taught electronics. From 1958 to 1999, he worked at RCA Laboratories/ Sarnoff Corporation, overseeing the development of materials used in electronic devices. In addition to ECS, Cullen was a member of the American Association for Crystal Growth, the Federation of Materials Society, and the Princeton Officers Society. Cullen was a multitalented scientist, known particularly for his pioneering work on the deposition of silicon and other semiconductor materials on insulating substrates. At the time of his death, he held 9 patents and was the author or coauthor of 61 publications, including a book, Heteroepitaxial Semiconductors for Electronic Devices. “I remember Glenn as one of the most genial people I ever met, always willing to share his extensive experience and knowledge of electronic materials and processes,” says John Blocher, emeritus member and fellow of ECS. Besides being an excellent scientist and researcher, Cullen was a gifted sculptor who displayed his work in several galleries, including one he cofounded in Kingston, NJ. An Eagle Scout in his youth, he was a fine boatsman, who sailed on Lake Erie near his summer home. For many years, he tutored students at Trenton Central High School, helping them to improve their writing skills. “Glenn was the first individual that I hired at RCA after I was promoted to group leader,” says James A. Amick, ECS emeritus member and fellow. “He was a true gentleman and a fine friend and colleague.” Cullen is survived by his wife, Patricia, and his daughter, Kimberly. Background information for this notice was contributed by James A. Amick.
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In Memoriam memoriam Irving Shain (1926 – 2018)
I
rving Shain passed away at the age of 92 on March 6, 2018, in Madison, WI. An emeritus member of the Society, Shain served as chair of the ECS Contributing Membership Committee (1988-1990), a standing committee that preceded the ECS Sponsorship Committee in the role of generating institutional members and corporate sponsorship. He introduced the benefactor level of ECS institutional membership and recruited the Olin Corporation as the first company to contribute at that level. In 1988 Shain proved instrumental in securing $30,000 in funding from Olin in support of the ECS Olin Palladium Award, an award the Society continues to bestow. Born in Seattle, Shain served in the U.S. Army during World War II before earning his PhD in chemistry from the University of Washington. He started teaching at the University of Wisconsin– Madison in 1952. Afterward he served as provost and vice president for academic affairs at his alma mater from 1975 to 1977, the year he returned to UW–Madison as its chancellor. Shain remained chancellor until 1986, when he stepped down and joined the Olin Corporation, where he served as vice president and chief scientist until 1992. Throughout his career, Shain published highly influential research in the field of electrochemistry. In the late 1950s and early 1960s, new electrochemical experimental protocols abounded thanks to the advent of the Hickling potentiostat, the three-electrode configuration and variations thereof. The dominant protocol to evolve was cyclic voltammetry, and advances were driven by Richard Nicholson and Irving Shain’s landmark paper, “Theory of Stationary Electrode Polarography. Single Scan and Cyclic Methods Applied to Reversible, Irreversible, and Kinetic Systems.” “Nicholson and Shain will have their names forever linked because of their collaboration on what must be the most cited paper in the history of the electrochemical literature—the paper that defined cyclic voltammetry: Analytical Chemistry, 36, 706 (1964),” said ECS
PLUS
fellow and honorary member Larry R. Faulkner during a speech at the dedication of the Shain Research Tower. “I did not have to look up the reference. I have known it by heart for decades.” “The paper describes the cyclic voltammetric responses for a variety of fundamental mechanistic examples and does so without burying the reader in a mathematical morass,” says Stephen W. Feldberg. “A number of other papers came out of Shain’s group at the University of Wisconsin. Now, over 50 years later, the legacy of Irving Shain continues to directly impact electrochemical science in general as well as my own research.” Shain is remembered, nevertheless, for far more than his publications. “He was a wonderful teacher,” says Robert P. Frankenthal, ECS fellow, former president of the Society, and Shain’s first graduate student. “He had a way about him. I can’t even put it into words.” “I have a somewhat unusual perspective on Irv,” says ECS fellow Albert J. Fry, “since as a Wisconsin grad student doing organic chemistry, I took his course on analytic chemistry to satisfy a course requirement. I never thought I’d ever need to know that stuff. After I got my academic position, I began doing electrochemical research and got to know and appreciate Irv in a very different context.” Later in his honorary speech, Faulkner attested that Shain “compiled a truly extraordinary record of achievement over distinct careers in teaching and research on the leading edge of science, in academic administration at the highest level, and in corporate leadership over research and development. Throughout it all, he was known for his courage and superb standards.” “My thanks to Irv for the enlightenment,” Feldberg says, “and my condolences to his family.” Shain is survived by four children and three grandchildren. Background information for this notice was contributed by Robert P. Frankenthal and Stephen W. Feldberg. The photograph of Shain is by Jeff Miller and comes courtesy of Bassam Z. Shakhashiri at UW–Madison.
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2018 ECS and SMEQ Joint International Meeting
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Looking at Patent Law: A Case Study Regarding the Patenting of a Plating Cell Invention Part II – From Office Actions to Issued U.S. Patents by E. Jennings Taylor and Maria Inman
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n this two-part article, we present a case study of an electrochemical plating cell invention. Part I of the case study1 began with the initial concept as described in the Invention Disclosure and highlights key steps in the prosecution of the patent application by the U.S. Patent & Trademark Office (USPTO). Recall from our previous article,2 the prosecution history of a patent application is publically available in the file wrapper on the USPTO Patent Application Information Retrieval (PAIR) system and is the basis for this case study.3 We chose this invention as particularly illustrative of a diverse number of prosecution “events” an inventor may encounter during the prosecution of their inventions. Table I summarizes this journey from the initial documentation and filing of the invention, through various interactions with the USPTO, to the issue of four separate but related patents. Part I concluded with the publication of the patent application eighteen months after filing.
Restriction/Election Requirement Leading to Divisional Patent Applications
On December 1, 2006, the USPTO issued a requirement for “Restriction/Election” for the 10/804,841 patent application in accordance with US patent laws. The “Restriction/Election” basically says that the 10/804,841 patent application contains two or more inventions and the applicant must “elect” which invention to prosecute first:4 “If two or more independent and distinct inventions are claimed in one application, … [the USPTO] may require the application to be restricted to one of the inventions.” The restriction requirement separated the two inventions as those claims directed towards an apparatus and those claims directed towards a process. The “Restriction/Election” requirement stated:
Invention I: Directed towards a distinct apparatus as described in claims 1-20 and 41-43 Invention II: Directed towards a distinct process as described in claims 21-40 and 44-46 As described in the Manual of Patent Examination Practice (MPEP), two inventions are “distinct” if either of the following can be demonstrated:5
The process as claimed can be practiced by another materially different apparatus …, or the apparatus as claimed can be used to practice another materially different process. We “elected” to prosecute Invention I directed towards an apparatus. The “process claims” that were the subject of Invention II were canceled from the 10/804,841 patent application. We retained the option to prosecute the canceled “process claims” in a subsequently filed “Divisional” patent application provided it was filed prior to the issuance of the original 10/804,841 patent application. As will be described below, we exercised this option in April 2009. This “Divisional” process patent application would have the same “priority date” as that of the “elected” 10/804,841 apparatus patent application and if the 10/804,841 patent application issued as a patent, it cannot be used as a reference against the “Divisional” patent application.4 On March 23, 2007, the USPTO issued a “Non-Final Rejection” regarding the “elected” 10/804,841 apparatus patent application. The ’841 patent application was rejected based on anticipation6 and obviousness7 in light of the prior art. On June 25, 2007, we conducted a telephone interview with the patent examiner in order to better
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(continued on next page) 47
Taylor and Inman
(continued from previous page)
understand the basis for the rejections in lieu of the cited prior art. While telephone interviews can be helpful in clarifying the issue with the examiner, a caution regarding telephone interviews is that a Table I. Timeline of steps in the subject case study. Internal Invention Disclosure Mar 19, 2004: Application filed Jun 3, 2004: Notice to File Missing Parts Jul 26, 2004: Submitted Information Disclosure Statement Apr 4, 2005: Acknowledged federally sponsored research Sep 25, 2005: Application published Dec 1, 2006: USPTO required Restriction/Election Elected Appl. 10/804,841: Apparatus Elected Div. Appl. 12/431/030: Process Mar 23, 2007: Non-Final Rejection Jun 25, 2007: Examiner Phone Interview Aug 10, 2007: Filed C-I-P Application Sep 21, 2007: Final Rejection Jan 22, 2008: Request for Continued Examination Aug 10, 2007: Filed C-I-P Application Apr 2, 2008: Non-Final Rejection
verbal agreement by the examiner does not bind the examiner to the agreement.8 More specifically, all business with the USPTO should be conducted in writing:9 “The action of the Patent and Trademark Office will be based exclusively on the written record in the Office. No attention will be paid to any alleged oral promise, stipulation, or understanding in relation to which there is disagreement or doubt.” During the phone call the examiner explained that there was no evidence that the claimed innovations in the apparatus made a difference in the performance of the cell in terms of uniformity, as compared to the prior art. Based on the examiner interview and cumulative information contained in the “Non-Final and Final” rejections of the ’841 patent application, we determined that a critical embodiment of our invention that could distinguish us from the prior art was the presence of the porous polymeric cloth (128) in combination with the shaped guides (136) shown in Fig. 1. We needed to perform additional experimental work to demonstrate that this embodiment did positively impact cell performance as compared to the prior art, so we ran tests with and without those embodiments. However, as will be shown below, we did not have time to run these experiments before we received the first Final Rejection of the 10/804,841 patent application. Therefore we had to submit a Request for Continued Examination and file an Affidavit containing the new experimental data.
Submission of Continuation-in-Part Applications Based on Ongoing Research Activities, and Types of Continuing Applications
Soon after the phone call with the examiner, we determined that we had invented a new embodiment related to plating of circuit boards containing through-holes, as a result of on-going plating cell research funded by the National Science Foundation. Based on this new embodiment, we elected to file a Continuation-in-Part patent application. Our “problem-solution” statement for this related invention was:
Sep 30, 2008: Submitted Affidavit Jan 8, 2009: Final Rejection Feb 20, 2009: Amended Claims Mar 16, 2009: Notice of Allowance Apr 28, 2009: Application Filed May 21, 2009: Paid Issue Fee Jun 30, 2009: 7,553,401 Patent Issued Aug 20, 2009: Application Published Sept 10, 2010: Non-Final Rejection & Restriction/Election Elected C-I-P Appl. 11/836/,903 Apparatus Elected Div. Appl. 13/086,683: Process Apr 14, 2011: Application Filed Sep 11, 2011: Application Published May 24, 2011: 7,947,161 Patent Issued Jul 24, 2012: 8,226,804 Patent Issued Dec 11, 2012: 8,329,006 Patent Issued
Legend Patent Application 10/804,841: Apparatus Continuation-in-Part Application 11/836,903: Apparatus Divisional Patent Application from 10/804,841: 12/431/030: Process Divisional Patent Application from C-I-P Application 11/836,903: 13/086,683: Process
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The problem of … electroplating a work piece with small through-holes (z-axis interconnects) through which the plating electrolyte would normally flow too slowly resulting in a poorly plated through-hole is solved by … generating a differential and alternating plating solution flow velocity on either side of the work piece such that the plating solution is pulled through the through hole, first one side and then the other, by the venturi effect and the combination of prior art elements such as work piece vibration and work piece oscillation leading to an improved plated through-hole. In Fig. 2, we illustrate the key elements of our new invention wherein the flow is sequentially alternated from either side of the circuit board creating a differential pressure causing a flow through the z-axis interconnect (through-hole). Since the alternating flow embodiment and the planar workpiece containing through-hole comprised new material compared to our original 10/804,841 patent application, our patent counsel drafted a new patent application and on August 10, 2007, we filed “Continuation-in-Part” (CIP) patent application 11/836,903. The ’903 CIP patent application is essentially the same as the 10/804,841 patent application with the exception of the addition of the new material and a new set of claims directed towards the new material. The ’903 CIP patent application claims the benefit of the filing date of ’841 patent application with respect to patent term, 20 years from filing. However, in terms of prior art, the new material receives the benefit of the filing date of the ’903 CIP The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
7. Illustration of the subject plating cell invention.
Request for Continued Examination of the Original Application with Affidavits On September 21, 2007, the USPTO issued a “Final Rejection” regarding the original 10/804,841 patent application. On January 22, 2008, we submitted a “Request for Continued Examination” (RCE) regarding the ’841 patent application. A RCE essentially provides another “bite at the apple” after “Final Rejection” of a pending patent application:10 “If prosecution in an application is closed, an applicant may request continued examination … by filing a submission and the fee … prior to the earliest of: 1. Payment of the issue fee … 2. Abandonment of the application, or 3. The filing of a notice of appeal.”
Fig. 1. Illustration of the subject plating cell invention.
patent application, not the filing date of the ’841 patent application. The ’903 patent application was published approximately seven months later on February 14, 2008. Note, the publication is based on eighteen months from the earliest priority date, which for the case of the ’903 CIP is the filing date of the ’841 patent application. The seven months from filing of the CIP was the time the USPTO needed to get the ’903 patent application in a publishable format. On September 30, 2010, the USPTO issued a “Non-Final Rejection” which consisted of a “Restriction/Election” requirement for the ’903 CIP patent application for the same reasons as denoted in the original 10/804,841 patent application. Therefore, as will be shown later, we elected to restrict the ’903 CIP application to an apparatus patent application, and also file a Divisional process patent application. Since the new material in the CIP was federally funded, any patents issuing from the 11/836,903 CIP patent application will have the government rights acknowledgement: “This application was developed under National Science Foundation Small Business Innovative Research Grant No. IIP-0944707.”
n of the subject plating cell invention with alternating electrolyte flow.
April 2, 2008, the USPTO issued a “Non-Final Rejection” regarding the 10/804,841 patent application. On September 30, 2008, we submitted an “Affidavit” regarding the ’841 patent application. There are generally three types of affidavits which may be submitted during the prosecution of a patent application: 1. Rule 130: To disqualify a disclosure as prior art:11 “[B]y establishing that the disclosure was made by the inventor … [or] by establishing that the subject matter disclosed had … been publically disclosed by the inventor.” 2. Rule 131: To disqualify a commonly owned patent or published patent application as prior art:12 “[P]atent owner may submit an oath or declaration to … establish invention of the subject matter of the rejected claim prior to the effective date of the reference or activity … .” 3. Rule 132: To provide evidence to traverse a rejection:13 “When any claim … is rejected … any evidence submitted to traverse the rejection … on a basis not otherwise provided for must be by way of an oath or declaration under this section.” Our “Affidavit” regarding the ’841 patent application was a “Rule 132 Affidavit” that presented additional experimental data demonstrating the positive impact on plating uniformity across an 18″ × 24″ panel with the subject combination. The experimental work supporting the “Rule 132 Affidavit” took approximately a year to complete and was conducted by an experienced research scientist who was not an inventor. In our opinion, this illustrates the importance of a team spanning numerous skill sets in order to move technology from concept to patentable invention. On January 8, 2009, the USPTO issued a “Final Rejection” regarding the 10/804,841 patent application. The Final Rejection was based on that fact that the original claims were not commensurate in scope with the new evidence contained in the Rule 132 Affidavit. The claims were amended to explicitly point out the subject combination of the porous polymeric cloth (128) and the shaped guides (136) (in Fig. 1) to redefine the boundaries of the “property” covered by the subject invention.14 Specifically, as described in independent claim 1:15 “[A] vertical solution flow that is uniform, parallel to and between the major surface of the workpiece and the parallel porous cloth of the anode chamber.” On March 16, 2009, the USPTO issued a “Notice of Allowance” regarding the 10/804,841 patent application. We paid the issue fee on May 21, 2009 and the patent issued as US patent number 7,553,401 on June 30, 2009. (continued on next page)
Fig. 2. Illustration of the subject plating cell invention with alternating electrolyte flow. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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Taylor and Inman
(continued from previous page)
Table II. Types of continuing patent applications. Type
Inventor Overlap
Disclosure in Parent
Claimed in Parent
Reason
Divisional
Yes — claim defined
Yes
Yes
Restriction requirement
Continuing
At least one common inventor
Yes
No
Applicant capture unclaimed embodiments
Continuation in Part
At least one common inventor
No
No
Applicant claim improvements after parent filing
Submission of Divisional Applications Based on Restriction/Election
On April 28, 2009, we filed a “Divisional” patent application 12/431,030 claiming priority to the 10/804,841 patent application. Note, a “Divisional” patent application must be filed prior to the issue date of the parent 10/804,841 patent application. The 12/431,030 “Divisional” patent application was published August 20, 2009, approximately four months after its filing date. Note, the publication is based on eighteen months from the earliest priority date, which for the case of this “Divisional” is the filing date of the 10/804,841 patent application. The four months from filing of the “Divisional” was the time the USPTO needed to get the 12/431,030 patent application in a publishable format. Recall that the 10/804,841 patent application issued as US patent 7,553,401 on June 30, 2009, approximately two months after the 12/431,030 divisional patent application was filed. In a general sense, once we overcame the objections of the USPTO examiner with the added supporting data in the “Rule 132 Affidavit”, then the CIP and both “Divisional” patent applications issued with similar arguments. As the primary technical argument regarding the original 10/804,841 patent application has been summarized above, we simply provide the timeline related to these continuing patent applications herein. On April 14, 2011, we filed a “Divisional” patent application 13/086,683 claiming priority to CIP patent application 11/836,903. Note, a “Divisional” patent application must be filed prior to the issue date of the parent 11/836,903 patent application. The 13/086,683 “Divisional” patent application was published September 11, 2011, approximately five months after its filing date. Note, the publication is based on eighteen months from the earliest priority date, which for the case of this “Divisional” is the filing date of the 11/836,903 patent application. The five months from filing of the “Divisional” was the time the USPTO needed to get the 13/086,683 patent application in a publishable format. The 11/836,903 patent application which is a CIP of US patent number 7,553,401, issued as US patent number 7,947,161 on May 24, 2011. The issue date is approximately a month after the 13/086,683 Divisional patent application was filed. The 13/086,683 patent application which is a Divisional of US patent number 7,947,161, issued as US patent number 8,226,804 on July 24, 2012. The 12/431,030 patent application which is a Divisional of US patent number 7,553,401, issued as US patent number 8,329,006 on December 11, 2012.
Concluding Remarks In this installment of our “Looking at Patent Law” series, we presented a case study of the conception and patenting of an electrochemical plating cell invention. The case study begins with an “Invention Disclosure” (ID) including the basic items required therein including 1) inventors; 2) title; 3) references; 4) funding source; 5) public disclosure if any; 6) problem-solution statement; and 7) detailed description. We particularly illustrated the value of the problem-solution statement with regards to drafting the patent drawings, detailed description and claims of the invention. We provided examples of patent drawings and their effectiveness in distinguishing the subject invention vis-à-vis the prior art. We described the patent application submission requirements to establish a filing date and the additional submission requirements to maintain the filing date. We introduced the requirement for an “Information Disclosure Statement” (IDS) and the associated “Duty of Candor” in interacting with the USPTO. We touched on the requirement to acknowledge federal funding sources. We discussed the eighteen month publication requirement of patent applications. We illustrated the “Restriction/Election” requirement and the resulting “Divisional” patent applications. We described how on-going research activities can lead to “Continuation-in-Part” (CIP) patent applications. In Table II, we present a description of the types of “continuing” patent applications. We introduced the use of a “Request for Continued Examination” (RCE) and the types of “Affidavits” relevant to prosecution of a patent application. We particularly emphasized the “Rule 132 Affidavit” used in the subject patent application. Finally we provided a timeline (Table III) for the filing and issuing of the patents based on our initial “Invention Disclosure.” Our objective is that electrochemical and solid state scientists, engineers, and technologists are better prepared to interact with their patent counsel regarding their inventions. © The Electrochemical Society. DOI: 10.1149/2.F02182if.
About the Authors E. Jennings Taylor is the founder of Faraday Technology, Inc., a small business focused on developing innovative electrochemical processes and technologies based on pulse and pulse reverse electrolytic principles. Taylor leads Faraday’s patent and commercialization strategy and has negotiated numerous via field of use licenses as well as patent sales. In addition to technical publications and presentations,
Table III. Timeline for the filing and issuing of patents based on the subject plating cell invention. Patent Appl. No.
Filing Date
Patent No.
Issue Date
10/804,841
March 19, 2004
7,553,401
June 30, 2009
11/836,903
August 10, 2007
7,947,161
May 24, 2011
C-I-P (7,553,401)
12/431,030
April 28, 2009
8,329,006
December 11, 2012
Divisional (7,553,401)
13/086,683
April 14, 2011
8,226,804
July 24, 2012
Divisional (7,947,161)
50
Type
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Taylor is an inventor on 40 patents. Taylor is admitted to practice before the United States Patent & Trademark Office (USPTO) in patent cases as a patent agent (Registration No. 53,676) and is a member of the American Intellectual Property Law Association (AIPLA). Taylor has been a member of ECS for 38 years and is a fellow of ECS. He may be reached at jenningstaylor@ faradaytechnology.com. http://orcid.org/0000-0002-3410-0267
Maria Inman is the research director of Faraday Technology, Inc., where she serves as principal investigator on numerous project development activities and manages the company's pulse and pulse reverse research project portfolio. In addition to technical publications and presentations, she is competent in patent drafting and patent drawing preparation and is an inventor on seven patents. Inman is a member of ASTM and has been a member of ECS for 21 years. Inman serves ECS as a member of numerous committees. She may be reached at mariainman@faradaytechnology.com. http://orcid.org/0000-0003-2560-8410
References 1. E. J. Taylor and Maria Inman, “Looking at Patent Law: A Case Study Regarding the Patenting of a Plating Cell Invention: Part I – From Conception to Published Patent Application,” Electrochem. Soc. Interface, 27(1), 37 (2018). 2. E. J. Taylor and Maria Inman, “Looking at Patent Law: Opportunity Prospecting by Analysis of Analogous Patent Art,” Electrochem. Soc. Interface, 26(4), 57 (2017).
3. USPTO Patent Application Information Retrieval (PAIR) https:// portal.uspto.gov/pair/PublicPair. 4. 35 U.S.C. §121 Divisional Applications. 5. Manual of Patent Examination Procedure (MPEP) §806.05(e) Process and Apparatus for Its Practice. 6. 35 U.S.C. §102(e) (pre-AIA) Conditions for Patentability; Novelty and the Loss of Right to Patent. 7. 35 U.S.C. §102(e) (pre-AIA) Conditions for Patentability; NonObviousness Subject Matter. 8. In re Milton (Patent Petition 2007, Appl. No. 09/938,465). 9. 37 CFR §1.2 Business to be Transacted in Writing. 10. 37 CFR §1.114 Request for Continued Examination. 11. 37 CFR §1.130 Affidavit or Declaration of Attribution or Prior Public Disclosure under the Leahy-Smith America Invents Act. 12. 37 CFR §1.131 Affidavit or Declaration of Prior Invention or to Disqualify Commonly Owned Patent or Published Application as Prior art. 13. 37 CFR §1.132 Affidavits or Declarations Traversing Rejections or Objections. 14. E. J. Taylor and Maria Inman, “Looking at Patent Law: Why Are Patents Often Referred to as Intellectual Property,” Electrochem. Soc. Interface, 26(1), 41 (2017). 15. L. E. Gebhart, J. J. Sun, P. O. Miller, and E. J. Taylor, “Electroplating Cell with Hydrodynamics Facilitating More Uniform Deposition Across a Workpiece During Plating,” U.S. Patent No. 7,553,401 issued June 30, 2009.
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t ech highligh t s Modeling the Viability of Polysulfide-Retaining Barriers for Li-S Batteries Lithium-sulfur (Li-S) batteries are one of the most promising candidates for future “beyond Li-ion” high capacity energystorage systems. However, a number of issues still need to be solved before widespread commercialization can occur. Polysulfide shuttle is the main reason why Li-S batteries have low coulombic efficiency and exhibit undesirable self-discharge. Many solutions have been proposed to reduce the effects of polysulfide shuttle such as electrode coatings, the addition of adsorbing inorganic materials and physical barriers in the form of membranes and interlayers. Researchers from the Paul Scherrer Institute have recently presented a model to evaluate the practicability of polysulfide barriers in terms of gravimetric and volumetric energy densities as well as cost. For practical applications comparing different battery chemistries solely in terms of their specific charge and theoretical voltage is not sufficient. The researchers discuss how a fair comparison requires all cell components, which contribute to the weight, volume and cost, to be considered. It is concluded that carbon-based interlayers may be a viable option for low-cost Li-S batteries if the consequential loss of gravimetric and volumetric energy density is acceptable for the particular application. From: E. J. Berg and S. Trabesinger, J. Electrochem. Soc., 165, A5001 (2018).
Au-Cu Alloys Prepared by Pulse Electrodeposition toward Applications as Movable Micro-Components in Electronic Devices Au-Cu alloys, having high density, chemical stability, electrical conductivity, ductility, and high yield strength (σy) properties, are candidates for movable microcomponents in micro-electro-mechanical systems (MEMS) devices. A research team in Japan investigated the micro-compression behavior of micro-pillars fabricated from thick Au-Cu films deposited by pulse current (PC) electrodeposition. The researchers varied the current density and time off (the time on, electrolyte solution composition, and temperature were kept constant) to deposit Au-Cu films in the 4-27% wCu range. Surface morphology and grain size, dg, also were characterized as a function of PC conditions. Engineering stress-strain curves revealed high σy, 1.36 and 1.38 GPa, for the higher wCu alloy samples, 21.9 and 14.2 wt%, respectively, than for the lower wCu micro-pillars. However, the 21.9 wt% sample underwent brittle fracture. The 14.2 wt% micro-pillar had lower dg of 4.68 nm, resulting in better grain boundary strengthening. Additionally, the relatively high solute concentration imparted greater solid solution strengthening to the alloy,
improving σy over that of pure Au. The authors conclude that the PC deposition method affords a simple and versatile means of controlling Au-Cu alloys fabricated in MEMS devices. From: H. Tang, C.-Y. Chen, T.-F. M. Chang, et al., J. Electrochem. Soc., 165, D58 (2018).
Formation Mechanisms of Self-Organized Needles in Porous Silicon-Based Needle-Like Surfaces Anodization of Si has been employed for creating porous silicon and for electropolishing of Si wafers. For the current-voltage conditions in the transition region between these two processes, needle-like structures are formed in lowly doped p-type Si in aqueous HF solutions. Researchers in Germany investigated in detail and modeled the instabilities in space and time occurring at the surface during anodic etching. Conditions spanned various current densities, wafer resistivity, electrolyte additives and etch times. The researchers found the morphology of the needles and surface had a strong dependence on current density. The clustered needle density and the length of these clustered needles increased with increasing current density. The diameter of and distance between these clustered needles decreased with increasing current density. Needle formation was characterized, and modeled, as a sequence of pore formation followed by resulting irregular islets remaining after adjacent pores widen to the point of contact and additional opening up between them. The authors combine the current burst and Zhang pore formation models to explain this process. Further definition of the needles via etching of the side walls and their adjacent pores is described by the Lehmann macropore formation model. From: S. Keshavarzi, U. Mescheder, and H. Reinecke, J. Electrochem. Soc., 165, E108 (2018).
Influence of the Bitline Length on the Resistance Consistency in Phase Change Memory Array Nonvolatile memory based on phase change memory (PCM) consumes low power, operates at high speed, and is able to be fabricated with high storage density in conjunction with the complementary metal-oxide semiconductor (CMOS) process. The PCM device writes by passing coordinated electrical pulses to the PCM cells to change between the highresistivity amorphous phase (Reset) and the low-resistivity crystalline phase (Set). Distinguishable resistances are required for accurate reading. As arrays become larger, effecting appropriate phase change at cells distant from the driving circuit becomes a challenge. Researchers in China investigated the resistance discrepancy amongst 8192 PCM cells (16 groups of 512) on a Bitline.
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Line resistance was considered the dominant factor amongst others such as parasitic capacitance and distribution capacitance and resistance. To counteract the resulting 40% lower resistance by the Reset operation in the 16th group of 512 PCM cells, a higher current (1.47 mA/100 ns compared to 1 mA/100 ns) was applied. Simulation modeling complemented experiments on the fabricated device that found the farthest PCM cell had been reduced ~30% in volume. Employing this approach, an increase in yield from 90% to 99.9% for the 64 Mb PCM test chip was achieved. From: Y.-Y. Lu, D.-L. Cai, Y.-F. Chen, et al., ECS J. Solid State Sci. Technol., 7, Q33 (2018).
Analysis of Near-Surface Metal Contamination by Photoluminescence Measurements Molybdenum and tungsten contamination has a detrimental performance impact on siliconbased devices due to their low diffusivity values. Even small levels of contamination can affect device performance and thus it is becoming more important to detect any contaminants present early on. Current techniques sample too deep into the material and therefore cannot detect the molybdenum or tungsten contaminants which are located close to the surface. An international team of researchers have developed a new technique based on photoluminescence (PL) to probe a sample’s surface for these near-surface metal contaminants. In this technique, a high-power above-gap laser is used to photoexcite the sample to produce PL light. A contaminant close to the surface acts as a recombination center which in turn affects the band-to-band PL intensity and therefore the carrier lifetime; this results in an associated decay due to higher concentrations of contaminants which can then be measured by the PL technique. Contamination in the region of ~1010 cm-2 contaminant dose has been easily detected using this method which is on par with the sensitivity of other conventional techniques which have extra difficulty probing at or near the surface. From: M. L. Polignano, A. Galbiati, I. Mica, et al., ECS J. Solid State Sci. Technol., 7, R12 (2018).
Tech Highlights was prepared by Colm Glynn of Analog Devices International, David McNulty of University College Cork, Ireland, and Donald Pile of Rolled-Ribbon Battery Company. Each article highlighted here is available free online. Go to the online version of Tech Highlights in each issue of Interface, and click on the article summary to take you to the full-text version of the article.
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UPD, SLRR, SEBALD: Abbreviations with Many Connotations by Stanko R. Brankovic
E
lectrochemical deposition is a complex phenomenon that spans over different areas of chemistry and kinetics, thermodynamics, mechanics, metallurgy, and material science. It takes place at the solid/liquid and/or liquid/ liquid interface, which makes the process somewhat unique and fascinating. Our knowledge in this area has significantly improved over the years, leading to the development of new methods and protocols with unprecedented levels of morphology control, composition, structure, and spatial resolution. Along these lines, in this issue of Interface, we focus our attention on several methods and phenomena that have attracted a growing interest in the past decades. Underpotential deposition (UPD) is an enabling phenomenon that exploits the low energy of the metal ion precursors in solution to control the formation of single atomic layers via self-limiting processes. A monoatomic layer of metal is deposited on a conductive substrate at a potential more positive than the redox potential. UPD has been used to modify catalyst surfaces with metallic sub- or monolayers and as an analytical method to determine surface area. In some instances, UPD monolayers are used to enhance deposition kinetics, either serving as surfactants or as flux mediators. The successive deposition of atomic layers at underpotential forming a surface compound—also called electrochemical atomic layer deposition (EC-ALD)—has found wide application in the layer-by-layer growth of semiconductor superlattices. Deposition via surface limited redox replacement (SLRR) of UPD monolayer involves UPD monolayer formation, followed by displacement of this layer with a full or partial monolayer of a more noble metal, through a cementation process (galvanic displacement). An analogous process, selective electrodesorption-based atomic layer deposition (SEBALD) consists of the formation of a sacrificial sulfur monolayer to induce UPD of late transition metals such as Fe, Co, and Ni in the form of monolayers or nanosized islands. Both processes are used extensively by practitioners in different areas to synthesize monolayer or nanocluster catalysts and ultrathin films with different compositions and applications.
The articles presented in the following text discuss the fundamentals and potential applications of these deposition methods. The journey starts with description of the fundamental relations between experimental conditions during SLRR of UPD monolayer and the resulting morphology of the deposit. The following article by Dimitrov et al. brings the example and a critical outlook to the thin film growth applications. As a second part of this story, the article by Vasiljevic delivers comprehensive insight into the SLRR of UPD monolayer for various catalyst synthesis applications. The final post in the journey is the article by Innocenti et al. showing an example of SEBALD for growth of high-quality Bi films. As many researchers in this field have contributed greatly to the magnificent development of these methods, I am sure that interested practitioners can find many other articles in the literature with a wealth of information. Therefore, there is no doubt that new ideas and approaches involving SLRR and SEBALD are being researched, which leaves the guest editor of this issue with a strong impression that the best is yet to come. © The Electrochemical Society. DOI: 10.1149/2.F04182if.
About the Guest Editor Stanko R. Brankovic is a professor in the Department of Electrical and Computer Engineering and the Department of Chemical and Biomolecular Engineering at the University of Houston. His research is focused towards better understanding of the physical and chemical processes at the electrochemical interface and their use in producing materials and nanostructures with novel functionality and applications. The diverse and multidisciplinary nature of his research spans the areas of sensors, magnetic materials, thin films, electrocatalysis, and nanofabrication. He may be reached at SRBrankovic@uh.edu.
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Fundamentals of Metal Deposition via Surface Limited Redox Replacement of Underpotentially-Deposited Monolayer by Stanko R. Brankovic
D
eposition via surface limited redox replacement (SLRR) of underpotentially-deposited (UPD) monolayer (ML)1 has gained many applications in the last two decades.2-4 The caveat of this deposition method is the use of the M UPD ML as sacrificial material to reduce/deposit a more noble metal P (galvanic displacement). Over the years, several experimental protocols have been developed. The first basic protocol1,5 involves formation of a UPD ML of M on the substrate S(h,k,l) (potential controlled step) and then subsequent immersion of MUPD/S(h,k,l) in a separate solution where SLRR occurs and deposition of P takes place at open circuit (sample shuffling approach). The second protocol involves a similar routine but with a stagnant substrate; the solutions for M UPD ML formation and P deposition are exchanged in a single SLRR cycle6 (solution shuffling approach). Finally, the latest developed protocol adopts a one-solution, one-cell experimental design.7,8 In this case, the same solution serves for UPD ML formation and subsequent SLRR reaction at opencircuit potential. In a first potential-controlled step, co-deposition of UPD ML of M with small amount of P occurs, then the potential control is turned off (opencircuit step), allowing the SLRR reaction and deposition of P to proceed. The details of these three protocols have been frequently discussed in literature4,5,9 and examples are presented also in this issue of Interface. In many applications concerned with deposition of only a single monolayer of P or ultra-thin films such as core-shell catalyst synthesis for example2,3,5 (PÂ =Â Pt, Ru, Pd), the properties of deposited films are a direct function of their morphology.10-15 Although the basic role of the UPD ML serving as a reducing agent for noble metal ions can be understood from fundamental electrochemical perception, successful control of the deposit morphology requires deeper insight. Specifically, the SLRR reaction stoichiometry, thermodynamics and kinetics and how these relate to the nucleation process11,16 on the one hand and the experimental conditions5,17 on the other. Therefore, identifying and understanding the fundamental relation between the experimental conditions and processes involved in deposition via SLRR reaction is mandatory if one is to claim full control over the deposit morphology. The aim of this article is to convey these relations using commonly adopted terminology and to point to some opportunities for future developments of this method.
Underpotential Deposition—The First Step and Enabling Phenomenon
UPD represents a potential dependent adsorption with great sensitivity and selectivity towards the nature of the metal surface and its termination. The characteristic cyclic voltammetry features associated with the UPD process are demonstrated by one or more deposition/stripping peaks in the underpotential region observed during the potential sweep in the cathodic/anodic direction. The complexity of the voltammetry features arises from the existence of one or more UPD ML superstructures22,23 and/or one or more UPD MLs formed.24,25 An example of UPD cyclic voltammograms (CVs) is shown in Fig. 1 for two UPD systems commonly used in deposition via SLRR of UPD ML. Over the years, different analytical models were developed to explain the UPD as a potential dependent adsorption process.26-29 The adsorption behavior, in the most cases, is determined by the attractive interactions between the UPD metal and the substrate, and the repulsive interactions between the adatoms within the UPD ML. However, the effect of stored elastic energy in the UPD ML due to the epitaxial strain and the energetics of the anion co-adsorption were found to be important as well. In the quest for proper description of the UPD system one usually resorts to the analytical expression which best describes the underpotential vs. coverage relation, i.e., the UPD isotherm. The Burkenstain-Shwatterian (BS) isotherm is the most general one and offers sufficient depth for the interpretation for most UPD systems. It is formulated as follows:30
E E 0 0
RT m F
ln 1
3/ 2 f g
(1)
Here the E 0 0 term represents the underpotential of the most positive stripping peak of the UPD adlayer where its coverage approaches zero. The term f is the Temkin parameter describing the attractive UPD ML-substrate interactions. The term g is the Frumkin parameter representing the lateral adatom interactions within the UPD ML. Examples of fits of the BS isotherm to θ vs. ΔE data for the two UPD systems in Fig. 1A are shown in Fig. 1B.
Stoichiometry of the Surface Limited Redox Replacement Reaction
The UPD ML coverage can be controlled effectively down to a fraction of a monolayer by proper choice of an underpotential (Fig. 1B). Accordingly, the same accuracy, for the coverage of metal P deposited via SLRR of the UPD M ML is expected. The amount/ coverage of deposited P is controlled by the reaction stoichiometry, and the structure and coverage of the UPD ML of metal M. The most general formulation of the SLRR reaction is given by the following equation:16
Many electrochemical systems that include a noble metal electrode in solution with different metal ions exhibit the UPD phenomenon. It is diagnosed by the formation of one or two wetting monolayers (MLs) on the electrode surface at potentials that are more positive than the equilibrium potential defined by Nernst equation. In the 1960s and UPD M 0 / S (h, k , l ) UPD m P p UPD M m UPD m P 0 / S (h, k , l ) (2) M M UPD M M p solv M M solv M M p s 1970s, extensive studies of many UPD systems were performed on single crystal Here, m and p are the oxidation states of the UPD metal M and the and polycrystalline electrodes.18,19 With the development of different more noble metal P. They are also the stoichiometry coefficients in in situ surface characterization methods during the 1980s and 1990s, the SLRR equation. Factors θM, and Ď MUPD are, respectively, the UPD many UPD systems were re-examined in detail, unraveling more (continued on next page) information about the UPD process, its mechanisms and diversity.20,21 The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
57
Brankovic
(continued from previous page)
1.0 0.8
20
1.0
CuUPD/Au(111) PbUPD/Au(111)
0.8
0.6
0
0.6
θPb
j / ÂľA/cm2
40
PbUPD/Au(111) CuUPD/Au(111)
A
θCu
60
-20 -40 -60
0.4
0.4
0.2
0.2
B
0.0
-80 0.0
0.1
0.2
∆E / V
0.3
0.0
0.0
0.4
0.1
0.2
0.3
∆Ε / V
0.4
Fig. 1. (A) Cyclic voltammograms for Pb UPD on Au(111) (black) and Cu UPD on Au(111) (red). Solution: 10−3 M Pb2+ (Cu2+) + 0.1 M HClO4, sweep rate 10 mV⋅s−1. Insets show atomic resolution of full Cu UPD layer (red) and full Pb UPD layer (black) on Au(111). (B) Coverage θ versus ΔE dependence for Cu UPD on Au(111), (red) and Pb UPD on Au(111), (black). The coverage is estimated from charge stripping experiments. The full lines represent fits of the BS isotherm model to the coverage data (see text for more details).
58
1014 1012 1010
m=2, p=4, m/p=0.50
aP
t 4+
m=1, p=4; m/p=0.25
=0 .01
108
=1
The electrochemical driving force for SLRR reaction between the Pp+ and M UPD ML is the positive difference between equilibrium potential of the bulk P and equilibrium potential of the M UPD ML at its coverage approaching zero limit, θUPD → 0.1 This condition is defined as: m RT aM m 0 0 ESLRR EEMF E 0 ln 0 (4) p F aP p
1016
4+
Driving Force for the SLRR Reaction and Nucleation Rate of Depositing Metal
a Pt
Practitioners should be aware that the overall stoichiometry of the SLRR reaction also depends on specific experimental conditions favoring one over the other oxidation states of the metal M constituting the UPD ML. A typical example is copper which is stable either as the Cu+ or Cu2+ ion. Direct ligand transfer from depositing noble metal ion complexed with halides ({PXn}(p-n), P = Pt, Pd, Ru, X = Cl−, Brâˆ’Â â€Ś) to dissolving Cu ions could stabilize a {CuX2}− complex where Cu has the +1 oxidation state.16 This situation is generally applicable to experiments where the supporting electrolyte in the SLRR solution does not contain anions with complexing/stabilizing ability towards Cu2+ such as {ClO4}− for example. Therefore, one should make sure to know the main complexing ligands at the interface when considering the stoichiometry of the SLRR of Cu UPD ML.
0 0 EEMF EP0 p / P EM0 m / M represents the electromotive Here, EEMF force for the bulk M and P galvanic couple at standard conditions. The E 0 0 is the equilibrium underpotential of M UPD ML at the θUPD → 0 limit (UPD shift) at standard conditions (aM m 1, aPp 1 , where a stand for activity). The logarithmic term provides a correction for the departure from standard conditions. In general, for most systems involving a noble metal ion-UPD metal ML, the condition described by Eq. 4 is always satisfied (Ag and Pd UPD MLs might be the only exceptions). It is important to recognize that ΔESLRR can be modified by adjusting the activities of Mm+ and Pp+ ions in the reaction solution, Eq. 4. Assuming that the ion concentrations are a good approximation for the activity of metal ions, it is a straightforward exercise to show that the nucleation overpotential and nucleation rate (JÂ âˆźÂ exp(−const/(ΔESLRR)2))31are effectively controlled by the metal ions concentration. Clearly, the link between the experimental
JPt / cm-2 s-1
ML coverage and the packing density of M atoms in the full UPD ML with respect to the underlying substrate S(h,k,l). These parameters serve to accurately express the amount of deposited metal P in ML units with respect to the substrate S(h,k,l). In many reports, they are commonly omitted as the authors use consolidated SLRR equation defined only in terms of the stoichiometry coefficients. These presentations generally lack the full information about the expected deposit coverage in a single SLRR cycle. For example, if the metal P forms a 2D-monoatomically thick deposit, one can easily deduce, from Eq. 2, the expected P coverage with respect to the atomic areal density of the substrate. It is defined as:16 m P M MUPD (3) p
106
aP
104
t 4+
2
10
100 10-7
10-6
10-5
aCu /aPt m+
=1 10-4
10-3
p+
Fig. 2. Estimates of the Pt nucleation rate versus aCu m+ / aPt 4+ ratio. Estimates are made for Pt deposition via SLRR of Cu UPD ML. SLRR reactions: 2Cu0UPD + {PtCl6}2− = Pt0 + 2Cu2+ + 6Cl− (black). 4Cu0UPD + {PtCl6}2− + 2Cl− = 4{CuCl2}− + Pt0 (red). The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
conditions and nucleation behavior of the system is rooted in the dependence of ΔESLRR on the SLRR reaction stoichiometry and the metal ion concentrations in the reaction solution. The special case for ΔESLRR is when there are no Mm+ in the reaction solution. Then, the logarithmic term is very large and its contribution dominates the value of ΔESLRR. This leads to high nucleation rates of P and formation of very small 2D nuclei on the surface. This discussion is qualitatively illustrated in Fig. 2. Using classical nucleation theory,31 the nucleation rate is approximately calculated for Pt deposition on Au(111) via SLRR of Cu UPD ML. For the two scenarios discussed previously (Cu+ vs. Cu2+), the nucleation rate is shown as a function of aCu m+ / aPt 4+ ratio. One can see that a change in the experimental conditions leading to a 10× decrease in aCu m+ / aPt 4+ produces approximately a 103 – 105 times higher nucleation rate. A similar effect is achieved by 100× dilution of Pt4+ while keeping the same aCu m+ / aPt 4+ ratio. It has to be mentioned that the calculations in Fig. 2 are considered only as an illustration of the qualitative trend in nucleation rate induced by the changes in reaction stoichiometry (m/p ratio) and solution design (aCu m+ / aPt 4+). The conclusion that one takes from this discussion is that the SLRR reactions with larger m/p ratio and solutions with smaller aM m+ / aP p + ratio yield higher nucleation rates and thus a P deposits consisting of smaller clusters.
Reaction Kinetics vs. Nucleation Kinetics
Thermodynamics arguments formulate a correct framework for understanding the trends in deposit morphology dependence on experimental conditions of SLRR. Nevertheless, they are insufficient to elucidate all mechanistic details of the nucleation process. For this reason, other approaches were developed to establish a complete understanding of the phenomena controlling the deposition via SLRR of UPD ML. Following theoretical considerations from nucleation kinetics,32,33 generalized results from recent work show that the nucleation density of P obtained during SLRR of UPD ML of metal M is well described by the following relation:11 nPSLRR 0 1 o , M o , M
N /3
(5) Here, nPSLRR is given in cm−2 units and Îą0 is the numerical constant 1/ 3
m UPD K defined as 0 M S SLRR . KSLRR is the SLRR reaction rate 2 p D a P constant in s−1 units, ΓUPD is the surface concentration of the full UPD M ML in mol∙cm−2 units, DPS is the surface diffusivity of P adatoms over the substrate S(h,k,l) in cm2∙s−1 and a is the nearest neighbor distance on the surface (cm). The term χ is the numerical constant defined as 1−(nP) where (nP) stands for the nucleation probability of P on top of the M UPD ML.11 θo,M represents the initial coverage of the UPD ML and the N is the SLRR reaction order in terms of the UPD ML as reactant. Equation 5 only applies for reaction orders where N > 0, i.e., for true SLRR reaction kinetics. When N > 1, the rate constant is defined as follows:17 K SLRR N 1 k CPis UPD M L
N 1
(6)
Here, k represents the fundamental rate constant, CPis is the concentration of Pp+ at the interface in mol∙cm−2 units and L is the SLRR reaction order in terms of Pp+ as reactant. For any practical consideration, CPis can be expressed as the product of the bulk concentration CP∞ , (mol∙dm−3) and the interface width 10 7 cm, CPis CP . For the case N = 1, the rate constant is defined as follows:17 K SLRR k CPis
L
(7)
The proper determination of the reaction order and rate constant during SLRR of UPD ML is a somewhat challenging task.17,34 To a first approximation, the value of N can be taken from the SLRR reaction stoichiometry assuming that it is an elementary red-ox process. However, a more proper methodology for the determination of the SLRR reaction kinetics parameters requires in situ measurements that monitor the UPD ML coverage during the reaction. One way to do this is by measuring the surface reflectivity during SLRR reaction and fitting the obtained data by an appropriate rate equation to extract the rate constant and reaction order.34 Another way to do this is by measuring the open circuit potential (OCP) during the SLRR reaction.17 This approach is somewhat easier to implement. It requires the derivation of an analytical model for the dependence of E vs. t during the SLRR reaction to fit the experimental OCP data and extract the parameters of the reaction kinetics.17 The E versus t models are obtained by combining the appropriate rate equation35 with a representative UPD adsorption isotherm, such as Eq. 1. Results from such an analysis are shown in Table I below.36 Equation 5 represents a bell-shape function whose maximum (nPSLRR = max) occurs for θo,M = N/(χ(3 + N), Fig. 3. nPSLRR is proportional to Îą0. Hence, with proper choice of θo,M as well as by careful design of the SLRR reaction and experimental conditions governing Îą0, it is possible to control nPSLRR and achieve the desired average cluster size 10 ,11 SLRR of the P deposit S P .This m / p o , M MUPD / nPSLRR P / nP is of particular importance for the catalysis community where finite size effects are shown to dominate the Pt ML catalyst activity.10,15,37 Control of the nucleation density and the average cluster size in a single SLRR cycle is also of great interest for thin film growth applications. Homo- and hetero-epitaxial systems that exhibit 3D growth at room temperature due to kinetics limitation can be effectively forced to grow in 2D mode by enhancing the nucleation density and producing smaller nuclei during the growth process.38 To illustrate the arguments presented here, we focus on Fig. 3 where plots of Eq. 5 are presented using SLRR kinetics parameters from Table I. The case N = 4 is the starting point in the discussion (bold red). First, we address the effect of KSLRR on nPSLRR . By definition, KSLRR is proportional to the bulk concentration of P (Pt) ions, Eq. 6 and Eq. 7. A 100Ă— dilution of {PtCl6}2− ions, (from 10−3 M to 10−5 M {PtCl6}2−) results in a 40Ă— decrease in KSLRR (Table I). Considering that Îą0 âˆź (KSLRR)1/3, an approximately 3.5Ă— lower nucleation rate is expected. The calculated functional relation between nPtSLRR and θo,Cu for 10−5 M {PtCl6}2− is shown in Fig. 3 as a green dashed line. The mathematical form of the relation does not change and evidently, higher concentration of {PtCl6}2− would produce qualitatively the same effect but in the opposite direction, i.e., nPtSLRR would increase 3.5Ă—. (continued on next page)
Table I. Parameters for SLRR reaction kinetics extracted from OCP measurements. SLRR Reaction
0 UPD
Cu
m m 0 m Ptpsolv Pt s . Cusolv . p p
KSLRR, [s−1]
N
m/p
Ref.
10−3 M {PtCl6}2− + 0.1 M H2SO4
4.08 ¹ 0.07
2a
0.5
17
10−3 M {PtCl6}2− + 0.1 M HClO4
3.61 ¹ 0.03
2b, 4a
0.25
17
10−5 M {PtCl6}2− + 0.1 M HClO4
0.089 ¹ 0.0008
2b, 4a
0.25
17
Solution, ω = 1000 rpm
Reaction order is taken based on the value of stoichiometry coefficients. Reaction order determined from the fits of the reaction kinetics model to the open circuit transients obtained during SLRR reaction.
a
b
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Brankovic
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Based on this discussion, one concludes that the nucleation density and nanocluster size is a strong function of the Pp+ ({PtCl6}2â&#x2C6;&#x2019;) concentration and the initial coverage of the UPD ML, θo,M (θo,Cu). The choice of supporting electrolyte in the SLRR reaction involving Cu UPD ML has a decisive effect on the oxidation state of Cu. In the case of 0.1 M HClO4, Table I, the absence of solution complexing ability for Cu2+ makes the Clâ&#x2C6;&#x2019; liberated from {PtCl6}2â&#x2C6;&#x2019; the only ligand at the interface.16 This leads to formation of the {CuCl2}â&#x2C6;&#x2019; complex with Cu being +1 oxidation state and m/p = 0.25. However, if the reaction solution has an abundance of sulfate ions, (for example: 0.1 M H2SO4) the Cu oxidation state in the SLRR reaction is +2. It means that the m/p ratio is 0.5. The reaction rate constant in this electrolyte is slightly higher too (KSLRR = 4.08 sâ&#x2C6;&#x2019;1, Table I). Both effects increase the value of Îą0 by approximately 30% . The additional outcome is that the reaction order in the case of a 0.1 M H2SO4 electrolyte changes to N = 2.17 This changes the qualitative shape of the nPtSLRR versus θo,Cu curve and the position of the maximum shifts to θo,Cu â&#x2030;&#x2C6; 0.4. Therefore, for the same concentration of Pt ions in solution (10â&#x2C6;&#x2019;3 M) but with a 0.1 M H2SO4 supporting electrolyte, roughly 30% higher nPtSLRR values are expected in the 0 < θo,Cu < 1 range with qualitatively different nPtSLRR dependence on θo,Cu, (Fig. 3, blue dashed line). Following the same logic, further enhancement in nucleation density should be expected if the {PtCl6}2â&#x2C6;&#x2019; ion is replaced with {PtCl4}2â&#x2C6;&#x2019; yielding m/p = 1. In this case, Îą0 is approximately 60% larger than the original one. In addition, one Pt ion reacts with one Cu UPD adatom and the reaction order takes N = 1.17,36 Both changes make a major impact on the nPtSLRR versus θo,Cu dependence even if the KSLRR remains the same (Fig. 3, black line). The maximum value of nPtSLRR increases almost 75% and further shifts toward the lower values of θo,Cu (θo,Cu = 0.23, for nPtSLRR = max). The overall conclusion is that a larger m/p ratio produces a higher nucleation density and a deposit with smaller nanoclusters. The opposite is true when the reaction order is considered. The higher the SLRR reaction order, the lower the nucleation density is, i.e., a deposit with larger nanoclusters is expected.
Fig. 3. Model predictions (Eq. 5) for nPtSLRR versus θο,Cu dependence on SLRR reaction kinetics parameters from Table I. Parameters of the model:11 2 DPtS / cm 2s â&#x2C6;&#x2019;1 = 3.5 Ă&#x2014; 10â&#x2C6;&#x2019;8; Ď&#x2021; = 0.9; UPC = 1.15 Ă&#x2014; 1015; Cut /cm a/cm = 0.408 Ă&#x2014; 10â&#x2C6;&#x2019;7.
An additional way to alter the values of KSLRR and nPSLRR is by manipulating the experimental conditions that directly influence the fundamental rate constant k. Studies of the SLRR reaction kinetics during Au deposition via SLRR of Pb UPD ML using a one-solution, one-cell protocol show that k is linearly dependent on â&#x2C6;&#x17E; Pb2+ concentration, CPb , Fig. 4A.34 A higher concentration of Pb2+ leads to larger values of k. 100% increase in the value of k (or kΞ) is observed for one order of magnitude increase in Pb2+ concentration. Considering the generalized notation adopted throughout the manuscript, we can state that experimental data in Fig. 4A indicate k = f(CMâ&#x2C6;&#x17E; ). The k dependence on CMâ&#x2C6;&#x17E; can be explained by looking into the intrinsic relations between the definitions for the fundamental rate constant,39 k â&#x2C6;źÂ exp(â&#x2C6;&#x2019;Î&#x201D;G#/RT), the free energy of the activated complex,40 Î&#x201D;G# = (Î&#x201D;GSLRR + Îť)2/4Îť and Î&#x201D;ESLRR, Eq. 4.1 After recalling
Activated Complex
{pM
3
3x10
UPD
p+ â&#x2C6;&#x2019; â&#x2C6;&#x2019; â&#x2C6;&#x2019; â&#x2C6;&#x2019;mPsolv
m p+ M UPD + Psolv p
2x103
Energy
kΞ / dm2s-1mol-1
Reactants
1x103
0 0.000
Surf. Reflectivity Data OCP Data eq(8) eq(8)
A 0.002
0.004 oo Pb
0.006
0.008
-3
C / mol dm
0.010
â&#x2C6;&#x2020;G
}
â&#x2C6;&#x2020;G #
#
â&#x2C6;&#x2020;GSLRR
Products
â&#x2C6;&#x2020;GSLRR
m+
CMâ&#x2C6;&#x17E;
B
>
CMâ&#x2C6;&#x17E;
M solv +
m Pdep p
Reaction coordinate
â&#x2C6;&#x17E; Fig. 4. (A) Experimental data for the product of fundamental rate constant and interface width (kΞ) as a function of Pb2+ concentration, CPb , for SLRR reaction: 2 2 0 3 2 0 ; surface reflectivity (black squares); OCP measurements (red circles); and dotted lines represent fits of Eq. 8. PbUPD Ausolv Pbsolv Aus 3 3 â&#x2C6;&#x17E; # (B) Schematics illustrating change of Î&#x201D;GSLRR and Î&#x201D;G with increasing CM . Adopted from Ref. 34 with permission.
60
The Electrochemical Society Interface â&#x20AC;˘ Summer 2018 â&#x20AC;˘ www.electrochem.org
m F ESLRR , and p CP , one can show easily that the assuming that M m M and aP p functional relation between k and CMâ&#x2C6;&#x17E; is given by: basic
thermodynamic
relation GSLRR
2 m F E 0 E 0 RT ln CP 0 EMF p CM k â&#x2C6;ź exp 4 RT
(8)
Here, Îť represents the reorganization energy in J.molâ&#x2C6;&#x2019;1 units while F and R are the Faraday and universal gas constants respectively. â&#x2C6;&#x17E; The fit of the functional defined by Eq. 8 to kΞ versus CPb data is plotted in Fig. 4A, dashed lines. We conclude that increasing the UPD metal ion concentration lowers the free energy for the SLRR reaction, which in turn leads to a lower free energy of the activated complex (energy barrier for SLRR reaction), and this leads to a larger value of the fundamental rate constant. A pictorial form of this conclusion is shown in Fig. 4B. Additionally, Eq. 8 provides functional describing of the of CPâ&#x2C6;&#x17E; effect on k. Significantly, an increase in CPâ&#x2C6;&#x17E; leads to lower values of k, i.e., CPâ&#x2C6;&#x17E; has an opposite effect on k than CMâ&#x2C6;&#x17E; . However, per Eq. 6 and L Eq. 7, the term CP is multiplicand in the mathematical description of KSLRR. These apparently conflicting effects of CPâ&#x2C6;&#x17E; on the overall value of KSLRR suggest a complex KSLRR versus CPâ&#x2C6;&#x17E; dependence. Yet, the experimental studies of SLRR kinetics during Au deposition via SLRR of UPD Pb ML show that KSLRR is increasing monotonically with increasing values of CPâ&#x2C6;&#x17E;.34 Therefore, more experiments with diverse conditions are necessary for a better understanding of the CPâ&#x2C6;&#x17E; effects on KSLRR. As a conclusion, we should emphasize the fact that proper design of the metal ion concentrations in the reaction solution represents an extra â&#x20AC;&#x153;knobâ&#x20AC;? to manipulate the nucleation density and to fine-tune the overall morphology of the deposit obtained by SLRR of UPD ML. Recent studies that certainly deserve more experimental and theoretical attention demonstrate a large effect of the supporting electrolyte on the fundamental rate constant. Experimental data are shown in Fig. 5 for the SLRR reaction between Au3+ and Pb UPD ML on Au(111).34 The results are intriguing since there is no obvious effect of the supporting electrolyte on reacting species neither is an obvious relation between the supporting electrolyte concentration â&#x2C6;&#x17E; and the definition of KSLRR or k. Nevertheless, the k versus CHClO 4 trend in Fig. 5 can be discussed by considering a basic postulate â&#x2C6;&#x17E; 41 of the Debye-Huckel theory of electrolyte. A higher CHClO4 in the solution influences the Debye length, ÎťD, which is a distance at which the ion charge and Coulomb potential are completely screened by the surrounding ions in solution. For a symmetric supporting electrolyte 0.5 such as HClO4, the Debye length has D â&#x2C6;ź CHClO4 dependence. Therefore, more perchlorate ions in solution will reduce the value of the Debye length. This means that the effective Coulomb field surrounding a potentially reacting Au3+ ion near the surface is felt at shorter distance if the reaction solution contains more HClO4. Because of that, the distance between Au3+ and Pb UPD adatoms necessary for effective electron transfer/tunneling has to be shorter. This leads to lower spatial probability of reactive encounter between Pb UPD adatoms and Au3+ ions and one could expect slower kinetics of the red-ox process and lower values of the rate constant in solution â&#x2C6;&#x17E; with higher CHClO . Therefore, the proper design of the supporting 4 electrolyte concentration in the reaction solution is an elegant way to control the SLRR reaction kinetics and nucleation density and thus to control the morphology of the deposit.
Conclusion and Future Prospects Future prospects for metal deposition via SLRR of UPD ML are quite exciting. New ideas and approaches focusing on development of diverse protocols with even more possibilities for deposit morphology control are being researched. Along these efforts, one concept that certainly deserves more attention is metal deposition via SLRR of a
0.06 0.05
k' / s-1
the
0.04 0.03 0.02 0.00
0.05
0.10
0.15
/ mol dm-3 Coo HClO
0.20
4
Fig. 5. Rate constant values plotted as a function of supporting electrolyte concentration. Data obtained from surface reflectivity measurements. Adopted from Ref. 34 with permission.
UPD ML guided by organic templates.42 This concept is based on the spatial control of the nucleation probability using an organic phase which shows ordering on the electrode surface in the potential range of the SLRR reaction. The proof of this concept is shown in Fig. 6. The STM image of an organized layer consisting of PTCDI + melamine molecules43 adsorbed on top of CuUPD/Au(111) and serving as a template is shown in Fig. 6A. The tri-fold symmetry and organization of the 2D organic phase is evident. The center to center spacing of the unit cells (cages) in the structures is approximately 0.9 nm while the diameter of the empty space within the cell is ~0.7 nm. After SLRR of Cu UPD ML by {PtCl6}2â&#x2C6;&#x2019; through the PTCDI + melamine layer, Pt is deposited on Au(111) forming islands/patches consisting of a wellorganized population of Pt nanoclusters, Fig. 6B and 6C.44 The effect of the organic template is obvious, Fig. 6B. The size and organization of Pt nanoclusters replicate the arrangement and symmetry of the organic template, Fig. 6C. The discussions presented in this article highlight the current understanding of the fundamental relations governing the nucleation process during metal deposition via SLRR of UPD ML. They describe phenomenological links between the reaction solution design, choice of the UPD metal ML and SLRR reaction stoichiometry on the one hand and the SLRR reaction kinetics parameters, nucleation density,11,16 and resulting morphology of the deposit4,10 on the other. The general trend is that experimental conditions and solution design leading to SLRR reactions with faster kinetics yield higher nucleation density and deposits with smaller clusters for a given starting coverage of UPD ML. The experimental conditions promoting a larger m/p ratio and lower reaction order in terms of the θo,M do promote higher nucleation density and formation of deposits with smaller nanoclusters. These considerations are particularly important when one considers deposition via SLRR of UPD ML for catalyst ML synthesis application. Design of the optimum experimental conditions for a desired catalyst ML morphology is a function of its application and intended use in a particular reaction. In the case where high activity of the catalyst ML is desired, the conditions promoting low nucleation density and formation of deposit ML morphology with larger nanocluster should be used. However, if poisoning of the catalyst by intermediates hinders the particular reaction kinetics, the synthesis of catalyst ML with modest activity might be beneficial to retain a good reaction yield and the desired reaction pathway.37 In this case, the conditions promoting high nucleation density and small average size of nanoclusters should be chosen. The same is true if one pursues the
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A
B
C
Figure 6. STM images of: (A) PTCDI + Melamine layer adsorbed on CuUPD/Au(111), E = −0.V versus SCE in 0.1 M HClO4, image size: 25 × 25 nm. (B) Pt on Au(111) after SLRR of Cu UPD ML by Pt4+ through PTCDI + Melamine layer, image size: 15 × 15 nm. (C) Same as in B, image size 5 × 5 nm. Cartoons of the structures (bottom left) corresponding to the situation in image A and B.
goal of depositing a high quality homo- and hetero-epitaxial thin films. In conclusion, the considerations presented in this article should be of broader significance for the catalysis and thin film communities as an effort in bridging the gap between the desired properties of metal deposit obtained by SLRR of UPD ML and the required conditions for its synthesis. © The Electrochemical Society. DOI: 10.1149/2.F05182if.
Acknowledgment The author greatly acknowledges financial support from the National Science Foundation under the grants CHE-0955922 and CBET 1605331.
About the Author Stanko R. Brankovic is a professor in the Department of Electrical and Computer Engineering and the Department of Chemical and Biomolecular Engineering at the University of Houston. His research is focused towards better understanding of the physical and chemical processes at the electrochemical interface and their use in producing materials and nanostructures with novel functionality and applications. The diverse and multidisciplinary nature of his research spans the areas of sensors, magnetic materials, thin films, electrocatalysis, and nanofabrication. He may be reached at SRBrankovic@uh.edu.
References 1. 2. 3. 4. 5. 6. 7.
S. R. Brankovic, J. X. Wang, and R. R. Adzic, Surf, Sci,, 474, L173 (2001). K. Sasaki, J. X. Wang, H. Naohara, N. Marinkovic, K. More, H. Inada, and R. R. Adžić, Electrochim. Acta, 55, 2645 (2010). A. Nilekar, Y. Xu, J. Zhang, M. Vukmirovic, K. Sasaki, R. Adžić, and M. Mavrikakis, Top. Catal., 46, 276 (2007). N. Dimitrov, Electrochim. Acta, 209, 599 (2016). M. B. Vukmirovic, S. T. Bliznakov, K. Sasaki, J. X. Wang, and R. R. Adzic, Electrochem. Soc. Interface, 20, 33 (2011). Y. G. Kim, J. Y. Kim, D. Vairavapandian, and J. L. Stickney, J. Phys. Chem. B, 110, 17998 (2006). C. Mitchell, M. Fayette, and N. Dimitrov, Electrochim. Acta, 85, 450 (2012).
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J. Nutariya, M. Fayette, N. Dimitrov, and N. Vasiljevic, Electrochim. Acta, 112, 813 (2013). S. R. Brankovic, N. Vasiljevic, N. Dimitrov in Modern Electroplating V, M. Paunovic and M. Schlesinger, Editors, p. 573, John Willey and Sons, Inc. New York, NY (2010). S.-E. Bae, D. Gokcen, P. Liu, P. Mohammadi, and S. R. Brankovic, Electrocatalysis, 3, 203 (2012). D. Gokcen, Q. Yuan, and S. R. Brankovic, J. Electrochem. Soc., 161, D3051 (2014). M. Fayette, Y. Liu, D. Bertrand, J. Nutariya, N. Vasiljevic, and N. Dimitrov, Langmuir, 27, 5650 (2011). L. T. Viyannalage, R. Vasilic, and N. Dimitrov, J. Phys. Chem. C, 111, 4036 (2007). J. Zhang, K. Sasaki, E. Sutter, and R. R. Adžić, Science 315, 220 (2007). R. Loukrakpam, Q. Yuan, V. Petkov, L. Gan, S. Rudi, R. Yang, Y. Huang, S. R. Brankovic, and P. Strasser, Phys. Chem. Chem. Phys., 16, 18866 (2014). D. Gokcen, S.-E. Bae, and S. R. Brankovic, J. Electrochem. Soc., 157, D582 (2010). D. Gokcen, S.-E. Bae, and S. R. Brankovic, Electrochim. Acta, 56, 5545 (2011). S. Trasatti, J. Electroanal. Chem., 33, 351(1971); and references therein. D. M. Kolb in Advances in Electrochemical Eng., H. Gerischer and W. Tobias, Editors, Wiley & Sons, New York (1978); and references therein. E. Budevski, G. Staikov, and W. J. Lorenz in Electrochemical Phase Formation and Growth, R. C. Alkire, P. N. Bartlett, and J. Lipkowski, Editors, p. 41, VCH, Berlin (1996); and references. therein. E. Herrero, L. J. Buller, and H. D. Abruña, Chem. Rev., 101, 1897 (2001). M. Will, M. Dietterle, and D. Kolb, in Nanoscale Probes of the Solid/ Liquid Interface, Vol. 288, A. Gewirth and H. Siegenthaler, Editors, p 137-162, Springer, Berlin (1995). S. Garcia, D. Salinas, and G. Staikov, Surf. Sci., 576, 9 (2005). S. Corcoran, G. Chakarova, and K. Sieradzki, J. Electranal. Chem., 377, 85 (1994). M. Esplandiu, M. Schneeweiss, and D. Kolb, Phys. Chem. Chem. Phys., 1, 4847 (1999). K. Engelsmann, W. Lorenz, and E. Schmidt, J. Electroanal. Chem., 114, 1 (1980). E. Schmidt, H. Gygax, and P. Bohlen, Helv. Chim. Acta, 49, 733 (1966). The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
28. R. Adzic, E. Yeager, and B. Cahan, J. Electrochem. Soc., 121, 474 (1974). 29. A. Bewick and B. Tomas, J. Electroanal. Chem., 84, 127 (1977). 30. S. Swathirajan and S. Bruckenstein, Electrochim. Acta, 28, 865 (1983). 31. I. V. Markov, Crystal Growth for Beginners, World Scientific, NY (1995). 32. S. Stoyanov and D. Kashchiev, in Current Topics in Material Acience, Vol. 7, E. Kaldis, Editor, p. 69, North Holland, NY (1981). 33. J. A. Venables, G. D. Spiller, and M. Hanbucken, Rep. Prog. Phys., 47, 339 (1984). 34. E. Bulut, D. Wu, N. Dole, H. Kilic, and S. R. Brankovic, J. Electrochem. Soc., 164, D159 (2017). 35. J. M. Smith, Chemical Engineering Kinetics, 2nd edition, p. 47 and 52, McGraw Hill, New York (1970). 36. S. R. Brankovic and G. Zangari in Electrochemical Engineering Across Scales: From Molecules to Processes, R. C. Alkire, P. N. Bartlett, and J. Lipkowski, Editors, p. 59-107, Wiley-VCH, New York (2015). 37. Q. Yuan, H. A. Doan, L. Grabow, and S. R. Brankovic, J. Am. Chem. Soc., 139, 13676 (2017). 38. K. Sieradzki, S. R. Brankovic, and N. Dimitrov, Science, 284,138 (1999). 39. S. Glasstone, K. J. Laidler, and H. Eyring, The Theory of Rate Processes, McGraw-Hill, New York (1941). 40. R. A. Marcus, Annu. Rev. Phys. Chem. 15, 155 (1964). 41. P. Debye and E. Hückel, Phyz Z. 24, 185 (1923). 42. D. Gokcen, O. Miljanic, and S. R. Brankovic, Abstract 2051, The Electrochemical Society Meeting Abstracts, MA 2010-02, Las Vegas, NV, Oct. 10-15 (2010). 43. R. Madueno, M. T. Raeisaenen, C. Silien and M. Buck, Nature, 454, 618 (2008) 44. D. Gokcen, O. Š. Miljanić, and S. R. Brankovic, Abstract 2443, The Electrochemical Society Meeting, Abstracts, MA 2009-02, Vienna, Austria, Oct. 4–9 (2009).
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Palladium Ultrathin Film Growth by Surface-Limited Redox Replacement of Cu and H UPD Monolayers: Approaches, Pros, Cons, and Comparison by Nikolay Dimitrov, Innocent Achari, and Stephen Ambrozik
P
alladium (Pd) is a Pt-group metal with unique properties relative to others within this group. It features high activity and remarkable selectivity in catalytic applications associated with pharmaceutical, agrochemical, and fine chemical industries.1 In addition, it has a very high affinity for hydrogen (H), so that it can, not only, selectively and reversibly adsorb a monolayer of H, but it is also capable of absorbing quantities of this element as high as 900 times its volume under ambient conditions of temperature and pressure.2 The absorbed H occupies the octahedral sites in the Pd fcc crystal lattice and forms a nonstoichiometric hydride compound, PdHx in addition to the adsorbed hydrogen at the electrochemical interface.3 Owing to the high affinity of Pd toward H and the very small size of the H atoms, they can freely and reversibly diffuse into, and out of, the Pd crystal lattice. Thus, depending on the pressure, Pd can be used to store H and thereby constitute a potential solution of the H-gas storage problem faced by hydrogen fuel cell powered vehicles.4 This could ultimately facilitate said vehiclesâ&#x20AC;&#x2122; commercialization. This high affinity toward H also makes Pd a good candidate for usage in catalytic scenarios associated with H sensing,5 as well as a potent fuel cell catalyst6 that could either replace Pt,7 or be alloyed with Pt and/or other elements to drive these applications forward. To date, Pt is utilized as the commercial standard for electrocatalysts in fuel cells but it is also known as an expensive rare metal and is less abundant relative to Pd. However, relative to Pt, the utilization of Pd in fuel cells does not provide significant monetary advantages, therefore minimizing its quantity while maximizing its utilization in relevant applications is one of the goals of state-of-the-art fundamental research and applied industrial developments. In practical realization, Pd or Pd-alloy ultrathin films, which have unique properties relative to the bulk counterparts, have been developed for application in H sensing, electrocatalysis, catalytic conversion, etc. Such ultrathin films grown on different substrates with strict structural and thickness control exhibit the said unique properties mostly owing to specific surface stress effects and/or the electronic interactions between the thin film atoms and those of the substrate.8 These interactions often lead to both improved catalytic activity and enhanced durability of the accordingly synthesized catalyst and improved electronic and magnetic properties.9 Such films can be grown for the purposes of heterogeneous catalysis on conductive (especially electrocatalysts) or nonconductive inert and inexpensive carriers.
Deposition of Pd Ultrathin Films and the SLRR Approach
The growth of thin metal films in a layer-by-layer mode is instrumental for the control of thickness, morphology, and continuity of the deposit. Moreover, to take advantage of unique catalytic properties owed to overlayer strain of ultra-thin films, the films must be epitaxial with respect to the substrate. Thin films of Pt-group metals, including Pd, have been deposited in quasi 2D growth mode
to a thickness of tens of nanometers on various substrates by utilizing atomic layer deposition (ALD) techniques such as physical vapor deposition (PVD),10 molecular beam epitaxy (MBE),11 chemical vapor deposition (CVD),12 metalorganic chemical vapor deposition (MOCVD),13 magnetron sputtering,14 and electrodeposition.15 The latter approach is often preferred due to a lower level of operational complexity, low cost of the instrumentation and its maintenance, and finally, its functioning under ambient conditions. Unlike all deposition approaches requiring ultra-high vacuum (UHV) along with elevated temperature, the electrochemical based approaches normally only require oxygen evacuation for proper functioning.16,17 As per other experimental requirements, the electrochemical deposition routines operate under applied potential enabling the reduction of ions of the metal or alloy thin film of interest thus producing a well-defined overlayer structure. Bulk metal deposition at a constant potential negative to the equilibrium potential of the metal ion/complex of interest generally results in the preferential formation of 3D deposits either starting with nucleation and growth of 3D clusters or (at best) following the so-called Stranski-Krastanov transition18 via the initial deposition of a few layers of 2D heteroepitaxial films which eventually transitions into the growth of 3D films. Normally, the bulk deposition routines allow for some control of amount of deposited metal or alloy but provide little or no control over the morphology of accordingly deposited films. More controlled electrodeposition can be realized by kinetic manipulation of the growth process through introducing a third-party mediating element that helps maintain the quasi 2D growth for a longer time of the process duration.19 Among these approaches, the Surface Limited Redox Replacement (SLRR) that utilizes underpotentially deposited (UPD)8 monolayer of sacrificial metal / element stands out as most widely applicable and highly efficient electrochemical deposition protocol for administering and control of a successive layer-by-layer growth of nearly atomically flat and remarkably conformal thin films of a variety of metals and alloys.20 (Ed. Note: See companion article by Brankovic elsewhere in this issue.) Realized initially by Brankovic, Adzic et al. for the electrodeposition of Ag, Pt, and Pd, and then furthered by this group for atomically platinizing catalysts for oxygen reduction21, SLRR growth protocols (as shown schematically in Fig. 1) have been used to facilitate and control the layer-by-layer growth of the thin films in an electrochemical ALD fashion in many homo- and hetero-epitaxial systems summarized in a recent review.20 Such protocols involve two-step cycles where the first step is to underpotentially deposit a sacrificial layer (SL) of a less noble element (Cu, H, Pb, Tl) on a carrier substrate followed by second step of replacing the SL atoms by a galvanic displacement reaction with the ions of the growing more noble element(s) such as Pd, Pt, Au, or Ag etc. The thickness of the growing thin film is quantitatively controlled as it is directly proportional to the number of the SLRR cycles applied in the growth process.
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Fig. 1. Cartoon showing the sequential steps of electrochemical ALD via SLRR of Cu UPD layer in a cycle employed for the deposition of Pd thin film on Au substrates.
Thick, Smooth, and Uniform Pd Films Deposited by SLRR in a Flow-Cell
The state-of-the-art in electrochemical deposition of thin Pd films in quasi 2D growth mode involves the use of SLRR powered ALD realized in two conceptually and technically different setups that both enable the administration of successive SLRR cycles. These include the variant originally introduced by Stickney et al. using an automated flow-cell22,23 and the more recently proposed by the present lead author (Dimitrov) et al. one-cell configuration.24 The flow-cell approach involves successive, computer-controlled valve-system-distribution of separately stored electrolytes and blank
Fig. 2. (a) An automated electrochemical flow cell system with (b) being the flow cell on (I) aerial view and (II) side view. (Reprinted by permission from Springer Nature; L. Sheridan, J. Czerwiniski, N. Jayaraju, D. Gebregziabiher, J. Stickney, D. Robinson, and M. Soriaga, “Electrochemical Atomic Layer Deposition (E-ALD) of Palladium Nanofilms by Surface Limited Redox Replacement (SLRR), with EDTA Complexation,” Electrocatalysis. Copyright 2012. Ref. 23.) 66
rinsing solvents (Fig. 2) whereas the one-cell approach entails work in a single cell which contains all electrolyte components combined at appropriate concentrations. The application of electrochemical ALD of Pd thin films on Pt and Au substrates by SLRR of a Cu UPD layer was pioneered by Stickney et al. in automated flow-cell.9,23,25,26 The applied experimental routine involves pumping of a solution containing the sacrificial element ions into the cell where the working electrode (WE) is held at a potential that enables the formation of a Cu UPD monolayer. The WE is then held at OCP while a Pd(II) complex containing solution flows through the cell, allowing for the replacement of the Cu UPD layer with Pd. Finally, upon reaching a pre-designated “stop potential,” the cell is rinsed with blank sulfuric acid solution to remove remnants of the Pd(II) complex and Cu2+ ions thus completing one SLRR cycle. The number of applied cycles depends on the targeted Pd-film thickness. While initially work on Pd SLRR deposition was done on Pt (111) substrates whereby up to eight perfectly epitaxial Pd layers were successfully deposited in classical Stranski-Krastanov transitional layout,9 most of the developments and progress in flowcell was made for Pd deposition on Au(poly) and (111)-textured thinfilm substrates.23 This work firstly came to determine that Cu was a more preferred sacrificial element than Pb for the production of
Fig. 3. Plot illustrating the linear relationship between Pd coverage (i.e., film thickness) determined by stripping experiments and the number of SLRR cycles performed. The Pd solution composition was [Cl−]/[Pd(II)] = 500. (Reprinted with permission from Ref. 25. Copyright 2013, American Chemical Society.) The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
pure Pd films, since the latter resulted in more Pb incorporation into the accordingly deposited films even when Pd steady-state OCP was used as SLRR stop-potential. The Pb contamination has been attributed to the high stability of the Pb-Pd alloy formed to some extent during the SLRR cycle.23 A key issue in the use of a flow-cell for SLRR deposition of Pd was the uneven nature of the resulting film manifested by descending thickness gradient from the ingress to the egress point of the cell (see Fig. 1b).23 This problem was also observed by authors on other systems and has been attributed to SLRR occurring in the flow cell at substantially higher rate relative to the time needed for a solution exchange, in turn leading to a dominant indirect Fig. 4. Schematic illustrating the growth of Pd films by SLRR of H UPD in one cell. The curves local-cell exchange mechanism.27,28 To slow down illustrate a CV characterization of the Au substrate (by Pb UPD) and the deposited Pd films (by H the rate of reaction of redox exchange between UPD). The STM images depict the surface quality of both the initial Au (111) substrate (left) and the the Pd2+ ions and the Cu UPD, Pd was complexed Pd film deposited by four SLRR cycles (right). (Reprinted with permission from Ref. 29. with EDTA at a [EDTA]/[Pd(II)] ratio of 1 which Copyright 2017, American Chemical Society.) improved the thickness uniformity of the growing conformal film but reduced substantially the exchange efficiency.23 accounts for the number of deposited Pd MLs in the first 3 cycles, In a step further aimed at addressing the low exchange efficiency the the second term, (0.5 × (i − 2)) is associated with the contribution of authors experimented with excess of chloride ions as complexing only adsorbed HUPD atoms, and the third term, (0.3 × (Δi − 2)) reflects agent and eventually obtained the best results at [Cl−]/[Pd2+] ratio the participation of absorbed HUPD atoms in the replacement process. of 500. Using accordingly optimized conditions, Stickney’s team Thus, after SLRR cycle #4 (i + 1 = 4), Δ4 = 2.5 as adsorption only not only minimized the displacement operating in a local-cell mode contributes to the SLRR cycle (the third term is 0), whereas Δ5 = 3.15 thus promoting conformal quasi 2D layer-by-layer growth across instead of 3.0, as 0.15 fraction of a ML is formed due to a contribution the substrate, but also managed to demonstrate reasonably high of absorbed H. To further elaborate in quantitative manner, Fig. 5 efficiency. The best results reported on accordingly performed Pd demonstrates calculated results by the proposed generic model are growth are shown in Fig. 3 that demonstrates the thickening of a plotted along with those determined experimentally as a function of conformal Pd film on Au(poly) with no roughness evolution in the the number of applied SLRR cycles. It can be clearly seen that up course of 75 SLRR cycles at exchange efficiency of about 95%.25 to a total of 30 SLRR cycles the experimental results fit the model accounting for adsorbed + absorbed HUPD atoms reasonably well. At more than 30 SLRR cycles a substantial thickness increase is Thinner, Inexpensive, and Greener, Pd observed, manifested by a significant departure of the experimentally Ultrathin Films Deposited in One Cell obtained results from those theoretically calculated implying that a conformal Pd film with roughness of ∼1.05 grows in quasi-2D mode More recent work by Dimitrov et al. has been done on the for up to 30 SLRR cycles. A transition from 2D to 3D (likely dendritic) deposition of Pd thin films by SLRR of both H UPD and Cu UPD growth has been considered as the reason for a drastic increase of layers in a one-cell configuration as an alternative to the automated the roughness factor to about 1.60 in the SLRR range of 30 to 40 29 flow cell. The one-cell configuration entails working in a solution (Fig. 5). Transition from quasi 2D to dendritic growth has also been containing both sacrificial element ions and ions/complex of the shown to occur in the SLRR and surfactant mediated growth of Au on growing metal(s) of interest in appropriate concentrations; the Pt surfaces.31 Overall, that growth mode transition could be enabled + 2+ UPD forming ions (H or Cu ) represented in one to two orders of (continued on next page) magnitude higher concentration than that of the growing metal ions/ complex (Pd(II)). The substantial concentration difference ensures virtually no Pd deposition upon the short (0.3 to 1.0 s) potential pulse aimed at formation of the H or Cu UPD sacrificial layer. After release of potential control, the WE is held at open circuit potential (OCP) so that the replacement of the Cu or H atoms by Pd(II) ions can be completed when the “spot potential” is reached thus closing the loop of the SLRR cycle. This can be repeated multiple times depending on the thickness needed for the target thin film.30 Using this protocol, Dimitrov et al. demonstrated the ability to deposit Pd ultrathin films on Au(poly) by SLRR of a H UPD layer.29 As schematically presented in Fig. 4, the original Au substrate was characterized by Pb UPD CV curves whereas the thus grown Pd films assessed for surface roughness evolution by H UPD and Cu UPD. Analysis of the Pd deposit thickness evolution was performed by stripping experiments and modeling the progress of the SLRR deposition process. It was shown that the Pd film growth on Au starts with formation of Pd UPD layer that works as carrier of H UPD layer that in turn powers the SLRR cycle initiating the formation of a second Pd layer. After completion of the second Pd layer anticipated to happen after the third cycle [0.5 monolayers (ML) of Pd per H UPD ML], the progress of Pd film thickening can continue by SLRR of either adsorbed HUPD atoms only (lower limiting case) or adsorbed and absorbed HUPD atoms (afterwards) according to the equation below: Fig. 5. Calculated and experimentally obtained thicknesses of Pd ultrathin Δi+1 = 2 + 0.5 × (i - 2) + 0.3 × (Δi - 2). film (in #equivalent MLs) as a function of the number of SLRR cycles. 29 This equation considers the number of deposited Pd MLs (Δ) (Reprinted with permission from Ref. 29. Copyright 2017, American after the third SLRR cycle, i.e., i ≥ 3. Therefore, the first term (2) Chemical Society.) The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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by a gradual establishment of strictly diffusion limited growth that most likely occurs with the increasing number of SLRR cycles. In additional characterization experiments, in situ STM imaging shown only illustratively in Fig. 4 to demonstrate the morphological changes after application of four SLRR also provided additional evidence of relatively smooth and conformal Pd growth via H UPD. This quality is representative for up to 20 SLRR cycles.29 Overall, the proposed strategy enables facile deposition of contamination-free, smooth and continuous Pd films of considerable thickness. In another developmental effort, Dimitrov’s team illustrated the application of E-ALD by SLRR in one-cell configuration for the growth of Pd thin films using Cu UPD as a sacrificial metal. Following previously described routines the growth of Pd films on Au was monitored by OCP transients while the roughness evolution and thickness of accordingly deposited Pd films were assessed by H UPD and Cu UPD cyclic voltammetry and stripping experiments, respectively. The uninterrupted SLRR growth in one-cell was optimized to yield smooth and continuous films of thickness up to 15 MLs at Pd2+ ion concentration of 0.3 mM and [Cl−]/[Pd(II)] ratios between 100 and 170. The thus deposited Pd films featured lower thickness (15-16 MLs) compared to those grown by SLRR of H UPD. Paralleling the latter case, after reaching that thickness, a transition to dendritic growth occurred owing to the previously mentioned establishment of mass-transport limitation at the growing interface. As a result of the hindered transport of the Pd2+ ions to the growing surface, a progressively formed concentration gradient (from zero on the electrode surface to the bulk Pd(II) concentration) serves to enhance the vertical growth of any 3D clusters nucleated in the initial deposition stages leading eventually to dendrite formation.32,33 In the general SLRR deposition protocol, the described sequential phenomenology promotes the transition to dendritic growth with every cycle. To minimize the propagation of this transition and to facilitate quasi-2D growth for as many SLRR cycles as thermodynamically possible, a modified SLRR protocol was implemented for Pd deposition in a single cell emphasizing: (i) an interruption of the successive cycle sequence at every four SLRR reaction events; and (ii) application of forced electrolyte convection during the break
time. Results of Cu UPD CV characterization of surface roughness and evolution of the surface morphology imaged by STM are comparatively presented in Fig. 6 for both, uninterrupted (UI) and modified by “breaking (contact) and shaking (the electrolyte)” (BS) the SLRR deposition in one-cell configuration. The comparison reveals virtually no roughness increase even after 24 SLRR cycles of “break and shake” SLRR growth. This constitutes about twofold thickness increase in comparison with the interrupted SLRR Pd deposition scheme suggesting that the cycle interruption and forced electrolyte convection facilitate the growth of thicker Pd films with minimal to no roughness.
The Choice Is up to the User
The presented snapshot of the state-of-the-art in the deposition of ultrathin Pd films using electrochemical ALD by SLRR not only summarizes the most recent limits of success in the growth of conformal, uniform, and smooth deposits but also puts forward some general drawbacks and/or limitations of most commonly used approaches for this type of deposition. Thus, a potential choice of approach to deposit Pd ultrathin films depends on the application purposes as well as on the desired film properties. For instance, if of interest is a thicker Pd film that is still continuous and uniform at thickness of 50-60 equivalent MLs, a better choice would be the flow-cell setup that once working under optimized conditions will guarantee the lack of mass-transport limitations and thus promote the deposition sustainability. Contrastingly, if the growth of costeffective catalytic coating of Pd or Pd-based alloys of thickness in the range of 1 to 10 equivalent MLs is of interest, a better and more straightforward choice would be the one-cell setup that would provide remarkable simplicity, low cost, and better time management for the overall deposition matter. In the meantime, work on addressing and minimizing the effect of all discussed limitations is under way. © The Electrochemical Society. DOI: 10.1149/2.F06182if.
Acknowledgment
The authors acknowledge financial support by the National Science Foundation, Division of Chemistry, CHE-1310297.
Fig. 6. Plots illustrating the growth of Pd films by SLRR of Cu UPD in one cell configuration. The presented curves illustrate Cu UPD CV characterization of (A) initial Au surface and (B) accordingly deposited Pd films. The presented STM images depict the surface quality of both, the initial Au (111) substrate (left inset, up), the Pd film deposited by five SLRR cycles (representative for both UI and BS growth; left inset, down), and the Pd film deposited by 20 SLRR cycles (BS growth only; right inset).
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About the Authors Innocent Achari is presently a graduate student in Nikolay Dimitrov’s research group in the Department of Chemistry at Binghamton University – SUNY. His research mainly deals with electrochemical synthesis of electrocatalysts and their comprehensive characterization. The synthesis employs electrochemical atomic layer deposition techniques that utilize the advantages of surface limited redox replacement reactions. He may be reached at iachari1@binghamton.edu. https://orcid.org/0000-0002-7801-8046 Stephen Ambrozik is a National Research Council postdoctoral associate at the National Institute of Standards and Technology. Working in Nikolay Dimitrov’s research group he received his PhD in 2017 from Binghamton University – SUNY. His research interests focus on the electrodeposition of well-defined metallic surfaces to probe the structure-function relationship of these surfaces on a variety of reactions at the electrochemical interface. He may be reached at stephen.ambrozik@nist.gov. https://orcid.org/0000-0003-3660-1687 Nikolay Dimitrov is a professor in the Department of Chemistry at the Binghamton University – SUNY. His research interests are mainly in electrodeposition, catalysis, and synthesis of nanomaterials. His fundamental research focuses on the understanding of morphology and structural evolution upon growth of metals and alloys that enables informed design and development of nano-sized materials such as conformal ultrathin films and nano-porous structures with precisely controlled structure and functionality. Such materials find applications in energy generation and storage industry, instrumental method development, and environmental protection and remediation. Another field of research emphasizes studies in applied electrochemistry aimed at understanding, controlling, and improving the reliability of interconnects and 2.5/3D packaging architectures in electronic industry. He may be reached at dimitrov@binghamton.edu. https://orcid.org/0000-0003-1787-4575
References 1. 2. 3. 4.
C. Torborg and M. Beller, Adv. Synth. Catal., 351, 3027 (2009). M. Łukaszewski, A. Żurowski, M. Grdeń, and A. Czerwiński, Electrochem. Commun. 9, 671 (2007). T. B. Flanagan and W. A. Oates, Annu. Rev. Mater. Sci., 21, 269 (1991). B. D. Adams and A. Chen, Mater. Today, 14, 282 (2011).
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A. N. Correia, L. H. Mascaro, S. A. S. Machado, and L. A. Avaca, Electrochim. Acta, 42, 493 (1997). R. Pattabiraman, Appl. Catal., A, 153, 9 (1997). E. Antolini, Energy Environ. Sci., 2, 915 (2009). E. Herrero, L. J. Buller, and H. D. Abruña, Chem. Rev., 101, 1897 (2001). M. A. Hossain, K. D. Cummins, Y. S. Park, M. P. Soriaga, and J. L. Stickney, Electrocatalysis, 3, 183 (2012). M. Eyrich, S. Kielbassa, T. Diemant, J. Biskupek, U. Kaiser, U. Wiedwald, P. Ziemann, and J. Bansmann, ChemPhysChem, 11, 1430 (2010). K. Nishikawa, M. Yamamoto, and T. Kingetsu, Appl. Surf. Sci., 113, 412 (1997). G. Xomeritakis and Y. S. Lin, J. Membr. Sci., 120, 261 (1996). W. Lin, T. H. Warren, R. G. Nuzzo, and G. S. Girolami, J. Am. Chem. Soc., 115, 11644 (1993). H. B. Zhao, G. X. Xiong, and G. V. Baron, Catal. Today, 56, 89 (2000). M. M. E. Duarte, A. S. Pilla, J. M. Sieben, and C. E. Mayer, Electrochem. Commun., 8, 159 (2006). H. Naohara, S. Ye, and K. Uosaki, J. Phys. Chem. B, 102, 4366 (1998). J. L. Stickney, Electrochem. Soc. Interface, 20, 28 (2011). E. Budevski, G. Staikov, and W. J. Lorenz, Electrochim. Acta, 45, 2559 (2000). K. Sieradzki, S. R. Brankovic, and N. Dimitrov, Science, 284, 138 (1999). N. Dimitrov, Electrochim. Acta, 209, 599 (2016). S. R. Brankovic, J. X. Wang, and R. R. Adzic, Surf. Sci., 474, L173 (2001). B. H. Flowers, T. L. Wade, J. W. Garvey, M. Lay, U. Happek, and J. L. Stickney, J. Electroanal. Chem., 524, 273 (2002). L. B. Sheridan, J. Czerwiniski, N. Jayaraju, D. K. Gebregziabiher, J. L. Stickney, D. B. Robinson, and M. P. Soriaga, Electrocatalysis, 3, 96 (2012). L. T. Viyannalage, R. Vasilic, and N. Dimitrov, J. Phys. Chem. C, 111, 4036 (2007). B. L. Sheridan, D. K. Gebregziabiher, J. L. Stickney, and D. B. Robinson, Langmuir, 29, 1592 (2013). L. B. Sheridan, K. Youn-Geun, B. R. Perdue, K. Jagannathan, J. L. Stickney, and D. B. Robinson, J. Phys. Chem. C, 117, 15728 (2013). Y. G. Kim, J. Y. Kim, D. Vairavapandian, and J. L. Stickney, J. Phys. Chem. B, 110, 17998 (2006). C. Thambidurai, D. K. Gebregziabiher, X. H. Liang, Q. H. Zhang, V. Ivanova, P. H. Haumesser, and J. L. Stickney, J. Electrochem. Soc., 157, D466 (2010). I. Achari, S. Ambrozik, and N. Dimitrov, J. Phys. Chem. C, 121, 4404 (2017). M. Fayette, Y. Liu, D. Bertrand, J. Nutariya, N. Vasiljevic, and N. Dimitrov, Langmuir, 27, 5650 (2011). C. Mitchell, M. Fayette, and N. Dimitrov, Electrochim. Acta, 85, 450 (2012). J. Mostany, J. Mozota, and B. R. Scharifker, J. Electroanal. Chem., 177, 25 (1984). B. R. Scharifker and J. Mostany, J. Electroanal. Chem., 177, 13 (1984).
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Electrodeposition of Pt-Bimetallic Model Systems for Electrocatalysis and Electrochemical Surface Science by Natasa Vasiljevic
O
ver the past few decades, low-temperature fuel cells have undergone rapid development delivering prototypes and commercially available cars with impressive performance.1,2 The achievements and progress of the fuel cell research and development have been enthusiastically embraced by the transport industry boosting public and governmental interest and support.3,4 Besides polymer electrolyte membrane fuel cells (PEM FCs) based on hydrogen fuel, the direct alcohol fuel cell (DAFC) based on liquid fuels, such as methanol, ethanol and formic acid (alcohol fuels) have been viewed as possible power systems for portable electronic devices.5 In spite of the considerable progress, commercially competitive fuel cell cars and technology are still hindered by performance limitations and the high cost of Pt catalysts. Development of nanoscale bimetallic catalysts with low content of Pt and Pt-group metals exhibiting enhanced activity, and better stability than the pure metal has been pursued actively as the most promising strategy to make future advances.1 Pt-bimetallic systems comprise of nanoscale structures of Pt in contact with another metal. Some of the examples, shown in Figure 1, include Pt-nanoclusters (sub-ML) on top of another metal, strained Pt monolayers and ultrathin films (over layers on top of another metal or alloys), Pt-alloys and Pt-alloy overlayers (random alloys and intermetallics). Besides the low content, a combination of Pt with another metal at nanoscales often result in the catalysts with superior activity compared to the single metal components. The reduced dimensionality coupled by geometric (ensemble effect) and electronic (ligand) effects can substantially alter the Pt activity. Real-world fuel cell catalysts (such as nanoparticles on carbon support) are complex and often it is hard to decouple different aspects that contribute to the catalytic activity and performance such as size, shape, and composition. For that reason catalytic reactions
are best studied on well-defined single crystal surfaces, the so called model systems (Figure 1).6 Single-crystal metal electrodes have a special place in the field of electrochemical surface science and electrocatalysis.6 They have been essential for shaping our fundamental understanding of the processes and structure-reactivity relationship. The use of single-crystal vicinal surfaces enabled decoupling of electronics and surface structure effects resulting from the crystallographic orientation alone, and structural features such as terraces, steps, and kinks. Single crystal model systems have been essential for developing our understanding of the kinetics and mechanisms of electrocatalytic reactions providing an invaluable support for theoretical models and analysis (i.e., DFT, MD calculations).7,8 Without model system it would have been impossible to establish links between the bulk surfaces and nanoscale effects of size and shape.9
Electrodeposition of Pt-Bimetallic Surfaces Electrodeposition of electrocatalysts has an advantage in contrast to other chemical and physical, synthesis routes. Electrochemical routes are inexpensive and readily accessible; they are attractive because of their versatility, simplicity and easy scalability on electrodes of various shape and sizes ideal for a number of fundamental and practical studies. Moreover, they are an effective way of making clean surfaces, i.e., free of capping agents and organic molecules often used in the chemical synthesis methods, thus providing an ideal platform for studying electrocatalytic reactions on single crystals10 as well as on mesoporous nanocomposite electrodes.11 (continued on next page)
Fig. 1. Schematics of different bimetallic system configurations presented in the form of nanoparticles (NP) (top row) and corresponding 2D analogues (bottom row). Examples from left to right include single metal, Pt-nanoclusters on metal surfaces, Pt-films (or core shell NP), Pt-alloys supported of different substrates. The Electrochemical Society Interface â&#x20AC;˘ Summer 2018 â&#x20AC;˘ www.electrochem.org
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Controlled epitaxial deposition of Pt is a challenge. Due to the very high surface energy and low diffusivity, Pt growth, regardless of the method of deposition, is non-uniform and proceeds via 3D island formation (Volmer Weber growth).12-14 The electrodeposition community has been actively pursuing different strategies and conditions for epitaxial films and alloy deposition, as reviewed next.
The SLRR Method The surface limited redox replacement (SLRR) deposition method enabled for the first time successful epitaxial deposition of Pt films and nanoclusters with atomic scale control,15-19 on to other metal surfaces. Very quickly the method has become one of the most exploited to design 2 dimensional and nanoparticle Pt-bimetallic systems. The SLRR method has been outlined elsewhere in this issue and utilizes the galvanic replacement of an underpotentially deposited (UPD) epitaxial metal layer, such as Cu and Pb, by a more noble metal such as Pt. The electrochemical surface science studies of UPD processes on single crystal surfaces over four decades20 provided a wealth of information about the epitaxial nature, thermodynamics and kinetics aspects of these and many other UPD processes. The UPD processes have been now used as fine tools for surface characterization (area, structure and composition) of complex systems,21-25 as well as enablers to grow and design thin films and alloys.15,18,26-32 From the first demonstration of 2D deposition of a Pt monolayer, Cu UPD15 has now become the most commonly used sacrificial layer to design highly active Pt-monolayer catalysts,28,33 as well as functional nanoporous fuel cell electrodes.34,35 Further demonstration of the SLRR controlled deposition of Pt films has been done using Pb UPD18,19 as an excellent alternative for the comparative studies of the nature of UPD layer on the replacement kinetics, deposit structure and high deposition yield. Furthermore, the H UPD36 based Pt deposition has been shown on a proof of concept level and quickly extended to other Pt- group metals such as Pd well known for its unique H-sorption behavior.37,38 The coverage of deposited Pt in each SLRR cycle is generally defined by stoichiometry of the redox reaction, replacement reaction kinetics and structure of the UPD layer.39,40
Experimental Configurations
There are different experimental configurations by which SLRR protocol can be conducted: 1) by electrode immersion and transfer between the cells containing the UPD metal ions and the second one with Pt-ion complex for the replacement reaction;15 2) by exchanging the two solutions in the flow-cell set up;31 and 3) by the controlled deposition in a single-cell configuration,18 where growth of Pt films is maintained from the same solution containing both Pt and UPDsacrificial metal ions18 with concentrations and the potential control optimized to avoid co-deposition of Pt during UPD metal formation step and avoid UPD metal incorporation during the replacement step. Each configuration has adavntages and disadvantages for the design of different Pt-bimetallic systems. The design of Ptnanoclusters and monolayer catalysts (0 – 1 ML) can be best achieved by the immersion and transfer method with special care given to the control of the oxygen-free environment to prevent oxidation of UPD layer. Either by conducting deposition in a glove-box or using custom designed set-ups41 a secure transfer of stable and uncompromised UPD covered electrode can be achieved. For deposition of multi-layered thin films of Pt, the automated flowcell and the single-cell configuration (Ed. Note: See also companion article by Dimitrov et al. in this issue.) offer easier control, and handling, but they require careful optimization of the conditions and monitoring of the potential changes during process. For illustration, the single cell approach requires the metal ions concentrations and the control of the potential limits, to be optimized to maintain growth of high quality Pt, with minimum possible electrodeposition of Pt during UPD metal formation step and minimum possible UPD metal incorporation.18 The single-cell approach illustrated in Fig. 2 requires controlled application of the elemental SLRR steps: (1) a potential step typically of few seconds duration to form UPD sacrificial layer at negative potential limit E1 followed by (2) an open circuit potential (OCP) galvanic displacement by a more noble Pt ions monitored in time and terminated at the potential corresponding to a UPD-free surface of the growing film, E2 (positive potential limit). Moreover, by limiting the potential of the replacement reaction to value E2ʹ, E2ʺ < E2 can be exploited for deliberate incorporation of the UPD sacrificial metal and design of nanoalloys.42
Fig. 2. Schematics of the SLRR protocol of Pt and Pt Pb alloy deposition in the single-cell configuration using Pb UPD. 72
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Pt-Bimetallic Model Systems for Electrocatalysis
So far the SLRR method has been used in many fundamental studies to design and study various catalytic reactions. Separating the contributions of the two key mechanism of modification of the chemical properties of surfaces (geometric and ligand effects) is often very difficult because they usually occur together. Firstly, the activity of Pt can be altered by strain, i.e., by changing the average bond lengths between the Pt atoms in the supported ultra-thin layers on different substrates. Also, bonding interactions between the surface atoms of Pt and the substrate results in modification of the Pt electronic structure (ligand effect) therefore can change its surface catalytic properties. Here we would like to draw attention to a few systematic approaches oriented toward understanding of general trends in electrocatalysis by systematic variations of the structure of the Pt surface using SLRR method. Interested readers may also find more details and information in a recent review by Dimitrov.43 Pt films (overlayers)4Epitaxial monolayers of Pt deposited via SLRR of Cu UPD on different single crystal surfaces such as Au(111), Rh(111), Pd(111), Ru(0001), and Ir(111)28,44 have been used as model systems to explore the effect of strain on the kinetics of reactions such as the oxygen reduction reaction, methanol oxidation, ethanol oxidation (EOR), and formic acid oxidation. The established experimental trends were used in combination with DFT calculations to rationalize to what extent changes in the average bond length of PtPt (strained on the substrates with different lattice spacing) affect the kinetics rate and/or selectivity of the complex reactions with different pathways. Another way to explore the effect of strain on Pt electrocatalytic properties is to vary the thickness of Pt films. Repeated application of SLRR cycles using UPD layers of Cu or Pb have been shown to produce epitaxial films of controlled thickness but with different roughness dependant on the stoichiometry and kinetics of the redox replacement reaction.18,45 For example, the studies of thickness dependant CO electrooxidation showed that besides strain in the layer, the morphology and roughness of the deposited Pt films play an important role in the potential shift, i.e., the strength of CO adsorption.45,46 Pt-nanoclusters (sub-ML)4Two dimensional Pt nanoclusters at sub-ML coverage (θ ≤ 1 ML) on different substrates are ideal for studies of coverage dependant electrocatalytic behaviour. A recent study of Pt sub-ML on Au(111) grown by SLRR of Cu UPD showed
that the kinetics of hydrogen oxidation reaction (HOR)47 is dependent on the size of Pt clusters (smaller clusters being less active for HOR), Fig. 3. The results were rationalized by average active strain in Pt nanoclusters that has two contributions: the tensile strain due to epitaxial misfit (4%) and the compressive strain due to the clusters finite size. Agreement with the DFT-derived model of the sizedependent strain indicates that the morphology/size of Pt-nanoclusters can be exploited to fine tune Pt activity on different substrates. The coverage dependant studies of CO electrooxoidatoon and the EOR of Pt on Au-poly and Au(hkl) stepped surfaces also confirmed the dominant role of the structure and morphology of Pt-nanoclusters on the overall activity and product distribution of the EOR.48,49 Pt nano alloys4Nanoalloys are even more challenging systems as the effects of the surface structure and chemical composition equally shape Pt electrocatalytic behaviour. Studies on single crystal surfaces of Pt alloys and Pt- intermetallics50,51 have been extremely valuable but they are limited. Alloy single crystal surfaces are not easily grown and in some cases not available. The SLRR based deposition is one of the most promising pathways to controllably grow model 2D nanoalloy systems and study their properties. This is one of the least explored applications of SLRR method but one that could potentially have high impact. So far three different approaches have been explored to grow nanoalloy films: 1) the galvanic replacement of a UPD metal later in the solution with both Pt and alloying metal mixed in a desired concentration ratio52,53 (examples include Pb UPD based growth of and Pt 0.8X0.2 monolayers on Pd(111) surface where X = Ir, Ru, Rh, Pd, Au, Re, or Os); 2) the alternation of the replacement cycles of Pb UPD between separate solutions of Pt and Ru using flow-cell set up54 (alloys of different compositions 70:30, 82:28, and 50:50 were grown by controlling the number of alternating replacement cycles in Pt and Ru solutions); and 3) controlled incorporation of the sacrificial Pb UPD metal during Pt deposition to form PtPb alloys (up to 10% Pb composition) by controlling the potential of the replacement step. In the last case of PtPb alloys it has been shown that Pb has a strong screening effect on the adsorption of both H and CO. The changes in alloy composition cause a negative shift in the potential of the peaks of CO oxidation (weaker CO bond) that scales with the increase of Pb content. The results suggest electronic and bifunctional effects of incorporated Pb on the electrochemical behaviour of Pt. (continued on next page)
Fig. 3. Normalized exchange current density for HOR on Pt sub ML on Au (111) as a function of: a mean size of Pt clusters population and B) average active strain calculated for Pt clusters with size corresponding to the mean of Pt clusters’ population for each Pt sub-ML coverage on Au(111). Reprinted by permission from Springer Nature and Copyright Clearance Centre: Springer, Ref [47]. Copyright (2012). The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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What Is in the Future? The SLRR based approaches will undoubtedly play an important role in the future of fuel cell develoment and electrocatalysis in general. Control of the structure, thickness and composition on atomic scales provides an excellent platform for model studies on different types of bimetallic systems. In combination with theoretical modelling, the systematic design and studies of various systems will enable the development of more powerful and stable catalysts with tailored electrocatalytic properties. It can also contribute to the understanding of other equally important aspects of the ideal catalysts such as durability. In this vein, recent studies have shown that SLRR grown films and structures are ideal systems to study Pt-dissolution during different catalytic reactions.55,56 In this article the focus was on Pt-electrocatalyts for fuel cell applications as the SLRR method has made the biggest impact in this area. The potential and challenges, of extending the approach to the design of other (both noble and transition) bimetallic systems of interest, are exciting. Some of the active areas of research include improving the activity and selectivity of bimetallic catalysts for carbon dioxide electrochemical reduction, environmental and water cleaning, and sensing. Design of multilayers and 2D nanoalloys (particularly those with no bulk counterparts) with controlled composition and distribution of components, can open new avenues of interest beyond the field of electrocatalysis such as nanophotonics, corrosion and microelectronics. The future is bright indeed. © The Electrochemical Society. DOI: 10.1149/2.F07182if.
About the Author Natasa Vasiljevic is a senior lecturer of physics at the University of Bristol in the UK and current secretary of the ECS Electrodeposition Division. Her research interests include electrochemical surface science, and electrodeposition of thin films and functional nanomaterials for electrocatalysis, magnetics, and optoelectronics. Her work is focused on fundamental aspects and design of new materials with targeted properties by manipulating surface structure and interfacial processes. She may be reached at n.vasiljevic@bristol.ac.uk. https://orcid.org/0000-0002-7515-9708
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48. M. J. Prieto, U. P. R. Filho, R. Landers, and G. Tremiliosi-Filho, Phys. Chem. Chem. Phys., 14, 599 (2012). 49. M. J. Prieto and G. Tremiliosi-Filho, Phys. Chem. Chem. Phys., 15, 13184 (2013). 50. V. R. Stamenkovc, S. B. Mun, M. Arenz, K. J. J. Mayrhofer, C. A. Lucas, G. Wang, P. N. Ross, and N. M. Markovic, Nat. Mater., 6, 241 (2007). 51. V. R. Stamenkovc, S. B. Mun, K. J. J. Mayrhofer, P. N. Ross, and N. M. Markovic, J. Am. Chem Soc., 128, 8813 (2006). 52. J. Zhang, M. B. Vukmirovic, K. Sasaki, A. U. Nilekar, M. Mavrikakis, and R. R. Adzic, J. Am. Chem. Soc., 127, 12480 (2005).
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rl Hering a C
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The Carl Hering Legacy Circle The Hering Legacy Circle recognizes individuals who have participated in any of ECS’s planned giving programs, including IRA charitable rollover gifts, bequests, life income arrangements, and other deferred gifts. ECS thanks the following members of the Carl Hering Legacy Circle, whose generous gifts will benefit the Society in perpetuity: K. M. Abraham
George R. Gillooly
Keith E. Johnson
Masayuki Dokiya
Stan Hancock
Mary M. Loonam
Robert P. Frankenthal
Carl Hering
Edward G. Weston
W. Jean Horkans
Carl Hering was one of the founding members of ECS. President of the Society from 1906-1907, he served continuously on the Society’s Board of Directors until his death on May 10, 1926. Dr. Hering not only left a legacy of commitment to the Society, but, through a bequest to ECS, he also left a financial legacy. His planned gift continues to support the Society to this day, and for this reason we have created this planned giving circle in his honor.
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Selective Electrodesorption-Based Atomic Layer Deposition (SEBALD) of Bismuth under Morphological Control by Walter Giurlani, Andrea Giaccherini, Emanuele Salvietti, Maurizio Passaponti, Andrea Comparini, Vittorio Morandi, Fabiola Liscio, Massimiliano Cavallini, and Massimo Innocenti
T
he development of next-generation electronics is very dependent on the discovery of materials with exceptional surface-state spin and valley properties. Bismuth has most of the characteristics required for technological development in this field. Thin films of this element have shown nontrivial topology1-3 enabling their definition as a topological insulator and a distribution of spin states and valleys in the band diagram that are suitable for both spintronics and valleytronics applications.4 In some cases, these properties depend on the quantum confinement of the related particles or quasi-particles; hence they can be tuned by varying the thickness in the ultrathin film range.5 Finally, thin films of Bi can be processed by electrochemical lithographic methods.6 Bismuth ultrathin films can be obtained by techniques that require vapor phase with different degrees of vacuum (e.g., PVD and CVD).7- 9 These methods are efficient for producing flat polycrystalline thin films of Bi. Similarly, Bi thin films were electrodeposited from an aqueous solution containing organic additives with multiple morphologies and textures according to the different surface effect promoted by these substances.10 These studies have demonstrated that Bi thin films are among the wide range of technologically interesting coatings that cannot be easily obtained from aqueous solutions without interference from metal oxide growth. In most cases, these processes lead to films with uncontrolled morphology.
adlayer covering the electrode surface. The combination between the alternation of solutions containing precursor elements that form this type of compound and UPD is the basis of E-ALD. Repetition of the basic cycle of depositions leads to the growth of semiconductor materials whose thickness increases with the number of cycles, up to the ultrathin film range. Then, after selective electrodesorption of the chalcogen layer, the resulting film is constituted by a confined layer of metal, which reorganizes its shape in ordered crystalline domains. Therefore, the selective desorption of the chalcogen leaves an increasingly higher amount of metals with the number of cycles. The combination of E-ALD with this second stage leads to a process called selective electrodesorption-based atomic layer deposition (SEBALD), which is depicted by the scheme in Fig. 1. SEBALD was successfully used to grow Cd with a control level not achievable in overpotential deposition through the application of Faraday’s laws (even when deposition was limited to very low overpotentials)11 and to obtain Co/Fe catalytic clusters.12 In what follows, we show that with the SEBALD protocol it is possible to obtain the growth of a high-quality bismuth ultrathin film on the Ag (111) surface. In this way, we have overcome most of the problems derived from the electrochemical properties of bismuth at the solid-water electrified interface.
Introduction to SEBALD
As often happens in E-ALD,13 deposition during the first step plays a crucial role for the growth of the following layers. The first phase of SEBALD consisted of the deposition of (Se/Bi)n on Ag, followed by the removal of selenium (Fig. 1). For this reason, the deposition conditions and the stability of the two elements were investigated first. The deposition of Se is a well-known process described in literature.14,15 A selenide solution was used, and silver working electrode potential was set at −0.90 V versus Ag/AgCl sat. KCl
To avoid these limitations, we explored the possibility of using electrochemical atomic layer deposition (E-ALD) to deposit highly ordered ultrathin films from diluted aqueous solutions at room temperature and pressure. In the present context, we use E-ALD for the growth of metal chalcogenide films. Underpotential deposition (UPD) of metal chalcogenide is possible due to the energy gain involved in the formation of the corresponding chalcogenide, so that an adlayer of metal can be deposited at an underpotential on a chalcogenide
SEBALD of Bismuth Thin Films
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Fig. 1. Schematic operations of a SEBALD alternating a chalcogenide layer to a metal one. In our study, the chalcogenide is represented by selenium while bismuth is the metal. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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reference electrode for one minute. Then, to remove the excess bulk selenium deposited, leaving only the UPD layer on silver, the working electrode was immersed in ammonia buffer solution for another minute at the same potential value. The bismuth settles to more positive potentials than selenium; therefore it is crucial for a correct E-ALD to verify the stability of Se with an anodic scan, and the results show that it does not get oxidized. Once we had ensured the stability of the Se UPD layer, we proceeded with the UPD of bismuth. The thermodynamic possibility of this deposition is justified by the presence of a cathodic peak (−0.40 – −0.50 V) slightly before the massive deposition one (over −0.50 V) in a cyclic voltammetry scan of a bismuth (III) solution (inset image in Fig. 2). After that, a conventional UPD study was carried out to evaluate the amount of metal deposited in function of the deposition potential and time.16 The optimal UPD condition to deposit bismuth on selenium consists of keeping the potential fixed at −0.43 V for one minute in the presence of the bismuth solution and then washing the sample with ammonia buffer solution. After having optimized the UPD conditions of both the elements, the first step of SEBALD was performed by sequential automatic alternate deposition for multiple cycles, obtaining a deposit of increasing thickness. After the deposition process, SEBALD was completed by setting the working electrode potential at −2.0 V and washing the cell in the buffer solution, in order to remove all the selenium previously deposited. Anodic stripping of the remaining bismuth confirmed its growth over the number of cycles performed (Fig. 2). For the very first cycles, a typical rapid growth, due to interaction phenomena confined to the nanoscale, is present. After the fifth deposition cycle, the trend becomes linear. A 50-cycles final bismuth deposit was morphologically characterized, revealing that this simple SEBALD process, performed at room conditions, allows obtainment of a highly ordered and crystalline deposit difficult to obtain with other techniques. From the SEM image (Fig. 3A), we can observe how the bismuth deposit obtained by SEBALD has reorganized into its typical crystalline shape,17 hard to obtain with direct bulk deposition. The EDX (Fig. 3B)
data confirm the presence of bismuth metal on the silver electrode without any traces of selenium, diagnostic of a proper SEBALD. AFM measurements (Fig. 3C) give useful information on the surface topology: the estimated RMS roughness is only 5.06 nm; moreover the image shows an overview of the sample. Finally, the quality of the Bi thin film was quantified by XRD. The specular scan reported in Fig. 4 shows the peak of the substrate (Ag (111)) and, more importantly, peaks of Bi thin film corresponding to (102) and (204) crystalline planes. This observation indicates the growth of high-crystalline films with [102] texturing.
Conclusions and Outlook The development of next-generation electronic devices demands specific materials that often are not simple to synthesize in the required way. SEBALD opens up the possibility of employing electrochemical processes to build, one by one, monolayers of highly pure and ordered structures. The SEBALD methodology constitutes an efficient approach to overcome the limitations of electrodepositing bismuth layers from aqueous solution. This is done by exploiting the SLRs of bismuth and selenium on Ag (111), characterized conclusively by means of electrochemical methods. The UPD experiments proved the occurrence of a SLR leading to the growth of a Biad on Se. On this basis, multiple E-ALD cycles could be performed to grow the Bi2Se3 compound. Subsequent selective desorption of selenium concludes the SEBALD process and allows obtainment of the bismuth ultrathin film. We were able to grow extremely ordered bismuth layers with exquisite control on film thickness, as proven by the topography and morphology of the resulting ultrathin films. This process is a very promising candidate for the growth of metal ultrathin films and constitutes an easy way to obtain an ordered bismuth ultrathin film of controlled thickness under room temperature and pressure. The films obtained by SEBALD are highly crystalline and oriented; moreover they are characterized by low roughness. All these properties are promising for ultimate application in new-generation electronic devices. © The Electrochemical Society. DOI: 10.1149/2.F08182if.
Fig. 2. Deposit growth according to the number of deposition cycles. After the first five cycles, the deposition rate becomes linear. Inset shows the cyclic voltammetry of bismuth solution on Ag/Se in which is evident the cathodic UPD peak of the metal. 78
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Fig. 3. A) Secondary electrons SEM image of the 50-layers bismuth sample, showing the shape and morphology of the deposit. B) EDX spectrum collected on the same area, with an accelerating voltage of 10 kV that confirms the absence of selenium. C) AFM image of the same sample.
About the Authors Walter Giurlani is a PhD student of chemistry at the University of Florence. Prior to this he earned both a BS and MS in chemistry at the same university, working on the electrochemistry of electrocatalysis, energy production, and the storage of fuel cells. He is part of the Applied Electrochemistry Group of the University of Florence Department of Chemistry. Currently he is focusing his studies on the electrodeposition and characterization of interesting materials for industrial application and next-generation technological devices. He is also collaborating with galvanic industries in R&D on the development of new deposition methods and quality control protocols for different practical applications. He may be reached at walter.giurlani@unifi.it. Fig. 4. XRD measurement of the 50-layers bismuth sample to prove the crystallinity of the deposit. https://orcid.org/0000-0002-9949-3751 Andrea Giaccherini received his MS in chemistry in 2014 and his PhD in chemical sciences in 2018 from the University of Florence. His PhD research was focused on the characterization of ultrathin films of compound semiconductors grown by means of electrochemical atomic layer deposition (E-ALD). He is now serving as a postdoc at the University of Florence in the Department of Earth Sciences on a project aimed at finding new solvothermal synthesis of nanostructured quaternary sulfides for photovoltaics applications. He continues to collaborate with the Department of Chemistry of the University of Florence on the characterization of new compound semiconductors deposited by means of E-ALD. He may be reached at andrea.giaccherini@unifi.it. https://orcid.org/0000-0003-0915-1318 The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Emanuele Salvietti is a temporary research fellow in the Department of Chemistry “Ugo Schiff” at the University of Florence. He received a BS in chemistry in 2004 at the same university for his work on nanostructured materials produced through electrochemistry. In 2008 he obtained his PhD in chemical science from the University of Florence, working on chemical and physical characterization on thin film by surface analysis techniques. From 2008 to 2016 he worked on the development of colorimetric kits for food analysis and the monitoring of industrial emissions and the healthiness of workplaces. He is currently working on innovative electroplating baths and the electrodeposition of 2D materials. He may be reached at emanuele.salvietti@unifi.it. (continued on next page) 79
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Maurizio Passaponti is a PhD student of chemistry at the University of Florence. He graduated in biology in 2011 from the same university. From 2000 to 2016 he worked as a laboratory technician in the Department of Chemistry of the University of Florence. Currently he is studying electrocatalysis for energy conversion and production in fuel cells. He is collaborating with researchers in the Applied Electrochemistry Laboratory of the Department of Chemistry on the electrodeposition of active materials for scientific and industrial purpose. In addition, he conducts collaborative studies with galvanic industries on the development and quality control of corrosion and the durability of manufactured goods. He may be reached at maurizio.passaponti@unifi.it. https://orcid.org/0000-0003-0931-3970 Andrea Comparini graduated with a degree in chemistry in April 2016 from the University of Florence. His bachelor’s as well as his master’s thesis focused on the development of green semiconductors. After graduating he became an independent collaborator at the National Interuniversity Consortium for Materials Science and Technology, where he focused on the development and characterizations of twodimensional semiconductors through the E-ALD technique, a low-cost and green method to produce nanostructures. Currently he serves as an R&D analyst working in the white biotech sector, developing bioproducts as bioadhesives for the wood sector. He may be reached at a.comparini@agroils.com. Vittorio Morandi is the deputy director of the Bologna Unit of the CNR-IMM Institute (www.bo.imm.cnr.it), a chair and member of the committees of several international conferences, and a permanent reviewer of international projects and top-level scientific journals. He is directly involved in several national and international research projects and industrial contracts and has published more than 100 papers (h = 24) in international peer-reviewed journals. His main research interests concern the development of advanced electron microscopy techniques, their application to the study of nanomaterials, and the synthesis, characterization, and technological integration of graphene and graphene-based materials. He may be reached at morandi@bo.imm.cnr.it. https://orcid.org/0000-0002-8533-1540 Fabiola Liscio is a postdoctoral fellow at CNRIMM Bologna. She received a laurea in physics, magna cum laude, in 2005 from Roma Tre University in Rome, Italy, and received a PhD in conjunction in physics/materials science in 2009 from SIMaP-INPG in Grenoble, France. She gained experience in structural and morphological characterizations of nanostructured organic and inorganic films by means of elastic X-ray scattering techniques from a synchrotron light source. Her current research interests are focused on the role of the structure and the morphology of organic semiconductors in the optimization of their thermoelectrical properties. She may be reached at liscio@bo.imm.cnr.it. https://orcid.org/0000-0002-4865-1385
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Massimiliano Cavallini is the director of research at CNR-ISMN Bologna, where he heads the multidisciplinary Nanotechnology of Multifunctional Materials Group. He received a laurea cum laude in 1995 and a PhD in chemistry in 1999 from the University of Florence. His multidisciplinary research spans unconventional bottom-up nanofabrication, applications of unconventional properties phenomena such as dewetting and polymorphism, information storage, development of time-temperature integrators, and nanoelectrochemistry. He is the author of over 120 papers in peerreviewed international journals and several book chapters, with an h-index of 46 and more than 5,800 citations (source: Google Scholar). He is the inventor of 15 international patents and cofounded the spinoff company Scriba Nanotecnologie Srl in 2005. He has been the principal investigator of several EU projects and received the ESFEuropean Yang Investigator Award in 2006. He may be reached at m.cavallini@bo.ismn.cnr.it. https://orcid.org/0000-0001-9802-0058 Massimo Innocenti is the head of the Applied Electrochemistry Laboratory of the Department of Chemistry at the University of Florence. He graduated with a degree in chemistry in 1989 and is currently an associate professor of analytical chemistry. Recently he has obtained a license to serve as a full professor of analytical chemistry. His research activity is focused on nanomaterials obtainable by electrochemistry and used in the field of electrocatalysis, energy, and sensors. Also relevant is research and industrial development in the applied galvanic field and analysis of surface to obtain many industrial contracts. Since May 2013 he has served as associate editor for the journal Coatings. He has been elected two times to be a member of the executive council of the Interdivisional Group on Chemistry for Renewable Energy, also known as EnerChem (2013-2018). From 2013 to 2016 he was a member of the ESRF Review Committee at the Synchrotron of Grenoble. He may be reached at minnocenti@unifi.it. https://orcid.org/0000-0003-1044-5583
References 1.
M. Y. Yao, F. Zhu, C. Q. Han, D. D. Guan, C. Liu, D. Qian, and J. F. Jia, Sci. Rep., 6, 21326 (2016). 2. A. D. Liao, M. Yao, F. Katmis, M. Li, S. Tang, J. S. Moodera, C. Opeil, and M. S. Appl. Phys. Lett., 105, 063114 (2014). 3. C. A. Hoffman, J. R. Meyer, F. J. Bartoli, A. D. Venere, X. J. Yi, C. L. Hou, H. C. Wang, J. B. Ketterson, and G. K. Wong, Phys. Rev. B, 48, 11431 (1993). 4. H. Du, X. Sun, X. Liu, X. Wu, J. Wang, M. Tian, A. Zhao, Y. Luo, J. Yang, B. Wang, and J. G. Hou, Nat. Commun., 7, 10814 (2016). 5. H. T. Chu, “J. Phys. Chem. Solids, 48, 845 (1987). 6. C. Albonetti, J. Martinez, N. S. Losilla, P. Greco, M. Cavallini, F. Borgatti, M. Montecchi, L. Pasquali, R. Garcia, and F. Biscarini, Nanotechnology, 19, 435303 (2008). 7. J. Waters, D. Crouch, J. Raftery, and P. O’Brien, Chem. Mater., 16, 3289 (2004). 8. E. Camps, S. E. Rodil, J. A. Salas, and H. V. Estrada, Mater. Res. Soc. Symp. Proc., 1477, 21 (2012). 9. F. Song, J. W. Wells, Z. Jiang, M. Saxegaard, and E. Wahlström, ACS Appl. Mater. Interfaces, 7, 8525 (2015). 10. D. I. Tishkevich, S. S. Grabchikov, L. S. Tsybulskaya, V. S. Shendyukov, S. S. Perevoznikov, S. V. Trukhanov, E. L. Trukhanova, A. V. Trukhanov, and D. A. Vinnik, J. Alloys Compd., 735, 1943 (2018).
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11. M. Innocenti, S. Bellandi, E. Lastraioli, F. Loglio, and M. L. Foresti, Langmuir, 27, 11704 (2011). 12. M. Innocenti, G. Zangari, C. Zafferoni, I. Bencistà, L. Becucci, and A. Lavacchi, “J. Power Sources, 241, 80 (2013). 13. M. Cavallini, M. Facchini, C. Albonetti, F. Biscarini, M. Innocenti, F. Loglio, E. Salvietti, G. Pezzatini and M. L. Foresti, J. Phys. Chem. C, 111, 1061 (2007). 14. G. Pezzatini, F. Loglio, M. Innocenti, and M. L. Foresti, Collect. Czechoslov. Chem. Commun., 68, 1579 (2003).
15. M. Cavallini, G. Aloisi, and R. Guidelli, Langmuir, 15, 2993 (1999). 16. W. Giurlani, A. Giaccherini, N. Calisi, G. Zangari, E. Salvietti, M. Passaponti, S. Caporali and M. Innocenti, Materials (Basel), In press (2018). 17. R. W. G. Wyckoff, Crystal Structures, p. 1, Interscience Publishers, New York (1963).
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SEC TION NE WS Detroit Section In the 2017-2018 academic year, the ECS Detroit Section has held regular meetings serving southeastern Michigan members largely from the Detroit area. Section members are primarily from the automotive and battery industries, but are also from local universities, including the University of Michigan, Michigan State University, Wayne State University, Oakland University, and Kettering University. The section meetings occur on campus at Lawrence Technological University in Southfield, MI. Below are a few of the events from the previous year. • September 27, 2017: Tom Guarr of MSU Bioeconomy Institute spoke to 22 attendees on “Durable Organic Redox Systems for Practical Energy Storage Applications.” • October 24, 2017: Alvaro Masias of Ford Motor Company spoke to 24 attendees on “Improving Battery Prognostics Through High Precision Testing.”
• November 28, 2017: Levi Thompson of the University of Michigan spoke to 38 attendees on “Non-Aqueous Redox Flow Batteries for Grid-Scale Energy Storage.” • January 16, 2018: Balasubramanian Lakshmanan of General Motors spoke to 35 attendees on “Recent Technical and Commercial Developments in Fuel Cells and Its Impact on Transportation Applications.” • February 15, 2018: John Warner of Ener1 spoke to 31 attendees on the “World Battery Market for Hybrid and Electric Bus Applications.” • March 22, 2018: John Camardese of XALT Energy spoke to 29 attendees on “Material Advancements for Lithium-Ion Batteries, the Hype versus Reality.” • April 25, 2018: Peter Gibson of LG Chem spoke on “Global Markets for Stationary Energy Storage.”
Georgia Section The ECS Georgia Section held its local conference at the Georgia Institute of Technology on April 27, 2018. The meeting was organized by Marta Hatzell, Paul Kohl, Jung Fang, and Seung Woo Lee. The event started with a reception and an invited seminar entitled “Electrochemically Instrumenting Organs on a Chip,” given by
David Cliffel, Cornelius Vanderbilt Professor and Chair, Department of Chemistry, Vanderbilt University. It was followed by a group lunch for the audience and a student poster session. Finally, three student poster awards were presented at the award ceremony: Garrett Huang (first place, Georgia Tech), Shan Xiong (second place, Georgia Tech), and Srinivas Hanasoge (third place, Georgia Tech).
Attendees gathered at Georgia Tech Manufacturing Institute during the 2018 ECS Georgia Section local conference.
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SEC TION NE WS Korea Section On April 5, 2018, the ECS Korea Section hosted a ceremony recognizing the Korea Section Student Award at the Changwon Exhibition Convention Center in Korea, an event that took place concurrently with the Korean Electrochemical Society’s spring meeting. Hieu Quang Pham received the 2018 student award with a cash prize of $500 from the Society. During the KECS spring meeting, Pham presented the results of his research, which had been conducted with his adviser Seung-Wan Song. His presentation was titled “Development of Multi-Functional Binder for Li-Rich Layered Oxide Cathode of High-Energy Li-ion Batteries.” Pham reported rationally designed fluorinated polyimide as a novel high-voltage
(4.7 V) binder for high-capacity Li1.13Mn0.463Ni0.203Co0.203O2 cathode in a 55 °C full-cell with graphite anode and conventional electrolyte without any electrolyte additive. Pham is a PhD candidate in the Department of Chemical Engineering and Applied Chemistry at Chungnam National University in the Republic of Korea. His current research interests focus on the development of high-voltage electrolyte materials and binders for high-capacity Li-rich layered oxide cathodes of Li-ion batteries as well as high-voltage interfacial phenomena and electrochemical reaction mechanisms for performance enhancement. The section will present the next award at its 2019 spring symposium.
Hieu Quang Pham gave a presentation on the “Development of MultiFunctional Binder for Li-Rich Layered Oxide Cathode of High-Energy Li-ion Batteries.”
Hieu Quang Pham (right) received the 2018 ECS Korea Section Student Award from KECS President Won Il Cho (left).
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AWARDS NE W MEMBERS Program
Awards, Fellowships, Grants ECS distinguishes outstanding technical achievements in electrochemistry, solid state science and technology, and recognizes exceptional service to the Society through the Honors & Awards Program. Recognition opportunities exist in the following categories: Society Awards, Division Awards, Student Awards, and Section Awards. ECS recognizes that today’s emerging scientists are the next generation of leaders in our field and offers competitive Fellowships and Grants to allow students and young professionals to make discoveries and shape our science long into the future.
See highlights below and visit www.electrochem.org for further information.
Society Awards The ECS Carl Wagner Memorial Award was established in 1980 to recognize mid-career achievement and excellence in research areas of interest of the Society, and significant contributions in the teaching or guidance of students or colleagues in education, industry, or government. The award consists of a silver medal, a wall plaque, Society life membership, complimentary meeting registration, and travel assistance of up to $1,000. Materials are due by October 1, 2018. The ECS Olin Palladium Award was established in 1950 to recognize distinguished contributions to the fields of electrochemical or corrosion science. The award consists of a palladium medal, a wall plaque, a $7,500 prize, Society life membership, and complimentary meeting registration. Materials are due by October 1, 2018.
Division Awards The ECS Energy Technology Division Research Award was established in 1992 to encourage excellence in energy-related research. The award consists of a framed certificate, a $2,000 prize, and membership in the Energy Technology Division for as long as the recipient is an ECS member. Materials are due by September 1, 2018. The ECS Energy Technology Division Supramaniam Srinivasan Young Investigator Award was established in 2011 to recognize and reward an outstanding young researcher in the field of energy technology. The award consists of a framed certificate, a $1,000 prize, and complimentary meeting registration. Materials are due by September 1, 2018.
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The ECS Nanocarbons Division Richard E. Smalley Research Award was established in 2006 to encourage excellence in fullerenes, nanotubes, and carbon nanostructures research. The award is intended to recognize, in a broad sense, those persons who have made outstanding contributions to the understanding and applications of fullerenes. The award consists of a framed certificate, a $1,000 prize, and assistance up to a maximum of $1,500 to facilitate attendance of the meeting at which the award is to be presented. Materials are due by September 1, 2018. The ECS Physical and Analytical Electrochemistry Division David C. Grahame Award was established in 1981 to encourage excellence in physical electrochemistry research and to stimulate publication of high-quality research papers in ECS journals. The award consists of a framed certificate and a $1,500 prize. Materials are due by October 1, 2018. The ECS Corrosion Division Herbert H. Uhlig Award was established in 1972 to recognize excellence in corrosion research and outstanding technical contributions to the field of corrosion science and technology. The award consists of a framed certificate, a $1,500 prize, and possible travel assistance. Materials are due by December 15, 2018. The ECS High Temperature Materials Division J. Bruce Wagner, Jr. Award was established in 1998 to recognize a young Society member who has demonstrated exceptional promise for a successful career in science and/or technology in the field of high temperature materials. The award consists of an appropriately worded scroll and the sum of $1,000. The recipient may receive (if required) complimentary registration and up to $1,000 in financial assistance toward travel expenses for attendance of the Society meeting at which the award is to be presented. Materials are due by January 1, 2019.
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AWARDS NE W AWA MEMBERS PROGRAM RDS (continued from previous page)
Section Awards The ECS Europe Section Heinz Gerischer Award was established in 2001 to recognize an individual or a small group of individuals (no more than three) who have made an outstanding contribution to the science of semiconductor electrochemistry and photoelectrochemistry including the underlying areas of physical and materials chemistry of significance to this field. The award consists of a framed certificate, a EUR 2,000 prize and, if required, financial assistance for unreimbursed travel expenses incurred to receive the award, not to exceed EUR 1,000. Materials are due by September 30, 2018.
Student Awards The ECS Corrosion Division Morris Cohen Graduate Student Award was established in 1991 to recognize and reward outstanding graduate research in the field of corrosion science and/or engineering. The award consists of a certificate and the sum of $1,000. The award, for outstanding master’s or PhD work, is open to graduate students who have successfully completed all the requirements for their degrees, as testified to by the students’ advisers, within a period of two years prior to the nomination submission deadline. Materials are due by December 15, 2018.
The ECS Energy Technology Division Graduate Student Award sponsored by Bio-Logic was established in 2012 to recognize promising young engineers and scientists in fields pertaining to this division. The award consists of a framed certificate, a $1,000 prize, complimentary student meeting registration, and complimentary admission to the ETD business meeting. Materials are due by September 1, 2018. The ECS Georgia Section Outstanding Student Achievement Award was established in 2011 to recognize academic accomplishments in any area of science or engineering in which electrochemical and/or solid state science and technology is the central consideration. The award consists of a $500 prize. Materials are due by August 15, 2018. The ECS Industrial Electrochemistry and Electrochemical Engineering Division H. H. Dow Memorial Student Achievement Award was established in 1990 to recognize promising young engineers and scientists in the field of electrochemical engineering and applied electrochemistry. The award consists of a framed certificate and a $1,000 prize to be used for expenses associated with the recipient’s education or research project. Materials are due by September 15, 2018.
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AWARDS NE W MEMBERS Program The ECS Industrial Electrochemistry and Electrochemical Engineering Division Student Achievement Award was established in 1989 to recognize promising young engineers and scientists in the field of electrochemical engineering and to encourage the recipients to initiate careers in this field. The award consists of a framed certificate and a $1,000 prize. Materials are due by September 15, 2018.
The ECS Korea Section Student Award was established in 2005 to recognize academic accomplishments in any area of science or engineering in which electrochemical and/or solid state science and technology is the central consideration. The award consists of a $500 prize and is presented at a designated Korea Section meeting. At that time, the recipient may be requested to speak on a subject of major interest to him/her in the field of electrochemical and/or solid state science and technology. Materials are due by September 30, 2018.
ECS Introduces
the 2018 Winner of the ECS Canada Section Electrochemical Award: Ashok Vijh Ashok Vijh is maître-de-recherche at the Institut de recherche d’Hydro-Québec and, concurrently, an invited professor at the National Institute of Scientific Research of the Université du Québec. Vijh is an electrochemist of international stature who has published over 380 refereed papers and 7 books on various areas of interfacial electrochemistry. His original and extensive research contributions have advanced the following areas: the conversion and storage of energy (electrocatalysis, fuel cells, batteries, photoelectrochemical cells, and hydrogen economy), corrosion, and oxidation of metals. Particularly noteworthy is his seminal work on the mechanisms of a large number of electrode reactions involving surface films— based on his theoretical insights on demetallized surfaces where solid state properties of passive layers (including those on the battery electrodes, now so-called solid-electrolyte interphases) control the kinetics of charge transfer. His pathbreaking work on electrochemical reactions across metal/plasma, metal polymer, and metal/dielectric interfaces, as well as the electrochemical treatment of cancerous tumors is of extraordinary originality. Vijh’s distinctions are many. He is a fellow of the following: the Royal Society of Chemistry, the Institute of Physics, the American Physical Society, and the Institute of Electrical and Electronics Engineers. His academy memberships include: the Royal Society of Canada, where he served as president from 2005 to 2007; the World Academy of Sciences; the European Academy of Sciences, Arts and Letters; and the Indian National Science Academy. He was the youngest winner of the I. W. Killam Memorial Prize of the Canada Council (1987)—the highest Canadian prize in any field of science. He was the first physical scientist to become a Knight of the National Order of Quebec in 1987 and was promoted to the rank of officer in 2008. He was decorated as an Officer of the Order of Canada in 1990. He received the Golden Jubilee Medal (2002) and the Diamond Jubilee Medal (2012) from Her Majesty Queen Elizabeth II. In 2017, he was made a Knight of the Order of Montreal.
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Article Credits: An Overview
ECS Members and Student Members ECS members receive one article credit per membership year.* Any papers published after this credit has been used will receive a 75% discount, bringing our already low APC down to only $200. ECS membership is an incredible value for authors – the cost of membership is $130 per year, and student membership is only $30 per year. This means that becoming an ECS member has the potential to Article credits are provide up to $770 off an article processing charge. ECS’s way of offering discounts on
What is an article credit?
Focus Issues
Papers submitted and accepted for publication in an ECS focus issue are published as open access at no cost to authors. Focus issues have proven to contain some of the most-read and highly-cited ECS content. In order to promote maximum dissemination of this important research, at the beginning of 2017 ECS made the decision to convert all future focus issues to OA-only. Please visit www.electrochem.org/focusissues to view our full listing of focus issues now accepting submissions.
Perspective Articles In order to increase readership and impact, Perspective articles are published as open access at no cost to authors. Perspective articles are brief, insightful assessments of and directions for new, developing, or established fields. They present thoughtprovoking perspectives and novel assimilation of scientific information in current or emerging fields that indicate potential trends or innovative applications.
ECS Plus Authors affiliated with an organization that holds a current ECS Plus subscription are entitled to unlimited article credits. Researchers from over 1,000 institutions qualify. Visit the ECS Digital Library (ecsdl.org) to find out more about ECS Plus.
Institutional Members As part of our institutional membership program, member organizations are able to select additional benefits to complement and customize their standard packages. Depending on your institution’s level of membership, there may be up to 45 article credits available to authors. For more information, or to determine if you are eligible for article credits through your organization, please email Shannon.Reed@electrochem.org.
open access publishing. An article credit entitles you to publish one open access paper in either of our peer-reviewed journals (Journal of The Electrochemical Society or the ECS Journal of Solid State Science and Technology) with a 100% discount on the article processing charge (normally $800 USD).*
*Please note that article credits do not provide discounts on Supplemental Material charges.
How do I get an article credit?
ECS has a robust discount program for our open access article processing charges (APCs). In total, more than 90% of open access articles published with ECS are published at no cost to the authors due to the use of article credits. This document provides a quick overview of different types of article credits and how to get them.
For more information, including instructions on how to apply article credits, visit: www.electrochem.org/oa
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NE W MEMBERS ECS is proud to announce the following new members for January, February, and March 2018.
Members Daniel Abraham, Chevy Chase, MD, USA Chic Allen, Independence, OH, USA Fumiaki Amano, Kitakyushu, Fukuoka, Japan Nigel Becknell, Lombard, IL, USA Kevin Bergemann, Livermore, CA, USA Fabien Besnard, Charlotte, NC, USA Hans Beyer, Munich, BY, Germany Timothy Bogart, Redwood City, CA, USA Robert Braendle, Salem, OR, USA Sven Burger, Berlin, BE, Germany Richard Carter, Saratoga Springs, NY, USA Jingyi Chen, Fayetteville, AR, USA Ping Chen, Dalian, China Seong Soo Choi, Ahsan, South Korea Md Delwar Hossain Chowdhury, Cambridge, Cambridgeshire, UK Po-Ya Chuang, Merced, CA, USA Woon Jin Chung, Cheonan, South Korea Finn Deckert, Kirkel, SL, Germany Pravas Deria, Carbondale, IL, USA Edmund Dickinson, Teddington, UK Xochitl Dominguez-Benetton, Mol, Belgium Ban Dong, Chicago, IL, USA Mateusz Donten, Kehlen, Luxembourg Yueying Fan, Morgantown, WV, USA Zhenxing Feng, Corvallis, OR, USA Lin Gan, Shenzhen, China Michael Gerhardt, Berkeley, CA, USA Livia Giordano, Auburndale, MA, USA Jorge Gonzalez-Sanchez, Campeche, Campeche, Mexico Padma Gopalan, Madison, WI, USA Reuven Gordon, Victoria, BC, Canada Sergio Granados-Focil, Worcester, MA, USA Robert Grim, Golden, CO, USA Christopher Hahn, Stanford, CA, USA Alexander Harris, Setauket, NY, USA Melissa Helm, Chicago, IL, USA Jason Hicks, Notre Dame, IN, USA Caleb Hill, Laramie, WY, USA Shun Hirota, Ikoma, Nara, Japan James Hofmann, Romeoville, IL, USA Eric Hostetler, Lebanon, OR, USA Michael Hughes, Northampton, PA, USA James Hurst, Oxford, MI, USA Haiping Jia, Richland, WA, USA Yan-Xia Jiang, Xiamen, China Sadia Kabir, Golden, CO, USA Yongmook Kang, Seoul, South Korea Yu Katayama, Ube, Yamaguchi, Japan
Shrikant Kawale, London, London, UK Isaiah Kellogg, Union, MO, USA Jungseung Kim, Lebanon, OR, USA Samuel Kirk, Mayfield West, NSW, Australia Joel Kirner, Darien, IL, USA Daniel Kissel, Brookfield, IL, USA Jesse Ko, Arlington, VA, USA Masaya Kobayashi, Ann Arbor, MI, USA Gregory Korshin, Seattle, WA, USA Darshan Kundaliya, Beverly, MA, USA Oleg Kuznetsov, Columbus, OH, USA Christophe Labbé, Caen, France Bin Liu, Manhattan, KS, USA Jenifer Locke, Columbus, OH, USA Marc Madou, Irvine, CA, USA Claudia Marcela Bazan, Montreal, QC, Canada Joshua Maurer, Troy, NY, USA Eric McCalla, Montreal, QC, Canada James McKone, Pittsburgh, PA, USA Eric Meshot, Livermore, CA, USA Giuseppe Milano, Yamagata-shi, Yamagata, Japan Elisa Miller-Link, Lakewood, CO, USA Gregory Moore, Groton, CT, USA Pavel Moreno Garcia, Bern, BE, Switzerland Takumi Mori, Ueda, Nagano, Japan Kirsten Moselund, Rueschlikon, ZH, Switzerland Santanu Mukherjee, Manhattan, KS, USA Yoshinori Naruta, Kasugai, Aichi, Japan Richard Nichols, Liverpool, Merseyside, UK Ken Ogata, Minoh, Osaka, Japan Hyukkeun Oh, Boulder, CO, USA Nagore Ortiz-Vitoriano, Vitoria-Gasteiz, EUS, Spain Luigi Osmieri, Golden, CO, USA Chanho Pak, Gwangju, South Korea Matteo Palma, London, London, UK Satyavolu Papa Rao, Albany, NY, USA Pekka Peljo, Sion, VS, Switzerland Stephen Percival, Albuquerque, NM, USA Nicolas Plumere, Bochum, NW, Germany Bruno Pollet, Trondheim, Norway Arnold Putten, Eindhoven, Netherlands Jahangir Rather, Muscat, Oman Olivia Reddy, Bristol, UK Engelbert Redel, EggensteinLeopoldshafen, BW, Germany Joan Redwing, University Park, PA, USA Tania Ripenbein, Natanya, Israel KwangSun Ryu, Ulsan, South Korea
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Hidehiro Sakurai, Suita, Osaka, Japan Mílton Santos Cordeiro, Vallejo, CA, USA Brett Savoie, West Lafayette, IN, USA Jeremy Schrooten, Spokane, WA, USA Mohtashim Shamsi, Carbondale, IL, USA Yong Gun Shul, Seoul, South Korea Li Shuzhou, Singapore, Singapore Harsono Simka, Saratoga, CA, USA Niraj Singh, Milwaukee, WI, USA Varshni Singh, Durham, NC, USA Eric Sorte, Albuquerque, NM, USA Xiao Tang, Gainesville, FL, USA Raghavender Tummala, Novi, MI, USA Miguel Velazquez-Manzanares, Saltillo, Coahuila, Mexico Dan Verser, San Carlos, CA, USA Dan Wei, Beijing, China Wei Wei, Wichita, KS, USA Yanfen Wen, Xiamen, China Ryan West, San Francisco, CA, USA Edwin Wong, Maple Ridge, BC, Canada Sharon Wong, Port Coquitlam, BC, Canada Su-Yuan Xie, Xiamen, PR, China Lijun Yang, Burnaby, BC, Canada Lifeng Zhang, Xi’an, China Linghong Zhang, Lemont, IL, USA Jing Zhao, Storrs, CT, USA Yun Zhao, Newark, DE, USA Ilya Zharov, Salt Lake City, UT, USA Nan Zheng, Fayetteville, AR, USA
Student Members Richard Aadahl, Charlottesville, VA, USA Fatemeh Abbasi, Guelph, ON, Canada Fahimah Abd Lah Halim, Kanazawa, Ishikawa, Japan Asha Abiade, New Orleans, LA, USA Jada Adams, New Orleans, LA, USA Viacheslav Agafonov, Seattle, WA, USA Jinhyeok Ahn, Ansan, South Korea Ali Alshanoon, Manassas, VA, USA Rakan Altarawneh, St. John’s, NL, Canada Erik Anderson, Atlanta, GA, USA Chalita Aphirakaramwong, Wangchan, Thailand Jared Arabit, Buena Park, CA, USA Alina Arslanova, Leuven, Flanders, Belgium Kalin Baca, Albuquerque, NM, USA Mehrdad Balandeh, Los Angeles, CA, USA Pete Barnes, Boise, ID, USA Jack Beane, Liverpool, Merseyside, UK Melissa Becker, Rochester, NY, USA Jon Bender, Austin, TX, USA
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
NE W MEMBERS William Bennett, Charlottesville, VA, USA Ashlesha Bhide, Richardson, TX, USA Emamnuel Boateng, Guelph, ON, Canada Jan Borchers, West Des Moines, IA, USA Tory Borsboom-Hanson, Victoria, BC, Canada Luke Brown, Charlottesville, VA, USA Maja Budanovic, Singapore, Singapore Nora Buggy, Golden, CO, USA Rosemary Calabro, Lexington, KY, USA Qun Cao, Charlottesville, VA, USA Aliya Carter, Baltimore, MD, USA Samuel Castro Pardo, Houston, TX, USA Landon Caudill, Nicholasville, KY, USA Mario Cedano, Chula Vista, CA, USA Chian-Hsiu Chan, Taoyuan City, Taiwan Utibe-Eno Charles-Granville, Charlottesville, VA, USA Patcharawat Charoen-amornkitt, Suita, Osaka, Japan Kanchan Chavan, Lansing, MI, USA Madelaine Chavez, Albuquerque, NM, USA Fu-Chun Chen, Hsinchu, Taiwan Hung-Yu Chen, Hsinchu City, Taiwan, Taiwan Miao Chen, Yonezawa, Yamagata, Japan Shuai Chen, Guelph, ON, Canada Ting Chen, Fukuoka, Fukuoka, Japan Che Chiu, Taipei, Taiwan Eunbyul Cho, Carson, CA, USA Jui-Hui Chung, Taipei, Taiwan, Taiwan Yun-Jung Chung, Taoyuan, Taiwan, Taiwan Joseph Cirone, St Catharines, ON, Canada Rebecca Clark, Mission Viejo, CA, USA Fabien Claudel, Saint-Martin-d’Hères, France Karlie Cummins, Farmington Hills, MI, USA David Curran, Lakewood, CO, USA Kasun Dadallagei, Iowa City, IA, USA Ana Marija Damjanovia, Muenchen, BY, Germany Sofya Danilova, Nuneaton, Warwickshire, UK Debashish Dash, Silchar, AS, India Jeremy Dawkins, Montreal, QC, Canada Brandon Day, Moscow, ID, USA Vincent DeBiase, Syracuse, NY, USA Matthew Denecke, Stafford, VA, USA Panpan Dong, Pullman, WA, USA Deepak Dubey, Hsinchu City, Taiwan, Taiwan Sharmila Durairaj, Guelph, ON, Canada Thomas Ebaugh, Storrs, CT, USA Daniel Esteban, Madrid, MAD, Spain Ehsan Faegh, West Columbia, SC, USA Justin Fagnoni, Glastonbury, CT, USA
Filippo Fenini, Roskilde, Denmark Joseph Fleming, Coventry, West Midlands, UK Sonia Foley, Charlottesville, VA, USA Anat Friedman, Beer Sheva, Israel Eiche Gardner, Weaverville, NC, USA Raghav Garg, Pittsburgh, PA, USA Dan Gil, Shaker Heights, OH, USA John Gomez, Oxnard, CA, USA Yukun Gong, Cleveland, OH, USA Ruben Govindarajan, Vancouver, BC, Canada Dmitrii Govorov, Shuya, Russia Lukas Graser, Royal Oak, MI, USA Sara Guerrero, Madrid, MAD, Spain Steven Hand, Champaign, IL, USA Louis Hartmann, Muenchen, BY, Germany Mojgan Hatami, Montreal, QC, Canada William Hawley, Knoxville, TN, USA Madison Hill, Pekin, IL, USA Yuji Hirai, Yamagata-shi, Yamagata, Japan Mark Holtan, Auburn, AL, USA Sean Hong, Charlottesville, VA, USA Seyyedamirhossein Hosseini, Bloomington, IN, USA Ching Hsieh, Hsinchu, Taiwan, Taiwan Chih Yang Huang, Hsinchu, Taiwan, Taiwan Nolan Ingersoll, Salt Lake City, UT, USA Reiko Izumi, Ibaraki, Osaka, Japan Jakub Jagielski, Zurich, ZH, Switzerland Kamil Jaššo, Brno, Czech Republic Isanka Udayani Jayawardhena, Auburn, AL, USA Katherine Jinkins, Madison, WI, USA Kurian Jomy Vachaparambil, Trondheim, Norway Ashley Jordan, Macomb, MI, USA Merin K Wilson, Cochin, KL, India Surasak Kaenket, Wangchan, Thailand Henning Kaland, Trondheim, Norway Guruprakash Karkera, Chennai, TN, India Ryan Katona, Charlottesville, VA, USA Kenta Kawashime, Austin, TX, USA Ryoma Kawazoe, Noda-shi, Chiba, Japan Bethany Kersten, Moscow, ID, USA Shervin Keshavarzi, Furtwangen, BW, Germany Ieeba Khan, New Delhi, DL, India Kwangnam Kim, Ann Arbor, MI, USA Kwiyong Kim, Daejeon, South Korea Suhyun Kim, Seoul, South Korea Ke’La Kimble, New Orleans, LA, USA Kevin Kimura, Ithaca, NY, USA Jeffrey Klein, Cleveland Heights, OH, USA Subarna Kole, Baton Rouge, LA, USA
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Kaitlin Kollins, Charlottesville, VA, USA Tomoki Komura, Aoba-ku,Sendai, Miyagi, Japan Ketsuda Kongsawatvoragul, Wangchan, Thailand Mohamed Koronfel, London, London, UK Soracha Kosasang, Nakhon Phanom, Thailand Burak Koyuturk, Munich, BY, Germany Amit Kumar, Hsinchu, Taiwan, Taiwan Yuta Kushida, Noda-shi, Chiba, Japan Jason Kwan, Richmond, BC, Canada Purim Ladpli, Los Altos Hills, CA, USA Clemence Lafforgue, Saint Martin d’Heres, France Lucia Lain, Ferney-Voltaire, France Leatham Landon-Lane, Christchurch, New Zealand Naziah Latiff, Singapore, Singapore Dongho Lee, Madison, WI, USA Martin Leimbach, Ilmenau, TH, Germany Daniel Leonard, Corvallis, OR, USA Graham Leverick, Cambridge, MA, USA Guangfu Li, Merced, CA, USA Jinke Li, Muenster, NW, Germany Tianyu Li, Victoria, BC, Canada Yuanjiao Li, Montreal, QC, Canada Jinkyu Lim, Berkeley, CA, USA Chia-Te Lin, Taipei, Taiwan, Taiwan Ya-Hsuan Lin, Hsinchu City, Taiwan Yanfen Lin, Xiamen, China Chang Liu, Charlottesville, VA, USA Sizhe Liu, Urbana, IL, USA Tong Liu, London, London, UK Matthew Lloyd, Coventry, Warwickshire, UK Tim Lochner, Munich, BY, Germany Linfang Lu, Hangzhou, China Monika Lukaczyńska, Brussels, Belgium Hailong Lyu, Knoxville, TN, USA Min Lyu, Gaithersburg, MD, USA Priya M J, Kochi, KL, India Kavitha M K, Kochi, Kerala, India Jeffrey Ma, Fort Collins, CO, USA Nattapol Ma, Bangkok, Thailand Christian Macambira, Sao Paulo, Sao Paulo, Brazil Kiran Mahankali, Detroit, MI, USA Monu Malik, Toronto, ON, Canada Maidhily Manikandan, Trondheim SorTrondelag, Norway Venkatesh Subramanian Manikandan, Guelph, ON, Canada Scohy Marion, Saint Martin d’Heres Cedex, France Tim Marshall, Philadelphia, PA, USA (continued on next page) 89
NE W MEMBERS (continued from previous page)
Nontlantla Maseko, Pretoria, South Africa Kengo Matsumura, Sendai, Miyagi, Japan Madisen McCleary, Bozeman, MT, USA Patrick McCormack, Charlottesville, VA, USA Jessica McGlynn, Ayrshire, UK Eric McKenzie, Bloomington, IN, USA Kevin Meisner, Charlottesville, VA, USA Quinton Meisner, Tallahassee, FL, USA El Amine Mernissi Cherigui, Brussels, Belgium Andrew Meyer, Lexington, KY, USA Allison Mills, Germantown, MD, USA Pratyush Mishra, Ames, IA, USA Neera Mistry, Frankfort, IL, USA Norraihanah Mohamed Aslam, Kanazawa, Ishikawa, Japan Robert Morasch, Garching, BY, Germany Pratik Murkute, Corvallis, OR, USA Joseph Murphy, Cleveland, OH, USA Bouzid Naidji, Besançon Cedex, France Tenshou Nakamura, Yamagata-shi, Yamagata, Japan Savitha Nalini, Ernakulam, KL, India Lauren Nalley, Charlottesville, VA, USA Swati Narasimhan, Miami, FL, USA Kok Long Ng, Toronto, ON, Canada Ziyang Nie, Charlottesville, VA, USA Nobuyuki Nishiumi, Yamagata-shi, Yamagata, Japan Uzoma Nwabara, Urbana, IL, USA Mariana Ordaz, Querétaro, Querétaro, Mexico Elise Ostli, Trondheim Sor-Trondelag, Norway Ryan Ouimet, Storrs, CT, USA Fiki Owhoso, Gainesville, FL, USA Midhun P S, Kochi, KL, India Subin P S, Ernakulam, KL, India Rajesh Pachimatla, Chennai, TN, India Sabhapathy Palani, Taipei, Taiwan Haesun Park, Ann Arbor, MI, USA Brenna Parke, Iowa City, IA, USA Retha Peach, Potchefstroom, South Africa Xiong Peng, West Columbia, SC, USA Aswathy Pillai, Kalamassery, KL, India Stefan Piontek, Philadelphia, PA, USA Niroodha Pitawela, Iowa City, IA, USA Abhinav Poozhikunnath, Storrs, CT, USA Fatemeh Poureshghi Oskouei, Trondheim, Norway Nuttanit Pramounmat, Cleveland, OH, USA Pumidech Puthongkham, Charlottesvle, VA, USA
Kathleen Quiambao, Charlottesville, VA, USA Kira Rahn, Ames, IA, USA Aravindh Rajan, Atlanta, GA, USA Yash Raka, Trondheim, Norway Ricardo Rangel, Sao Paulo, Sao Paulo, Brazil Soumya Ravi, Ernakulam, KL, India Pinals Rebecca, Berkeley, CA, USA Mackenzie Ridley, Charlottesville, VA, USA Nathaniel Rieders, Bozeman, MT, USA Nathalie Riphaus, Munich, BY, Germany Daniel Rogstad, Trondheim Sor-Trondelag, Norway Nur Farhanah Binte Rosli, Singapore, Singapore Kelly Rudman, Bloomington, IN, USA Louise Ryan, Cork, Ireland Anantharaj S, Karaikudi, TN, India Sudip Saha, Hamilton, ON, Canada Memoon Sajid, Jeju-si, South Korea Daniel San Roman, Pittsburgh, PA, USA Devangsingh Sankhala, Richardson, TX, USA Sangchai Sarawutanukul, Rayong, Thailand Prince Sarfo, Butte, MT, USA Kamalasekaran Sathasivam, Hsinchu, Taiwan, Taiwan Ryota Sato, Yonezawa, Yamagata, Japan Travis Schmauss, Evanston, IL, USA Richard Senegor, Santa Clara, CA, USA Nannan Shan, Manhattan, KS, USA Qiurong Shi, Pullman, WA, USA Louis Sieuw, Louvain-la-Neuve, Brabant Wallon, Belgium Dylan Siltamaki, Guelph, ON, Canada Vanessa Silva, Guarulhos, Sao Paulo, Brazil Olja Simoska, Austin, TX, USA Jan Singer, Stuttgart, BW, Germany Jonathan Skelton, Charlottesville, VA, USA Junhua Song, Pullman, WA, USA Christopher Stachurski, Nashville, TN, USA Matthew Stewart, Burnaby, BC, Canada Michael Strand, Stanford, CA, USA Callie Stuart, Clemson, SC, USA Zihang Su, Cleveland, OH, USA Baviththira Suganthan, Athens, GA, USA He Sun, Yonezawa, Yamagata, Japan Yunkai Sun, Charlottesville, VA, USA Tse-Yu Tai, Hsinchu, Taiwan, Taiwan Natsumi Takaya, Sendai, Miyagi, Japan Greg Tatar, Kalispell, MT, USA
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Linnette Teo, Seattle, WA, USA Antony Raj Thiruppathi, Guelph, ON, Canada Seamus Thomson, Sydney, New South Wales, Australia Sophia Tiano, Westford, MA, USA Yi-Hsin Ting, Hsinchu, Taiwan, Taiwan Mineyoshi Tomie, Noda, Chiba, Japan Nam Tran, New Orleans, LA, USA Ngoc Tham Tran, Brisbane, Queensland, Australia Wendy Tran, Edmonton, AB, Canada Yuki Tsuda, Yamagata-shi, Yamagata, Japan Kyota Uda, Yonezawa, Japan Can Uzundal, Ankara, Turkey Matthias van den Borg, Ulm, Germany Joshua van der Zalm, Guelph, ON, Canada Eva Vandaele, Kessel-Lo Vlaams-Brabant, Belgium Sofie Vandenbroucke, Sint-Denijs-Westrem Oost-Vlaanderen, Belgium Mariana Vasquez, Durham, NC, USA Gokul Venugopalan, Baton Rouge, LA, USA Mary Vijila, Ernakulam, KL, India Julija Vinckeviciute, Goleta, CA, USA Ruiyu Wang, Philadelphia, PA, USA Shaofei Wang, Rochester, NY, USA Shin Wang, Hsinchu, Taiwan, Taiwan Ting-Yi Wang, Taipei, Taiwan, Taiwan Zhiyang Wang, Bloomington, IN, USA Jon Weller, Phoenix, AZ, USA Benjamin Whitman, Cleveland, OH, USA Cedrik Wiberg, Mölndal, Sweden Anna Winiwarter, Kgs. Lyngby, Denmark Min-Ci Wu, Hsinchu, Taiwan Xinxin Xiao, Limerick, Ireland B?o xiong, Hamilton, ON, Canada Stephanie Xiong, Placentia, CA, USA Xinzhao Xu, London, London, UK Jiancheng Yang, Gainesville, FL, USA Tzu-Chin Yang, Taipei, Taiwan, Taiwan Yuxiang Yao, Toronto, ON, Canada Dai Yifan, Cleveland Heights, OH, USA Jae Young Yoo, Daejeon, South Korea Ji Mun Yoo, Woodridge, IL, USA Seungho Yu, Ann Arbor, MI, USA Xiaoyun Yu, Palo Alto, CA, USA Nina Zensen, Ulm, BW, Germany Qiang Zhang, Kami, Japan Xiaoxuan Zhang, Union City, CA, USA Xueli Zheng, Palo Alto, CA, USA Shan Zhu, Bethlehem, PA, USA Yufeng Zhu, Cleveland, OH, USA
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
NE W MEMBERS Member Anniversaries It is with great pleasure that we recognize the following ECS members who have reached their 30, 40, 50, and 60 year anniversaries with the Society in 2018. Congratulations to all!
60 Years
David S. Newman S. A. Prussin Arthur M. Wilson Petr Zuman
50 Years
Eric W. Brooman John S. Dunning George H. Fraser George W. Luckey Robert E. Palmer Frank Parsen Howard W. Pickering Allan H. Reed Ashok K. Vijh Hiry B. West Jerry M. Woodall
40 Years
Lionel P. Adda Albert S. Bergendahl Andrew B. Bocarsly Sid Clouser Geoffrey John Dudley Wolfgang R. Fahrner Hisashi Harada Kurt R. Hebert Raji Heyrovska Curtis F. Holmes Rudolf Holze Harold W. Korb Michael Krumpelt Thomas F. La Gess Robert Charles McDonald Leroy J. Miller Sudhan S. Misra Joseph R. Monkowski Timothy A. Moore Colin W. Oloman
Tetsuo Osa Detchko Pavlov Michael R. Polcari Robert F. Savinell Robert Spotnitz Hans-Henning Strehblow Micha Tomkiewicz Michael S. Waite Arthur Yelon
30 Years
Derryl D. J. Allman Jeffrey Stuart Buchanan Stephanie Watts Butler Kwong-Yu Chan Alison J. Davenport Hugh C. De Long Peter C. Foller Jeffrey C. Gelpey Hossein Ghezel-Ayagh
Andrew N. Jansen David Kaplin G. H. Kelsall Chi-Woo Lee Andrei Leonida Azzam N. Mansour Mohammad R. Mirabedini Katsuhiko Naoi Demetrius Papapanayiotou Michael F. Pyszczek Jimmie L. Russell Alberto A. Sagues Michael J. Sailor Yuichi Sato Eric M. Stuve Francis L. Tanzella D. Morgan Tench Markku V. Tilli Bernard Tribollet Young-Chung Wang Xiaoge Zhang
ECS Electrochemistry
KNOWLEDGE BASE One site. Thousands of resources. 4 Over 1,000 electrochemical definitions 4 Dozens of articles by leading experts 4 Links to over 1,000 electrochemical websites 4 Over 3,000 books and proceedings volumes listed
http://knowledge.electrochem.org The Electrochemical Society Interface â&#x20AC;˘ Summer 2018 â&#x20AC;˘ www.electrochem.org
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ECS 2018 Summer Fellowships This year marks the 90th anniversary of ECS providing summer fellowships to assist students in continuing their graduate and postdoctoral work in a field of interest to the Society. Each awardee receives up to $5,000 to support their research efforts. Congratulations to the following five summer fellowship recipients. We look forward to reading their reports in this year’s winter issue of Interface.
2018 Colin Garfield Fink Fellowship Recipient Haegyeom Kim received a BSc degree from the Department of Materials Science and Engineering in Hanyang University, a MSc degree on graphene-based hybrid electrodes for lithium rechargeable batteries from the Korea Advanced Institute of Science and Technology, and a PhD degree on graphite derivatives for Li and Na rechargeable batteries at Seoul National University. Now, he serves as a postdoctoral researcher in Prof. Gerbrand Ceder’s group at Lawrence Berkeley National Laboratory. His current research interest lies in the design and development of novel electrode materials for Li-, Na-, and K-ion batteries as well as the investigation on underlying energy storage mechanisms within. To date, he has published more than 50 papers in peer-reviewed journals, including 27 first-authored papers. According to Google Scholar, his papers have been cited over 4,000 times and his H-index is 33. His accomplishments have been recognized by the ECS Battery Division Postdoctoral Associate Research Award, ECS Energy Technology Division Graduate Student Award, ECS Student Award of the Korea Section, ECS Battery Division and ECS Energy Technology Division, travel grants, the Best Graduate Thesis Award of Seoul National University, and a Korea Global PhD Fellowship. For his summer fellowship, he will investigate how intercalating ion species affect electrochemical properties of electrode materials in the rechargeable battery system.
2018 Edward G. Weston Fellowship Recipient Aashutosh N. Mistry has been pursuing his doctoral studies with Prof. Partha P. Mukherjee at Purdue University. His present research focuses on the mesoscale understanding of transport phenomena in lithium batteries. He investigates the physicochemical interactions taking place in electrodes, how microstructure affects these processes and the role of this coupling at an observable scale. His research and academic achievements have been recognized in the form of various awards and fellowships throughout his student career. He is the recipient of the Purdue College of Engineering Outstanding Research Award 2018 and Lambert Graduate Teaching Fellowship at Purdue University.
2018 F. M. Becket Fellowship Recipient Xinyou Ke is a PhD candidate in the Department of Mechanical and Aerospace Engineering at Case Western Reserve University under the supervision of Dr. Robert F. Savinell, Dr. Joseph M. Prahl, and Dr. Jesse S. Wainright. He has focused on understanding the fundamentals involved in high performance flow batteries with flow field and stack designs, and electronic conduction mechanisms of slurry or semi-solid electrodes used for electrochemical flow capacitors and flow batteries through both modeling and experimental approaches. To date, he has authored and coauthored 10 peer-reviewed journal articles and has been awarded several scholarships and certificates for 92
his contributions to research, academic records, and professional services. He served as the treasurer of the ECS Case Western Reserve University Student Chapter during 2016-2017.
2018 Joseph W. Richards Fellowship Recipient Yi Peng is pursuing his PhD degree at the University of California-Santa Cruz (UCSC) under the supervision of Prof. Shaowei Chen. In 2017, he won the John and Grace Wang Award in Physical Chemistry from UCSC and a STEM Chateaubriand Fellowship from the Embassy of France, and is carrying out collaborative research in spring 2018 in Prof. Pierre Millet’s laboratory in Universite Paris-Sud in France. His research interests include surface functionalization and engineering of metal/semiconductor nanoparticles, their chargetransfer dynamics, and single atom catalysis for electrochemical energy conversion and storage such as oxygen reduction, hydrogen evolution, and CO2 reduction reactions. Thus far, he has authored 26 peer-reviewed publications and one U.S. patent.
2018 H. H. Uhlig Fellowship Recipient Jeffrey Henderson is a third year PhD candidate at the University of Western Ontario with Dr. David W. Shoesmith and Dr. James J. Noël serving as his advisors. Henderson focuses his attention on the corrosion behavior of NiCr-Mo alloys while under aggressive conditions. During his graduate studies, he has received a total of six honors and awards including the prestigious Alexander Graham Bell Canada Graduate Scholarship given by the Natural Sciences and Engineering Research Council of Canada. As a recipient of this year’s ECS summer fellowship, Henderson will travel to Chimie ParisTech in Paris, France, where he will work alongside Dr. Kevin Ogle and Dr. Philippe Marcus to better understand the corrosion behavior and oxide properties of commercially available Ni-based Hastelloy materials.
2018 Summer Fellowship Committee ECS thanks the 2018 Summer Fellowship Committee for its time and effort in selecting this year’s recipients: Vimal Chaitanya, Committee Chair Director, Energy Research Lab New Mexico State University, USA Peter Mascher Professor and William Sinclair Chair in Optoelectronics McMaster University, Canada David Hall Postdoctoral Researcher Dalhousie University, Canada Kalpathy Sundaram Professor & Graduate Coordinator University of Central Florida, USA The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
ST UDENT NE WS Auburn University Student Chapter The ECS Auburn University Student Chapter is comprised of a multidisciplinary group of student members from the materials engineering, chemical engineering, chemistry, and electrical engineering departments. Chapter members were surveyed on their interests and indicated a strong interest in industry. The chapter organized a professional development lecture, a plant tour focused on sustainability, three invited talks, and two student member talks. The theme of the chapter’s activities focused on global sustainability challenges. Dr. Jeffrey Fergus, Dr. Xinyu Zhang, and Dr. Byron Farnum shared their research and perspectives on solid oxide fuel cells, chemical vapor sensors using conducting polymers and carbon nanotubes,
and inorganic nanomaterials and molecules for renewable energy conversion and storage. Dr. Dale Watson provided a professional development workshop on job searching techniques and preparing for a career in electrochemistry. On March 23, 2018, the chapter enjoyed a tour of InterfaceFLOR, the world’s largest manufacturer of commercial carpet tile. InterfaceFLOR’s initiative Mission Zero promises to eliminate the organization’s negative environmental impacts by 2020. Chapter members are actively involved in presentations and discussions on MXene 3D materials in energy storage application. The members want to make contributions to global sustainability.
ECS Auburn University Student Chapter members visited InterfaceFLOR, the world’s largest manufacturer of commercial carpet tile.
Members of the ECS Auburn University Student Chapter with Emre Kayali, who presented his work on the electrochemical performance of 2D Mxenes.
2019 Summer Fellowships Dates Application opens – September 2019 Application deadline – January 15, 2019 The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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ST UDENT NE WS Brno University of Technology Student Chapter The ECS Brno University of Technology Student Chapter has enjoyed a number of successes since the beginning of the year. The chapter successfully recruited another member, Kamil Jaššo, who shares an interest in post-lithium systems; more specifically, his work is focused on lithium-sulfur systems. The chapter also hosted José Francisco Dos Santos from Federal University Santa Catarina. Dos Santos visited through the support of the international project UNIGOU, organized by the Institute of Czech-Brazilian Academic Cooperation. Dos Santos was with the department from January 15 to March 31, 2018. His work was focused on aprotic sodium-ion systems. His task was to lay on solidliquid synthesis of sodium titanate electrode material (NaxTiyOz) for negative electrode in sodium-ion cell. The chapter looks forward to future collaborations with him. The chapter is also preparing for the arrival of Dr. Mariela Ortiz from National Technological University in La Plata, Argentina. She is
an expert on energy storage and renewable energy sources along with electrochemical energy sources such as Li-ion and Li-sulfur batteries. The chapter anticipates that Dr. Ortiz will be with the department for the upcoming year. Additionally, the chapter is planning to participate in the 19th International Conference on Advanced Batteries, Accumulators and Fuel Cells (conference webpage: www.aba-brno.cz) that is held in Brno. ABAF is an ECS-sponsored meeting. Its meeting proceedings will be published in a special volume of ECS Transactions. The chapter’s members will continue to participate in international meetings focused on lithium-ion systems organized by the International Society of Electrochemistry, like the one held in Japan from April 15 to 18, 2018. The chapter will soon host its own meeting, which will be held in Blansko, Czech Republic, July 17-18, 2018. The meeting will be focused on batteries, energy storage systems, and renewable energy.
Case Western Reserve University Student Chapter The ECS Case Western Reserve University Student Chapter established a service outreach team, and in February 2018, the chapter partnered with the Chemical Engineering Graduate Student Organization to volunteer at the university’s annual engineering carnival event. Participation involved showing interactive science concepts to students in second to eighth grade. The chapter and ChEGSO showed these prospective scientists two different experiments: an electrochemical lemon battery and a Cartesian diver. When the children’s LED light illuminated, their faces simultaneously lit up with wonder and curiosity. The chapter also brought outside speakers to campus and had them showcase their research. Its speakers included Dr. Daniel Scherson, Dr. Anne Co from The Ohio State University, and Dr. Yanhai Du from Kent State University. The chapter partnered with the Graduate Materials Society and brought in Dr. Gerald Frankel from The Ohio State University. The speakers’ seminars ranged from topics on the technical details of their research as a professor to what it is like running a startup. The chapter continues to grow its service outreach team as well as its partnerships with other on-campus organizations by bringing together students and faculty from other on-campus organizations and by helping tie in professional, personal, and service development for its students and affiliates.
Dr. Daniel Scherson (left) met with members of the ECS Case Western Reserve University Student Chapter during the social hour after his presentation. 94
Dr. Anne Co presented her work on electrocatalysis to the chapter.
Xinyou Ke (left) and Jason Pickering (right), the chapter’s service outreach team lead, set up a lemon battery experiment for the children attending the Case Western Reserve University Engineering Carnival Fair. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
ST UDENT NE WS Calgary Student Chapter The ECS Calgary Student Chapter organized an afternoon workshop on advanced electrochemical impedance spectroscopy (EIS) at the end of October 2017. The instructor for this workshop was Dr. Mark Orazem, a distinguished professor of chemical engineering at the University of Florida, an adjunct professor at the Beijing University of Chemical Technology, and a highly respected expert in EIS. This workshop reviewed the basics of impedance measurements and then focused on how to develop models for interpreting impedance data.
In addition, equivalent circuits, kinetic models, diffusion impedance, and constant phase elements were covered during the workshop. The workshop was very successful, with over 40 attendees from the Department of Chemistry and a number of departments within the Schulich School of Engineering at the University of Calgary, as well as a few students from the University of Alberta in Edmonton. This event also served to attract a number of new members to the Calgary Student Chapter.
A portion of the attendees of the chapter’s advanced impedance workshop in Calgary, Alberta, Canada. Dr. Mark Orazem introduced a resource for electrochemical impedance spectroscopy at the start of the ECS Calgary Student Chapter’s workshop.
Oklahoma Student Chapter The ECS Oklahoma Student Chapter was established in 2017 with six members and three co-advisors from local institutions: Dr. Sadagopan Krishnan and Dr. Barry K. Lavine from Oklahoma State University and Dr. Gabriel LeBlanc from the University of Tulsa. The chapter participated in National Lab Day 2017, a nationwide initiative to foster ongoing collaboration among volunteers, students, and educators. The chapter demonstrated single-drop electrochemical analysis at the event. This year, to expand the chapter membership, the new executive committee organized an orientation and membership recruitment session on April 2, 2018, at Oklahoma State University. The president of the chapter, Gayan Premaratne, presented an overview of ECS, details on student chapters, and the benefits associated with ECS membership. Plans were also discussed on the activities to be conducted for the fiscal year to improve intellectual and professional development of the members. The chapter aims to hold monthly chalkboard talks, an invited seminar on a focused area of electrochemistry, and live electrochemistry demonstrations at public events in Oklahoma. The event recruited 12 enthusiastic graduate students who are driven to be involved in the activities of ECS and learn insights on electrochemistry.
Executive committee of the ECS Oklahoma Student Chapter (left to right): Gayan Premaratne, president, Isio Sota-Uba, secretary, Zainab Al Mubarak, vice president, and Jinesh Niroula, treasurer.
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ST UDENT NE WS Lewis University Student Chapter Throughout the 2017 fall and 2018 spring semesters, the ECS Lewis University Student Chapter traveled and hosted demonstrations and community outreach events at various high schools, elementary schools, and community centers to promote STEM awareness. The demos allowed students and members of the community of all backgrounds, ages, and interest levels to participate in handson activities and learn about concepts such as polymerization, metal complexation, and surfactant interactions. These events truly stimulate an interest in science among students and parents due to their applications in everyday life. The chapter hosted its first annual water filtration competition, called Shipwrecked, which allowed students from community high schools to remediate synthetic wastewater. Students had the ability to improve skills in critical thinking, problem solving, and team building. Water quality specialists came to judge the competition, evaluating the designs based on innovation, efficiency, and repeatability. An Elkay-sponsored water filtration system was presented to the winning school of the competition.
Furthermore, in order to give back to the community, the chapter hosted its first Pedal for Pi-Day event, called Pedal for Preemies. In honor of the Lewis University volleyball coach’s premature daughter, a stationary bike was pedaled over the course of 26 hours by volunteers, resulting in a total of 939,574 revolutions of pis generated by the rotation of the bike wheel. Donations amounting to a total of $5,000 were raised and presented to the Loyola neonatal intensive care unit. This event brought math and science together while also emphasizing the importance of giving back to the community. In addition to participating in community outreach, members have had the opportunity to present their work at numerous conferences, such as the Lewis University Celebration of Scholarship Symposium, an ECS meeting, the American Chemical Society Regional Conference, and the Associated Colleges of the Chicago Area Symposium. In the coming semesters, the chapter is looking forward to hosting more community outreach events, offering tutoring hours, and continuing to promote STEM.
The ECS Lewis University Student Chapter at the White Oak Library STEM Fest on March 3, 2018.
Look Out!
We want to hear from you! Students are an important part of the ECS family and the future of the electrochemistry and solid state science community . . .
Send your news and a few good pictures to Shannon Reed, director of membership services, at Shannon.Reed@electrochem.org. We’ll spread the word around the Society. Plus, your student chapter may also be featured in an upcoming issue of Interface!
www.electrochem.org/student-center 96
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
ST UDENT NE WS Norwegian University of Science and Technology Student Chapter The ECS Norwegian University of Science and Technology Student Chapter in Trondheim, Norway, is always looking to recruit new members. On March 1, 2018, the student chapter held a recruitment seminar inviting both students looking for a master’s
thesis project as well as those currently writing their thesis. After a variety of presentations on different topics related to electrochemistry, the lively discussion was continued over dinner with professors dazzling the minds of young, enthusiastic prospective researchers.
Kristian Thorbjørnsen presented on the electrochemical energy group.
Henning Kaland presented on the battery group.
Ohio University Student Chapter On March 6, 2018, the ECS Ohio University Student Chapter organized an outreach event for the Margaret Boyd Scholars of Ohio University. The event allowed 20 undergraduate students to visit the Center for Electrochemical Engineering Research over two days to become familiar with highlighted research going on in the center, such as ammonia synthesis, ammonia and urea electrolysis for wastewater
treatment, coal electrolysis, lithium-ion batteries, and transmission electron microscopy and its application in electrochemistry and fuel cell technology. At the end of the outreach program, the students were trained to run fuel cell cars that operated on hydrogen fuel cells. (continued on next page)
Members of the ECS Ohio University Student Chapter with the Margaret Boyd Scholars of Ohio University and Dr. Gerardine Botte (front row, second from right). The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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They also had the opportunity to race their cars a calculated distance. The students shared their thoughts with Dr. Gerardine Botte on how this outreach caught their attention and how useful electrochemistry can be in real world. The outreach also provided chapter members an opportunity to mentor and teach young minds and support science education in schools around the country. On April 2, 2018, the chapter hosted Dr. Viola Birss, professor of chemistry at the University of Calgary, Canada. Dr. Birss graciously accepted the chapter’s invitation and presented a talk during the Russ College of Engineering’s weekly chemical and biomolecular engineering seminar. The audience was a mixture of undergraduate
students, graduate students, and faculty. The title of the lecture was “Novel Electrode and Catalyst Support Materials for Reversible Fuel Cell Applications.” Dr. Birss joined the chapter committee over lunch for an informal discussion in which she imparted her cognizance in electrochemistry. Later that evening, Dr. Birss joined the members of CEER, other students from the Department of Chemical and Biomolecular Engineering, and students from the Department of Chemistry for a friendly discussion session, which centered mostly upon her experiences as well as future career options in the field of electrochemistry, and provided members new perspectives on the field.
From left to right: Mehrdad Abbasi, Ali Yazdani, Ashwin Ramanujam, Alamgir Haque, Dr. Madhivanan Muthuvel, Dr. Gerardine Botte, Bertnard Neyhause, Dr. Viola Birss, Benjamin Sheets, Behnaz Jafari, Amy Linderberger, Raziyeh Ghahremani, Payman Sharifi, Bahareh Baheri, Andrew Kasick, Xiang Lyu, and Mohiedin Bagheri.
University of Iowa Student Chapter In the months leading up to April 8, 2018, members of the ECS University of Iowa Student Chapter worked collaboratively with faculty from the Chemistry Department and the School of Music at the University of Iowa to develop the chemical element of a musical production titled Musical Chemistry orchestrated by Prof. Jean-François Charles. This project allowed members to bridge the gap between the physical sciences and fine arts. The production featured a water clock, rijke tubes, a soxhlet extraction, several chemiluminescent reactions, and fluorescent compounds. The chapter was happy to work as chemical consultants in regard to what reactions would work and the chemical safety required. In the end, luminol and fluorescein prevailed as the primary sources of chemiluminescence and fluorescence under UV light. Members of the chapter also hosted chemical demonstrations prior to the show on April 8, demonstrating how common household items (e.g., tonic water, detergent, etc.) have additives that cause them to fluoresce under UV light. In addition to working as consultants and doing demonstrations prior to the show, members assisted in writing the show’s program, which included information on the physics and chemistry observed in the show. The club worked to make the information accessible to the general public in order to spread the joys of chemistry. 98
From left to right: Sidney DeBie, Michaella Raglione, Daniel Parr, and Kasun Dadallagei with the water clock used in the Musical Chemistry production at the University of Iowa. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
ST UDENT NE WS University of Kentucky Student Chapter The ECS University of Kentucky Student Chapter hosted Prof. Martin Maldovan from Georgia Institute of Technology on March 30, 2018. His seminar titled “New Approaches for Thermal Transport Control in Nanomaterials and Metamaterials” gave insights into manipulations of thermal energy transfer using wave interference and thermal band gaps. Prof. Maldovan also visited Prof. Y. T. Cheng’s
Energy, Nanomechanics, and Surfaces Research Laboratory at the University of Kentucky and discussed energy-related topics with the group. Prof. Maldovan’s seminar was a campus-wide event attended by faculty and students from both the College of Engineering and the College of Arts & Sciences at the University of Kentucky.
University of Texas at Austin Student Chapter The ECS University of Texas at Austin Student Chapter hosted two chalk talks for the 2017-2018 academic year. The first talk, on October 26, 2017, was presented by Dr. Charuksha Walgama, who discussed “Voltage Driven Drug Metabolism by Wired Human Liver Enzyme.” In the talk, he explored how electrochemistry can be used in biocatalysts to have drugs react with liver cells to produce metabolites. The second talk was presented on March 2, 2018, by Matthew Boyer, who is a fourth-year PhD candidate in the McKetta Department of Chemical Engineering. He presented his talk on “A Computational Approach to Li-ion Battery Interfaces,” which elucidated SEI layer Li-ion transport characteristics through modeling of ethyl carbonate and diethyl carbonate SEI layers on electrodes.
On March 3, 2018, the chapter participated in the annual Explore UT event, where students, parents, teachers, and community members from across Texas come to participate and learn about research happening at UT Austin. Explore UT seeks to get the community interested in education and motivate them to pursue higher education. The chapter discussed the science behind clean energy by demonstrating a fuel cell car and modeling layered Li-ion battery structures in cell phones and electric vehicles. The chapter looks forward to continuing these activities and hopes to expand its involvement inside and outside the university while planning potential collaborations with other student chapters.
University of Washington Student Chapter During its winter quarter proceedings, the ECS University of Washington Student Chapter focused on supporting the holistic development of its student members. Specifically, the chapter organized several opportunities for students to expand their understanding of the foundations of electrochemistry, engage in community outreach, and learn skills relevant to their professional development. To foster academic growth, senior members organized and led various educational seminars. First, an Introduction to Electrochemistry series aimed at new members explored the field’s foundations. This spanned the topics of thermodynamics, kinetics, transport, and a formal discussion of electrostatic effects in electrochemical cells. Second, a series of short talks highlighted technologies influenced by electrochemistry, including simulations of neural interfaces, water purification, and the processing of rare earth ores. Third, a survey of characterization techniques began with presentations on cyclic voltammetry and electrochemical impedance spectroscopy. Following this theme, talks on electron microscopies and X-ray absorption spectroscopies are scheduled for later in the spring. In addition to the student-led events, the chapter continued its Coffee Talk series with visiting faculty on December 4, 2017, by welcoming Prof. Elizabeth J. Biddinger from the City College of New York. Prof. Biddinger communicated some of her past and present research, suggested several useful electrochemistry resources for the annual Coffee & Electrochemistry book series the chapter hosts each summer, and facilitated a discussion regarding opportunities for community involvement. The meeting summary can be found on the chapter’s official website. On December 14, 2017, the chapter hosted a workshop geared toward helping students establish an online presence by creating and maintaining websites showcasing their professional achievements. The event was led by Neal Dawson-Elli, an ECS@UW member, and reached over 30 individuals, including nonmembers not in regular attendance. Discussions for a second installment are underway. Another professional development event, the chapter’s annual
Industry Panel, is scheduled for this spring. Last year’s inaugural Industry Panel was a huge success, connecting over 50 graduate students with panelists from Boeing, UniEnergy Technologies, PolyDrop, Intellectual Ventures Labs, and Microsoft. This winter, the chapter participated in the 6th Annual Enumclaw Interactive STEM Expo hosted by the Enumclaw School District and the Enumclaw Schools Foundation. Each year, the event draws volunteers from myriad technology organizations to provide a truly unique experience for the local youth. The expo involved over 70 exhibits, each with an engaging demonstration of science specific to the host organization’s expertise. The chapter elected to present the popular hand battery experiment (as outlined by the Royal Society of Chemistry), an endeavor that proved highly successful. In this (continued on next page)
ECS volunteers at the Enumclaw Interactive STEM Expo (left to right): Linnette Teo, Erica Eggleton, Keith Steele, and Evan Jahrman.
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ST UDENT NE WS (continued from previous page)
demonstration, participants were invited to form a mock battery by placing each of their hands on two dissimilar metals connected by an ammeter. The experiment not only permitted aspiring scientists to investigate variations on the basic premise, but initiated several fun, organic moments such as family members linking hands to increase the resistance in the circuit. The event served as an exciting opportunity to engage with children and present science in a positive light.
The chapter is committed to continuing this theme of civic outreach and will participate in next quarter’s UW Discovery Days, in which the chapter traditionally features an electrodeposition experiment, Enginearrings, which reached more than 800 K-12 students last year.
ECS University of Washington Student Chapter members with Prof. Elizabeth J. Biddinger (fifth from right) from the City College of New York following an installment of the chapter’s Coffee Talk series.
University of Maryland Student Chapter On April 14, 2018, the ECS University of Maryland Student Chapter gathered at the National Mall in Washington, DC, for the second annual March for Science. With science skeptics holding high-up positions in government, it is important for scientists, engineers, and STEM advocates to urge evidence-based policy. Last spring, tens of thousands of scientists and engineers marched because government agencies such as the Department of Energy and the Environmental Protection Agency were being threatened by major budget cuts and complete abolishment, respectively. This year, many government agencies are still being threatened; this could hamper numerous funding opportunities, including those for electrochemical and solid state sciences. By participating in the March for Science, the chapter hopes to support and publicize evidence-based studies and to improve scientific literacy and policy in the United States.
The ECS University of Maryland Student Chapter participated in the second annual March for Science in Washington, DC. Griffin Godbey (left), vice president, and Steven Lacey (right), president, showed their support near the main stage with #FreetheScience T-shirts and a handmade sign.
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ST UDENT NE WS University of Virginia Student Chapter The ECS University of Virginia Student Chapter organized a seminar given by Dr. David Green on March 2, 2018. His seminar “Development of Experiment and Theory to Detect, Predict, and Visualize Ligand Phase Separation on Metal Nanoparticles” introduced a way to drive vital innovation in the realm of nanoparticle surface engineering, which has applications in a broad range of fields, including personalized medicine and energy conversion. The seminar was attended by faculty and students from the Department of Materials Science and Engineering, the Department of Chemical Engineering, as well as the Department of Chemistry. The chapter will continue to support ECS in promoting quick and efficient ways for students to learn and exchange information in the field of electrochemistry, as well as in reaching out to and benefiting the community in Charlottesville, VA.
Dr. David Green provided a seminar that was hosted by the ECS University of Virginia Student Chapter.
The volunteers from the NanoDays outreach to Murray Elementary School in Charlottesville, VA (left to right): Hongxu Dong, Chao Liu, Wade Jensen, Will Blade, Prof. Jerry Floro, Nate Kabat, Jonathan Skelton, and Katie Lutton.
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ECS STUDENT PROGRAMS Awarded Student Membership
Student Chapter Membership
Our divisions offer free memberships to full-time students.You can re-apply to receive an awarded student membership for up to four years!
Apply for a free student membership for those involved in active ECS student chapters.You must apply or re-apply each year for a student chapter membership.
Check out www.electrochem.org/student-center for qualifications! Biannual Meeting Travel Grants Many ECS divisions offer funding to undergraduates, graduate students, postdocs, and young professionals that are presenting research at ECS biannual meetings.
Make the Connection The ECS Career Expo gives students the opportunity to meet with interested employers and advance their job search with various career services.
Visit www.electrochem.org/travel-grants to learn more!
More information at www.electrochem.org/career-expo.
Summer Fellowships
Enhance Your Resume
Apply for a $5,000 summer fellowship with ECS! The annual deadline for applications is January 15. Review candidate qualifications at www.electrochem.org/summer-fellowships.
Student Chapters
ECS equips our student members to be successful when starting their careers. The professional development workshops provide attendees with skills not often learned in the classroom. View offerings on www.electrochem.org/education.
There are more than 75 student chapters worldwide. ECS offers funding to support chapter events! Find the guidelines for starting a student chapter at www.electrochem.org/student-center.
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Call for Papers
235th ECS Meeting May 26-May 31, 2019
Dallas, TX
Sheraton Dallas
Abstract Submission Deadline: Friday, December 14, 2018 For more information, please contact Abstracts@electrochem.org
Meeting Information General Information
The 235th ECS Meeting will be held in Dallas, Texas, USA from May 26-31, 2019 at the Sheraton Dallas Hotel. This international conference will bring together scientists, engineers, and researchers from academia, industry, and government laboratories to share results and discuss issues on related topics through a variety of formats, such as oral presentations, poster sessions, panel discussions, tutorial sessions, short courses, professional development workshops, a career fair, and exhibits. The unique blend of electrochemical and solid state science and technology at an ECS Meeting provides an opportunity and forum to learn and exchange information on the latest scientific and technical developments in a variety of interdisciplinary areas.
Abstract Submission
To give an oral or poster presentation at the 235th ECS Meeting, you must submit an original meeting abstract for consideration via the ECS website, https://ecs.confex. com/ecs/235/cfp.cgi no later than December 14, 2018. Faxed, e-mailed, and/or late abstracts will not be accepted. Meeting abstracts should explicitly state objectives, new results, and conclusions or significance of the work. Once the submission deadline has passed, the symposium organizers will evaluate all abstracts for content and relevance to the symposium topic, and will schedule all acceptable submissions as either oral or poster presentations. In February 2019, Letters of Acceptance/Invitation will be sent via email to the corresponding author of all accepted abstracts, notifying them of the date, time, and location of their presentation. Regardless of whether you requested a poster or an oral presentation, it is the symposium organizers’ discretion to decide how and when it is scheduled. For abstract submission questions, contact abstracts@ electrochem.org.
Paper Presentation
Oral presentations must be in English; LCD projectors and laptops will be provided for all oral presentations. Presenting authors MUST bring their presentation on a USB flash drive to be used with the dedicated laptop that will be in each technical session room. Speakers requiring additional equipment must make written request to meetings@electrochem.org at least one month prior to the meeting so that appropriate arrangements may be worked out, subject to availability, and at the expense of the author. Poster presentations must be displayed in English, on a board approximately 3 feet 10 inches high by 3 feet 10 inches wide (1.17 meters high by 1.17 meters wide), corresponding to their abstract number and day of presentation in the final program.
Meeting Publications
ECS Meeting Abstracts—All meeting abstracts will be published in the ECS Digital Library (www.ecsdl.org), copyrighted by ECS, and all abstracts become the property of ECS upon presentation. ECS Transactions— Select symposia will be publishing their proceedings in ECS Transactions (ECST). Authors presenting in these symposia are strongly encouraged to submit a full-text manuscript based on their presentation. Issues of ECST will be available for sale at the meeting, through the ECS Digital Library, and through the ECS Online Store. Please see each individual symposium listing in this Call for Papers to determine if your symposium will be publishing an ECST issue. Please visit the ECST website (www.ecst.ecsdl.org) for additional information, including overall guidelines, author and editor instructions, a downloadable manuscript template, and more. ECSarXiv – All authors are encouraged to submit their full-text manuscripts, posters, slides, or data sets to ECS’s new preprint service, ECSarXiv. For more information on this new offering, please visit http://www.electrochem.org/ecsarxiv. Please note that submission to ECSarXiv does not preclude submission to ECST or ECS Journals. ECS Journals–Authors presenting papers at ECS meetings, and submitting to ECST or ECSarXiv, are also encouraged to submit to the Society’s technical journals: Journal of The Electrochemical Society and ECS Journal of Solid State Science and Technology. Although there is no hard deadline for the submission of these papers, it is considered that six months from the date of the symposium is sufficient time to revise a paper to meet the stricter criteria of the journals. Author instructions are available from http://www.electrochem.org/submit.
Short Courses
Three short courses will be offered on Sunday, May 26, 2019 from 0900-1630h. Short courses require advanced registration and may be cancelled if enrollment is under 10 registrants in the respective course. The following short courses are scheduled: 1) Advanced Impedance Spectroscopy, 2) Fundamentals of Electrochemistry: Basic Theory and Thermodynamic Methods and 3) Lithium-Ion Battery Safety and Reliability Analysis. Registration opens February 2019.
Technical Exhibit
The 235th ECS Meeting will include a Technical Exhibit, featuring presentations and displays by dozens of manufacturers of instruments, materials, systems, publications, and software of interest to meeting attendees. Coffee breaks are scheduled in the exhibit hall along with evening poster sessions. Interested in exhibiting at the meeting with your company? Exhibitor opportunities include unparalleled benefits and provide an extraordinary chance to present your scientific products and services to key constituents from around the world. Exhibit opportunities can be combined with sponsorship items and are customized to suit your needs. Please contact sponsorship@electrochem.org for further details.
Meeting Registration
All participants—including presenters and invited speakers—are required to pay the appropriate registration fees. Hotel and meeting registration information will be posted on the ECS website as it becomes available. The deadline for discounted early-bird registration is April 22, 2019.
Hotel Reservations
The 235th ECS Meeting will be held at the Sheraton Dallas Hotel. Please refer to the meeting website for the most up-to date information on hotel availability and information about the blocks of rooms where special rates have been reserved for participants attending the meeting. The hotel block will be open until April 22, 2019 or until it sells out.
Letter of Invitation
In February 2019, Letters of Invitation will be sent via email to the corresponding author of all accepted abstracts, notifying them of the date, time, and location of their presentation. Anyone else requiring an official letter of invitation should email abstracts@electrochem.org; such letters will not imply any financial responsibility of ECS.
Financial Assistance
ECS divisions and sections offer travel grants to students, postdoctoral researchers, and young professionals to attend ECS biannual meetings. Applications are available beginning November 1, 2019 at www.electrochem.org/travel-grants and must be received no later than the submission deadline of Monday, February 25, 2019. Additional financial assistance is very limited and generally governed by symposium organizers. Individuals may inquire directly to organizers of the symposium in which they are presenting to see if funding is available. For general travel grant questions, please contact travelgrant@electrochem.org.
Sponsorship Opportunities
ECS biannual meetings offer a wonderful opportunity to market your organization through sponsorship. Sponsorship allows exposure to key industry decision makers, the development of collaborative partnerships, and potential business leads. ECS welcomes support in the form of general sponsorship at various levels. Sponsors will be recognized by level in the Meeting Program, meeting signage, and on the ECS website. In addition, sponsorships are available for the plenary, meeting keepsakes and other special events. In addition, ECS offers specific symposium sponsorship. By sponsoring a symposium your company can help offset travel expenses, registration fees, complimentary proceedings, and/or host receptions for invited speakers, researchers, and students. Advertising opportunities for the Meeting Program as well as in Interface magazine are also available. Please contact sponsorship@ electrochem.org for further details.
Contact Information If you have any questions or require additional information, contact ECS. 104
The Electrochemical Society 65 South Main Street, Pennington, NJ, 08534-2839, USA tel: 1.609.737.1902, fax: 1.609.737.2743 meetings@electrochem.org
www.electrochem.org Call for Papers • 235th ECS Meeting • DALLAS, TX May 26-31, 2019 • www.electrochem.org
Symposium Topics & Deadlines A— Batteries and Energy Storage
A01— Battery and Energy Technology Joint General Session A02— Lithium Ion Batteries and Beyond A03— Large Scale Energy Storage 10 A04— Battery Student Slam 3 A05— Battery Characterization A06— Battery Safety and Failure Modes B— Carbon Nanostructures and Devices
K— Organic and Bioelectrochemistry K01— Bioelectrochemistry: From Nature-Inspired Electrochemical Systems to Electrochemical Biosensors K02— Electron-Transfer Activation in Organic and Biological Systems K03— Young Investigators in Organic and Biological Electrochemistry L— Physical and Analytical Electrochemistry, Electrocatalysis, and Photoelectrochemistry L01— Physical and Analytical Electrochemistry, Electrocatalysis, and Photoelectrochemistry General Session and Grahame Award Symposium
B01— Carbon Nanostructures for Energy Conversion and Storage
L02— Impedance Technologies, Diagnostics, and Sensing Applications 5
B02— Carbon Nanostructures in Medicine and Biology
L03— Computational Electrochemistry 5
B03— Carbon Nanotubes - From Fundamentals to Devices
L04— Polyoxometallates and Nanostructured Metal Oxides in Efficient Electrocatalysis, Energy Conversion, and Charge Storage
B04— Nano in Latin America B05— Fullerenes - Endohedral Fullerenes and Molecular Carbon B06— 2D Layered Materials from Fundamental Science to Applications
L05— Spectroelectrochemistry 4 L06— Supramolecular Materials M— Sensors
B07— Light Energy Conversion with Metal Halide Perovskites, Semiconductor Nanostructures, and Inorganic/Organic Hybrid Materials
M01— Sensors, Actuators, and Microsystems General Session
B08— Porphyrins, Phthalocyanines, and Supramolecular Assemblies
M02— Semiconductor Electrochemistry and Photoelectrochemistry in Honor of Krishnan Rajeshwar
B09— Nano for Industry C— Corrosion Science and Technology
C01— Corrosion General Session D— Dielectric Science and Materials
D01— Chemical Mechanical Polishing 15 D02— Low Cost Photovoltaic Materials and Devices for Clean Energy
M03— Sensors for Precision Medicine Z— General Z01— General Student Poster Session Z02— Sustainable Materials and Manufacturing 3 Z03— Nanoscale Electrochemical Imaging and Detection
E— Electrochemical/Electroless Deposition
E01— Electrodeposition for Advanced Node Interconnect Metallization Beyond Copper F— Electrochemical Engineering
F01— Industrial Electrochemistry and Electrochemical Engineering General Session F02— Tutorial on Industrial Electrochemistry F03— Characterization of Porous Materials 8 F04— Multiscale Modeling, Simulation and Design 3: Enhancing Understanding, and Extracting Knowledge from Data G— Electronic Materials and Processing
G01— Silicon Compatible Emerging Materials, Processes, and Technologies for Advanced CMOS and Post-CMOS Applications 9 G02— Processes at the Semiconductor Solution Interface 8 G03— Organic Semiconductor Materials, Devices, and Processing 7 H— Electronic and Photonic Devices and Systems
H01— Wide Bandgap Semiconductor Materials and Devices 20 H02— Solid-state Electronics and Photonics in Biology and Medicine 6 H03— Wearable and Flexible Electronic and Photonic Technologies 2 I— Fuel Cells, Electrolyzers, and Energy Conversion I01— Hydrogen or Oxygen Evolution Catalysis for Water Electrolysis 5 I02— Materials for Low Temperature Electrochemical Systems 5
Important Dates and Deadlines Meeting Abstract submission opens..............................................August 2018 Meeting Abstracts submission deadline............................December 14, 2018 Notification to Corresponding Authors of abstract acceptance or rejection..................................... February 11, 2019 Technical Program published online.......................................... February 2019 Meeting registration opens........................................................ February 2019 ECS Transactions submission site opens for enhanced issues.............................................................. February 15, 2019 Travel Grant application deadline........................................ February 25, 2019 ECS Transactions submission deadline for enhanced issues.................................................................. March 15, 2019 Meeting Sponsor and Exhibitor deadline (for inclusion in printed materials)........................................... March 15, 2019 Travel Grant approval notification.............................................. March 8, 2019 Hotel and Early Bird meeting registration deadlines.................. April 22, 2019 Release date for ECST enhanced issues.......................................May 17, 2019 235th ECS Meeting – Dallas, TX............................................. May 26-31, 2019
I03— Renewable Fuels via Artificial Photosynthesis or Heterocatalysis 4 I04— Energy Conversion Systems Based on Nitrogen 2 I05— Heterogeneous Functional Materials for Energy Conversion and Storage 2 I06— An Invited Symposium on Advances and Perspectives on Modern Polymer Electrolyte Fuel Cells – In Honor of Shimshon Gottesfeld
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Why Join ECS? ViSibility Involved members get noticed! Join a committee and enhance your leadership skills.
It’s not just who you know, it’s who others know! Networking is powerful!
$
DiSCountS
GroWth
Members receive exclusive pricing on meeting registrations, publications, and professional development opportunities.
Educational programming is growing to support our membership.
CrEDibility Formed in 1902 – become a part of this highly respected community.
nEtWork
CarEEr Utilize the ECS network to advance your career!
“Our community is more than just academics and subject matter. It’s family.” – Jim Fenton, Secretary of The Electrochemical Society
Join online: www.electrochem.org/join The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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2017
Annual Report
“The ECS community is a place to go when you have that question that you can’t get an answer to.” Johna Leddy ECS president 2017-2018
Get the latest ECS news at www.electrochem.org
Discover Your Community “No one interested in electrochemistry can belong to such a society and participate in its work, without receiving from it many times more than the small share he contributes.” – Joseph Richards, first Society president
I
n 2017, ECS celebrated its 115th anniversary. Over a century ago, our founders set out to create a place where researchers could discover their community. We recalled the principles expressed by Joseph Richards, the Society’s first president, in the introduction to the Society’s first meeting Transactions. Richards wanted to bring electrochemists into personal contact with each other, disseminate the research, stimulate original thought and discussions, and encourage electrochemical work worldwide “by publishing the news of what is being done here.” It is a great matter of pride to say ECS has been vigorously carrying out this mission for 115 years. We will continue to advocate for our community and its work for years to come by supporting the next generation of scientists and publishing highquality peer-reviewed research with broad implications for fundamental science, advanced technologies, energy, and sustainability. We had great success in 2017. Published ECS journal articles now number over 50,000. The ECS Digital Library has grown to contain over 141,000 articles and abstracts. New member and student member applications are on the rise, and we added a new section in Singapore, our first new section in over 20 years. The Society fully embraced open science by sponsoring events like OpenCon and ECS Data Sciences Hack Day.We are proud to report that more than 35% of the ECS journal articles published since 2014 were published open access after critical review. And we know that open access enhances visibility and citation of ECS content. In August of 2017, coauthor of this letter and ECS Executive Director Roque Calvo established an agreement with the ECS Board of Directors to conclude his time with the Society. Roque has served as an outstanding steward of the Society for over 37 years, advancing the Society through revolutionary upheaval in publications and communications technologies as well as effectively managing the rampant growth and interest in electrochemical and solid state science and technology. Roque took the Society from print to digital, created an international audience for its programs and meetings, promoted open science, expanded the ECS Honors & Awards program, and encouraged student participation by instituting student chapters and adding more travel grants and fellowships. The Society, its members, and the other coauthor of this letter applaud Roque for his outstanding contributions and unwavering commitment to advance The Electrochemical Society and its mission. In honor of Roque’s devotion to ECS, the Society has established the Roque Calvo Next Generation Scholarship Fund, which is dedicated to provide students and early-career researchers opportunity to participate in biannual ECS meetings. Learn more about the fund and make a donation in honor of Roque at www.electrochem.org/next-gen.
Roque J. Calvo ECS Executive Director & CEO http://orcid.org/0000-0002-1746-8668
Johna Leddy President 2017-2018 https://orcid.org/0000-0001-8373-0452
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Publications
T
he enduring success of ECS publications is the result of dynamic, concentrated efforts in content procurement, dissemination, and enhancement. In 2017, these efforts elevated ECS publications to new heights. The year 2017 saw ECS take huge strides in the areas of content acquisition and dissemination. • From 2016 to 2017, the total number of journal articles published increased 16.7%. • In 2017, the total amount of published journal articles surpassed 50,000. By the year’s end, over 35% of the journal content published since 2014 was open access. • By the conclusion of 2017, the ECS Digital Library contained over 141,000 articles and abstracts. • The year 2017 was record-setting in terms of content access; over 3.5M articles and abstracts were downloaded. • Announced in 2017, the 2016 journal impact factors for the Journal of The Electrochemical Society and the ECS Journal of Solid State Science and Technology both rose 8% (JES: 3.259, JSS: 1.787). JES ranked #2 in Materials Science, Coatings and Films and #9 in Electrochemistry with a cited half-life of greater than 10 years—the highest value awarded by Journal Citation Reports.
Over
35%
open access journal content published since 2014
These accomplishments are owed in large part to the strength of ECS subscriptions, which remain the predominate method for dissemination of Society research. They are also products of ECS’s continual efforts to expand and enhance the influence of its publications, which in 2017 included participation in the Society’s first-ever Free the Science Week, International Open Access Week 2017, and endeavors to refine the journal manuscript submission system.
Over
141,000 articles and abstracts ECS Digital Library total content
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Over 50,000
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Meetings 4,262
attendees at the 2017 biannual meetings
T
hough it is doubtful that our founders ever envisioned that 115 years of ECS meetings lay ahead, we did our best to honor their legacy in 2017 with gatherings around the world! For the 231st ECS Meeting, almost 2,000 attendees convened in New Orleans, LA, in order to meet, connect, present, and learn. They took part in the technical presentations, exhibits, short courses, and the plenary by Way Kuo, president of the City University of Hong Kong. The 232nd ECS Meeting was in National Harbor, MD. Over 2,400 delegates converged near the nation’s capital for a week of presentations, networking, and professional development. In addition to a plenary talk by Nobel Prize winner Steven Chu, ECS held the 7th International Electrochemical Energy Summit, consisting of the symposia Energy-Water Nexus, The Brain and Electrochemistry, and Sensors for Food Safety, Quality, and Security. In July, ECS ran the 15th International Symposium on Solid Oxide Fuel Cells in Hollywood, FL. Attendees heard over 400 talks, attended an afternoon workshop on SOFC use in data centers and other embedded energy applications, and kicked up their heels at the traditional banquet! Also in July, ECS co-organized the First International Semiconductor Conference for Global Challenges with the Chinese Physical Society, where 84 speakers gathered in Nanjing, China, to discuss how semiconductor technology can help address global challenges. Finally, in December, ECS co-organized a joint symposium on Electrochemistry for Energy and the Environment (ECEE) in Shanghai, China, with the Chinese Electrochemical Society, where 40 leading researchers gave talks in the areas of batteries, fuel cells, and CO2 reduction. Though we may not know where the next 115 years will take us, you can be sure we’ll be looking for a space to hold a meeting!
43%
first time attendees at the 2017 biannual meetings
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4,459
presentations at the 2017 biannual meetings
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Membership & Education
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n 2017, the Society experienced a 7.6% increase in new member and student member applications. The increase in membership applications is attributed to the new online membership wizard launched in 2017. This feature allows people to join ECS instantly. ECS provided almost $56,000 in biannual meeting travel grants through division funding in 2017. More than 300 travel grant applications were received. ECS divisions approved 44% of the biannual meeting travel grant applicants. Student chapters continue to experience growth. In all, five new student chapters were chartered, bringing the number of student chapters to 69 worldwide. The Society also charted a new section in 2017—the ECS Singapore Section. This is the first new section in almost 20 years. ECS and the Toyota Research Institute of North America renewed their partnership agreement for the ECS Toyota Young Investigator Fellowship that supports young researchers working in the area of green energy technology. Since 2014, nine recipients were awarded $495,144 through the Toyota Young Investigator Fellowship; this includes the $150,000 awarded to three recipients in 2017. ECS also offered four new professional development workshops at the 2017 biannual meetings. Education and professional development remain a focus in equipping our members with the tools they desire to succeed.
$150,000 awarded for three ECS Toyota Young Investigator Fellowships
$20,000 awarded for four ECS summer fellowships
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8,202
members
2,574
student members
7.6%
increase in new membership applications
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Honors & Awards “The encouragement from ECS is like a light on the academic path for me and other young scholars.” -Peng Sun, winner of the ECS Bruce Deal & Andy Grove Young Author Award
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his is the story of a category of the ECS Honors & Awards program that is a big deal, but goes under the radar. Allow us to explain. ECS young author awards are quite special as they are the only two among the 50-plus within the recognition program that are based specifically on the quality of articles that were published in ECS journals. As the second-oldest Society award, the ECS Norman Hackerman Young Author Award was established in 1928 and acknowledges the best paper published in the Journal of The Electrochemical Society by a young author or young coauthors. When the Society initiated the ECS Journal of Solid State Science and Technology, it created the Bruce Deal & Andy Grove Young Author Award to follow form. For both awards, Peng Sun, postdoctoral research fellow at the University of Michigan, receives the ECS Bruce Deal & Andy Grove Young Author Award from ECS President there is a rigorous review process of articles that Johna Leddy. were published in the preceding volume year. The reward is lucrative: a hefty cash prize and travel stipend to attend the ECS biannual meeting for recognition. Winning our young author awards proves to be a precursor to great careers in our sciences, both professionally and as volunteers in our Society’s history.Winners have included past presidents such as Larry Faulkner, Barry MacDougall, and legends Stanley Whittingham and John Newman. So congratulations to those who were recognized as amazing young authors and scientists in 2017 as we acknowledge that this is just the beginning of great things to come!
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Open Science “Open science is building openness from the beginning and having an environment that fosters collaboration, so you have open notebooks and open data. It promotes equity among scientists and really supports collaboration.” — Ashley Farley, open access program associate at the Bill & Melinda Gates Foundation, during ECS OpenCon
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he Free the Science initiative aims to move ECS toward an open science model that creates greater transparency from research design to sharing data and conclusions. ECS firmly believes that more sharing means more progress, because more minds will discover information to help move technology and solutions forward. To give the ECS community even more exposure to open science, ECS hosted its first-ever satellite OpenCon event during the ECS fall meeting. This event—the first from a scholarly society—featured the leading vocal advocates in the open science movement. The event examined the intersection of advances in research infrastructure, the researcher experience, funder mandates and policies, as well as the global shift that is happening in traditional scholarly communications. The Society’s first foray into building a data sciences and open source community for electrochemistry and solid state science took place at the ECS fall meeting, with the ECS Data Sciences Hack Day. Dataset sharing and open source software have transformed many big data areas such as astronomy, particle physics, synchrotron science, protein and genomic sciences, as well as computational sciences. There is a fast-growing demand for turning big data into actionable information. In the open access arena, efforts continued in 2017 to build support for more openness in ECS content, and opening up citations is one way to make content more accessible. ECS has joined the Initiative for Open Citations and is now making the references in its journal articles completely open. The ECS Plus program, a subscription plan that includes access to the entire ECS Digital Library plus unlimited article credits, continued to grow, and by the end of 2017, there were 27 libraries and consortia that took advantage of this opportunity, almost double the 2016 number. For the third year, ECS opened up the entire ECS Digital Library for International Open Access Week. ECS also promoted the power of openness during Free the Science Week in April. During these weeks, content from the ECS Digital Library was downloaded 32% more than the average amount downloaded in other months when the content was closed.
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Donors hank you to all the individuals and organizations that made either unrestricted or program gifts to ECS during 2017. With their support ECS is able to honor leaders in its fields, support travel grants, create innovative programs, and build the Free the Science fund.
Special thanks Scribner Associates U.S. Bank Foundation Houston Endowment, Inc. University of Virginia Toyota Research Institute of North America Thanks to all of our 2017 individual donors. Kuzhikalail M. Abraham James C. Acheson Shiva Adireddy Radoslav Adzic Iain M. Aldous Mark D. Allendorf Khalil Amine John C. Angus Casey Annunziata Randall Blair Archer Craig B Arnold Marcelle Austin Ahmad Shawqi Barham Daniel Bauza Susan Beatty Valerie Bertagna Judith Maja Biedermann Thomas J. Blakley Christina Bock** Charles Boyer Gessie Brisard William D. Brown Glen M. Brown Declan Bryans Rudolph G. Buchheit D. Noel Buckley James D. Burgess Keith T. Burnette George L. Cahen, Jr. Roque J. Calvo** On Chang
Graham T. Cheek** Giovanni Pietro Chiavarotti Kalairaja Chitharanjan Karen Chmielewski David E. Cliffel* Edward L Colvin Emanuel I. Cooper Patricia Gon Corradini Beth Craanen Stephen E. Creager Amantay Dalbanbay Ghazwan Darzi Craig Davidson Ahmed Debela Johan Deconinck Lili Deligianni Howard D. Dewald George A. Dibari Daniel Mark Dobkin Marca M. Doeff Jesse S Dondapati Ray J. Donohoe Wei-Ping Dow James Earthman Karen Eggers John F. Elter Darell E. Engelhaupt Ronald E. Enstrom Mohsen Esmaily Thomas Z. Fahidy Larry R. Faulkner Xuning Feng Jeffrey W. Fergus* Antoni Forner-Cuenca Gerald S. Frankel* Robert P. Frankenthal Hiroyuki Fujimori Shinji Fujimoto Yasuhiro Fukunaka Andrew Fynan Tim Gamberzky
Richard P. and Margaret M. Gangloff Zhengning Gao Boris Garin Fernando H. Garzon Erin Gawron Rob Gerth Don F. Gervasio Robert Glass Jeffrey T Glass Annie F. Goedkoop Norman Goldsmith Nathan Goldy Ignacio Gonzalez Heiner J. Gores Shimshon Gottesfeld Heiko Gräbe Lorenz Gubler Turgut M. Gur** Elena Haddon Ion C. Halalay Douglas C. Hansen Joel Hansen Meelis Harmas Adam Heller Martin Heller Emily Sarah Hersh Dennis W. Hess* Tohru Higuchi Fumihiko Hirose Michael Hoehlinger Andrew M. Hoff Gordon Holcomb Curtis F. Holmes Teruhisa Horita W. Jean Horkans Zhaozhao Hou Kevin Huang Howard R. Huff Henry G. Hughes Charles L. Hussey*
Sheila Isaacs Greg S. Jackson** Kaushik Jayasayee Carol Jeffcoate Laurie I. Hill Jegaden Derek A. Johnson Christopher S. Johnson ** Ilwoo Jung Yara Kadria-Vili Egwu Eric Kalu Neha Karmeshu Chockkalingam Karuppaiah Daiki Kawachino Robert G. Kelly Martin W. Kendig Juhyung Kim Marco Kirm Harry N. Knickle Takeshi Kobayashi Zlata Kovac Bianca Kovalenko Bruce Arthur Kowert Simeon J. Krumbein James Landon Rachel Langenbacher Kelly Cubicciotti Lazzaroni Arthur J. Learn Johna Leddy** Hyo-Jong Lee Benjamin T.-H. Lee Peter A. Lewis John Lewis Da Li Xuan Li Chek Hai Lim Jeonghoon Lim Clovis A. Linkous Chung-Chiun Liu Xinyu Liu Jingli Luo *Denotes ECS Editorial Board Member **Denotes ECS Board Member
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Donors Robert Lynch Stuart B. Lyon Henri J. R. Maget Tyler X. Mahy Marek L. Marcinek Gangadhara S. Mathad James A. McIntyre Shirley Meng Richard E. Meyers Elizabeth C Miller Morris Milner Shelley D. Minteer Nancy A. Missert Brandon Mitchell Tomofumi Miyashita Thomas Polk Moffat Patrick J. Moran Ashley Moran Sanjeev Mukerjee Rangachary Mukundan* Vivek S. Murthi Winnie Mutch Madhivanan Muthuvel Hiroki Nagashima Keisuke Nagato Kiyoharu Nakagawa Paul M. Natishan* John S. Newman Trung Van Nguyen Roberta Nipoti Alex R. Nisbet
Jun-Ichi Nishizawa James J. Noel Filipe Nogueira Colm O’Dwyer Kenji Ogisu Toshikazu Okubo Colin W. Oloman Anna Olsen Yasuhisa Omura Tetsuya Osaka Carlton M. Osburn Anna Ostroverkh Mengzheng Ouyang Christoforos Panteli Sang-Hoon Park Nia Parker Oliver Pecher Dennis G. Peters Peter N. Pintauro Bryan S. Pivovar Elizabeth J. Podlaha-Murphy** Jeffrey Poirier Piotr Polczynski Daniel Pritzl Ramaraja P Ramasamy Robert A. Rapp Shannon C. Reed David Reichert Cynthia A. Rice Marc Robert Uwe Rossow Andrew Ryan Mukundan R Sarukkai Kotaro Sasaki Robert F. Savinell* Daniel A. Scherson
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Thomas J. Schmidt* Pat and Louie Scribner John Robert Scully Tae-Yeon Seong Gayatri Seshadri David W. Shoesmith Nelson Alexandre Galiote Silva Aleksandr L. Simonian Diane K. Smith Stephen W. Smith Nathalie Solladie Seoung-Bum Son Donald Songstad Narasi Sridhar Suresh Sriramulu Gery R. Stafford Kurt H. Stern Frederick J. Strieter Yoshiyuki Suda Svein Sunde Alice H. Suroviec ** Hendro Sutisna Anne Swartz Lindsey Syktich Tomofumi Tada Norio Takami Kazuhisa Tamura Meng Tao E. Jennings Taylor** Tobias Teufl Dominique Thierry Carl W. Townsend Orlin D. Trapp Wei-Tsu Tseng Hiroaki Tsuchiya
Atsushi Ueda Francois Usseglio-Viretta Honorio Valdes-Espinosa Marko J.Vehkamaki Gomathi Venkat Ramakrishnan Venkataraman Philippe M.Vereecken Francisco Vicente Anil V.Virkar Sannakaisa Virtanen** Dunyang Wang Hong Wang Masahiro Watanabe Takanobu Watanabe Adam Z. Weber John Weidner Travis A White Hazel Whitlow Clinton S. Winchester David Wipf Jessica Wisniewski Mark Wolf Andrew Allen Wong Robert Wong Nae-Lih Wu* She-Huang Wu Wangwang Xu Shozo Yanagida Cheng-Hsien Yang Takeshi Yao Mary Yess Thomas A. Zawodzinski Le Zhang Meijie Zhang Jinbao Zhao Eugeniusz Zych
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Donors ECS is grateful to the following companies and institutions that have supported the Society through membership, sponsorship, advertising, and exhibits. Their involvement ensures that we are able to advance the most cutting-edge research in our fields through conferences and publications. Advanced Semiconductor Processing Technology, LLC Air Liquid Advanced Materials Air Liquide Aixtron Inc. ALS Co. Ltd. AMETEK - Scientific Instruments Applied Materials Arbin Instruments ASME Auburn University AVL LIST GmbH Axiall Corporation BASi Bio-Logic Science Instruments Bio-Logic USA BMW of North America Bruker Optics Inc. CAP CO Ltd. Center for Nanoscale Science and Technology (CNST) Central Electrochemical Research Inst Chroma ATE, Inc. Contemporary Amperex Technology Co., Ltd. Daimler De Nora Tech
DigiM Solution LLC Dioxide Materials Duracell EL-CELL GmbH Energizer Eugenus, Inc. Faraday Technology, Inc. Fiaxell sarl Ford Motor Company Fraunhofer-Center for Coatings and Diamond Technologies (CCD) Fuel Cell Materials Fuelcell Energy Inc. FuelCon AG Fujifilm Diamatix, Inc. Gamry Instruments Gelest, Inc. General Motors Holdings LLC Giner, Inc. GS Yuasa International Ltd. Haiku Tech., Inc. Hangzhou ChangKai Energy Technology Co. Ltd. Hiden Analytical Inc. Honda R&D Co., Ltd. Honda Research Institute USA Inc. Horiba Scientific Hydro-Quebec IBM Corporation Industrie De Nora S.p.A. International Lead Association Ion Power Inc. Ionomr Innovations Inc. IVIUM Technologies JX Nippon Mining & Metals Corporation Kanto Chemical Co., Inc. Karlsruher Institut fuer Technologie Keithley Instruments Inc. King Abdullah University of Science and Technology, PSE Division
Koslow Scientific Co. Lam Research Corporation Lawrence Berkeley National Lab Leclanche SA LG Chem Los Alamos National Laboratory Maccor, Inc. Math2Market GmbH Mattson Thermal Products GmbH Medtronic Inc. Metrohm USA, Inc. MilliporeSigma Mitsui Mining & Smelting Co MTI Corporation National Renewable Energy Laboratory Naval Research Laboratory Nissan Motor Co., Ltd. Occidental Chemical Corporation Office of Naval Research PANalytical, Inc. Panasonic Corporation PAR/Solartron Park Systems, Inc. Permascand AB Photon Etc. Pine Research Instrumentation Praxair Surface Technologies Process Systems Enterprise Qualcomm Technologies, Inc. Quantachrome Instruments RASIRC Rice University Saft Batteries, Specialty Batteries Group Sandia National Laboratories SanDisk Scribner Associates, Inc. SOFC Society of Japan Stanford Research Systems
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Sumitomo Metal Mining Co., Ltd. Targray Technic Inc. Tektronix Teledyne Energy Systems, Inc. The Electrosynthesis Company, Inc. The Family of H. Russell Kunz Tianjin Lishen Battery JointStock Co., Ltd. Tokyo Electron America Ltd. Top Med LLC Toyota Central R & D Labs., Inc. Toyota Research Institute of North America U.S. Naval Research Laboratory ULVAC Technologies, Inc. United States Army Research Office University of Connecticut Vacuum Technology Inc. Wildcat Discovery Technologies, Inc. Xergy Inc. Yeager Center for Electrochemical Sciences Zahner-elektrik GmbH & Co KG ZSW Special recognition for donations in honor of: William D. Brown Ernest Yeager Ansrzej Wieckowski Rajeshwar Krishnan S. K. Rangarajan Thank you to all of our supporters. If there is a mistake in our listings, please contact development@electrochem.org and we will issue a correction.
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Financials Statement of Activities Year Ended December 31, 2017
2017 REVENUE Total Operating Revenue
$7,725,014
EXPENSE Program Services
5,641,652
Rental Operations
512,972
Fundraising
409,644
General & Administrative
699,751
Total Expense
7,264,019
TOTAL INCREASE IN NET ASSETS FROM OPERATIONS Net change in fair value of investments
460,995 1,078,557
INCREASE IN NET ASSETS
$1,539,552
STATEMENT OF FINANCIAL POSITION Year Ended December 31, 2017
2017 ASSETS Cash, Investments and other Property & Equipment Total Assets
$15,308,935 4,064,275 $19,373,210
LIABILITIES AND NET ASSETS Liabilities
$2,322,726
Net Assets
17,050,484
Total Liabilities and Net Assets
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$19,373,210
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Mission
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he mission of ECS is to advance and disseminate knowledge in the fields of electrochemical and solid state science and technology, and allied subjects. To encourage research, discussion, and critical assessment, the Society holds meetings, publishes scientific papers, fosters training and education of scientists and engineers, and cooperates with other organizations to promote science and technology in the public interest. ECS envisions a future where our published peer-reviewed research will be completely open access, an initiative that we call Free the Science. ECS is leading the way as a steward of scientific knowledge in our technical domains and accelerating scientific discovery and innovation by promoting openness and increased accessibility of research, the scientific process, and data. To support our bold vision for open access you can make a gift directly to the Free the Science campaign or to any ECS program area that contributes to the overall financial position of the organization: • Awards • Specific collections in the ECS Digital Library • Meeting symposia • ECS Fund, an unrestricted fund supporting the greatest needs of the organization as determined by leadership • Roque Calvo Next Generation Scholarship Fund Visit www.electrochem.org or www.freethescience.org to donate online or send an email to development@electrochem.org to discuss ways to give, including planned giving and IRA charitable rollovers. Other ways to contribute to ECS include membership, exhibiting, sponsoring, advertising, and submitting abstracts to our meetings or articles to our journals. Together, our Society can share solutions for the benefit of our global society. Thank you. CONTACT ECS The Electrochemical Society 65 South Main Street, Building D Pennington, NJ 08534-2839, USA 609.737.1902
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2017 By the Numbers By the Community What follows are the statistics that chart the progress of ECS and the names of our community members who are making ECS work. Thank you! 120
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Board and Staff ECS Board of Directors
ECS Staff
Officers Johna Leddy, President Associate Professor The University of Iowa
Dinia Agrawala, Graphic Designer & Print Production Manager
(as of December 31, 2017)
Yue Kuo, Sr. Vice President Holder of the Dow Professorship Texas A&M University
(as of December 31, 2017)
Casey Annunziata, Meetings Specialist Marcelle Austin, Board Relations Specialist Roque J. Calvo, Executive Director/Chief Executive Officer Linda Cannon, Staff Accountant Karen Chmielewski, Finance Associate
Christina Bock, 2nd Vice President Senior Research Officer National Research Council of Canada
Paul Cooper, Editorial Manager
Stefan De Gendt, 3rd Vice President Research Manager/Chemistry Professor Imec/KULeuven
Tim Gamberzky, Chief Operating Officer
James Fenton, Secretary Director, Florida Solar Energy Center University of Central Florida
Karla Cosgriff, Director of Development Beth Craanen, Director of Publications Rob Gerth, Director of Marketing & Communications Annie Goedkoop, Associate Director of Publications/ Interface Managing Editor Paul Grote, Director of Finance Andrea L. Guenzel, Publications Specialist JES/JSS
E. Jennings Taylor, Treasurer Chief Technical Officer Intellectual Property Director Faraday Technology, Inc.
Mary Hojlo, Membership and Constituent Services Specialist
Roque J. Calvo, Executive Director Chief Executive Officer The Electrochemical Society
Ashley Moran, Corporate Programs Manager
Directors Stanko Brankovic, Chair,, Electrodeposition Division
Shannon Reed, Director of Membership Services
Mikhail Brik, Chair, Luminescence & Display Materials Division Graham Cheek, Chair, Organic & Bio. Electrochemistry Division Andy Herring, Chair, Energy Technology Division Greg Jackson, Chair, High Temperature Materials Division Christopher Johnson, Chair, Battery Division Alice Suroviec, Chair, Physical & Analytical Electrochemistry Division
Bianca Kovalenko, Meetings Program Specialist John Lewis, Director of Meetings and Corporate Programs Winnie Mutch, Web Manager Anna Olsen, Senior Content Specialist & Library Liaison Andrew Ryan, Publications Specialist ECST/Interface Beth Schademann, Publications Specialist JES/JSS Amanda Staller, Web Content Specialist Logan Streu, Publications Content Manager Jessica Wisniewski, Human Resources & Operations Manager Mary E. Yess, Chief Content Officer/Publisher
Yaw Obeng, Chair, Dielectric Science & Technology Division Colm O’Dwyer, Chair, Electronics & Photonics Division Krishnan Rajeshwar, Past President Douglas Riemer, Chair, Indust. & Electrochem. Eng. Division Slava Rotkin, Chair, Nanocarbons Division Stuart Swirson, Nonprofit Financial Professional Sannakaisa Virtanen, Chair, Corrosion Division Eric Wachsman, Chair, Interdisciplinary Sci. & Tech. Subcommittee Nianqiang Wu, Chair, Sensor Division
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Editorial Boards Editorial Boards (as of December 31, 2017)
Journal of The Electrochemical Society Editor: Robert Savinell
ECS Journals Editorial Advisory Committee S. V. Babu Mike Hickner Sean King Rainer Küngas
Technical Editors Doron Aurbach, Batteries and Energy Storage
Anant Setlur
David Cliffel, Physical and Analytical Electrochemistry, Electrocatalysis, and Photoelectrochemistry
ECS Transactions Editor: Jeffrey W. Fergus
Gerald S. Frankel, Corrosion Science and Technology Thomas F. Fuller, Fuel Cells, Electrolyzers, and Energy Conversion Charles L. Hussey, Electrochemical/Electroless Deposition Janine Mauzeroll, Organic and Bioelectrochemistry Rangachary Mukundan, Sensors Venkat Subramanian, Electrochemical Engineering Associate Editors Thierry Brousse, Batteries and Energy Storage Raymond J. Gorte, Fuel Cells, Electrolyzers, and Energy Conversion Takayuki Homma, Electrochemical/Electroless Deposition Ajit Khosla, Sensors Scott Lillard, Corrosion Science and Technology Brett Lucht, Batteries and Energy Storage Stephen Maldonado, Physical and Analytical Electrochemistry, Electrocatalysis, and Photoelectrochemistry Paul M. Natishan, Corrosion Science and Technology Thomas J. Schmidt, Fuel Cells, Electrolyzers, and Energy Conversion Minhua Shao, Fuel Cells, Electrolyzers, and Energy Conversion Venkat Srinivasan, Batteries and Energy Storage Alice Suroviec, Physical and Analytical Electrochemistry, Electrocatalysis, and Photoelectrochemistry
Editorial Advisory Board Christopher Johnson, Battery Division Dev Chidambaram, Corrosion Division Zhi (David) Chen, Dielectric Science and Technology Division Stanko Brankovic, Electrodeposition Division Robert Lynch, Electronics and Photonics Division Cynthia Rice, Energy Technology Division Cortney Kreller, High Temperature Materials Division John Harb, Industrial Electrochemistry and Electrochemical Engineering Division Mikhail Brik, Luminescence and Display Materials Division Slava Rotkin, Nanocarbons Division James Burgess, Organic and Biological Electrochemistry Division Petr Vanýsek, Physical and Analytical Electrochemistry Division Dong-Joo Kim, Sensor Division Interface Editor: Krishnan Rajeshwar Advisory Board Christopher Johnson, Battery Division Masayuki Itagaki, Corrosion Division
Nae-Lih (Nick) Wu, Batteries and Energy Storage
Durga Misra, Dielectric Science and Technology Division
ECS Journal of Solid State Science and Technology Editor: Dennis Hess
Jennifer Hite, Electronics and Photonics Division
Technical Editors Jennifer A. Bardwell, Electronic Materials and Processing
Paul Gannon, High Temperature Materials Division
Philippe Vereecken, Electrodeposition Division Mani Manivannan, Energy Technology Division
Francis D’Souza, Carbon Nanostructures and Devices
John Weidner, Industrial Electrochemistry & Electrochemical Engineering Division
Peter Mascher, Dielectric Science and Materials
Uwe Happek, Luminescence and Display Materials Division
Kailash C. Mishra, Luminescence and Display Materials, Devices, and Processing
Slava Rotkin, Nanocarbons Division
Fan Ren, Electronic and Photonic Devices and Systems
Andrew Hillier, Physical and Analytical Electrochemistry Division
Associate Editor George Celler, Electronic Materials and Processing & Electronic and Photonic Devices and Systems
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James Burgess, Organic and Biological Electrochemistry Division Nianqiang (Nick) Wu, Sensor Division
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Finance
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e are pleased to present the audited financial statements of ECS for the year ending December 31, 2017.These reports indicate that our financial health continues to be strong and that we continue to work towards the Society’s objectives of contributing to the advancement of electrochemical and solid state science through the dissemination of technical content. For the year ended December 31, 2017, net assets increased by $1.54 million. The increase was a result of operating revenues, which exceeded the budget, totaling $7.72 million, plus the net increase in the fair value of investments of $1.08 million less expenses of $7.26 million. The revenue performance against the budget was largely due to the increases in the market value of the investment portfolio, supplemented by positive performance in the publications, membership, and meetings areas. The total operating expenses remained virtually flat compared to the prior year, primarily due to decreased meetings, general and administrative, marketing, and fundraising costs, partially offset by increases in publications and membership costs compared to the previous year. Membership and publications costs increased as a result of organizational structure and personnel changes in 2017. The Society’s Statement of Financial Position reflects assets of $19.4 million. Of these total assets, 76.7% are either custodial or endowment funds. Growth in these funds is important because it is clear that there will be pressure to generate financial support through investment and contribution revenues. Changes in the scientific publishing industry have inspired the Society’s Free the Science open access initiative, the goal of which is to make ECS content free to publish and free to access. Digital library subscription revenue, over time, will begin to decline. In anticipation of a declining subscription revenue model, ECS continues to look for opportunities to generate additional revenues and operating margins from both traditional and new revenue sources. Our broader financial goal is to avoid the use of the endowment funds to cover operating expenses for as long as possible, enabling the funds to maintain future growth. From an operational perspective, 2017 was an outstanding year for ECS, largely due to the strong performance of the investment portfolio and the positive financial performance of many of our program areas. We anticipate the continued need for program growth and growth in our investment portfolio to fund advances in our programs, the broader dissemination of our content, and the open access initiative. The Society’s current financial strength will aid in this growth.
ECS Revenue Percentages - 2017 Constituent programs 0.4%
Membership 7.8%
Society meetings and activities 34.9%
Publications 33.7%
Other revenues 0.0% Rental income 7.3%
Grants 2.1%
Investment income 11.5%
Contributions 2.3%
ECS Expense Percentages - 2017 Membership 6.1% Publications 33.9%
Rental operations 7.0%
Fundraising 5.6%
Marketing 4.1%
Constituent programs 1.3% Society meetings and activities 31.8%
General and administrative 5.5%
Grant subawards 2.1% Awards, fellowships and grants 2.6%
NOTE: Marketing expense depicted above does not include marketing expenses for program-specific purposes. Those are included in the individual program areas. E. Jennings Taylor Treasurer
Tim Gamberzky Chief Operating Officer
NOTE: The Electrochemical Society is a nonprofit international association of scientists and engineers chartered as a tax-exempt organization under Section 501(c)(3) of the United States Internal Revenue Code. The Board of Directors engages the services of an independent auditor to assure that the Society maintains an effective system of financial management, and operates under its nonprofit charter. The Board of Directors received an unmodified or clean opinion from their independent auditors, Horvath & Giacin, P.C. for the fiscal year ending December 31, 2017. To obtain a complete copy of the Audit Financial Statements, interested parties can email their request to paul.grote@electrochem.org. The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
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Financial Summary Consolidated Statement of Financial Position (For the year ended December 31, 2017) ASSETS Cash and cash equivalents Accounts receivable, net Prepaid expenses, deposits and other assets Investments in marketable securities Custodial account investments Deferred rent Investments in real estate: Land Buildings, less accumulated depreciation of $943,337 Intangible assets Total assets
2017
$1,491,540 33,385 338,035 13,380,408 423 65,144 1,603,427 2,460,848 $19,373,210
Liabilities and Net Assets
Liabilities Accounts payable and accrued expenses Deferred revenue Custodial account liability Security deposits Deferred compensation
$432,168 1,641,330 424 38,248 210,556
Net Assets
Unrestricted Temporarily restricted Permanently restricted Total net assets Total liabilities and net assets
15,408,075 683,341 959,068 17,050,484 $19,373,210
Consolidated Statement of Changes in Net Assets Revenues
(For the year ended December 31, 2017)
Publications Membership Constituent programs Society meetings and activities Investment income Contributions Grants Rental income Other revenues Total Revenues
$2,599,315 606,331 29,595 2,697,400 889,603 176,421 160,000 564,674 1,675 7,725,014
Expenses
Program services Publications Membership Constituent programs Society meetings and activities Grant sub-awards Awards, fellowships and grants Total Program Services Expenses Supporting services General and administrative Marketing Fundraising Rental operations Total Supporting Services Expenses
$2,460,962 442,494 91,705 2,307,847 150,000 188,644 5,641,652 401,332 298,419 409,644 512,972 1,622,367
Total Expenses
7,264,019 460,995 1,078,557 1,539,552 15,510,932 $17,050,484
Increase in net assets from operations Net change in fair value of investments Change in net assets Net assets, beginning of year Net assets, end of year These financial statements are a condensed version of the audited statements of ECS for the year ending December 31, 2017. ECS will be pleased to provide complete copies along with all footnotes and the unqualified report of our auditors upon request.
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Notes to Financial Statements 1 - Summary of Significant Accounting Policies The consolidated financial statements include the accounts of The Electrochemical Society, Inc. (the Society) and its Divisions, Groups and Sections and ECS Holdings, LLC, (the LLC). All intercompany balances and transactions have been eliminated in consolidation. The consolidated financial statements are prepared on the accrual basis of accounting. Revenue, other than contributions, is recognized when earned and expense is recognized when the obligation is incurred. The consolidated financial statements have been prepared to focus on the Society and its subsidiaries as a whole, and to present balances and transactions according to the existence or absence of donor-imposed restrictions. Accordingly, net assets and changes therein are classified as follows: Unrestricted net assets – net assets not subject to donor-imposed stipulations; Temporarily restricted net assets – net assets subject to donor-imposed stipulations that will be met by actions of the Society and/or by the passage of time; Permanently restricted net assets (endowment funds) – net assets subject to donor-imposed stipulations that they be maintained permanently by the Society.
4 - Endowment Funds The Society’s endowment funds consist of several funds established to support awards, as well as an educational endowment fund and a Free the Science fund. The endowment funds include both donorrestricted funds and funds designated by the Board of Directors to function as endowments. As required by generally accepted accounting principles (GAAP), net assets associated with endowment funds are classified based on the existence or absence of donorimposed restrictions. The Society’s policy requires the preservation of the fair value of the original gift as of the gift date of the donor-restricted endowment funds absent explicit donor stipulations to the contrary. As a result, the Society classifies as permanently restricted net assets the original value of gifts donated to the permanent endowment and the original value of subsequent gifts to the permanent endowment. The remaining portion of the donor-restricted endowment fund that is not classified in permanently restricted net assets is classified as temporarily restricted net assets until those amounts are appropriated for expenditure by the Society.
2 - Income Tax Status and Income Taxes ECS and its Divisions, Groups, and Sections qualify as a tax-exempt organization described under Section 501(c)(3) of the Internal Revenue Code and all of its income, except income generated through the advertising included in its publications, is exempt from Federal income taxes. As a single-member limited liability company, the LLC is treated as a “disregarded entity” for income tax purposes and, as such, its financial activity is reported in conjunction with the Federal income tax filings of ECS. The Society has adopted the accounting pronouncement that provides guidance on uncertain tax positions. The Society has no unrecognized tax benefits at December 31, 2017.
5 - ECS Holdings, LLC ECS Holdings LLC was chartered in 1998 to manage the real estate assets of the Society. Current real estate holdings include five buildings at Howe Commons in Pennington, NJ valued at a cost of $5,007,611. The Society occupies one of the buildings and the other four are classified as an investment. The LLC leases office space in these four buildings to various tenants under operating lease arrangements expiring through 2023. Rental income under the aforementioned leases totaled $564,674 (excluding intercompany rentals of $91,416) for the year ended December 31, 2017.
3 - Investments Investments in equities and fixed income instruments are reported at fair market value, and investment in real estate is reported at cost. Investment income and realized and unrealized net gains and losses on investments of permanently restricted net assets are reported as follows: as increases or decreases in temporarily restricted net assets if the terms of the gift impose restrictions on the use of the income and/or net gains; as increases or decreases in unrestricted net assets in all other cases. Cost, market value and unrealized appreciation (depreciation) at December 31, 2017 are summarized as follows:
Cost Stocks and mutual funds Corporate and U.S. bonds Real estate
Fair Market Value
Unrealized Appreciation (Depreciation)
$ 8,016,495
$10,501,491
$ 2,484,996
2,086,447
2,183,241
96,794
5,007,611
5,007,611
--
Real Estate Trust
250,000
348,895
98,895
Other Investments
298,329
347,204
48,875
$15,658,882
$18,388,442
$ 2,729,560
Total
Report of the ECS Audit Committee The ECS Audit Committee provides oversight of The Electrochemical Society’s financial reporting process on behalf of the Board of Directors. Management (ECS Staff Directors and Officers) is responsible for the financial statements and the financial reporting process, including the system of internal control. In fulfilling its oversight responsibilities, the Committee discussed the financial statements in the annual report with management, including a discussion of quality, not just the acceptability, of the accounting principles; the reasonableness of significant judgments; and the clarity of disclosures in the financial statements. The members of the Audit Committee in 2017 were Krishnan Rajeshwar (Chair), E. Jennings Taylor, Johna Leddy,Yue Kuo and Stuart Swirson. The ECS Audit Committee discussed with the independent auditors the overall scope and plans for their respective audits. The Committee meets with the independent auditors with and without management present, to discuss the results of their examinations, their evaluations of the Society’s internal control, compliance with laws and regulations, and the overall quality of the Society’s financial reporting. Based on the discussions referenced above, the ECS Audit Committee recommended for acceptance to the Board of Directors the audited financial statements for the year ended December 31, 2017 and the Board unanimously approved.
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ECS Membership Statistics As of October 1, 2017
Table I. ECS Membership by Class
Category 2011 2012 Members-Good Standing 4731 4657 Members-Expired N/A N/A Members-Lapsed N/A N/A Member Representatives-Good Standing 112 134 Member Representatives-Expired N/A N/A Member Representatives-Lapsed N/A N/A Retired Members N/A N/A Life Members (Paid Life + Award Life) 52 64 Emeritus Members 289 288 Honorary Members 23 22 Subtotal Members in Good Standing 5207 5165 Total Delinquent (Expired + Lapsed) 1236 1302 Total Members 6443 6467 Student Members-Good Standing 1427 1502 Student Members-Expired N/A N/A Student Members-Lapsed N/A N/A Total Student Members Delinquent (Expired + Lapsed) 825 847 Total Students Members 2252 2349 Total Individual Members 8695 8816 Automatic Renewal Enrollment N/A N/A *Number represents a recategorization in 2015 of good standing, expired & lapsed members. **Membership numbers no longer include free memberships from ECS meetings.
2013 4253 N/A N/A 175 N/A N/A N/A 101 283 25 4837 1225 6062 1438 N/A N/A 775 2213 8275 N/A
2014 4260 N/A N/A 219 N/A N/A N/A 105 296 27 4907 1143 6050 1497 N/A N/A 760 2257 8307 N/A
2015* 3889 393 1235 269 16 10 N/A 117 299 22 4596 1654 6250 1519 228 858 1086 2605 8855 N/A
2016** 3536 382 1035 316 7 18 6 131 330 23 4342 1442 5784 1625 270 798 1068 2693 8477 176
2017 3311 364 787 282 2 29 19 127 336 21 3814 1578 5346 1532 280 762 1042 2574 8202 248
2017-2016 2017-2016 # Change % Change -225 -6.36 -18 -4.71 -248 -23.96 -34 -10.76 -5 -71.43 11 61.11 13 216.67 -4 -3.05 6 1.82 -2 -8.70 -528 -12.16 136 9.43 -438 -7.57 -93 -5.72 10 3.70 -36 -4.51 -26 -2.43 -119 -4.42 -275 -3.24 72 40.91
Table II. ECS Membership by Section Section Arizona Brazil Canada Chicago Chile China Cleveland Detroit Europe Georgia India Israel Japan Korea Mexico National Capital New England Pittsburgh San Francisco Singapore Taiwan Texas Twin Cities
Division Battery Dielectric Science & Technology Electrodeposition Electronics & Phontonics Energy Technology Nanocarbons Division High Temperature Materials Industrial Electrochemistry & Electrochemical Eng Luminescence & Display Materials Organic & Biological Electrochemistry Physical & Analytical Electrochemistry Sensor
(data does not include member representatives) 2011 2012 2013 2014** 109 98 102 N/A 65 66 47 N/A 381 382 371 N/A 182 180 155 N/A N/A 10 13 N/A 81 86 78 N/A 123 124 106 N/A 118 116 96 N/A 1105 1108 1041 N/A 171 179 133 N/A 58 59 59 N/A 39 39 27 N/A 771 775 756 N/A 243 253 205 N/A 31 30 30 N/A 159 154 162 N/A 381 360 292 N/A 87 80 58 N/A 413 416 376 N/A N/A N/A N/A N/A 122 123 87 N/A 144 146 142 N/A 74 76 53 N/A
2015* 89 27 256 215 7 64 74 94 1005 136 70 31 636 146 49 147 217 66 244 N/A 64 122 47
2016** 67 26 217 137 8 72 83 56 768 87 49 19 553 75 37 103 168 43 198 N/A 68 112 40
2017 47 16 195 108 7 91 59 49 630 60 38 18 510 48 26 105 128 49 145 5 62 129 37
2017-2016 2017-2016 # Change % Change -20 -29.85 -10 -38.46 -22 -10.14 -29 -21.17 -1 -12.50 19 26.39 -24 -28.92 -7 -12.50 -138 -17.97 -27 -31.03 -11 -22.45 -1 -5.26 -43 -7.78 -27 -36.00 -11 -29.73 2 1.94 -40 -23.81 6 13.95 -53 -26.77 5 -6 -8.82 17 15.18 -3 -7.50
(data does not include member representatives) 2011 2012 2013 2014 1668 1709 1987 1824 319 275 256 235 483 448 464 445 679 550 581 556 1220 1194 1122 1025 176 160 183 177 184 218 212 202 307 290 303 282 111 97 94 90 184 176 180 166 618 564 609 561 229 217 233 218
2015* 1701 204 392 511 995 154 218 286 64 161 560 225
2016** 1605 194 365 502 930 171 184 257 68 150 545 212
2017 1545 171 338 433 858 152 174 248 59 139 492 203
2017-2016 2017-2016 # Change % Change -60 -3.74 -23 -11.86 -27 -7.40 -69 -13.75 -72 -7.74 -19 -11.11 -10 -5.43 -9 -3.50 -9 -13.24 -11 -7.33 -53 -9.72 -9 -4.25
2016** 2151 1288 309 137 33
2017 1990 1089 315 203 38
2017-2016 2017-2016 # Change % Change -161 -7.48 -199 -15.45 6 1.94 66 48.18 5 15.15
Table III. ECS Membership by Division
Table IV. ECS Membership by Occupation Occupation Academic Industry Government Retired Other
(data does not include member representatives or student members) 2011 2012 2013 2014 2015* 2434 2362 2206 2346 2227 2094 2123 1902 1900 1724 387 377 377 435 360 109 110 111 117 119 N/A N/A N/A N/A 121
Meeting Statistics Papers
231st ECS Meeting, New Orleans Abstracts by the numbers
Invited & Keynote talks Oral Presentations Posters Total Presentations
439 1,254 375 2,088
615
Invited & Keynote talks Oral Presentations Posters Total Presentations
15 531 1,259 566 2,371
Total Student Presentations
644
Total Countries 58
Attendees Total Attendance
Award Talks (Society and Division)
Student Presentations
Total Countries Number of Countries Represented
2,438 2,371
All presentations 20
Student Presentations Total Student Presentations
1,914 2,088
232nd ECS Meeting, National Harbor Abstracts by the numbers
All presentations Award Talks (Society and Division)
2,200 2,171
2,076 1,749
2,391 2,274
2,144 2,054
1,709 1,640
1,351 1,514
1,645 1,653
3,094 2,748
3,917 4,011
3,961 4,196
Attendance
Number of Countries Represented
54
Attendees 1,914
Total Attendance
New Attendees
829
New Attendees
Percentage of New Attendees
43%
Percentage of New Attendees
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2,438 1,006 43%
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ECS Student Chapters Student Chapter Name
Year Chartered
Aalborg University
2017
Auburn University
2007
Belgium Student Chapter
2015
Boston Student Chapter British Columbia University Brno University of Technology California State University-Fullerton Case Western Reserve University Central Illinois Student Chapter Clemson University Colorado School of Mines
2009 2013 2006 2012 2005 2008 2014 2012
Drexel University
2012
Georgia Institute of Technology
2008
Hong Kong University of Science and Technology
2016
Illinois Institute of Technology
2015
Indiana University
2012
Kerala, India at CUSAT Student Chapter Lahore, Pakistan Student Chapter Lewis University Louisiana State University
2008 2008 2015 2016
Missouri University of Science and Technology
2017
Montana State University
2013
Montreal Student Chapter Munich Student Chapter
2010 2015
New Mexico State University
2015
North Florida Student Chapter Norwegian University of Science and Technology Ohio State University Ohio University Oklahoma Student Chapter
2014 2014 2006 2011 2017
Rensselaer Polytechnic Institute
2013
Research Triangle Student Chapter South Brazil Student Chapter
2013 2010
SRM University
2013
Tel Aviv University
2009
Texas A&M University Tyndall National Institute UK Northwest Student Chapter University of Alabama University of Calgary University of California–Berkeley University of California–Los Angeles
2016 2012 2015 2016 2011 2014 2015
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Faculty Advisor(s) Daniel-Ioan Stroe Maciej Swierczynski Majid Beidaghi Philippe M.Vereecken Stefan De Gendt Eugene Smotkin Dan Bizzotto Jiri Vondrak John L. Haan Robert F. Savinell Andrzej Wieckowski Stephen E. Creager Andy M. Herring Yury Gogotsi Ekaterina A. Pomerantseva Seung Woo Lee Francesco Ciucci Minhua Shao Wei Chen Adam Hock Dennis Peters Lane A. Baker Madambi K. Jayaraj Inam Ul Haque Jason Keleher Christopher G. Arges Amitava Choudhury Jay A. Switzer Manashi Nath Ryan W. Anderson Paul E. Gannon Steen B. Schougaard Hubert Gasteiger Vimal H. Chaitanya Hongmei Luo Pedro Moss Ann Mari Svensson Anne C. Co Gerardine Gabriela Botte Sadagopan Krishnan David J. Duquette Daniel J. Lewis Jeffrey Glass Luís F. P. Dick Ranjit Thapa Bhalchandra Anand Kakade Eliezer Gileadi Yosi Shacham-Diamand Yue Kuo Alan O’Riordan Laurence J. Hardwick Shanlin Pan Viola Ingrid Birss Bryan D. McCloskey Sarah H. Tolbert
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Chapter Name University of California–Riverside University of California–San Diego University of Central Florida University of Cincinnati University of Florida University of Houston
Year Chartered 2011 2014 2000 2007 2005 2016
University of Illinois at Chicago
2016
University of Iowa University of Kansas University of Kentucky University of Maryland University of Nevada-Reno
2014 2016 2014 2011 2014
University of New Mexico
2017
University of Oxford
2016
University of Pittsburgh
2014
University of South Carolina University of St. Andrews University of Tartu University of Texas at Austin University of Texas at Dallas University of Toronto University of Utah University of Virginia
2010 2015 2013 2006 2012 2016 2015 2006
University of Washington
2016
University of Western Ontario
2017
Valley of the Sun (Central Arizona)
2013
Faculty Advisor(s) Alexander A. Balandin Shirley Meng Kalpathy B. Sundaram Marc Cahay Erin Patrick Yan Yao Sanjay Kumar Behura Brian P. Chaplin Johna Leddy Trung Van Nguyen Doo Young Kim Eric D. Wachsman Dev Chidambaram Fernando H. Garzon Plamen B. Atanassov Charles W. Monroe Kylie A.Vincent Prashant N. Kumta Spandan Maiti William Mustain John T. S. Irvine Kaido Tammeveski Arumugam Manthiram Moon J. Kim Donald W. Kirk Shelley D. Minteer Giovanni Zangari Daniel T. Schwartz Venkat R. Subramanian Stuart B. Adler Jungsook Clara Wren Zhifeng Ding James J. Noel D. W. Shoesmith Candace Kay Chan
ECS Sections Arizona Section
Candace Kay Chan, Chair
Japan Section
Hiroshi Iwai, Chair
Brazil Section
Ernesto Pereira, Chair
Korea Section
Yung-Eun Sung, Chair
Canada Section
Christa Brosseau, Chair
Mexico Section
Ignacio Gonzalez, Chair
Chicago Section
Alan Zdunek, Chair
National Capital Section Eric D. Wachsman, Chair
Chile Section
Jose H. Zagal, Chair
New England Section
Sanjeev Mukerjee, Chair
China Section
Yong Yao Xia, Chair
Pittsburgh Section
Clifford W. Walton, Chair
Cleveland Section
Heidi B. Martin, Chair
San Francisco Section
Yarik Syzdek, Chair
Detroit Section
Srikanth Arisetty, Chair
Singapore Section
Qingui Yan, Chair
Europe Section
Petr Vanýsek, Chair
Taiwan Section
Bing-Joe Hwang, Chair
Georgia Section
Seung Woo Lee, Chair
Texas Section
Jeremy P. Meyers, Chair
India Section
Vijayamohanan K. Pillai, Chair
Twin Cities Section
Peter Zhang, Chair
Israel Section
Daniel Mandler, Chair
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ECS Honor Roll Past Presidents of the Society J. W. Richards............................... 1902-1904 H. S. Carhart................................. 1904-1905 W. D. Bancroft............................... 1905-1906 C. Hering....................................... 1906-1907 C. F. Burgess................................. 1907-1908 E. G. Acheson................................ 1908-1909 L. H. Baekeland............................. 1909-1910 W. H. Walker................................. 1910-1911 W. R. Whitney............................... 1911-1912 W. L. Miller.................................... 1912-1913 E. F. Roeber................................... 1913-1914 F. A. Lidbury.................................. 1914-1915 L. Addicks..................................... 1915-1916 F. A. J. FitzGerald........................... 1916-1917 C. G. Fink...................................... 1917-1918 F. J. Tone....................................... 1918-1919 W. D. Bancroft............................... 1919-1920 W. S. Landis.................................. 1920-1921 A. Smith........................................ 1921-1922 C. G. Schluederberg.................................1922-1923 A. T. Hinckley................................ 1923-1924 H. C. Parmelee.............................. 1924-1925 F. M. Becket................................... 1925-1926 W. Blum........................................ 1926-1927 S. C. Lind...................................... 1927-1928 P. J. Kruesi.................................... 1928-1929 F. C. Frary...................................... 1929-1930 L. Kahlenberg................................ 1930-1931 B. Stoughton................................. 1931-1932 R. A. Witherspoon......................... 1932-1933 J. Johnston................................... 1933-1934 H. S. Lukens.................................. 1934-1935 J. H. Critchett................................ 1935-1936 D. A. MacInnes.............................. 1936-1937 W. G. Harvey................................. 1937-1938 R. L. Baldwin................................. 1938-1939 H. J. Creighton.............................. 1939-1940 F. C. Mathers................................. 1940-1941
R. R. Ridgway............................... 1941-1942 E. M. Baker.................................... 1942-1943 R. M. Burns................................... 1943-1944 S. D. Kirkpatrick............................ 1944-1945 W. R. Veazey................................. 1945-1946 W. C. Moore.................................. 1946-1947 G. W. Heise................................... 1947-1948 J. A. Lee........................................ 1948-1949 A. L. Ferguson............................... 1949-1950 C. L. Faust..................................... 1950-1951 R. M. Hunter................................. 1951-1952 J. C. Warner.................................. 1952-1953 R. J. McKay................................... 1953-1954 M. J. Udy...................................... 1954-1955 H. H. Uhlig.................................... 1955-1956 H. Thurnauer................................. 1956-1957 N. Hackerman............................... 1957-1958 S. Swann....................................... 1958-1959 W. C. Gardiner............................... 1959-1960 R. A. Schaefer............................... 1960-1961 H. B. Linford.................................. 1961-1962 F. L. LaQue.................................... 1962-1963 W. J. Hamer.................................. 1963-1964 L. I. Gilbertson.............................. 1964-1965 E. B. Yeager................................... 1965-1966 H. J. Read..................................... 1966-1967 H. C. Gatos.................................... 1967-1968 I. E. Campbell................................ 1968-1969 N. C. Cahoon................................. 1969-1970 C. W. Tobias.................................. 1970-1971 C. V. King...................................... 1971-1972 T. D. McKinley............................... 1972-1973 N. B. Hannay................................. 1973-1974 D. A. Vermilyea............................. 1974-1975 T. R. Beck...................................... 1975-1976 M. J. Pryor.................................... 1976-1977 D. N. Bennion................................ 1977-1978 D. R. Turner.................................. 1978-1979
J. B. Berkowitz.............................. 1979-1980 E. M. Pell....................................... 1980-1981 R. J. Brodd.................................... 1981-1982 F. J. Strieter................................... 1982-1983 J. B. Wagner, Jr............................. 1983-1984 P. C. Milner.................................... 1984-1985 R. C. Alkire.................................... 1985-1986 R. E. Enstrom................................ 1986-1987 F. G. Will........................................ 1987-1988 B. E. Deal...................................... 1988-1989 E. J. Cairns.................................... 1989-1990 J. M. Woodall................................ 1990-1991 L. R. Faulkner................................ 1991-1992 W. L. Worrell................................. 1992-1993 R. P. Frankenthal........................... 1993-1994 J. A. Amick.................................... 1994-1995 K. R. Bullock................................. 1995-1996 D. W. Hess.................................... 1996-1997 B. Miller........................................ 1997-1998 G. M. Blom.................................... 1998-1999 D. E. Hall....................................... 1999-2000 C. M. Osburn................................. 2000-2001 J. Talbot........................................ 2001-2002 K. Spear........................................ 2002-2003 B. Scrosati.................................... 2003-2004 R. Susko....................................... 2004-2005 W. Smyrl....................................... 2005-2006 Mark Allendorf.............................. 2006-2007 Barry MacDougall......................... 2007-2008 D. Noel Buckley............................. 2008-2009 Paul Natishan................................ 2009-2010 William D. Brown.......................... 2010-2011 Esther S. Takeuchi......................... 2011-2012 Fernando Garzon........................... 2012-2013 Tetsuya Osaka............................... 2013-2014 Paul Kohl....................................... 2014-2015 Daniel Scherson............................ 2015-2016 Krishnan Rajeshwar...................... 2016-2017
I. E. Campbell................................ 1959-1965 R. F. Bechtold................................ 1965-1968 D. R. Turner.................................. 1968-1974 P. C. Milner.................................... 1974-1980 F. A. Trumbore............................... 1980-1984 J. A. Amick.................................... 1984-1988 E. W. Brooman.............................. 1988-1992
J. McBreen.................................... 1992-1996 R. Susko....................................... 1996-2000 P. Natishan.................................... 2000-2004 P. Vanýsek..................................... 2004-2008 J. Leddy........................................ 2008-2012 H. Deligianni.................................. 2012-2016
E. G. Enck...................................... 1961-1964 R. H. Schaefer............................... 1964-1967 R. H. Cherry.................................. 1967-1973 F. J. Strieter................................... 1973-1976 J. L. Griffin.................................... 1976-1982 J. Kruger....................................... 1982-1986 R. P. Frankenthal........................... 1986-1990
R. E. White.................................... 1990-1994 W. M. Bullis................................... 1994-1997 Y. H. Wong.................................... 1997-1998 W. D. Brown.................................. 1998-2002 P. Fedkiw....................................... 2002-2006 J. Susko........................................ 2006-2010 Christina Bock............................... 2010-2014 E. J. Taylor.................................... 2014-2018
Past Secretaries of the Society C. Hering.................................................1902 C. J. Reed...................................... 1902-1904 S. S. Sadtler.................................. 1904-1907 J. W. Richards............................... 1907-1921 C. G. Fink...................................... 1921-1947 R. M. Burns................................... 1947-1949 H. B. Linford.................................. 1949-1959
Past Treasurers of the Society P. G. Salom................................... 1902-1920 F. A. Lidbury.................................. 1920-1924 A. Smith........................................ 1924-1931 R. M. Burns................................... 1931-1943 W. W. Winship............................... 1943-1949 E. G. Widell................................... 1949-1955 L. I. Gilbertson.............................. 1955-1961
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Edward Goodrich Acheson Award
Olin Palladium Award
E. G. Acheson...........................................1929 E. F. Northrup...........................................1931 C. G. Fink.................................................1933 F. J. Tone..................................................1935 F. M. Becket..............................................1937 F. C. Frary.................................................1939 C. F. Burgess............................................1942 W. Blum...................................................1944 H. J. Creighton.........................................1946 D. A. MacInnes.........................................1948 G. W. Vinal...............................................1950 J. W. Marden............................................1952 G. W. Heise..............................................1954 R. M. Burns..............................................1956 W. J. Kroll................................................1958 H. B. Linford.............................................1960 C. L. Faust................................................1962 E. A. Gulbransen......................................1964 W. C. Vosburgh........................................1966 F. L. LaQue...............................................1968 S. Ruben..................................................1970 C. W. Tobias.............................................1972 C. V. King.................................................1974 N. B. Hannay............................................1976 D. A. Vermilyea........................................1978 E. B. Yeager..............................................1980 H. C. Gatos...............................................1982 N. Hackerman..........................................1984 E. M. Pell..................................................1986 H. H. Uhlig...............................................1988 T. R. Beck.................................................1990 D. R. Turner.............................................1992 J. B. Wagner, Jr........................................1994 R. C. Alkire...............................................1996 J. M. Woodall...........................................1998 L. R. Faulkner...........................................2000 B. Deal.....................................................2002 W. L. Worrell............................................2004 V. de Nora................................................2006 Robert P. Frankenthal...............................2008 John Newman..........................................2010 Dennis Hess.............................................2012 Ralph J. Brodd.........................................2014 Barry Miller..............................................2016
C. W. Wagner...........................................1951 N. H. Furman............................................1953 U. R. Evans..............................................1955 K. F. Bonhoeffer........................................1957 A. N. Frumkin...........................................1959 H. H. Uhlig...............................................1961 N. Hackerman..........................................1965 P. Delahay................................................1967 T. P. Hoar..................................................1969 L. Brewer.................................................1971 V. G. Levich..............................................1973 M. J. N. Pourbaix.....................................1975 H. Gerischer.............................................1977 R. Parsons...............................................1979 I. M. Kolthoff............................................1981 M. Cohen.................................................1983 M. Fleischmann........................................1985 A. J. Bard.................................................1987 B. E. Conway............................................1989 J. Newman...............................................1991 J.-M. Savéant...........................................1993 J. Kruger..................................................1995 R. W. Murray............................................1997 J. B. Goodenough....................................1999 N. Sato.....................................................2001 E. Gileadi..................................................2003 R. Rapp....................................................2005 Sergio Trasatti..........................................2007 Dieter M. Kolb..........................................2009 Koji Hashimoto........................................2011 Ralph White.............................................2013 Digby Macdonald.....................................2015 Philippe Marcus.......................................2017
(formerly the Palladium Medal Award, 1951-1977)
Gordon E. Moore Medal for Outstanding Achievement in Solid-State Science and Technology
A. Y. Cho..................................................1987 J. F. Gibbons............................................1989 J. D. Plummer..........................................1991 B. E. Deal.................................................1993 W. L. Worrell............................................1995 K. E. Spear...............................................1997 I. Akasaki.................................................1999 A. Reisman...............................................2001 R. B. Fair..................................................2003 D. Hess....................................................2005 Tak H. Ning..............................................2007 C. Grant Willson.......................................2009 Stephen Pearton......................................2011 Fan Ren....................................................2013 Yue Kuo...................................................2015 Paul Kohl..................................................2017
Vittorio de Nora Award in Electrochemical Engineering and Technology (formerly the Electrochemical Science and Technology Award, 1974-1977)
A. Brenner................................................1974 R. B. MacMullin.......................................1976 F. T. Bacon................................................1978 H. B. Beer.................................................1980 J. C. Schumacher.....................................1982 D. E. Danly...............................................1984 K. Kordesch.............................................1986 A. Heller...................................................1988 C. W. Tobias.............................................1990 E. B. Yeager..............................................1992 L. T. Romankiw........................................1994 R. Baboian...............................................1996 W. G. Grot................................................1998 D. R. Turner.............................................2000 R. C. Alkire...............................................2004 F. Mansfeld...............................................2006 John S. Newman......................................2008 Derek Pletcher..........................................2010 Bruno Scrosati.........................................2012 Chad Mirkin..............................................2014 Ralph White.............................................2016
(formerly the Solid State Science & Technology Award, 1973-2005)
W. G. Pfann..............................................1973 H. C. Gatos...............................................1975 R. N. Hall..................................................1977 M. B. Panish.............................................1979 G. L. Pearson...........................................1981 N. Holonyak, Jr.........................................1983 J. M. Woodall...........................................1985 The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Carl Wagner Memorial Award A. J. Bard.................................................1981 G. C. Wood...............................................1983
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ECS Honor Roll Carl Wagner Memorial Award (continued) R. C. Alkire...............................................1985 R. W. Murray............................................1987 W. L. Worrell............................................1989 D. D. Macdonald .....................................1991 J. Jorné....................................................1993 B. R. MacDougall.....................................1995 M. J. Weaver............................................1997 C. R. Martin..............................................1999 P. A. Kohl.................................................2001 R. M. Crooks............................................2003 J. Hupp....................................................2005 Philip N. Bartlett.......................................2007 Henry S. White.........................................2009 Peter Bruce..............................................2011 Marc T. M. Koper......................................2013 Martin Winter...........................................2015 Eric Wachsman........................................2017
Henry B. Linford Award for Distinguished Teaching C. W. Tobias.............................................1982 B. E. Conway............................................1984 A. J. Bard.................................................1986 L. Brewer.................................................1988 J. Newman...............................................1990 K. Nobe....................................................1992 J. O’M. Bockris.........................................1994 T. C. Franklin............................................1996 R. A. Rapp................................................1998 G. Stoner..................................................2000 D. Peters..................................................2002 R. M. Latanision.......................................2004 D. Pletcher...............................................2006 Eliezer Gileadi...........................................2008 Daniel T. Schwartz....................................2010 Mark E. Orazem........................................2012 Dennis Hess.............................................2014 John Scully..............................................2016
Charles W. Tobias Young Investor Award Stuart B. Adler..........................................2004 Hock Min Ng............................................2006 Yang Shao-Horn.......................................2008 Thomas J. Schmidt..................................2010 Bryan S. Pivovar......................................2012 Bilge Yildiz...............................................2012 Adam Weber............................................2014 Y. Shirley Meng........................................2016
Allen J. Bard Award Henry White.............................................2015 Doron Aurbach.........................................2017
Honorary Members Charles F. Chandler..................................1919 Edgar F. Smith..........................................1919 Carl Hering...............................................1922 Edward G. Acheson..................................1923 Wilder D. Bancroft....................................1925 Edward Weston........................................1926 Thomas A. Edison....................................1928 W. Lash Miller..........................................1929 Edward Dean Adams................................1930 Charles F. Burgess....................................1932 Frederick M. Becket..................................1934 L. H. Baekeland........................................1936 Robert A. Witherspoon............................1940 Archer E. Wheeler....................................1941 W.R. Whitney...........................................1944 Paul J. Kruesi...........................................1944 Colin G. Fink.............................................1946 Oliver W. Brown.......................................1946 John W. Marden.......................................1947 William Blum............................................1953 Robert M. Burns......................................1959 George W. Heise......................................1959 Frank C. Mathers......................................1959 Stanislaus Skowronski.............................1962 Oliver W. Storey.......................................1962 A. Kenneth Graham..................................1963 Howard A. Acheson..................................1971 Charles L. Faust.......................................1971 Cecil V. King.............................................1973 Herbert H. Uhlig.......................................1973 Norman Hackerman.................................1973 Henry B. Linford.......................................1974 Sherlock Swann.......................................1974 Ernest G. Enck..........................................1975 W. C. Gardiner..........................................1975 Ivor E. Campbell.......................................1976 Ernest B. Yeager.......................................1977 David A. Vermilyea...................................1977 Charles W. Tobias.....................................1977 Harry C. Gatos.........................................1978 Ralph M. Hunter.......................................1979 Dennis R. Turner......................................1980 Henry F. Ivey............................................1980 Walter J. Hamer.......................................1980 Michael J. Pryor.......................................1981 Francis L. LaQue......................................1981 N. Bruce Hannay......................................1982 Theodore R. Beck.....................................1982 Vittorio de Nora........................................1982
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John L. Griffin..........................................1983 Erik M. Pell...............................................1983 Samuel Ruben..........................................1983 Paul C. Milner..........................................1986 Harold J. Read.........................................1986 Forrest A. Trumbore.................................1986 Douglas N. Bennion.................................1987 Ralph J. Brodd.........................................1987 Jerome Kruger.........................................1987 Glenn W. Cullen........................................1990 James C. Acheson....................................1990 Richard C. Alkire......................................1991 Bertram Schwartz....................................1991 J. Bruce Wagner, Jr..................................1991 V. H. Branneky..........................................1991 R. S. Karpiuk............................................1996 F. J. Strieter..............................................1996 W. L. Worrell............................................1996 Barry Miller..............................................1999 Jefferson Cole..........................................2001 L. Faulkner...............................................2003 R. Frankenthal..........................................2003 L. Romankiw............................................2003 Gordon E. Moore......................................2007 John S. Newman......................................2007 Jerry M. Woodall......................................2007 Allen J. Bard.............................................2013 John B. Goodenough...............................2013 Adam Heller.............................................2015 Dennis Hess.............................................2016
Fellows of The Electrochemical Society Allen J. Bard.............................................1990 Robert B. Comizzoli..................................1990 Glenn W. Cullen........................................1990 Theodore I. Kamins..................................1990 Paul C. Milner..........................................1990 Edward H. Nicollian..................................1990 Robert A. Osteryoung..............................1990 Arnold Reisman.......................................1990 Lubomyr T. Romankiw.............................1990 Geraldine C. Schwartz..............................1990 Ben G. Streetman.....................................1990 J. Bruce Wagner, Jr..................................1990 Theodore R. Beck.....................................1991 Elton J. Cairns..........................................1991 Bruce E. Deal............................................1991 Werner Kern.............................................1991 William A. Pliskin.....................................1991 Charles W. Tobias.....................................1991 Rolf Weil..................................................1991 Richard C. Alkire......................................1992 Vittorio de Nora........................................1992 Jerome Kruger.........................................1992 Barry Miller..............................................1992 Dennis R. Turner......................................1992 Jerry M. Woodall......................................1992 Richard P. Buck........................................1993 Larry. R. Faulkner.....................................1993
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Dennis W. Hess........................................1993 Vik J. Kapoor............................................1993 Rolf H. Muller...........................................1993 Carlton M. Osburn....................................1993 Robert A. Rapp........................................1993 George L. Schnable..................................1993 Y. H. Wong...............................................1993 Petr Zuman..............................................1993 George K. Celler.......................................1994 Sung-Nee George Chu.............................1994 John P. Dismukes....................................1994 Richard B. Fair.........................................1994 Adam Heller.............................................1994 Richard A. Oriani......................................1994 Boone B. Owens.......................................1994 Wayne L. Worrell.....................................1994 Fred Anson...............................................1995 Laurence D. Burke....................................1995 Brian E. Conway.......................................1995 Robert P. Frankenthal...............................1995 Karl M. Kadish..........................................1995 Digby D. Macdonald.................................1995 Gleb Mamantov........................................1995 Florian Mansfeld......................................1995 Royce W. Murray.....................................1995 John Newman..........................................1995 Yutaka Okinaka.........................................1995 Howard W. Pickering................................1995 George Rozgonyi......................................1995 Mordechay Schlesinger............................1995 Karl E. Spear............................................1995 John M. Blocher, Jr..................................1996 Hans K. Böhni..........................................1996 Der-Tau Chin............................................1996 Hugh Isaacs.............................................1996 Wolfgang J. Lorenz..................................1996 S. J. Pearton............................................1996 Subhash C. Singhal..................................1996 Venkataraman Swaminathan....................1996 James A. Amick.......................................1997 Denis Noel Buckley..................................1997 Eliezer Gileadi...........................................1997 Michel J. Froment....................................1997 Koji Hashimoto........................................1997 Chung-Chiun Liu......................................1997 Edward McCafferty..................................1997 Theodore D. Moustakas...........................1997 Shyam P. Muraka.....................................1997 Stella W. Pang..........................................1997 Joachim Walter Schultze..........................1997 James D. Sinclair.....................................1997 Norman L. Weinberg................................1997 Lawrence Young......................................1997 Huk Y. Cheh..............................................1998 Donald E. Danly........................................1998 Dennis H. Evans.......................................1998 Fumio Hine...............................................1998 Dennis C. Johnson...................................1998 Zoltan Nagy..............................................1998 Katsumi Niki.............................................1998 Jun-ichi Nishizawa...................................1998
Fan Ren....................................................1998 Antonio J. Ricco.......................................1998 David A. Shores.......................................1998 William H. Smyrl......................................1998 George Thompson...................................1998 Eric Brooman...........................................1999 Stanley Bruckenstein................................1999 Kathryn Bullock........................................1999 Shimshon Gottesfeld................................1999 Yue Kuo...................................................1999 Dieter Landolt..........................................1999 Jerzy Ruzyllo............................................1999 Norio Sato................................................1999 Ralph White.............................................1999 William Yen..............................................1999 Cammy Abernathy....................................2000 Kuzhikalail M. Abraham............................2000 John C. Angus..........................................2000 W. Ronald Fawcett...................................2000 David S. Ginley.........................................2000 Yasuhiko Ito.............................................2000 Howard Huff.............................................2000 Robert F. Savinell.....................................2000 Roger Staehle..........................................2000 Charles W. Struck....................................2000 Sergio Trasatti..........................................2000 Dieter M. Kolb..........................................2001 David J. Lockwood...................................2001 James McBreen.......................................2001 Patrick J. Moran.......................................2001 Shohei Nakahara......................................2001 William E. O’Grady...................................2001 Supramanian Srinivasan..........................2001 Mark Allendorf.........................................2002 William Brown..........................................2002 Cor Claeys................................................2002 Martin Kendig..........................................2002 Kim Kinoshita...........................................2002 Paul Kohl..................................................2002 Zempachi Ogumi......................................2002 Tetsuya Osaka..........................................2002 Krishnan Rajeshwar.................................2002 Israel Rubinstein......................................2002 Sigeru Torii..............................................2002 Toshio Shibata.........................................2002 Sorin Cristoloveanu..................................2002 David Duquette........................................2003 Peter Fedkiw............................................2003 Charles Hussey........................................2003 Richard McCreery....................................2003 Frank McLarnon.......................................2003 Robin Susko............................................2003 Darrel Untereker.......................................2003 Osamu Yamamoto....................................2003 G. T. Burstein...........................................2004 C. Clayton.................................................2004 G. Davis...................................................2004 M. J. Deen................................................2004 S. Fonash.................................................2004 M. Meyyappan.........................................2004 J. F. Rusling.............................................2004
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M. Seo.....................................................2004 M. Shur....................................................2004 J. Simonet................................................2004 M. Stratmann...........................................2004 J. Talbot...................................................2004 M. S. Whittingham...................................2004 R. Adzic....................................................2005 J. Davidson..............................................2005 T. Hattori..................................................2005 J. P. Leburton...........................................2005 P. Marcus.................................................2005 C. Martin..................................................2005 P. Natishan...............................................2005 D. Pletcher...............................................2005 B. Scrosati...............................................2005 J. Scully...................................................2005 R. Singh...................................................2005 H. H. Strehblow........................................2005 M. Williams..............................................2005 A. Baca.....................................................2006 S. Bandyopadhyay...................................2006 T. Fahidy...................................................2006 G. Frankel.................................................2006 C. Jagadish..............................................2006 N. Koshida...............................................2006 J. Lessard................................................2006 H. Massoud..............................................2006 H. Yokokawa............................................2006 B. MacDougall..........................................2006 M. Orazem...............................................2006 D. Misra...................................................2006 A. Virkar...................................................2006 A. Wieckowski..........................................2006 Simon S. Ang...........................................2007 Viola Birss................................................2007 Marc Cahay..............................................2007 James M. Fenton......................................2007 Dennis G. Peters......................................2007 Daniel A. Scherson...................................2007 Eric D. Wachsman....................................2007 Doron Aurbach.........................................2008 Albert J. Fry.............................................2008 Fernando Garzon......................................2008 Yury Gogotsi............................................2008 Curtis F. Holmes.......................................2008 Prashant V. Kamat....................................2008 Patrik Schmuki.........................................2008 Gery R. Stafford.......................................2008 Joseph R. Stetter.....................................2008 John Stickney..........................................2008 Thomas Thundat......................................2008 Vladimir Bagotsky....................................2009 Ugo Bertocci............................................2009 Manfred Engelhardt..................................2009 Tom Fuller................................................2009 Peter Hesketh...........................................2009 Uziel Landau............................................2009 Dolf Landheer..........................................2009 Thomas P. Moffat.....................................2009 Ikuzo Nishiguchi......................................2009 Kohei Uosaki............................................2009 133
ECS Honor Roll Fellows (continued) Rudolph G. Buchheit................................2010 Francis D’Souza.......................................2010 Toshio Fuchigami.....................................2010 Michel Houssa.........................................2010 Robert G. Kelly.........................................2010 Roger C. Newman....................................2010 Peter N. Pintauro......................................2010 Peter C. Searson......................................2010 David Shoesmith......................................2010 Bernard Tribollet......................................2010 John W. Weidner......................................2010 David J. Young.........................................2010 Hugh C. DeLong.......................................2011 Hubert Gasteiger......................................2011 Arumugam Manthiram.............................2011 Ashok Kumar Shukla................................2011 Paul C. Trulove.........................................2011 Karim Zaghib............................................2011 Giovanni Zangari......................................2011 Thomas A. Zawodzinski...........................2011 Jeffrey R. Dahn........................................2012 Stefan DeGendt........................................2012 Hariklia Deligianni....................................2012 Andrew Gewirth.......................................2012 Meilin Liu.................................................2012 Junichi Murota.........................................2012 Sri Narayan..............................................2012 Trung Van Nguyen....................................2012 Winston Revie..........................................2012 Daniel Schwartz.......................................2012 Esther Takeuchi........................................2012 Mark Verbrugge.......................................2012 Petr Vanýsek............................................2012 Bruce Weisman........................................2012 Hector Abruña..........................................2013 Nancy Dudney..........................................2013 Gary Hunter.............................................2013 Jiri Janata................................................2013 Johna Leddy............................................2013 Shelley Minteer........................................2013 Sanjeev Mukerjee.....................................2013 Elizabeth Opila..........................................2013 Jan Robert Selman...................................2013 Kalpathy Sundaram..................................2013 Enrico Traversa........................................2013 Martin Winter...........................................2013 George E. Blomgren.................................2014 Gerardine Botte........................................2014 Ralph J. Brodd.........................................2014 Yasuhiro Fukunaka...................................2014 Jay W. Grate.............................................2014 Dirk Guldi.................................................2014 Bruce Parkinson.......................................2014 Fred Roozeboom......................................2014 Alvin Salkind............................................2014 Sudipta Seal.............................................2014 Michael Thackeray...................................2014 Tooru Tsuru..............................................2014 Harry Tuller..............................................2014
Jose Zagal................................................2014 Piotr Zelenay............................................2014 Simon Deleonibus....................................2015 Raymond Gorte........................................2015 Ellen Ivers-Tiffeé......................................2015 Deborah Jones.........................................2015 Robert Kostecki........................................2015 Mogens Mogensen..................................2015 Kailash Mishra.........................................2015 Emanuel Peled.........................................2015 E. Jennings Taylor....................................2015 John Turner..............................................2015 Steven Visco............................................2015 Nick Birbilis..............................................2016 John Goodenough....................................2016 Masahiro Watanabe.................................2016 Hiroshi Imahori........................................2016 Alan C. West............................................2016 Eddy Simoen............................................2016 Bryan Chin...............................................2016 Ram S. Katiyar.........................................2016 Bor Yann Liaw..........................................2016 Jeffrey Fergus..........................................2016 Peter Mascher..........................................2016 A. Robert Hillman.....................................2016 Jürgen Fleig ............................................2016 Christian Amatore....................................2017 Khalil Amine.............................................2017 Plamen Atanassov....................................2017 Scott Barnett............................................2017 Christina Bock..........................................2017 Marca Doeff.............................................2017 Mario Ferreira..........................................2017 Clare Grey................................................2017 Robert Huggins........................................2017 Christopher Johnson................................2017 Joachim Maier.........................................2017 Rangachary Mukundan............................2017 Tae-Yeon Seong.......................................2017 Yang Shao-Horn.......................................2017 Nianqiang Wu..........................................2017
Edward G. Weston Summer Fellowship
(formerly the Edward G. Weston Fellowship, 1930-1945)
E. B. Sanigar............................................1930 K. Solliner................................................1931 M. E. Fogle...............................................1932 R. D. Blue.................................................1933 P. A. Jacquet............................................1934 M. A. Coler...............................................1935 H. B. Linford.............................................1936 G. L. Putnam............................................1937 V. de Nora................................................1938 W. P. Ruemmier.......................................1940 R. E. Black................................................1941 W. E. Roake..............................................1942 R. D. Misch..............................................1947 M. T. Simnad............................................1948 R. L. Brubaker..........................................1961
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D. Yohe....................................................1962 H. O. Daley, Jr..........................................1963 M. D. Hawley............................................1964 T. G. McCord............................................1965 J. D. McLean............................................1966 K. B. Prater...............................................1967 K. Doblhofer.............................................1968 L. R. Faulkner...........................................1969 W. J. Horkans...........................................1970 W. J. Horkans...........................................1971 W. J. Bover...............................................1972 B. J. Alexander.........................................1973 S. S. Fratoni, Jr. ......................................1974 M. Suchanski...........................................1975 R. J. Nowak..............................................1976 P. A. Kohl.................................................1977 C. D. Jaeger.............................................1978 L. Bottomley.............................................1979 G. L. McIntire...........................................1980 J. Pemberton...........................................1981 M. E. Kordesch.........................................1982 R. G. Tompson.........................................1983 P. M. Kovach............................................1984 J. N. Harb.................................................1985 S. E. Creager............................................1986 X. Zhang...................................................1987 C. Amass..................................................1988 R. J. Phillips.............................................1989 J. E. Franke..............................................1990 S. R. Snyder.............................................1991 P. Pantano................................................1992 G. J. Edens...............................................1993 B. Idriss...................................................1994 D. Bizzotto................................................1995 L. A. Lyon.................................................1996 C. Claypool...............................................1997 B. Bath.....................................................1998 A. C. Templeton........................................1999 P. W. Wuelfing..........................................2000 K. Balss....................................................2001 T. Hu........................................................2002 J. Mauzeroll.............................................2003 J. Seegmiller............................................2004 E. Blair.....................................................2005 F. Laforge.................................................2006 Aleix G. Güell............................................2007 Matthew J. Banholzer...............................2008 Shulei Chou..............................................2009 Binh-Minh Nguyen...................................2010 Abrin Schmucker.....................................2011 Sujat Sen..................................................2012 Philippe Dauphin Ducharme.....................2013 Tuncay Ozel..............................................2014 Gen Chen.................................................2015 Soo Kim...................................................2016 Lushan Zhou............................................2017
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Colin Garfield Fink Summer Fellowship
Joseph W. Richards Summer Fellowship
P. Brown...................................................1962 W. G. Lemmermann.................................1963 W. G. Stevens...........................................1964 J. P. Carney..............................................1965 S. Piekarski..............................................1966 B. S. Pons................................................1967 R. E. Bonewitz..........................................1968 L. Papouchado.........................................1969 R. G. Reed................................................1970 R. Fike......................................................1971 D. L. McAllister........................................1972 R. R. Chance............................................1973 P. I. Lee....................................................1974 J. B. Flanagan...........................................1975 J. S. Hammond........................................1976 P. D. Tyma................................................1977 S. M. Wilhelm..........................................1978 J. D. Porter...............................................1979 R. S. Glass...............................................1980 E. E. Bancroft...........................................1981 T. D. Cabeika............................................1982 B. L. Wheeler...........................................1983 E. T. T. Jones............................................1984 D. A. Van Galen........................................1985 J. S. Hanson.............................................1986 P. Gao.......................................................1987 D. T. Schwartz..........................................1988 A. E. Russell.............................................1989 J. Xue.......................................................1990 C. K. Rhee................................................1991 M. J. Shane..............................................1992 C. M. Pharr...............................................1993 J. M. Lauerhaus.......................................1994 S. M. Hendrickson...................................1995 J. C. Hutchinson.......................................1996 P. V. A. Pamidi..........................................1997 G. S. Hwang.............................................1998 W. Baker...................................................1999 A. Crown..................................................2000 R. Maus...................................................2001 S. Peper...................................................2002 M. Alpuche-Aviles....................................2003 A. Mugweru.............................................2004 G. Lica......................................................2005 A. Martinson............................................2006 Prabeer Barpanda....................................2007 Sau Yen Chew..........................................2008 Hyea Kim..................................................2009 Brian Adams............................................2010 Tae-Ho Shin.............................................2011 Devika Sil.................................................2012 Gabriel G. Rodríguez-Calero.....................2013 Christena K. Nash....................................2014 Hadi Khani................................................2015 Yelena Gorlin ...........................................2016
V. E. Hauser, Jr.........................................1960 M. J. Schaer.............................................1961 R. E. Visco...............................................1961 A. K. Postma............................................1962 C. C. Liu...................................................1963 M. J. Vasile..............................................1964 M. J. Vasile..............................................1965 C. C. Liu...................................................1966 B. N. Baron...............................................1967 L. P. Zajicek, Jr.........................................1968 K. R. Bullock............................................1969 S. H. Cadle...............................................1970 J. W. Webb...............................................1971 C. P. Keszthelyi.........................................1972 M. Shabrang............................................1973 D. H. Karweik...........................................1974 T. P. DeAngelis.........................................1975 D. L. Feke.................................................1976 H. Faulkner...............................................1977 D. M. Novak.............................................1978 B. R. Karas...............................................1979 R. M. Cohen.............................................1980 R. N. Dominey..........................................1981 R. M. Ianniello..........................................1982 D. F. Tessier..............................................1983 N. T. Sleszynski........................................1984 C. M. Lieber.............................................1985 J. L. Valdes..............................................1986 R. Q. Bligh................................................1987 D. W. Conrad............................................1988 S. A. Schofield.........................................1989 J. A. Roberts............................................1990 M. S. Freund............................................1991 L. Gao......................................................1992 H. Gasteiger.............................................1993 J. Schoer..................................................1994 S. Morin...................................................1995 N. Madigan...............................................1996 S. Petrovic...............................................1997 J. J. Sumner.............................................1998 A. Wijayawardhana...................................1999 B. Liu.......................................................2000 C. Noble...................................................2001 C. B. France..............................................2002 P. Ramadass............................................2003 J. Carroll..................................................2004 K. Salaita..................................................2005 J. Breger..................................................2006 Sadagopan Krishnan................................2007 Meng Jiang..............................................2008 Haizhou Liu..............................................2009 Mohammad Rez Khajavi...........................2010 Jeyavel Velmurugan.................................2011 Balazs Berkes...........................................2012 Yongjin Lee..............................................2013 Andrey Gunawan......................................2014 Mohammad Mahdi Hasani-Sadrabadi......2015 Charuksha T. Walgama ............................2016 Zakaria Y. Al Balushi.................................2017
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Frederick M. Becket Summer Fellowship
(formerly the F. M. Becket Memorial Award 1962-1999)
R. B. Johnson..........................................1962 J. K. Johnstone........................................1964 K. Lehman................................................1966 H. K. Bowen.............................................1967 T. E. Parker...............................................1971 G. M. Crosbie...........................................1973 N. A. Godshall..........................................1975 J. D. Hodge..............................................1977 W. Cheng.................................................1979 P. Davies..................................................1981 P. A. Barron..............................................1983 G. J. Miller...............................................1985 M. Rosenbluth.........................................1987 J. D. Cotton..............................................1989 J. Philliber................................................1991 P. Agarwal................................................1993 H. C. Slade...............................................1995 K. S. Weil.................................................1997 G. S. Hwang.............................................1999 J. Parrish.................................................2001 S. Wasileski.............................................2002 E. Clark.....................................................2003 F. Deng.....................................................2004 S. Harrison...............................................2005 Y. Yang.....................................................2006 Michael Orthner.......................................2007 Marcos Jose Leitos Santos......................2008 Steve Rhieu..............................................2009 James Whitaker.......................................2011 Celeste Morris..........................................2012 Carlo Santoro...........................................2013 Brandy Kinkead........................................2014 Raphaële Clément....................................2015 Muhammad Boota ...................................2016 Siddesh Umapathi....................................2017
Herbert H.Uhlig Summer Fellowship Natalia Shustova......................................2008 Venkatasubramanian Viswanathan...........2009 Swetha Puchakayala................................2011 Julia van Drunen......................................2012 Junsi Gu...................................................2013 Hadi Tavassol...........................................2014 Alexander Pak..........................................2015 Michael Metzger ......................................2016 Debasmita Dwibedi..................................2017
Energy Research Summer Fellowship
(supported by the U.S. Department of Energy)
M. R. Deakin............................................1985 P. B. Johnson...........................................1985 D. A. La Hurd...........................................1985 S. E. Morris..............................................1985 D. P. Wilkinson.........................................1985 D. G. Frank...............................................1986 K.-C. Ho...................................................1986 135
ECS Honor Roll Energy Research Summer Fellowship (continued)
R. G. Kelly................................................1986 I.-H. Yeo...................................................1986 J. Kwak....................................................1986 L. C. Dash................................................1987 S. A. Naftel...............................................1987 T. R. Nolen...............................................1987 D. Schwartz..............................................1987 T. H. Wong...............................................1987 S. D. Fritts................................................1988 D. A. Koos................................................1988 D. A. Hazlebeck........................................1988 M. O. Schloh............................................1988 S. S. Perine..............................................1988 J. E. Baur.................................................1989 C.-P. Chen................................................1989 D. W. Eng.................................................1989 R. L. McCarley.........................................1989 C. J. Murphy............................................1989 C. K. Nguyen............................................1990 I.-H. Oh....................................................1990 T. G. Strein...............................................1990 J. W. Weidner...........................................1990 S. E. Gilbert..............................................1990 C. S. Johnson...........................................1991 H. Huang..................................................1991 D. R. Lawson...........................................1991 B. D. Pendley...........................................1991 C. C. Streinz.............................................1991 P. A. Connick............................................1992 A. C. Hillier...............................................1992 D. L. Taylor...............................................1992 K. K. Lian.................................................1992 T. T. Nadasdi.............................................1992 D. G. Jensen.............................................1993 J. C. Bart..................................................1993 G. Seshadri..............................................1993 J. A. Poirier..............................................1993 K. W. Vogt................................................1993 Z. Shi.......................................................1994 C.-C. Hsueh..............................................1994 V. A. Adamian...........................................1994 K. M. Maness...........................................1994 K. M. Richard...........................................1994 Y.-E. Sung................................................1995 J. C. Conboy.............................................1995 L. A. Zook.................................................1995 W. R. Everett............................................1995 H. Zhang..................................................1995 S. Grabtchak............................................1996 J.-B. Green...............................................1996 S. Motupally.............................................1996 C. Nasr.....................................................1996 S. Nayak...................................................1996 K. Hu........................................................1997
M. E. Williams..........................................1997 A. Zolfaghari.............................................1997 C. R. Horne..............................................1997 G. K. Jennings..........................................1997 M. Zhao....................................................1998 S. Sriramulu.............................................1998 J. Ritchie..................................................1998 M. A. Elhamid...........................................1998 S. Zou......................................................1998 K. Cooper.................................................2000 K. Grant....................................................2000 D. Hansen................................................2000 J. F. Hicks.................................................2000 Z. Liu........................................................2000
Oronzio de Nora Industrial Electrochemistry Fellowship N. Mano...................................................2004 N. Mano...................................................2005 N. Mano...................................................2006 Vijayasekaran Boovaragavan....................2007 Vijayasekaran Boovaragavan....................2008 Vijayasekaran Boovaragavan....................2009 Wenjing (Angela) Zhang...........................2010
Norman Hackerman Young Author Award (formerly the Young Authors Prize, 1929-1988)
W. C. Gardiner..........................................1929 D. K. Alpern..............................................1930 F. L. Jones................................................1931 F. W. Godsey, Jr........................................1932 B. L. Bailey...............................................1933 J. R. Heard, Jr..........................................1934 U. B. Thomas, Jr......................................1935 W. A. Johnson..........................................1936 R. S. Soanes............................................1937 N. B. Nichols............................................1938 G. A. Moore..............................................1939 J. S. Mackay.............................................1940 E. Adler....................................................1941 S. Speil.....................................................1942 W. G. Berl.................................................1943 J. P. Coyle................................................1944 A. E. Hardy...............................................1945 N. A. Nielsen............................................1946 H. Leidheiser, Jr.......................................1947 M. A. Streicher.........................................1948 J. C. Griess, Jr..........................................1949 G. W. Murphy...........................................1950 J. T. Byrne................................................1951 W. E. Kuhn...............................................1952 J. Halpern.................................................1953 M. J. Pryor...............................................1954 M. Stern...................................................1955 R. S. Cooper.............................................1956 P. Ruetschi...............................................1957 M. Stern...................................................1958 F. A. Posey ..............................................1959 A. C. Makrides..........................................1960
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J. D. Newson............................................1961 M. J. Dignam...........................................1962 J. A. Cunningham.....................................1963 R. E. Westerman......................................1964 R. E. Visco...............................................1965 J. Newman...............................................1966 H. W. Pickering........................................1967 G. G. Charette...........................................1968 G. Dryhurst..............................................1969 J. Newman...............................................1969 W. R. Parrish............................................1969 A. J. Appleby............................................1970 D. C. Johnson..........................................1970 D.-T. Chin.................................................1971 M. S. Whittingham...................................1971 M. A. Hopper............................................1972 F. Kuhn-Kuhnenfeld..................................1972 M. J. Bowden...........................................1973 L. Thompson............................................1973 D. Simonsson..........................................1973 S. H. Cadle...............................................1974 A. D. Dalvi................................................1974 L. R. Faulkner...........................................1975 S. Solmi...................................................1975 P. Negrini.................................................1975 B. MacDougall..........................................1976 S. K. Ubhayakar.......................................1976 C. W. Manke.............................................1977 W. J. Horkans...........................................1977 A. G. Gonzalez..........................................1978 C. H. Tsang...............................................1978 D. A. Antoniadis.......................................1978 D. Y. Wang...............................................1979 C. W. Magee.............................................1979 E. Takayama.............................................1980 H. Reller...................................................1980 W. J. P. Van Enckevort..............................1981 M. W. M. Graef.........................................1981 C. Y. Chao................................................1981 L. F. Lin....................................................1981 D. W. Sittari..............................................1982 T. P. Chow................................................1982 P. G. Pickup..............................................1983 K. F. Jensen..............................................1983 D. B. Graves.............................................1983 N. A. Godshall..........................................1984 E. K. Broadbent........................................1984 J. C. Farmer.............................................1985 G. S. Oehrlein...........................................1985 J. Richer...................................................1986 T. Tanaka..................................................1986 C. P. Wilde................................................1987 P. N. Bartlett.............................................1987 J. Maier....................................................1987 J. A. Bardwell...........................................1988 C.-J. Han..................................................1988 A. E. Husser.............................................1989 D. H. Craston...........................................1989 J. M. Rosamilia........................................1989 J. H. Comfort...........................................1989 M. W. Verbrugge......................................1990
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C. J. Giunta..............................................1990 T. J. Mountziaris.......................................1991 J. V. Cole..................................................1991 D. W. Suggs.............................................1991 B. W. Gregory...........................................1991 D. B. Bonham...........................................1992 E. S. Aydil.................................................1992 P. P. Apte..................................................1993 A. West....................................................1993 H. A. Gasteiger.........................................1994 F. R. Myers...............................................1994 R. Vidal....................................................1995 G. D. Papasouliotis...................................1995 J. H. Nordlien...........................................1996 J. Lee.......................................................1996 A. K. Padhi...............................................1997 S. M. Han.................................................1997 A. D. Robertson.......................................1998 Y. Shao-Horn............................................1998 S. R. Kaluri...............................................1998 A. Bautista................................................1999 P. A. O’Neil...............................................1999 R. T. Leah.................................................2000 J. W. Klaus...............................................2000 J. F. Whitacre...........................................2001 P. Feichtinger...........................................2001 T. J. Pricer................................................2002 P. S. Lee...................................................2002 K. Jambunathan.......................................2003 S. Noda....................................................2003 M. Miyamoto............................................2003 R. Akolkar................................................2004 Y.-K. Hong................................................2004 S. Borini...................................................2005 M. Kunimatsu...........................................2005 Mathieu Bervas........................................2006 Pradeep Dixit............................................2006 Steffen Eccarius.......................................2007 A. T. J. van Niftrik.....................................2007 Kevin Ralston...........................................2008 Eu Jin Tan................................................2008 Yudi Setiawan..........................................2008 Paul Albertus............................................2009 Louis Hutin..............................................2009 Gijs Dingemans........................................2010 Erik Langereis..........................................2010 Stephen E. Potts......................................2010 Xingbao Zhu.............................................2010 Igor Volov................................................2011 Claudia Fleischmann................................2011 Sebastien Couet.......................................2011 Koen Schouteden.....................................2011 Philipp Hönicke........................................2011 Kiersten Horning......................................2012 Sykes Mason ...........................................2012 Balavinayagam Ramalingam....................2012 Rahul Malik..............................................2013 Aziz Abdellahi...........................................2013 Nathaniel D. Leonard................................2014 Trevor M. Braun.......................................2015 Mark Burgess...........................................2016
Kenneth Hernandez-Burgos.....................2016 Raymond Smith.......................................2017
Bruce Deal & Andy Grove Young Author Award Konstantinos Spyrou................................2013 Pengfei Guo.............................................2014 Ran Cheng...............................................2014 Wei Wang.................................................2014 Kohei Shima.............................................2015 Peng Sun.................................................2016 Shihyun Ahn............................................2017
ECS General Society Student Poster Session Awards F. Forouzan...............................................1993 D. L. Taylor...............................................1993 L. Abraham..............................................1994 A. J. Aldykiewicz......................................1994 A. Dalmia.................................................1994 M. Murthy................................................1994 R. Munkundan.........................................1995 A. E. Thomas............................................1995 C. E. Ramberg..........................................1995 W. Wang..................................................1995 S. Chen....................................................1996 K. Kowal...................................................1996 C. Leger...................................................1997 E. Potteau.................................................1997 K. Bera.....................................................1998 E. Dickenson............................................1998 G. Q. Lu....................................................1998 M. W. Riley...............................................1998 J. Pearton.................................................1999 A. Templeson...........................................1999 N. Baydokhi..............................................2000 A. Pismenny.............................................2000 A. Besing..................................................2001 V. Sochnikov............................................2001 S. Dimovski..............................................2002 P. Maitra...................................................2002 H. Ohtsuka...............................................2002 T. Wiley....................................................2002 P. Kavanagh.............................................2003 B. Monahan..............................................2003 O. Rabin...................................................2003 P. Scopece...............................................2003 K. Yasuda.................................................2003 M. Guan...................................................2004 K. Kanaizuka.............................................2004 A. Oide.....................................................2004 R. M. Todi................................................2004 W. J. Cheong............................................2005 J. Chmiola................................................2005 S. Chrisanti..............................................2005 C. Drake...................................................2005 D. L. Gonzalez-Parra................................2006 Naoko Kamiura........................................2006 T. Takeyasu...............................................2006 Arun Vijayakumar.....................................2006
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Naoaki Hashimoto....................................2007 Daisuke Kikutani......................................2007 Toyoki Okumura.......................................2007 Gholamreza Rostamikia...........................2007 Arun Vijayakumar.....................................2007 Rajwant Singh Bedi..................................2008 Bryan K. Boggs........................................2008 John Chmiola...........................................2008 Yuta Ishigami...........................................2008 J. S. O’Brien.............................................2008 Tyler Osborn............................................2008 Ralf Peipmann..........................................2008 Philippe Perret.........................................2008 Kenji Takada.............................................2008 Vinit Todi..................................................2008 Natalia B. Shustova..................................2008 Joshua Snyder.........................................2008 Tomomasa Sugiyama...............................2008 Anasuya Adibhatla....................................2009 Magdalena Gizowska................................2009 Frederik Golks..........................................2009 Karina Kangas..........................................2009 Kiera A. Kurak..........................................2009 Manale Maalouf........................................2009 Debasish Mohanty...................................2009 Natalia Shustova......................................2009 Joko Sutrisno...........................................2009 Jaroslaw Syzdek......................................2009 Alex Avekians...........................................2010 Shayna Brocato........................................2010 Pablo de la Iglesia....................................2010 Christian Desilets.....................................2010 Ayesha Maria Hashambhoy......................2010 Carolin Lau...............................................2010 Raja S. Mannam.......................................2010 Joshua P. McClure...................................2010 Sarvesh Pasem........................................2010 Robert Sacci............................................2010 Misato Tashiro.........................................2010 Jesse Benck.............................................2011 Benjamin Caire.........................................2011 Zhebo Chen..............................................2011 Damilola Daramola...................................2011 Kirsten Marie Jensen...............................2011 Javed Khan..............................................2011 Simon Lux................................................2011 Ashley Maes.............................................2011 Lingchong Mai.........................................2011 Francis Richey..........................................2011 Neil Spinner.............................................2011 Melissa Vandiver......................................2011 Georgi Bodurov........................................2012 Aurelien Etiemble ....................................2012 Kiersten Horning .....................................2012 Yoon Jang Kim.........................................2012 Prabhu Doss Mani...................................2012 K. Sykes Mason.......................................2012 Seungha Oh.............................................2012 Michael Siedlik.........................................2012 Bong Seob Yang......................................2012 Yoshinobu Adachi....................................2012 137
ECS Honor Roll ECS General Society Student Poster Session Awards (continued)
Kwi Nam Han...........................................2012 Takashi Hasegawa....................................2012 Cheng Ai Li...............................................2012 Shigeta Yagyu..........................................2012 Michal Osiak............................................2013 Andrew J. Naylor......................................2013 Danielle Smiley........................................2013 Mohammed Boota....................................2013 Kelsey B. Hatzall.......................................2013 Christopher R. Dennison..........................2013 Tobias Placke...........................................2013 Buido Schmuelling...................................2013 Richard Kloepsch.....................................2013 Olga Fromm.............................................2013 Sergej Rothermel.....................................2013 Paul Meister.............................................2013 Kristy Jost................................................2013 John McDonough....................................2013 Takashi Tsuda...........................................2013 Masanari Hashimoto................................2013 Axel Gambou-Bosca.................................2014 Miguel Angel Arellano Gonzalez...............2014 Andrew Durney........................................2014 Elizabeth Hotvedt.....................................2014 Andrew R. Akbashev................................2014 Jorge Ivan Aldana-Gonzalez.....................2014 Heather Barkholtz.....................................2015 Subrahmanyam Goriparti.........................2015 Daiki Ito....................................................2015 Jonathan Kucharyson..............................2015 Maria Lukatskaya.....................................2015 Kenta Machida.........................................2015 Rajankumar Patel.....................................2015 Xiaoxing Xia.............................................2015 Mallory Fuhst...........................................2016 Shota Matsumura....................................2016 Hiyori Sakata............................................2016 Masahiro Kato..........................................2016 Futaba Yamamoto....................................2016 Masha Lotfi Marchoubeh.........................2016 Leanne Mathurin......................................2016 Isaac Taylor..............................................2016 Haitham Kalil............................................2016 Katrina Vuong and Laurie Clare................2017 Emily Gullette, Natalie Handson, Emily Klutz, and Meredith Hammer..........2017 Oliver Harris.............................................2017 Josie Duncan and Mary Heustess............2017 Saad Intikhab...........................................2017 Sungyup Jung..........................................2017 Mariko Kadowaki......................................2017 Abubakar Khaleed....................................2017 Yubin Liu..................................................2017 Phuong Tu Mai.........................................2017 Travis Omasta..........................................2017 Hiroki Shiikuma........................................2017 Sanjana Das and Stephanie Silic..............2017
ECS Sponsored Meeting Student Poster Award Winners Simposio Brasileiro de Electroquimica e Eletroanalitica (SIBEE) L. M. Nunes.............................................2009 Felipe Ibanhi Pires....................................2011 V. Dos Santos...........................................2013 China Semiconductor Technology International Conference (CSTIC) C. Santini.................................................2009 L. Ma........................................................2010 M. B. Gonzalez.........................................2011 Chien Chi Chen.........................................2012 Tao Deng..................................................2013 Meng Lin..................................................2014 Jin Jisong................................................2015 Xiaofei Wu................................................2015 Yanfen Xiao..............................................2015 Alberto V. de Oliveira ...............................2016 Jie Cheng.................................................2016 SImposio Brasileiro de Extroquimica e Electroanalitica (XXI SIBEE) Marilya Palmeira Galdino da Silva............2017 Filipe Soares da Cruz................................2017 Thais Tasso Guaraldo...............................2017 Euro CVD Award A. Szkudlarek...........................................2011 IC4N: From Nanoparticles and Nanomaterials to Nanodevices and Nanosystems M. Gharbi.................................................2009 H. N. Green..............................................2011 Mariana Sendova.....................................2013 Brian DiMarco..........................................2016 Sociedad Mexicana de Electroquímica (SMEQ) and ECS Mexican Section Meeting A. Mendez-Albores...................................2008 L. S. Hernandez-Munoz............................2009 C. Avila-Gonzalez.....................................2010 D. C. Martinez-Casillas.............................2011 Lidia G. Trujano-Ortiz...............................2012 Paola Yamela De la Cruz-Guzmán............2013 Maria Dámaris Cortez Diaz.......................2015 Gibran Hernandez-Moreno.......................2016
ECS Toyota Young Investigator Fellowship Awards
Patrick Cappillino.....................................2015 David Go..................................................2015 Yogesh Surendranath...............................2015 Elizabeth Biddinger..................................2016 Joaquin Rodriguez Lopez.........................2016 Joshua Snyder.........................................2016 Ahmet Kusoglu........................................2017 Julie Renner.............................................2017 Shuhui Sun..............................................2017
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Turner Book Prize
S. Speil.....................................................1942 W. G. Berl.................................................1943 J. P. Coyle................................................1944 J. T. Waber...............................................1945 B. Cartwright............................................1946 A. E. Hardy...............................................1947 M. A. Streicher.........................................1948 R. E. Hoeckelman.....................................1949 P. Delahay................................................1950 K. H. Stern...............................................1951 C. C. Templeton........................................1951 P. T. Gilbert...............................................1952 R. B. Holden.............................................1953 D. A. Vermilyea........................................1954 J. G. Jewell...............................................1955 J. H. Westbrook.......................................1956 A. C. Makrides..........................................1957 J. P. Pemsler............................................1958 R. G. Carlson............................................1959 R. E. Meyer..............................................1960 P. C. Milner...............................................1960 H. Freitag.................................................1961 P. J. Boddy...............................................1962 E. J. Cairns...............................................1963 M. Weinstein............................................1963 R. W. Bartlett............................................1964 E. M. Hofer...............................................1965 C. S. Tedmon, Jr.......................................1966 F. P. Kober................................................1967 J. M. Hale.................................................1968
Leadership Circle Awards Legacy Level Dow Chemical Co., Central Research, received 2011 Olin Chlor Alkali Products Division, received 2011 Occidental Chemical Corp., received 2013 Energizer, received 2015 Medallion Level Occidental Chemical Corp., received 2007 Atotech USA, Inc., received 2009 Energizer, received 2009 Diamond Level General Electric Co., Corporate Research & Development, received 2011 General Motors Research Laboratories, received 2001 Rayovac, received 2002 Duracell, received 2006 IBM Corporation, received 2006 Gold Level Toshiba Corp., Research & Development Center, received 1998 Siltronic AG, received 1998 Osram Sylvania, Inc., Chemical & Metallurgical Division, received 1999 Sandia National Laboratories, received 2000 International Lead Zinc Research Organization, Inc., received 2003
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Medtronic, Inc., Energy and Component Center, received 2004 Toyota Central Research and Development Labs, Inc., received 2004 Yuasa Corp, received 2004 Princeton Applied Research/Solartron Analytical, received 2005 Saft Batteries, received 2006 CSIRO Minerals, received 2007 Industrie de Nora, received 2007 Ballard Power Systems, Inc., received 2008 ECO Energy Conversion, received 2008 Varta Automotive GmbH, Advanced Battery Division, received 2008 Leclanche S. A., received 2009 Max-Planck-Institut für Festkörperforschung, received 2009 Giner, Inc., received 2010 Greatbatch, Inc., received 2010 TIMCAL Graphite and Carbon Ltd., received 2011 3M Company, received 2014 Princeton Applied Research/Solartron Analytical, received 2016 Silver Level Eltech Systems Corp., received 1992 Tronox LLC, received 1994 Japan Storage Battery Co., Ltd., received 1997 3M Company, received 1998 E. I. Du Pont de Nemours & Co., Inc., HD Microsystems, received 1998 Solartron Instruments, received 1999 Central Electrochemical Research Institute, received 2002 TDK Corp., R&D Center, received 2002 Valence Technology, received 2002 DAISO, Co., Ltd., received 2003 Panasonic Corp., received 2003 C. Uyemura & Co., Ltd., Central Research Lab, received 2005 Electrosynthesis Co., Inc., received 2005 FMC Corporation, Active Oxidants Division, received 2005 Nacional de Grafite, LTDA, received 2005 Permelec Electrode, Ltd., received 2005 PPG Industries, Inc., Chemicals Group Technical Center, received 2005 Scribner Associates, Inc., received 2005 Technic Inc., received 2005 Advance Research Chemicals, Inc., received 2007 Yeager Center for Electrochemical Sciences at CWRU, received 2007 PEC North America, received 2009 Quallion, LLC, received 2009 UTC Power, received 2009 Broddarp of Nevada, received 2010 Teledyne Energy Systems, Inc., received 2010 OM Group, Inc., received 2012 Evonik Degussa GmbH, received 2013 Permascand AB, received 2013
Lawrence Berkeley National Lab, received 2014 ZSW, received 2014 Faraday Technology, Inc., received 2016 Metrohm USA, received 2016 Pine Research Instrumentation, received 2016 Bronze Level Hach Company, Radiometer Analytical Division, received 2002 De Nora Technologie Elettrochimiche S.r.L., received 2003 BAE Systems Battery Technology Center, received 2005 Agilent Laboratories, received 2008 Evonik Degussa GmbH, received 2008 Samsung SDI, received 2008 GAIA-Akkumulatorenwerke GmbH, received 2009 Permascand AB, received 2009 ZSW Center for Solar Energy & Hydrogen Research, received 2009 Coolohm, Inc., received 2010 ElectroChem, Inc., received 2010 Faraday Technology, Inc., received 2010 Johnson Matthey, received 2010 Metrohm USA, received 2010 Pine Research Instrumentation, received 2010 Sanyo Electric Co. Ltd., received 2011 Nissan Motor Co. Ltd., received 2011 Hydro-Québec, received 2011 Bio-Logic USA/Bio-Logic SAS, received 2012 ENEOS CELLTECH Co. Ltd., received 2012 Fortu Research GmbH, received 2012 Gamry Instruments, received 2012 Rockwood Lithium, received 2012 Asahi Kasei E-Materials Corp., received 2014 Gelest, Inc., received 2014 Honda R+D Co. Ltd., received 2014 Next Energy EWE-Forschungszentrum, received 2014 Los Alamos National Laboratory, received 2015 Toyota Research Institute of North America, received 2015
Battery Division Student Research Award
J. R. Waggoner........................................1980 K. E. Yee...................................................1980 W. A. van Schalkwijk................................1981 C. Y. Mak..................................................1986 T. I. Evans................................................1987 C. C. Streinz.............................................1988 J. Weidner................................................1989 M. G. Lee.................................................1990 E. J. Podlaha............................................1991 G. E. Gray.................................................1992 D. Qu........................................................1993 P. De Vidts................................................1994
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S. Motupally.............................................1995 J. Xu.........................................................1996 Y. Shao-Horn............................................1997 I. Courtney...............................................1998 G.E. Rousse.............................................1999 V. Srinivasan............................................2000 M. Zhao....................................................2001 V. Subramaniam.......................................2001 L. Fransson..............................................2002 K.-W. Park................................................2003 A. Weber..................................................2004 C. Delacourt.............................................2005 K. Kang....................................................2006 Feng Jiao..................................................2007 Nonglak Meethong...................................2009 Yi-Chun Lu...............................................2010 Christopher Fell........................................2011 Yuhui Chen...............................................2012 Mohammed Ati........................................2013 Martin Ebner............................................2014 Matteo Bianchini......................................2015 Billur Deniz Polat Karahan .......................2016 Lin Ma......................................................2017
Battery Division Research Award
J. J. Lander..............................................1958 D. M. Smyth.............................................1959 T. P. Dirkse...............................................1962 F. G. Will...................................................1964 J. Burbank................................................1966 C. P. Wales...............................................1966 D. Tuomi..................................................1968 Y. Okinaka................................................1970 A. C. Simon .............................................1972 S. M. Caulder...........................................1972 J. McBreen...............................................1974 T. Katan....................................................1976 S. Szpak...................................................1976 A. Heller...................................................1978 K. R. Bullock............................................1980 R. A. Huggins...........................................1982 D. Pavlov..................................................1984 G. H. J. Broers.........................................1985 J. L. Devitt................................................1986 D. H. McClelland......................................1986 J. P. Gabano.............................................1987 M. Armand...............................................1988 J. Jorne....................................................1989 A. N. Dey..................................................1990 R. E. White...............................................1991 D. N. Bennion...........................................1992 E. Peled....................................................1993 K. M. Abraham.........................................1995 J. Dahn.....................................................1996 B. Scrosati...............................................1997 C. Delmas.................................................1999 J. B. Bates................................................2000 S. Wittingham..........................................2002 K. Kinoshita..............................................2003 J. Newman...............................................2004 G. Ceder...................................................2004 M. Thackeray...........................................2005 139
ECS Honor Roll Battery Division Research Award (continued)
T. Ohzuku.................................................2006 Clare P. Grey............................................2007 Peter G. Bruce..........................................2008 Linda Nazar..............................................2009 Dominique Guyomard..............................2010 Yang-Kook Sun........................................2011 Stefano Passerini.....................................2012 Doron Aurbach.........................................2013 Arumugam Manthiram.............................2014 Martin Winter...........................................2015 Yang Shao-Horn.......................................2016 Nobuyuki Imanishi...................................2016 Ryoji Kanno..............................................2017
Battery Division Technology Award Y. Nishi.....................................................1994 K. Ozawa..................................................1994 E. S. Takeuchi...........................................1995 S. Gilman.................................................1996 J.-M. Tarascon.........................................1997 G. E. Blomgren.........................................1998 A. Yoshino................................................1999 H. Y. Cheh................................................2000 B. B. Owens.............................................2001 D. Wilkinson.............................................2002 M. Winter.................................................2002 J. Yamaki.................................................2003 M. Yoshio.................................................2003 M. Ue.......................................................2004 D. Aurbach...............................................2005 P. Novak...................................................2005 K. Lee.......................................................2006 Michel Broussely......................................2007 Hiroshi Inoue...........................................2008 Satoshi Mizutani......................................2008 Eiji Endoh.................................................2009 Khalil Amine.............................................2010 Jeffrey Dahn.............................................2011 Yet-Ming Chiang.......................................... 2012 Karim Zaghib................................................ 2013 Feng Wu....................................................... 2014 Ashok Shukla............................................... 2015 Dominique Guyomard.................................. 2016
Jun Liu.....................................................2017
Battery Division Postdoctoral Associate Research Award Sponsored by MTI Corporation and the Jiang Family Foundation Yelena Gorlin............................................2016 Liumin Suo..............................................2016 Haegyeom Kim ........................................2017 Kimberly See............................................2017
Corrosion Division H. H. Uhlig Award (formerly the Outstanding Achievement Award of the Corrosion Division 1973-1983)
M. Cohen.................................................1973 D. A. Vermilyea........................................1975 J. Kruger..................................................1977 M. J. Pryor...............................................1979 T. R. Beck.................................................1981 N. Sato.....................................................1983 P. Kofstad.................................................1985 H. W. Pickering........................................1987 R. P. Frankenthal......................................1989 H. Leidheiser............................................1991 H. Isaacs..................................................1993 W. H. Smyrl..............................................1995 M. J. Graham...........................................1997 K. Hashimoto...........................................1999 D. Macdonald...........................................2001 F. Mansfeld...............................................2002 C. Leygraf.................................................2003 R. Newman..............................................2004 P. Marcus.................................................2005 G. T. Burstein...........................................2006 Edward McCafferty...................................2007 Martin Stratmann.....................................2008 John R. Scully..........................................2009 Gerald S. Frankel......................................2010 Patrik Schmuki.........................................2011 Hans-Henning Strehblow.........................2012 Mário Ferreira..........................................2013 Paul Natishan...........................................2014 David Shoesmith......................................2015 Robert G. Kelly.........................................2016 Herman Terryn.........................................2017
Corrosion Division Morris Cohen Graduate Student Award (formerly the Corrosion Division Award for Summer Study 1986-1988)
S. D. Scarberry........................................1986 C. C. Streinz.............................................1987 R. Bianco.................................................1988 M. A. Harper.............................................1992 R. G. Buchheit..........................................1993 J.-F. Yan...................................................1994 B. V. Cockeram.........................................1995 I. Odnevall................................................1996 D. G. Kolman............................................1997 C. S. Brossia............................................1998 M. Verhoff................................................1999 S. Yu........................................................2000 S. F. Nitodas.............................................2001 K. Cooper.................................................2002 T. Ramgopal.............................................2003 Q. Meng...................................................2004 D. Chidambaram......................................2005 H. Tsuchiya..............................................2006
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Magnus Johnson.....................................2007 Christopher D. Taylor...............................2008 Mariano Iannuzzi......................................2009 Pouria Ghods...........................................2010 Hongbo Cong...........................................2011 Mariano Kappes.......................................2012 Quentin Van Overmeere...........................2013 Yolanda Hedberg......................................2014 Eric Schindelholz......................................2015 Saman Hosseinpour.................................2016 Mohsen Esmaily.......................................2017
Dielectric Science and Technology Division Thomas D. Callinan Award J. A. Davies..............................................1968 J. P. S. Pringle..........................................1968 G. M. Sessler...........................................1970 J. E. West.................................................1970 C. A. Mead...............................................1971 W. Kern....................................................1972 J. R. Szedon.............................................1973 C. M. Osburn............................................1975 T. W. Hickmott..........................................1976 J. R. Ligenza............................................1977 R. Williams...............................................1978 R. J. Kriegler............................................1979 B. E. Deal.................................................1982 L. Young..................................................1983 A. K. Sinha...............................................1985 A. C. Adams.............................................1986 S. P. Murarka...........................................1987 R. B. Comizzoli.........................................1988 E. A. Irene................................................1988 R. A. Levy.................................................1989 M. H. Woods............................................1990 V. J. Kapoor..............................................1991 S. I. Raider...............................................1992 D. W. Hess...............................................1993 Y.-H. Wong...............................................1994 K. L. Mittal...............................................1995 W. D. Brown.............................................1996 J. P. Dismukes.........................................1997 R. Singh...................................................1998 A. Rohatgi................................................1999 K. Saraswat..............................................2000 P. Ho........................................................2001 J. Deen.....................................................2002 S. K. Banerjee...........................................2003 A. G. Revesz.............................................2003 S. Fonash.................................................2004 Paul A. Kohl.............................................2008 Tsu-Jae King Liu......................................2011 Durgamadhab (Durga) Misra...................2013 Kalpathy Sundaram..................................2015 Hiroshi Iwai..............................................2017
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Electrodeposition Division Early Career Investigator Award Yihua Liu..................................................2016 Jiahua Zhu...............................................2017
Electrodeposition Division Research Award W. Weil.....................................................1980 Y. Okinaka................................................1981 E. B. Budevski..........................................1982 R. C. Alkire...............................................1983 L. T. Romankiw........................................1984 R. J. von Gutfeld......................................1984 J. W. Dini.................................................1985 H. R. Johnson..........................................1985 H. Leidheiser............................................1986 J. P. Hoare................................................1987 H. Y. Cheh................................................1988 D. S. Lashmore........................................1989 S. Nakahara..............................................1990 T. C. Franklin............................................1991 R. E. White...............................................1992 P. C. Andricacos.......................................1993 M. J. Froment...........................................1994 D. Landolt................................................1995 T. Osaka...................................................1996 M. Schlesinger.........................................1997 Madhav Datta...........................................1998 R. Winand................................................1999 H. Honma.................................................2000 D. Kolb.....................................................2002 J. Switzer.................................................2003 J. Dukovic................................................2004 P. Bartlett.................................................2005 T. P. Moffat.............................................. 2006 Ibro Tabakovic..........................................2007 Olaf Magnussen.......................................2008 John Stickney..........................................2009 Takayuki Homma......................................2010 Philippe Allongue.....................................2011 Hariklia Deligianni....................................2012 Daniel Lincot............................................2013 Alan C. West............................................2014 Daniel Schwartz.......................................2015 Stephen Maldonado.................................2016 Stanko Brankovic.....................................2017
Electronics and Photonics Division Award F. A. Trumbore..........................................1970 F. C. Palilla................................................1971 M. B. Panish.............................................1972 W. A. Pliskin.............................................1973
B. E. Deal.................................................1974 H. M. Manasevit.......................................1975 M. G. Craford...........................................1976 A. Y. Cho..................................................1977 C. M. Wolfe..............................................1978 E. Sirtl......................................................1979 J. M. Woodall...........................................1980 G. A. Rozgonyi.........................................1981 G. W. Cullen.............................................1982 D. W. Shaw..............................................1983 A. Reisman...............................................1984 S-M. Hu...................................................1985 E. H. Nicollian...........................................1986 B. Schwartz..............................................1987 K. E. Bean.................................................1988 T. Kamins.................................................1989 D. M. Brown.............................................1990 C. M. Osburn............................................1991 G. S. Oehrlein...........................................1992 B. S. Meyerson.........................................1993 G. K. Celler...............................................1994 L. C. Kimerling.........................................1995 H. Huff.....................................................1996 A. F. Tasch................................................1997 U. M. Gösele............................................1999 S. N. G. Chu.............................................2000 S. P. Murarka...........................................2001 S. Cristoloveanu.......................................2002 T. Ohmi....................................................2003 C. Claeys..................................................2004 S. Pearton................................................2005 H. Massoud..............................................2006 Yue Kuo...................................................2007 Fan Ren....................................................2008 Eicke R. Weber.........................................2009 Lih J. Chen...............................................2010 M. Jamal Deen.........................................2011 Chennupati Jagadish ...............................2012 Durgamadhab (Durga) Misra...................2013 Albert Baca...............................................2014 Cammy Abernathy....................................2015 Michael Shur............................................2016 D. Noel Buckley........................................2017
Energy Technology Division Research Award M. W. Verbrugge......................................1994 S. Srinivasan............................................1996 H. R. Kunz................................................1998 A. W. Czanderna.......................................1999 R. Selman................................................2001 I. Uchida...................................................2001 A. Nozik....................................................2003 K. Kinoshita..............................................2004 K. Kanamura............................................2005 S. Licht.....................................................2006 Radoslav Adzic.........................................2007
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Yang Kook Sun........................................2007 Tom Fuller................................................2008 Krishnan Rajeshwar.................................2009 Jai Prakash..............................................2009 John Weidner...........................................2010 Karim Zaghib............................................2010 Claude Levy-Clément...............................2011 Piotr Zelenay............................................2013 James Fenton...........................................2014 Rodney Borup..........................................2015 Thomas Zawodzinski ...............................2016 Hubert Gasteiger......................................2017
Energy Technology Division Srinivasan Young Investigator Award Vijay Ramani............................................2012 Adam Weber............................................2012 Stefan Freunberger..................................2013 Minhua Shao............................................2014 William Mustain.......................................2015 Prabeer Barpanda ...................................2016 Ahmet Kusoglu........................................2017
Energy Technology Division Graduate Student Award sponsored by Bio-Logic Thomas Dursch........................................2014 James Radich..........................................2014 Scott Cushing..........................................2015 Haegyeom Kim.........................................2015 Matthew Genovese ..................................2016 Antoni Forner-Cuenca..............................2017
High Temperature Materials Division Outstanding Achievement Award J. B. Wagner, Jr........................................1986 W. L. Worrell............................................1988 R. A. Rapp................................................1990 H. Schmalzried.........................................1992 S. C. Singhal............................................1994 C. G. Vayenas...........................................1996 C. Bernard................................................2001 H. Yokokawa............................................2002 K. Spear...................................................2004 A. Virkar...................................................2006 David J. Young.........................................2008 Harry L. Tuller..........................................2010 Eric Wachsman........................................2012 Janusz Nowotny.......................................2014 Harlan Anderson......................................2016
High Temperature Materials Division J. B. Wagner, Jr. Young Investigator Award S. Mohney................................................1999 S. M. Haile...............................................2001 M. Swihart...............................................2003 141
ECS Honor Roll High Temperature Materials Division J. B. Wagner, Jr. Young Investigator Award (continued) R. Mukundan...........................................2005 Xiao-Dong Zhou.......................................2007 Juan Claudio Nino....................................2009 Toshiaki Matsui........................................2011 Paul Gannon............................................2013 Sean Bishop.............................................2015 Cortney Kreller.........................................2017
Industrial Electrochemistry and Electrochemical Engineering Division New Electrochemical Technology (NET) Award Asahi Glass Company..............................1999 DeNora Tecnologie...................................2005 E-Tek........................................................2005 Bayer Material Science AG.......................2005 Ballard Power Systems............................2007 FuelCell Energy........................................2009 U.S. Army Engineer Research and Development Center, Construction Engineering Research Laboratory, and Electro Tech CP........................................2011 UTC Power...............................................2013 Matthew Ward Brodt................................2014 Proton OnSite..........................................2015
Industrial Electrochemistry and Electrochemical Engineering Division H. H. Dow Memorial Student Achievement Award R. Bakshi..................................................1991 G. J. Yusem..............................................1992 J. A. Poirier..............................................1993 S. Siu.......................................................1994 M. Vreeke.................................................1995 A. E. Thomas............................................1996 S. A. Leith................................................1997 P. Soo.......................................................1998 S. Sriramulu.............................................1999 K. M. Jeerage...........................................2000 A. L. Prieto...............................................2001 W. He.......................................................2002 J. Zhang...................................................2003 S. Basker..................................................2004 V. Ramani.................................................2005 N. Jalani...................................................2006 Brenda L. Garcia-Diaz..............................2007 Sunil Roy.................................................2008 Prabeer Barpanda....................................2009 Brandon Bartling......................................2010 Long Cai...................................................2011 Meng Li....................................................2012
Young Woo-Lee.......................................2013 Matthew Ward Brodt................................2014 Santosh Vijapu.........................................2015 Muhammad Boota....................................2017
Industrial Electrochemistry and Electrochemical Engineering Division Student Achievement Award Y.-E. Sung................................................1995 J. K. N. Mbindyo......................................1996 C. A. Smith...............................................1997 J. A. Drake...............................................1998 R. Lowrey.................................................1999 C. Arvin....................................................2000 B. Djurfors...............................................2001 V. Subramanian........................................2002 P. M. Gomadam.......................................2003 I. AlNashef...............................................2004 V. Sethuraman..........................................2006 Minhua Shao............................................2007 Vinten Dewikar.........................................2008 Paul Albertus............................................2009 Satheesh Sambandam.............................2010 Venkatasailanathan Ramadesigan............2011 Rainer Kungas..........................................2012 Wei Yan....................................................2013 Christopher Arges....................................2013 Paul Northrop..........................................2014 Venkata Raviteja Yarlagadda....................2014 Vedasri Vedharathinam............................2014 Mohammad Mahdi Hasani-Sadrabadi......2015 Regis P. Dowd, Jr.....................................2016 Bahareh Alsadat Tavakoli Mehrabadi........2017
SES Research Young Investigator Award of the Nanocarbons Division Nikhil Koratkar.........................................2009 Mark C. Hersam.......................................2010 Aurelio Mateo-Alonso..............................2012 Jiayan Luo................................................2016
Organic and Biological Electrochemistry Division Manuel Baizer Memorial Award T. Shono...................................................1994 H. Lund....................................................1996 H. Schäfer................................................1998 S. Torii.....................................................1998 J. Simonet................................................2000 J. Utley.....................................................2000 J. M. Savéant...........................................2002 M. Tokuda................................................2004 D. Evans...................................................2004 I. Nishiguchi.............................................2006 Albert Fry.................................................2008 Toshio Fuchigami.....................................2010 Dennis Peters...........................................2012 Jun-Ichi Yoshida......................................2014 Kevin Moeller...........................................2016
Physical and Analytical Electrochemistry Division David C. Grahame Award Luminescence and Display Materials Division Centennial Award A. Meijerink..............................................2004 A. Srivastava............................................2004 H. Guedel.................................................2006 David J. Lockwood...................................2010 Hajime Yamamoto....................................2012 Baldassare Di Bartolo ..............................2016
Nanocarbons Division Richard E. Smalley Research Award Sumio Ijima..............................................2008 Phaedon Avouris......................................2009 Robert Haddon.........................................2011 Nazario Martín..........................................2013 Dirk Guldi.................................................2015 Shunichi Fukuzumi...................................2017
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F. C. Anson...............................................1983 J. Newman...............................................1985 A. Heller...................................................1987 M. J. Weaver............................................1989 B. Miller...................................................1991 A. T. Hubbard...........................................1993 R. M. Wightman.......................................1995 D. M. Kolb................................................1997 P. N. Ross, Jr............................................1999 D. A. Scherson.........................................2001 A. Wieckowski..........................................2003 H. White...................................................2005 Joseph T. Hupp........................................2007 Héctor D. Abruña.....................................2009 Masatoshi Osawa.....................................2011 Richard L. McCreery................................2013 Hubert Gasteiger......................................2015 Viola Birss................................................2017
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Physical and Analytical Electrochemistry Division Max Bredig Award in Molten Salt Chemistry M. Blander...............................................1987 G. P. Smith..............................................1990 R. A. Osteryoung......................................1992 G. Mamantov...........................................1994 N. Bjerrum...............................................1996 H. A. Øye..................................................1998 Y. Ito........................................................1999 G. N. Papatheodorou................................2002 M. Gaune-Escard.....................................2004 J. Wilkes..................................................2006 Bernard Gilbert.........................................2008 C. Austen Angell.......................................2010 Derek Fray................................................2012 Charles Hussey........................................2014 Masayoshi Watanabe...............................2016
Southern Wisconsin Section.......... 1989-1990 North Texas Section....................... 1990-1991 Southern Wisconsin Section.......... 1991-1992 Southern Wisconsin Section.......... 1992-1993 New England Section..................... 1993-1994 National Capital Section................. 1994-1995 National Capital Section................. 1995-1996 National Capital Section................. 1996-1997 Canadian Section and National Capital Section................. 1997-1998 Chicago Section............................. 1998-1999 New England Section..................... 1999-2000 National Capital and New England Section..................... 2000-2001 National Capital Section................. 2001-2002 National Capital Section................. 2002-2003 San Francisco Section.................... 2003-2004 San Francisco Section.................... 2004-2005 San Francisco Section.................... 2005-2006
Canada Section Electrochemical Award
Sensor Division Outstanding Achievement Award J. Janata...................................................1994 R. P. Buck.................................................1996 I. Lundström............................................1998 A. J. Ricco................................................2000 M. Aizawa.................................................2002 N. Yamazoe..............................................2004 W. Heineman............................................2006 Chung-Chiun Liu......................................2008 Thomas Thundat......................................2010 Sheikh Ali Akbar.......................................2012 Peter Hesketh...........................................2014 Rangachary Mukundan............................2016
Sensor Division Student Paper Award Jeffrey Kirsch...........................................2012 Kazuaki Edagawa......................................2012
Gwendolyn B. Wood Section Excellence Award Metropolitan New York Section...... 1975-1976 Columbus Section.......................... 1976-1977 Chicago Section............................. 1979-1980 Chicago Section............................. 1980-1981 Chicago Section............................. 1981-1982 Southern Wisconsin Section.......... 1982-1983 Southern Wisconsin Section.......... 1983-1984 Southern Wisconsin Section.......... 1984-1985 National Capital Section................. 1985-1986 North Texas Section....................... 1986-1987 Southern Wisconsin Section.......... 1987-1988 Chicago Section............................. 1988-1989
E. J. Casey...............................................1982 Brian E. Conway.......................................1986 L. Young..................................................1990 S. Flengas................................................1994 Jacek Lipkowski.......................................1998 Jean Lessard............................................2002 Jeffrey R. Dahn........................................2006 David Shoesmith......................................2010
Canada Section R. C. Jacobsen Award George Fraser..........................................1988 Barry MacDougall....................................1990 Louis Brossard.........................................1994 Ernest E. Criddle......................................2002 Sharon G. Roscoe....................................2006 Jacek Lipkowski.......................................2010
Canada Section W. Lash Miller Award J. L. Ord...................................................1969 J. E. Desnoyers........................................1971 A. K. Vijh..................................................1973 W. R. Fawcett...........................................1975 W. A. Adams, A. J. Spring Thorpe............1977 Barry MacDougall....................................1979 David W. Shoesmith.................................1981 A. Belanger...............................................1983 Viola I. Birss.............................................1985 S. Das Gupta............................................1987 K. Tomantscher, D. Leaist........................1989 Jennifer Bardwell.....................................1991 Jeff Dahn..................................................1993 Alireza Zolfaghari-Hesari..........................1999 Daniel Bizzotto.........................................2001 Jamie Noel...............................................2003 Aicheng Chen...........................................2009 Hua-Zhong (Hogan) Yu............................2011 Not Awarded............................................2013 Federico Rosei.........................................2015 Yurij Mozharivskyj....................................2017
The Electrochemical Society Interface • Summer 2018 • www.electrochem.org
Canada Section Student Award Jean St-Pierre..........................................1988 Gessie Brisard..........................................1989 James Hinatsu.........................................1990 Gregory Jerkiewicz...................................1991 Hubert Dumont........................................1992 Meijie Zhang............................................1993 Dan Bizzoto..............................................1994 Sylvie Morin.............................................1995 Alexandre Brolo........................................1996 Aicheng Chen...........................................1997 Ian A. Courtney........................................1998 Dany Brouillette........................................1999 Shiyuan Qian............................................1999 Bryan Park...............................................2000 Luc Beaulieu............................................2001 Vlad Zamliny............................................2002 Sandra Rifai.............................................2003 Amy Lloyd................................................2004 M. Toupin.................................................2006 Thamara Laredo.......................................2007 Arash Shahryari.......................................2008 Mohamed Naser.......................................2009 Mohammed Naser....................................2010 Ahmad Ghahremaninezhad......................2011 Karen Chan..............................................2012 Drew Higgins...........................................2013 Leah Ellis..................................................2017
Cleveland Section Ernest B. Yeager Electrochemistry Award B. Miller...................................................2004 Richard McCreery....................................2006 Uziel Landau............................................2008 Jacek Lipkowski.......................................2010 Gerald Frankel..........................................2012
Europe Section Heinz Gerischer Award Akira Fujishima........................................2003 Michael Graetzel.......................................2005 Allen J. Bard.............................................2007 Rüdiger Memming...................................2009 Helmut Tributsch......................................2011 Arthur Nozik.............................................2013 Adam Heller.............................................2015 Kazuhito Hashimoto.................................2017
Europe Section Alessandra Volta Award M. Armand...............................................2000 J.-M. Tarascon.........................................2002 R. G. Compton.........................................2004 Bruno Scrosati.........................................2006 Not Awarded............................................2010 Jean-Noël Chazalviel................................2012 Phillip Bartlett..........................................2014 Christian Amatore....................................2016
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ECS Honor Roll Georgia Section Student Award Matthew Lynch.........................................2012 Kara Evanoff.............................................2013 Johanna Karolina Stark............................2014
India Section S. K. R. Graduate Student Award S. Anantharaj...........................................2017
Korea Section Student Award Ho-Suk Ryu..............................................2006 Jae-Hwan Oh............................................2007 Sung Ki Cho.............................................2008 Cheol-Min Park........................................2009 Ji-Hyung Han...........................................2010 Young Woo Lee........................................2011 Not Awarded............................................2012 Seong Min Bak.........................................2013 Haegyeom Kim.........................................2014 Minah Lee................................................2015 Changshi Jo.............................................2016 Hye Won Jeong........................................2017
National Capital Section William Blum Award W. Blum...................................................1958 S. Schuldiner...........................................1960 D. N. Craig...............................................1962 A. Brenner................................................1964 J. Kruger..................................................1966 J. Burbank................................................1969 K. H. Stern...............................................1972 B. F. Brown...............................................1974 A. C. Simon..............................................1976 R. T. Foley................................................1978 R. de Levine.............................................1980 E. McCafferty...........................................1982 R. L. Jones...............................................1984 Ugo Bertocci............................................1986 P. J. Moran...............................................1988 M. H. Peterson.........................................1990 D. S. Lashmore........................................1992 J. R. Scully...............................................1994 Paul M. Natishan......................................1996 G. D. Davis...............................................1998 W. E. O'Grady...........................................2000 Thomas P. Moffat.....................................2002 J. L. Hudson.............................................2004
National Capital Section Robert T. Foley Award R. T. Foley................................................1989 W. J. Hamer.............................................1991 G. E. Stoner..............................................1993 P. J. Moran...............................................1995 P. M. Natishan..........................................1997 J. Kruger..................................................1999 R. G. Kelly................................................2001
San Francisco Section Daniel Cubicciotti Student Award L. J. Oblonsky..........................................1995 Y. Ma........................................................1996 C. Wade...................................................1997 C. R. Horne..............................................1998 M. Tucker.................................................1999 L. V. Protsailo...........................................2000 H. Visser..................................................2001 D. Wheeler...............................................2002 J. Hollingsworth.......................................2003 E. Guyer...................................................2004 D. Steingert..............................................2005 Sarah Stewart..........................................2006 James Wilcox...........................................2007 Susan Ambrose........................................2008 Que Anh Nguyen...... Honorable Mention 2008 Yuan Yang ............... Honorable Mention 2008 Paul Albertus............................................2009 Andrew Lee.............. Honorable Mention 2009 Mark Oliver ............. Honorable Mention 2009 Venkat Viswanathan.................................2010 Yi Wei Chen.............. Honorable Mention 2010 Thomas Conry......... Honorable Mention 2010 Maureen Tang..........................................2011 Yi Wei Chen.............. Honorable Mention 2011 Thomas Conry......... Honorable Mention 2011 Allison Engstrom......................................2012 Matthew McDowell...... Honorable Mention 2012 Xiongwu Kang.......... Honorable Mention 2012 Daniel Cohen............................................2013
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Mallory Hammock.... Honorable Mention 2013 Anthony Ferrese....... Honorable Mention 2013 Nian Liu....................................................2014 Isaac Markus............ Honorable Mention 2014 Alan Berger.............. Honorable Mention 2014 Karthish Manthiram.................................2015 Christina Li............... Honorable Mention 2015 Lei Cheng................. Honorable Mention 2015 Yiyang Li .................................................2016 William Nguyen........ Honorable Mention 2016 Katherine Harry........ Honorable Mention 2016 Andrew Scheuermann......Honorable Mention 2016 Tianyu Liu................................................2017 Colin Burke.............. Honorable Mention 2017 Limei Chen............... Honorable Mention 2017
Outstanding Student Chapter Award University of Maryland.............................2013 Ohio University.....Chapter of Excellence 2013 University of Texas at Austin......Chapter of Excellence 2013 University of Texas at Austin....................2014 University of Maryland...........Chapter of Excellence 2014 Valley of the Sun (Central Arizona).......Chapter of Excellence 2014 Indiana University....................................2015 University of Virginia.............Chapter of Excellence 2015 University of Maryland...........Chapter of Excellence 2015 University of South Carolina....................2016 University of Kentucky...........Chapter of Excellence 2016 University of Maryland...........Chapter of Excellence 2016 University of Maryland.............................2017 Munich Student Chapter.................Chapter of Excellence 2017 University of Washington.......Chapter of Excellence 2017
The Electrochemical Society Interface â&#x20AC;˘ Summer 2018 â&#x20AC;˘ www.electrochem.org
Future ECS Meetings CanCun, MEXiCO September 30-October 4, 2018
2018
aiMES 2018
TM
AMERICAS INTERNATIONAL MEETING ON ELECTROCHEMISTRY AND SOLID STATE SCIENCE
Moon Palace Resort
235th ECS Meeting DallaS, TX May 26-May 31, 2019 Sheraton Dallas
236th ECS Meeting aTlanTa, Ga October 13-17, 2019 Hilton Atlanta
2019 2019
237th ECS Meeting
with the 18th International Meeting on Chemical Sensors (IMCS 2020)
MOnTrEal, CanaDa May 10-15, 2020
Palais des congress de Montreal
www.electrochem.org/meetings
2020
ECS Institutional Members The Electrochemical Society values the support of its institutional members. These organizations help ECS support scientific education, sustainability, and innovation. Through ongoing partnerships, ECS will continue to lead as the advocate, guardian, and facilitator of electrochemical and solid state science and technology.
2018 Leadership Circle Award Recipients GOLD (25 years)
SILVER (10 years)
Bio-Logic USA/Bio-Logic SAS Central Electrochemical Research Institute
DLR-Institut für Vernetzte Energiesysteme e.V.
Benefactor Hydro-Québec (11) Industrie De Nora S.p.A. (35) Pine Research Instrumentation (12) Saft Batteries, Specialty Batteries Group (36)
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(Number in parentheses indicates years of membership)
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Please help us continue the vital work of ECS by joining as an institutional member today. Contact Shannon.Reed@electrochem.org for more information.