Abstract
Surfaces/interfaces that respond to external stimulus, such as pH, salt, temperature, photo and electric field, represent one of the most active and emerging scientific research areas and have many unexplored applications. This evolving research field faces lots of exciting challenges regarding the design, fabrication and engineering of the surfaces/interfaces. In this chapter, the scientific progress in the area of stimulus-responsive gas-solid and liquid-solid surfaces/interfaces is highlighted. First, the synthetic methods of stimulus-responsive surfaces/interfaces by polymerization (grafting-from, grafting-to and grafting-through approaches) and adsorption of stimulus-responsive polymeric materials (micelles and microgels) are introduced. Then, the methods for characterization of such surfaces/interfaces, including spectroscopic and radiation methods, are discussed followed by descriptions of their applications in adhesion, lubrication, sensor, actuator, drug delivery and cell culture. Finally, challenges and future trends in this exciting field are also discussed. Tight interdisciplinary research is crucial to continue developing science and engineering of the stimulus-responsive surfaces/interfaces.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Abbott S, Ralston J, Reynolds G, Hayes R (1999) Reversible wettability of photoresponsive pyrimidine-coated surfaces. Langmuir 15:8923–8928
Abbott SA, de Vos WM, Mears LLE, Skoda M, Dalgliesh R, Edmondson S, Richardson RM, Prescott SW (2016) Switching the interpenetration of confined asymmetric polymer brushes. Macromolecules 49:4349–4357
Abrakhi S, Péralta S, Fichet O, Teyssié D, Cantin S (2013) Poly(azobenzene acrylate-co-fluorinated acrylate) spin-coated films: influence of the composition on the photo-controlled wettability. Langmuir 29:9499–9509
Advicula RC, Brittain WJ, Caster KC, Ruhe J (2004) Polymer brushes. Wiley, Hoboken
Agrawal M, Rueda JC, Uhlmann P, Müller M, Simon F, Stamm M (2012) Facile approach to grafting of poly(2-oxazoline) brushes on macroscopic surfaces and applications thereof. ACS Appl Mater Interfaces 4:1357–1364
Ahn SK, Kasi RM, Kim SC, Sharma N, Zhou YX (2008) Stimuli-responsive polymer gels. Soft Matter 4:1151–1157
Akiyama Y, Kikuchi A, Yamato M, Okano T (2004) Ultrathin poly(N-isopropylacrylamide) grafted layer on polystyrene surfaces for cell adhesion/detachment control. Langmuir 20:5506–5511
Angelov B, Angelova A, Garamus VM, Lebas G, Lesieur S, Ollivon M, Funari SS, Willumeit R, Couvreur P (2007) Small-angle neutron and x-ray scattering from amphiphilic stimuli-responsive diamond-type bicontinuous cubic phase. J Am Chem Soc 129:13474–13479
Auernheimer J, Dahmen C, Hersel U, Bausch A, Kessler H (2005) Photoswitched cell adhesion on surfaces with RGD peptides. J Am Chem Soc 127:16107–16110
Azzaroni O, Brown AA, Huck WTS (2006) UCST wetting transitions of polyzwitterionic brushes driven by self-association. Angew Chem Int Ed 45:1770–1774
Azzaroni O, Brown AA, Huck WTS (2007) Tunable wettability by clicking counterions into polyelectrolyte brushes. Adv Mater 19:151–154
Baghi M, Mack MG, Hambek M, Rieger J, Vogl T, Gstoettner W, Knecht R (2005) The efficacy of MRI with ultrasmall superparamagnetic iron oxide particles (USPIO) in head and neck cancers. Anticancer Res 25:3665–3670
Bain CD (1995) Sum-frequency vibrational spectroscopy of the solid/liquid interface. J Chem Soc Faraday Trans 91:1281–1296
Balamurugan S, Mendez S, Balamurugan SS, O’Brien MJ, López GP (2003) Thermal response of poly(N-isopropylacrylamide) brushes probed by surface plasmon resonance. Langmuir 19:2545–2549
Barea MJ, Jenkins MJ, Gaber MH, Bridson RH (2010) Evaluation of liposomes coated with a pH responsive polymer. Int J Pharm 402:89–94
Basak S, Nanda J, Banerjee A (2014) Multi-stimuli responsive self-healing metallo-hydrogels: tuning of the gel recovery property. Chem Commun 50:2356–2359
Bassik N, Abebe B, Laflin K, Gracias D (2010) Photolithographically patterned smart hydrogel based bilayer actuators. Polymer 51:6093–6098
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL (1992) A new family of mesoporous molecular sieves prepared with liquid crystal templates. J Am Chem Soc 114:10834–10843
Bell NS, Piech M (2006) Photophysical effects between spirobenzopyran-methyl methacrylate-functionalized colloidal particles. Langmuir 22:1420–1427
Berry CC, Wells S, Charles S, Aitchison G, Curtis AS (2004) Cell response to dextran-derivatised iron oxide nanoparticles post internalization. Biomaterials 25:5405–5413
Bialk M, Prucker O, Rühe J (2002) Grafting of polymers to solid surfaces by using immobilized methacrylates. Colloids Surf A Physicochem Eng Asp 198-200:543–549
Biggs S, Sakai K, Addison T, Schmid A, Armes SP, Vamvakaki M, Bütün V, Webber GB (2007) Layer-by-layer formation of smart particle coatings using oppositely charged block copolymer micelles. Adv Mater 19:247–250
Binnig G, Quate CF, Gerberl C (1986) Atomic force microscope. Phys Rev Lett 56:930–933
Blasberg RG (2003) Molecular imaging and cancer. Mol Cancer Ther 2:335–343
Bonnemain B (1998) Superparamagnetic agents in magnetic resonance imaging: physicochemical characteristics and clinical applications a review. J Drug Target 6:167–174
Brown P, Butts CP, Eastoe J (2013) Stimuli-responsive surfactants. Soft Matter 9:2365–2374
Brunsen A, Díaz C, Pietrasanta LI, Yameen B, Ceolín M, Soler-Illia GJAA, Azzaroni O (2012) Proton and calcium-gated ionic mesochannels: phosphate-bearing polymer brushes hosted in mesoporous thin films as biomimetic interfacial architectures. Langmuir 28:3583–3592
Burtovyy R, Luzinov I (2008) Reversibility of pH-induced dewetting of poly(vinyl pyridine) thin films on silicon oxide substrate. Langmuir 24:5903–5910
Cassie ABD, Baxter S (1944) Wettability of porous surfaces. Trans Faraday Soc 40:546–551
Chaimberg M, Cohen Y (1994) Kinetic modeling of free-radical graft polymerization. AICHE J 40:294–311
Chécot F, Brûlet A, Oberdisse J, Gnanou Y, Mondain-Monval O, Lecommoandoux S (2005) Structure of polypeptide-based diblock copolymers in solution: stimuli-responsive vesicles and micelles. Langmuir 21:4308–4315
Cheesman BT, Willott JD, Webber GB, Edmondson E, Wanless EJ (2012) pH-responsive brush-modified silica hybrids synthesized by surface-initiated ARGET ATRP. ACS Macro Lett 1:1161–1165
Cheesman BT, Smith EG, Murdoch TJ, Guibert C, Webber GB, Edmondson S, Wanless EJ (2013) Polyelectrolyte brush pH-response at the silica-aqueous solution interface: a kinetic and equilibrium investigation. Phys Chem Chem Phys 15:14502–14510
Chen XY, Randall DP, Perruchot C, Watts JF, Patten TE, von Werne T, Armes SP (2003) Synthesis and aqueous solution properties of polyelectrolyte-grafted silica particles prepared by surface-initiated atom transfer radical polymerization. J Colloid Interface Sci 257:56–64
Chen L, Liu M, Bai H, Chen P, Xia F, Han D, Jiang L (2009) Antiplatelet and thermally responsive poly(N-isopropylacrylamide) surface with nanoscale topography. J Am Chem Soc 131:10467–10472
Chen T, Ferris R, Zhang J, Ducker R, Zauscher S (2010) Stimulus-responsive polymer brushes on surfaces: transduction mechanisms and applications. Prog Polym Sci 35:94–112
Chen Y-H, Chung Y-C, Wang I-J, Young T-H (2012) Control of cell attachment on pH-responsive chitosan surface by precise adjustment of medium pH. Biomaterials 33:1336–1342
Chen J, Xiao P, Gu J, Han D, Zhang J, Sun A, Wang W, Chen T (2014) A smart hybrid system of Au nanoparticle immobilized PDMAEMA brushes for thermally adjustable catalysis. Chem Commun 50:1212–1214
Cheng X, Canavan HE, Stein MJ, Hull JR, Kweskin SJ, Wagner MS, Somorjai GA, Castner DG, Ratner BD (2005) Surface chemical and mechanical properties of plasma-polymerized N-isopropylacrylamide. Langmuir 21:7833–7841
Chiefari J, Chong YK, Ercole F, Krstina J, Jeffery J, Le TPT, Mayadunnne RTA, Meijs GF, Moad CL, Moad G, Rizzardo E, Thang SH (1998) Living free-radical polymerization by reversible addition-fragmentation chain transfer: the RAFT process. Macromolecules 31:5559–5562
Cho EC, Kim YD, Cho K (2005) Temperature-dependent intermolecular force measurement of poly(N-isopropylacrylamide) grafted surface with protein. J Colloid Interface Sci 286:479–486
Choi J, Schattling P, Jochum FD, Pyun J, Char K, Theato P (2012) Functionalization and patterning of reactive polymer brushes based on surface reversible addition and fragmentation chain transfer polymerization. J Polym Sci A 50:4010–4018
Christau S, Möller T, Yenice Z, Genzer J, von Klitzing R (2014) Brush/gold nanoparticle hybrids: effect of grafting density on the particle uptake and distribution within weak polyelectrolyte brushes. Langmuir 30:13033–13041
Christau S, Möller T, Brose F, Genzer J, Soltwedel O, von Klitzing R (2016) Effect of gold nanoparticle hydrophobicity on thermally induced color change of PNIPAM brush/gold nanoparticle hybrids. Polymer 98:454–463
Chung PW, Kumar R, Pruski M, Lin VSY (2008) Temperature responsive solution partition of organic-inorganic hybrid poly(N-isopropylacrylamide)-coated mesoporous silica nanospheres. Adv Funct Mater 18:1390–1398
Coessens V, Pintauer T, Matyjaszewski K (2001) Functional polymers by atom transfer radical polymerization. Prog Polym Sci 26:337–377
Cole MA, Voelcker NH, Thissen H, Griesser HJ (2009) Stimuli-responsive interfaces and systems for the control of protein–surface and cell–surface interactions. Biomaterials 30:1827–1850
Cole MA, Voelcker NH, Thissen H, Horn RG, Griesser HJ (2010) Colloid probe AFM study of thermal collapse and protein interactions of poly(N-isopropylacrylamide) coatings. Soft Matter 6:2657–2667
Corbierre MK, Cameron NS, Sutton M, Mochrie SGJ, Lurio LB, Rühm A, Lennox RB (2001) Polymer-stabilized gold nanoparticles and their incorporation into polymer matrices. J Am Chem Soc 123:10411–10412
Corbierre MK, Cameron NS, Lennox RB (2004) Polymer-stabilized gold nanoparticles with high grafting densities. Langmuir 20:2867–2873
Crosby AJ, Shull KR (1999) Adhesive failure analysis of pressure-sensitive adhesives. J Polym Sci Polym Phys 37:3455–3472
Currie EPK, Sieval AB, Fleer GJ, Cohen Stuart MA (2000) Polyacrylic acid brushes: surface pressure and salt-induced swelling. Langmuir 16:8324–8333
Cunliffe D, Alarcon CD, Peters V, Smith JR, Alexander C (2003) Thermoresponsive surface-grafted poly(N-isopropylacrylamide) copolymers: effect of phase transitions on protein and bacterial attachment. Langmuir 19:2888–2899
D’Souza AJ, Schowen RL, Topp EM (2004) Polyvinylpyrrolidone–drug conjugate: synthesis and release mechanism. J Control Release 94:91–100
Daltorio KA, Horchler AD, Gorb S, Ritzmann RE, Quinn RD (2005) A small wall-walking robot with compliant, adhesive feet. Proc Int Conf Intell Robots Syst:3648–3653
Dar YL, Yuan-Huffman W, Shah S, Huang D, Xiao A (2007) Thermally activated pressure-sensitive adhesives. J Adhes Sci Technol 21:1645–1658
Datta P, Genzer J (2013) Computer simulation of template polymerization using a controlled reaction scheme. Macromolecules 46:2474–2484
Datta P, Genzer J (2016) “Grafting through” polymerization involving surface-bound monomers. Polym Chem 54:263–274
de Gennes PG (1980) Conformations of polymers attached to an interface. Macromolecules 13:1069–1075
Denes FS, Manolache S (2004) Macromolecular plasma-chemistry: an emerging field of polymer science. Prog Polym Sci 29:815–885
Dübner M, Spencer ND, Padeste C (2014) Light-responsive polymer surfaces via postpolymerization modification of grafted polymer-brush structures. Langmuir 30:14971–14981
Ducker WA, Senden TJ, Pashley RM (1991) Direct measurement of colloidal forces using an atomic force microscope. Nature 353:239–241
Dutta NK, Truong MY, Mayavan S, Choudhury NR, Elvin CM, Kim M, Knott R, Nairn KM, Hill AJ (2011) A genetically engineered protein responsive to multiple stimuli. Angew Chem Int Ed 50:4428–4431
Dzhoyashvili NA, Thompson K, Gorelov AV, Rochev YA (2016) Film thickness determines cell growth and cell sheet detachment from spin-coated poly(N-isopropylacrylamide) substrates. ACS Appl Mater Interfaces 8:27564–27572
Eastoe J, Sánchez-Dominguez M, Wyatt P, Heenan RK (2004) A photo-responsive organogel. Chem Commun:2608–2609
Edahiro J, Sumaru K, Tada Y, Ohi K, Takagi T, Kameda M, Shinbo T, Kanamori T, Yoshimi Y (2005) In situ control of cell adhesion using photoresponsive culture surface. Biomacromolecules 6:970–974
Edmondson S, Nguyen NT, Lewis AL, Armes SP (2010) Co-nonsolvency effects for surface-initiated poly(2-(methacryloyloxy)ethyl phosphorylcholine) brushes in alcohol/water mixtures. Langmuir 26:7216–7226
Ejaz M, Yamamoto S, Ohono K, Tsujii Y, Fukuda T (1998) Controlled graft polymerization of methyl nethacrylate on silicon substrate by the combined use of the Langmuir-Blodgett and atom transfer radical polymerization techniques. Macromolecules 31:5934–5936
Emilsson G, Schoch RL, Feuz L, Höök F, Lim RYH, Dahlin AB (2015) Strongly stretched protein resistant poly(ethylene glycol) brushes prepared by grafting-to. ACS Appl Mater Interfaces 7:7505–7515
Fazli Y, Kulani E, Khezri K, Alijani H (2015) PMMA-grafted silica aerogel nanoparticles via in situ SR&NI ATRP: grafting through approach. Micropor Mesopor Mat 214:70–79
Feiler A, Plunkett MA, Rutland MW (2003) Atomic force microscopy measurements of adsorbed polyelectrolyte layers. 1. Dynamics of forces and friction. Langmuir 19:4173–4179
Fielding LA, Edmondson S, Armes SP (2011) Synthesis of pH-responsive tertiary amine methacrylate polymer brushes and their response to acidic vapour. J Mater Chem 21:11773–11780
Fischer H (1997) The persistent radical effect in “living” radical polymerization. Macromolecules 30:5666–5672
Fischer H, Radom L (2001) Factors controlling the addition of carbon-centered radicals to alkenes-an experimental and theoretical perspective. Angew Chem Int Ed Engl 40:1340–1371
Fitzgerald PA, Dupin D, Armes SP, Wanless EJ (2007) In situ observations of adsorbed microgel particles. Soft Matter 3:580–586
Fitzgerald PA, Amalvy JI, Armes SP, Wanless EJ (2008) Film-forming microgels for pH-triggered capture and release. Langmuir 24:10228–10234
Fong W-K, Hanley T, Boyd BJ (2009) Stimuli responsive liquid crystals provide ‘on-demand’ drug delivery in vitro and in vivo. J Control Release 135:218–226
Fong W-K, Hanley TL, Thierry B, Hawley A, Boyd BJ, Landersdorfer CB (2016) External manipulation of nanostructure in photoresponsive lipid depot matrix to control and predict drug release in vivo. J Control Release 228:67–73
Frisman I, Shachaf Y, Seliktar D, Bianco-Peled H (2011) Stimulus-responsive hydrogels made from biosynthetic fibrinogen conjugates for tissue engineering: structural characterization. Langmuir 27:6977–6986
Fu Q, Rama-Rao GV, Ista LK, Wu Y, Andrzejewski BP, Sklar LA, Ward ST, López GP (2003) Control of molecular transport through stimuli-responsive ordered mesoporous materials. Adv Mater 15:1262–1266
Fujii S, Okada M, Furuzono T (2007) Hydroxyapatite nanoparticles as stimulus-responsive particulate emulsifiers and building block for porous materials. J Colloid Interface Sci 315:287–296
Fujii S, Suzaki M, Armes SP, Dupin D, Hamasaki S, Aono K, Nakamura Y (2011a) Liquid marbles prepared from pH-responsive sterically stabilized latex particles. Langmuir 27:8067–8074
Fujii S, Suzaki M, Nakamura Y, Sakai K, Ishida N, Biggs S (2011b) Surface characterization of nanoparticles carrying pH-responsive polymer hair. Polymer 51:6240–6247
Fujii S, Aono K, Suzaki M, Hamasaki S, Yusa S, Nakamura Y (2012a) pH-responsive hairy particles synthesized by dispersion polymerization with a macroinitiator as an inistab and their use as a gas-sensitive liquid marble stabilizer. Macromolecules 45:2863–2873
Fujii S, Sanada Y, Nishimura T, Akiba I, Sakurai K (2012b) A stimulus-responsive shape-persistent micelle bearing a calix[4]arene building block: reversible pH-dependent transition between spherical and cylindrical forms. Langmuir 28:3092–3101
Fujii S, Sawada S, Nakayama S, Kappl M, Ueno K, Shitajima K, Butt HJ, Nakamura Y (2016) Pressure-sensitive adhesive powder. Mater Horiz 3:47–52
Gao Q, Xu Y, Wu D, Sun Y, Li X (2009) pH-responsive drug release from polymer-coated mesoporous silica spheres. J Phys Chem C 113:12753–12758
Gawlitza K, Turner ST, Polzer F, Wellert S, Karg M, Mulvaney P, von Klitzing R (2013) Interaction of gold nanoparticles with thermoresponsive microgels: influence of the cross-linker density on optical properties. PCCP 15:15623–15631
Geoghegan M, Ruiz-Pérez L, Dang CC, Parnell AJ, Martin SJ, Howse JR, Jones RAL, Golestanian R, Topham PD, Crook CJ, Ryan AJ, Sivia DS, Websterc JRP, Menelled A (2006) The pH-induced swelling and collapse of a polybase brush synthesized by atom transfer radical polymerization. Soft Matter 2:1076–1080
Georges MK, Veregin RPN, Kazmaier PM, Hamer GK (1990) Narrow molecular weight resins by a free-radical polymerization process. Macromolecules 26:2987–2988
Giacomelli C, Le Men L, Borsali R, Lai-Kee-Him J, Brisson A, Armes SP, Lewis AL (2006) Phosphorylcholine-based pH-responsive diblock copolymer micelles as drug delivery vehicles: light scattering, electron microscopy, and fluorescence experiments. Biomacromolecules 7:817–828
Gong P, Wu T, Genzer J, Szleifer I (2007) Behavior of surface-anchored poly(acrylic acid) brushes with grafting density gradients on solid substrates: 2. Theory. Macromolecules 40:8765–8773
Groten J, Bunte C, Rühe J (2012) Light-induced switching of surfaces at wetting transitions through photoisomerization of polymer monolayers. Langmuir 28:15038–15046
Gupta AK, Gupta M (2005) Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials 26:3995–4021
Gurney RS, Dupin D, Nunes JS, Ouzineb K, Siband E, Asua JM, Armes SP, Keddie JL (2012) Switching off the tackiness of a nanocomposite adhesive in 30 s via infrared sintering. ACS Appl Mater Interfaces 4:5442–5452
Gurney RS, Dupin D, Siband E, Ouzineb K, Keddie JL (2013) Large-area patterning of the tackiness of a nanocomposite adhesive by sintering of nanoparticles under IR radiation. ACS Appl Mater Interfaces 5:2137–2145
Han D-M, Zhang QM, Serpe MJ (2015) Poly(N-isopropylacrylamide)-co-(acrylic acid) microgel/Ag nanoparticle hybrids for the colorimetric sensing of H2O2. Nanoscale 7:2784–2789
Hawker CJ, Bosman AW, Harth E (2001) New polymer synthesis by nitroxide mediated living radical polymerizations. Chem Rev 101:3661–3688
Hayashida S, Sato H, Sugawara S (1986) Photo-induced wettability change in films containing spiropyran microcrystals. Polym J 18:227–235
He Q, Küller A, Grunze M, Li JB (2007) Fabrication of thermosensitive polymer nanopatterns through chemical lithography and atom transfer radical polymerization. Langmuir 23:3981–3987
Henze M, Mädge D, Prucker O, Rühe J (2014) “Grafting through”: mechanistic aspects of radical polymerization reactions with surface-attached monomers. Macromolecules 47:2929–2937
Higaki Y, Fröhlich B, Yamamoto A, Murakami R, Kaneko M, Takahara A, Tanaka M (2017) Ion-specific modulation of interfacial interaction potentials between solid substrates and cell-sized particles mediated via zwitterionic, super-hydrophilic poly(sulfobetaine) brushes. J Phys Chem B 121:1396–1404
Higuchi A, Hamamura A, Shindo Y, Kitamura H, Yoon BO, Mori T, Uyama T, Umezawa A (2004) Photon-modulated changes of cell attachments on poly(spiropyran-co-methyl methacrylate) membranes. Biomacromolecules 5:1770–1774
Hill MR, Carmean RN, Sumerlin BS (2015) Expanding the scope of RAFT polymerization: recent advances and new horizons. Macromolecules 48:5459–5469
Hirotsu T, Isayama M (1989) Water-ethanol separation by pervaporation through plasma-graft-polymerized membranes of 2-hydroxyethyl methacrylate with acrylic acid or methacrylic acid. J Membr Sci 45:137–154
Hong CY, Li X, Pan CY (2008) Smart core-shell nanostructure with a mesoporous core and a stimuli-responsive nanoshell synthesized via surface reversible addition-fragmentation chain transfer polymerization. J Phys Chem C 112:15320–15324
Hong CY, Li X, Pan CY (2009) Fabrication of smart nanocontainers with a mesoporous core and a pH-responsive shell for controlled uptake and release. J Mater Chem 19:5155–5160
Hoogenboom R (2009) Poly(2-oxazoline)s: a polymer class with numerous potential applications. Angew Chem Int Ed 48:7978–7994
Howard SC, Craig VSJ, Fitzgerald PA, Wanless EJ (2010) Swelling and collapse of an adsorbed pH-responsive film-forming microgel measured by optical reflectometry and QCM. Langmuir 26:14615–14623
Howse JR, Topham P, Crook CJ, Gleeson AJ, Bras W, Jones RAL, Ryan AJ (2006) Reciprocating power generation in a chemically driven synthetic muscle. Nano Lett 6:73–77
Huang HQ, Penn LS (2005) Dense tethered layers by the “grafting-to” approach. Macromolecules 38:4837–4843
Huang H, Penn LS, Quirk RP, Cheong TH (2004) Kinetics of sequential tethering in formation of mixed layers. Macromolecules 37:5807–5813
Humphreys BA, Willott JD, Murdoch TJ, Webber GB, Wanless EJ (2016) Specific ion modulated thermoresponse of poly(N-isopropylacrylamide) brushes. Phys Chem Chem Phys 18:6037–6046
Husseman M, Eva Malmström EE, McNamara M, Mate M, Mecerreyes D, Benoit DG, Hedrick JL, Mansky P, Huang E, Russell TP, Hawker CJ (1999) Controlled synthesis of polymer brushes by “living” free radical polymerization techniques. Macromolecules 32:1424–1431
Hwang I, Jeon WS, Kim H-J, Kim D, Kim H, Selvapalam N, Fujita N, Shinkai S, Kim K (2007) Cucurbit[7]uril: a simple macrocyclic pH-triggered hydrogelator exhibiting guest-induced stimuli-responsive behaviour. Angew Chem 119:214–217
Ide M, Mori T, Ichikawa K, Kitano H, Tanaka M, Mochizuki A, Oshiyama H, Mizuno W (2003) Structure of water sorbed into poly(MEA-co-HEMA) films as examined by ATR-IR spectroscopy. Langmuir 19:429–435
Idota N, Kikuchi A, Kobayashi J, Akiyama Y, Sakai K, Okano T (2006) Thermal modulated interaction of aqueous steroids using polymer-grafted capillaries. Langmuir 22:425–430
Inoue M, Fujii S, Nakamura Y, Iwasaki Y, Yusa S (2011) pH-responsive disruption of ‘liquid marbles’ prepared from water and poly(6-(acrylamide)hexanoic acid)-grafted silica particles. Polym J 43:778–784
Ionov L, Houbenov N, Sidorenko A, Stamm M, Minko S (2006) Smart microfluidic channels. Adv Funct Mater 16:1153–1160
Ishida N, Biggs S (2007a) Direct observation of the phase transition for a poly(N-isopropylacryamide) layer grafted onto a solid surface by AFM and QCM-D. Langmuir 23:11083–11088
Ishida N, Biggs S (2007b) Salt-induced structural behavior for poly(N-isopropylacryamide)grafted onto solid surface observed directly by AFM and QCM-D. Macromolecules 40:9045–9052
Ishida N, Biggs S (2010) Effect of grafting density on phase transition behavior for poly(N-isopropylacryamide) brushes in aqueous solutions studied by AFM and QCM-D. Macromolecules 43:7269–7276
Ishida N, Kobayashi M (2006) Interaction forces measured between poly(N-isopropylacrylamide) grafted surface and hydrophobic particle. J Colloid Interface Sci 297:513–519
Islam M, Serpe MJ (2014) Poly(N-isopropylacrylamide) microgel-based thin film actuators for humidity sensing. RSC Adv 4:31937–31940
Ito A, Kuga Y, Honda H, Kikkawa H, Horiuchi A, Watanabe Y, Kobayashi T (2004) Magnetite nanoparticle-loaded anti-HER2 immunoliposomes for combination of antibody therapy with hyperthermia. Cancer Lett 212:167–175
Iwata H, Oodate M, Uyama Y, Amemiya H, Ikeda Y (1991) Preparation of temperature-sensitive membranes by graft polymerization onto a porous membrane. J Membr Sci 55:119–130
Iwata T, Yamato M, Tsuchioka H, Takagi R, Mukobata S, Washio K, Okano T, Ishikawa I (2009) Periodontal regeneration with multi-layered periodontal ligament-derived cell sheets in a canine model. Biomaterials 30:2716–2723
Jakubowski W, Matyjaszewski K (2005) Activator generated by electron transfer for atom transfer radical polymerization. Macromolecules 38:4139–4146
Jhon YK, Bhat RR, Jeong C, Rojas OJ, Szleifer I, Genzer J (2006) Salt-induced depression of lower critical solution temperature in a surface-grafted neutral thermoresponsive polymer. Macromol Rapid Commun 27:697–701
Jiang X, Lavender C, Woodcock J, Zhao B (2008) Multiple micellization and dissociation transitions of thermo- and light-sensitive poly(ethylene oxide)-b-poly(ethoxytri(ethylene glycol) acrylate-co-o-nitrobenzyl acrylate) in water. Macromolecules 41:2632–2643
Johnson CH, Moad G, Solomon DH, Spurling TH, Vearing DJ (1990) The application of supercomputers in modeling chemical reaction kinetics: kinetic simulation of ‘quasi-living’ radical polymerization. Aust J Chem 43:1215–1230
Jonas AM, Glinel K, Oren R, Nysten B, Huck WTS (2007) Thermo-responsive polymer brushes with tunable collapse temperatures in the physiological range. Macromolecules 40:4403–4405
Kalajahi MS, Asl VH, Sadabad FB, Razin SR, Mamaqani HR (2011) Properties of PMMA/carbon nanotubes nanocomposites prepared by “grafting through” method. Polym Compos 33:215–224
Kamigaito M, Ando T, Sawamoto M (2004) Metal-catalyzed living radical polymerization. Chem Rev 4:3689–3746
Kato M, Kamigaito M, Sawamoto M, Higshimura T (1995) Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris-(triphenylphosphine) ruthenium(II)/methylaluminum bis(2,6-di-tert-butylphenoxide) initiating system: possibility of living radical polymerization. Macromolecules 28:1721–1723
Katsumoto Y, Tanaka T, Sato H, Ozaki Y (2002) Conformational change of poly(N-isopropylacrylamide) during the coil-globule transition investigated by attenuated total reflection/infrared spectroscopy and density functional theory calculation. J Phys Chem A 106:3429–3435
Kaufman CL, Williams M, Ryle LM, Smith TL, Tanner M, Ho C (2003) Superparamagnetic iron oxide particles transactivator protein-fluorescein isothiocyanate particle labeling for in vivo magnetic resonance imaging detection of cell migration: uptake and durability. Transplantation 76:1043–1046
Kessler D, Jochum FD, Choi J, Char K, Theato P (2011) Reactive surface coatings based on polysilsesquioxanes: universal method toward light-responsive surfaces. ACS Appl Mater Interfaces 3:124–128
Kidoaki S, Ohya S, Nakayama Y, Matsuda T (2001) Thermoresponsive structural change of a poly(N-isopropylacrylamide) graft layer measured with an atomic force microscope. Langmuir 17:2402–2407
Kingshott P, Thissen H, Griesser HJ (2002) Effects of cloud-point grafting, chain length, and density of PEG layers on competitive adsorption of ocular proteins. Biomaterials 23:2043–2056
Kizhakkedathua JN, Kumara KR, Goodman D, Brooks DE (2004) Synthesis and characterization of well-defined hydrophilic block copolymer brushes by aqueous ATRP. Polymer 45:7471–7489
Klajn R (2014) Spiropyran-based dynamic materials. Chem Soc Rev 43:148–184
Koh AYC, Saunders BR (2005) Small-angle neutron scattering study of temperature-induced emulsion gelation: the role of sticky microgel particles. Langmuir 21:6734–6741
Kohler N, Fryxell GE, Zhang M (2004) A bifunctional poly(ethylene glycol) silane immobilized on metallic oxide-based nanoparticles for conjugation with cell targeting agents. J Am Chem Soc 126:7206–7211
Kohler N, Sun C, Wang J, Zhang M (2005) Methotrexate-modified superparamagnetic nanoparticles and their intracellular uptake into human cancer cells. Langmuir 21:8858–8864
Kolb HC, Finn MG, Sharpless KB (2001) Click chemistry: diverse chemical function from a few good reactions. Angew Chem Int Ed 40:2004–2021
Kou R, Zhang J, Wang T, Liu G (2015) Interactions between polyelectrolyte brushes and hofmeister ions: Chaotropes versus kosmotropes. Langmuir 31:10461–10468
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359:710–712
Kroft LJ, de Roos A (1999) Blood pool contrast agents for cardiovascular MR imaging. J Magn Reson Imaging 10:395–403
Kwak Y, Goto A, Tsujii Y, Muata Y, Komatsu K, Fukuda T (2002) A kinetic study on the rate retardation in radical polymerization of styrene with addition-fragmentation chain transfer. Macromolecules 35:3026–3029
Lai J, Mu X, Xu Y, Wu X, Wu C, Li C, Chen J, Zhao Y (2010) Light-responsive nanogated ensemble based on polymer grafted mesoporous silica hybrid nanoparticles. Chem Commun 46:7370–7372
Laible R, Hamann K (1980) Formation of chemically bound polymer layers on oxide surfaces and their role in colloidal stability. Adv Colloid Interf Sci 13:65–99
Laroussi M, Akan T (2007) Arc-free atmospheric pressure cold plasma jets: a review. Plasma Process Polym 4:777–788
Lauw Y, Horne MD, Rodopoulos T, Lockett V, Akgun B, Hamilton WA, Nelson ARJ (2012) Structure of [C4mpyr][NTf2] room-temperature ionic liquid at charged gold interfaces. Langmuir 28:7374–7381
Lee AS, Gast AP, Bütün V, Armes SP (1999) Characterizing the structure of pH dependent polyelectrolyte block copolymer micelles. Macromolecules 32:4302–4310
Lee H, Lee E, Kim DK, Jang NK, Jeong YY, Jon S (2006) Antibiofouling polymer-coated superparamagnetic iron oxide nanoparticles as potential magnetic resonance contrast agents for in vivo cancer imaging. J Am Chem Soc 128:7383–7389
Léger L, Creton C (2008) Adhesion mechanisms at soft polymer interfaces. Philos Trans R Soc 366:1425–1442
Lego B, Skene WG, Giasson S (2010) Swelling study of responsive polyelectrolyte brushes grafted from mica substrates: effect of pH, salt, and grafting density. Macromolecules 43:4384–4393
Lei H, Wang M, Tang Z, Luan Y, Liu W, Song B, Chen H (2014) Control of lysozyme adsorption by pH on surfaces modified with polyampholyte brushes. Langmuir 30:501–508
Lentacker I, De Geest BG, Vandenbroucke RE, Peeters L, Demeester J, De Smedt SC, Sanders NN (2006) Ultrasound-responsive polymer-coated microbubbles that bind and protect DNA. Langmuir 22:7273–7278
Li J, Chen XR, Chang YC (2005) Preparation of end-grafted polymer brushes by nitroxide-mediated free radical polymerization of vaporized vinyl monomers. Langmuir 21:9562–9567
Li D, Jones GL, Dunlap JR, Hua F, Zhao B (2006) Thermosensitive hairy hybrid nanoparticles synthesized by surface-initiated atom transfer radical polymerization. Langmuir 22:3344–3351
Li DX, He Q, Cui Y, Wang KW, Zhang XM, Li JB (2007a) Thermosensitive copolymer networks modify gold nanoparticles for nanocomposite entrapment. Chem Eur J 13:2224–2229
Li DX, Cui Y, Wang KW, He Q, Yan XH, Li JB (2007b) Thermosensitive nanostructures comprising gold nanoparticles grafted with block copolymers. Adv Funct Mater 17:3134–3140
Li D, He Q, Yang Y, Möhwald H, Li J (2008a) Two-stage pH response of poly(4-vinylpyridine) grafted gold nanoparticles. Macromolecules 41:7254–7256
Li DJ, Dunlap JR, Zhao B (2008b) Thermosensitive water-dispersible hairy particle-supported Pd nanoparticles for catalysis of hydrogenation in an aqueous/organic biphasic system. Langmuir 24:5911–5918
Liang L, Rieke PC, Liu J, Fryxell GE, Young JS, Engelhard MH, Alford KL (2000) Surfaces with reversible hydrophilic/hydrophobic characteristics on cross-linked poly(N-isopropylacrylamide) hydrogels. Langmuir 16:8016–8023
Liu S, Armes SP (2002) Polymeric surfactants for the new millennium: a pH-responsive, zwitterionic, schizophrenic diblock copolymer. Angew Chem Int Ed 41:1413–1416
Liu F, Urban MW (2010) Recent advances and challenges in designing stimuli-responsive polymers. Prog Polym Sci 35:3–23
Lu Y, Zhuk A, Xu L, Liang X, Kharlampieva E, Sukhishvili SA (2013) Tunable pH and temperature response of weak polyelectrolyte brushes: role of hydrogen bonding and monomer hydrophobicity. Soft Matter 9:5464–5472
Ma QG, Wooley KL (2000) The preparation of t-butyl acrylate, methyl acrylate, and styrene block copolymers by atom transfer radical polymerization: precursors to amphiphilic and hydrophilic block copolymers and conversion to complex nanostructured materials. J Polym Sci Polym Chem 38:4805–4820
Ma QG, Remsen EE, Kowalewski T, Wooley KL (2001) Two-dimensional, shell-cross-linked nanoparticle arrays. J Am Chem Soc 123:4627–4628
Martina MS, Fortin JP, Menager C, Clement O, Barratt G, Grabielle-Madelmont C, Gazeau F, Cabuil V, Lesieur S (2005) Generation of superparamagnetic liposomes revealed as highly efficient MRI contrast agents for in vivo imaging. J Am Chem Soc 127:10676–10685
Matsuda T, Ohya S (2005) Photoiniferter-based thermoresponsive graft architecture with albumin covalently fixed at growing graft chain end. Langmuir 21:9660–9665
Matyjaszewski K (2012) Atom transfer radical polymerization (ATRP): current status and future perspectives. Macromolecules 45:4015–4039
Matyjaszewski K, Xia J (2001) Atom transfer radical polymerization. Chem Rev 101:2921–2990
Meister A, Bastrop M, Koschoreck S, Garamus VM, Sinemus T, Hempel G, Drescher S, Dobner B, Richtering W, Huber K, Blume A (2007) Structure-property relationship in stimulus-responsive bolaamphiphile hydrogels. Langmuir 23:7715–7723
Memon IA, Sawa Y, Fukushima N, Matsumiya G, Miyagawa S, Taketani S, Sakakida SK, Kondoh H, Aleshin AN, Shimizu T, Okano T, Matsuda H (2005) Repair of impaired myocardium by means of implantation of engineered autologous myoblast sheets. J Thorac Cardiovasc Surg 130:1333–1341
Mendes PM (2008) Stimuli-responsive surfaces for bio-applications. Chem Soc Rev 37:2512–2529
Minko S, Patil S, Datsyuk V, Simon F, Eichhorn KJ, Motornov M, Usov D, Tokarev I, Stamm M (2002) Synthesis of adaptive polymer brushes via “grafting to” approach from melt. Langmuir 18:289–296
Miyamae T, Akiyama H, Yoshida M, Tamaoki N (2007) Characterization of poly(N-isopropylacrylamide)-grafted interfaces with sum-frequency generation spectroscopy. Macromolecules 40:4601–4606
Mizutani A, Kikuchi A, Yamato M, Kanazawa H, Okano T (2008) Preparation of thermoresponsive polymer brush surfaces and their interaction with cells. Biomaterials 29:2073–2081
Moglianetti M, Webster JR, Edmondson S, Armes SP, Titmuss S (2010) Neutron reflectivity study of the structure of pH-responsive polymer brushes grown from a macroinitiator at the sapphire−water interface. Langmuir 26:12684–12689
Möller M, Matyjaszewski K (eds) (2012) Polymer science: a comprehensive reference. Elsevier, Amsterdam
Murdoch TJ, Willott JD, de Vos WM, Nelson A, Prescott SW, Wanless EJ, Webber GB (2016a) Influence of anion hydrophilicity on the conformation of a hydrophobic weak polyelectrolyte brush. Macromolecules 49:9605–9617
Murdoch TJ, Humphreys BA, Willott JD, Gregory KP, Prescott SW, Nelson A, Wanless EJ, Webber GB (2016b) Specific anion effects on the internal structure of a poly(N-isopropylacrylamide) brush. Macromolecules 49:6050–6060
Murdoch TJ, Humphreys BA, Willott JD, Prescott SW, Nelson A, Webber GB, Wanless EJ (2017) Enhanced specific ion effects in ethylene glycol-based thermoresponsive polymer brushes. J Colloid Interface Sci 490:869–878
Murphy M, Tso WW, Tanzini M, Sitti M (2006) Waalbot: an agile small-scale wall climbing robot utilizing pressure sensitive adhesives. Proc Int Conf Intell Robots Syst:3411–3416
Murthy KS, Ma QG, Remsen EE, Kowalewski T, Wooley KL (2003) Thermal shaping of shell-crosslinked (SCK) nanoparticles, facilitated by nanoconfinement of fluid-like cores. J Mater Chem 13:2785–2795
Nagase K, Kobayashi J, Kikuchi A, Akiyama Y, Kanazawa H, Okano T (2007) Interfacial property modulation of thermoresponsive polymer brush surfaces and their interaction with biomolecules. Langmuir 23:9409–9415
Nagase K, Kobayashi J, Kikuchi AI, Akiyama Y, Kanazawa H, Okano T (2008a) Effects of graft densities and chain lengths on separation of bioactive compounds by nanolayered thermoresponsive polymer brush surfaces. Langmuir 24:511–517
Nagase K, Kobayashi J, Kikuchi A, Akiyama Y, Kanazawa H, Okano T (2008b) Preparation of thermoresponsive cationic copolymer brush surfaces and application of the surface to separation of biomolecules. Biomacromolecules 9:1340–1347
Nagase K, Watanabe M, Kikuchi A, Yamato M, Okano T (2011) Thermo-responsive polymer brushes as intelligent biointerfaces: preparation via ATRP and characterization. Macromol Biosci 11:400–409
Nakai K, Fujii S, Nakamura Y, Yusa S (2013) Ultraviolet-light-responsive Liquid Marbles. Chem Lett 42:586–588
Nash ME, Healy D, Carroll WM, Elvira C, Rochev YA (2012) Cell and cell sheet recovery from pNIPAm coatings; motivation and history to present day approaches. J Mater Chem 22:19376–19389
Nishida K, Yamato M, Hayashida Y, Watanabe K, Maeda N, Watanabe H, Yamamoto K, Nagai S, Kikuchi A, Tano Y, Okano T (2004) Functional bioengineered corneal epithelial sheet grafts from corneal stem cells expanded ex vivo on a temperature-responsive cell culture surface. Transplantation 77:379–385
Nordgren N, Rutland MW (2009) Tunable nanolubrication between dual-responsive polyionic grafts. Nano Lett 9:2984–2990
Oh JK, Kim K, Matyjaszewski K (2006) Preparation of poly(oligo(ethylene glycol) monomethyl ether methacrylate) by homogeneous aqueous AGET ATRP. Macromolecules 39:3161–3167
Ohki T, Yamato M, Murakami D, Takagi R, Yang J, Namiki H, Okano T, Takasaki K (2006) Treatment of oesophageal ulcerations using endoscopic transplantation of tissue-engineered autologous oral mucosal epithelial cellsheets in a canine model. Gut 55:1704–1710
Ohno K, Koh K, Tsujii Y, Fukuda T (2003) Fabrication of ordered arrays of gold nanoparticles coated with high-density polymer brushes. Angew Chem Int Ed 42:2751–2754
Ohno K, Akashi T, Huang Y, Tsujii Y (2010) Surface-initiated living radical polymerization from narrowly size-distributed silica nanoparticles of diameters less than 100 nm. Macromolecules 43:8805–8812
Okabe S, Seno K-I, Kanaoka S, Aoshima S, Shibayama M (2006) Micellization study on block and gradient copolymer aqueous solutions by DLS and SANS. Macromolecules 39:1592–1597
Okano T, Yamada N, Okuhara M, Sakai H, Sakurai Y (1995) Mechanism of cell detachment from temperature-modulated, hydrophilic-hydrophobic polymer surfaces. Biomaterials 16:297–303
Pan YV, Wesley RA, Luginbuhl R, Denton DD, Ratner BD (2001) Plasma polymerized N-isopropylacrylamide: synthesis and characterization of a smart thermally responsive coating. Biomacromolecules 2:32–36
Pasparakis G, Vamvakaki M (2011) Multiresponsive polymers: nano-sized assemblies, stimuli-sensitive gels and smart surfaces. Polym Chem 2:1234–1248
Patel NG, Cavicchia JP, Zhang G, Zhang Newby BM (2012) Rapid cell sheet detachment using spin-coated pNIPAAm films retained on surfaces by an aminopropyltriethoxysilane network. Acta Biomater 8:2559–2567
Paven M, Mayama H, Sekido T, Butt H-J, Nakamura Y, Fujii S (2016) Light-driven delivery and release of materials using liquid marbles. Adv Funct Mater 26:3199–3206
Pelton RH, Chibante P (1986) Preparation of aqueous latices with N-isopropylacrylamide. Colloids Surf 20:247–256
Piech M, Bell NS (2006) Controlled synthesis of photochromic polymer brushes by atom transfer radical polymerization. Macromolecules 39:915–922
Plunkett KN, Zhu X, Moore JS, Leckband DE (2006) PNIPAM chain collapse depends on the molecular weight and grafting density. Langmuir 22:4259–4266
Popa AM, Angeloni S, Bürgi T, Hubbell JA, Heinzelmann H, Pugin R (2010) Dynamic perspective on the function of thermoresponsive nanopores from in situ AFM and ATR-IR investigations. Langmuir 26:15356–15365
Pyun J, Kowalewski T, Matyjaszewski K (2003) Synthesis of polymer brushes using atom transfer radical polymerization. Macromol Rapid Commun 24:1043–1059
Radu DR, Lai CY, Wiench JW, Pruski M, Lin VSY (2004) Gatekeeping layer effect: a poly(lactic acid)-coated mesoporous silica nanosphere-based fluorescence probe for detection of amino-containing neurotransmitters. J Am Chem Soc 126:1640–1641
Rahane SB, Floyd JA, Metters AT, Kilbey SMII (2008) Swelling behavior of multiresponsive poly(methacrylic acid)-block-poly(N-isopropylacrylamide) brushes synthesized using surface-initiated photoiniferter-mediated photopolymerization. Adv Funct Mater 18:1232–1240
Raula J, Shan J, Nuopponen M, Niskanen A, Jiang H, Kauppinen EI, Tenhu H (2003) Synthesis of gold nanoparticles grafted with a thermoresponsive polymer by surface-induced reversible-addition-fragmentation chain-transfer polymerization. Langmuir 19:3499–3504
Rayatpisheh S, Li P, Chan-Park MB (2012) Argon-plasmainduced ultrathin thermal grafting of thermoresponsive pNIPAm coating for contractile patterned human SMC sheet engineering. Macromol Biosci 12:937–945
Richert L, Lavalle P, Vautier D, Senger B, Stoltz J-F, Schaaf P, Voegel J-C, Picart C (2002) Cell interactions with polyelectrolyte multilayer films. Biomacromolecules 3:1170–1178
Rizzardo E (1987) Living free radical polymerization. Chem Aust 54:32
Rogers WJ, Basu P (2005) Factors regulating macrophage endocytosis of nanoparticles: implications for targeted magnetic resonance plaque imaging. Atherosclerosis 178:67–73
Rosario R, Gust D, Hayes M, Jahnke F, Springer J, Garcia AA (2002) Photon-modulated wettability changes on spiropyran-coated surfaces. Langmuir 18:8062–8069
Sakai K, Smith EG, Webber GB, Schatz C, Wanless EJ, Bütün V, Armes SP, Biggs S (2006a) Comparison of the adsorption of cationic diblock copolymer micelles from aqueous solution onto mica and silica. Langmuir 22:5328–5333
Sakai K, Smith EG, Webber GB, Baker M, Wanless EJ, Bütün V, Armes SP, Biggs S (2006b) Characterizing the pH-responsive behavior of thin films of diblock copolymer micelles at the silica/aqueous solution interface. Langmuir 22:8435–8442
Sakai K, Smith EG, Webber GB, Baker M, Wanless EJ, Bütün V, Armes SP, Biggs S (2007) pH-responsive behavior of selectively quaternized diblock copolymers adsorbed at the silica/aqueous solution interface. J Colloid Interface Sci 314:381–388
Samanta S, Locklin J (2008) Formation of photochromic spiropyran polymer brushes via surface-initiated, ring-opening metathesis polymerization: reversible photocontrol of wetting behavior and solvent dependent morphology changes. Langmuir 24:9558–9565
Sanjuan S, Perrin P, Pantoustier N, Tran Y (2007) Synthesis and swelling behavior of pH-responsive polybase brushes. Langmuir 23:5769–5778
Saragi TPI, Spehr T, Siebert A, Fuhrmann-Lieker T, Salbeck J (2007) Spiro compounds for organic optoelectronics. Chem Rev 107:1011–1065
Sarsabili M, Parvini M, Kalajahi MS, Anzabi PG (2013) In situ reversible addition-fragmentation chain transfer polymerization of styrene in the presence of MCM-41 nanoparticles: comparing “grafting from” and “grafting through” approaches. Adv Polym Technol 32:21372
Satas D (1989) Handbook of pressure sensitive adhesives, 3rd edn. Van Nostrand Reinhold, New York
Schatz C, Smith EG, Armes SP, Wanless EJ (2008) Reversible pH-triggered encapsulation and release of pyrene by adsorbed block copolymer micelles. Langmuir 24:8325–8331
Schwartz E, Lim E, Gowda CM, Liscio A, Fenwick O, Tu G, Palermo V, de Gelder R, Cornelissen JJLM, Van Eck ERH, Kentgens APM, Cacialli F, Nolte RJM, Samorì P, Huck WTS Rowan AE (2010) Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides. Chem Mater 22:2597–2607
Seino M, Yokomachi K, Hayakawa T, Kikuchi R, Kakimoto MA, Horiuchi S (2006) Preparation of poly(N-isopropylacrylamide) grafted silica bead using hyperbranched polysiloxysilane as polymer brush and application to temperature-responsive HPLC. Polymer 47:1946–1952
Serpe MJ, Jones CD, Lyon LA (2003) Layer-by-layer deposition of thermoresponsive microgel thin films. Langmuir 19:8759–8764
Serpe MJ, Kim J, Lyon LA (2004) Colloidal hydrogel microlenses. Adv Mater 16:184–187
Serpe MJ, Yarmey KA, Nolan CM, Lyon LA (2005) Doxorubicin uptake and release from microgel thin films. Biomacromolecules 6:408–413
Shen YR (1989) Surface properties probed by second-harmonic and sum-frequency generation. Nature 337:519–525
Shen YR (1994) Surfaces probed by nonlinear optics. Surf Sci 299/300:551–562
Shimizu T, Sekine H, Isoi Y, Yamato M, Kikuchi A, Okano T (2006) Long-term survival and growth of pulsatile myocardial tissue grafts engineered by the layering of cardiomyocyte sheets. Tissue Eng 12:499–507
Shimoboji T, Ding ZL, Stayton SP, Hoffman AS (2002) Photoswitching of ligand association with a photoresponsive polymer-protein conjugate. Bioconjug Chem 13:915–919
Siewierski LM, Brittain WJ, Petrash S, Foster MD (1996) Photoresponsive monolayers containing in-chain azobenzene. Langmuir 12:5838–5844
Sobani M, Asl VH, Kalajahi NS, Mamaqani HR, Langari SAM, Khezri K (2013) “Grafting through” approach for synthesis of polystyrene/silica aerogel nanocomposites by in situ reversible addition fragmentation chain transfer polymerization. J Sol-Gel Sci Technol 66:337–344
Stein A, Melde BJ, Schroden RC (2000) Hybrid inorganic-organic mesoporous silicates-nanoscopic reactors coming of age. Adv Mater 12:1403–1419
Stevens MJ, Plimptom SJ (1998) The effect of added salt on polyelectrolyte structure. Eur Phys J B 2:341–345
Stieger M, Richtering W, Pedersen JS, Lindner P (2004) Small angle neutron scattering study of structural changes in temperature sensitive microgel colloids. J Chem Phys 120:6197–6206
Stratakis E, Mateescu A, Barberoglou M, Vamvakaki M, Fotakis C, Anastasiadis SH (2012) From superhydrophobicity and water repellency to superhydrophilicity: smart polymer-functionalized surfaces. Chem Commun 46:4136–4138
Stuart MAC, Huck WTS, Genzer J, Muller M, Ober C, Stamm M, Sukhorukov GB, Szleifer I, Tsukruk VV, Urban M, Winnik F, Zauscher S, Luzinov I, Minko S (2010) Emerging applications of stimuli-responsive polymer materials. Nat Mater 9:101–113
Sugihara S, Hashimoto K, Okabe S, Shibayama M, Kanaoka S, Aoshima S (2004) Stimuli-responsive diblock copolymers by living cationic polymerization: precision synthesis and highly sensitive physical gelation. Macromolecules 37:336–343
Sun TL, Wang GJ, Feng L, Liu BQ, Ma YM, Jiang L, Zhu DB (2004) Reversible switching between superhydrophilicity and superhydrophobicity. Angew Chem Int Ed 43:357–360
Sun JT, Hong CY, Pan CY (2010) Fabrication of PDEAEMA-coated mesoporous silica nanoparticles and pH-responsive controlled release. J Phys Chem C 114:12481–12486
Tadjeddine A, Peremans A (1996) Vibrational spectroscopy of the electrochemical interface by visible infrared sum-frequency generation. Surf Sci 368:377–383
Tan HS, Pfister WR (1999) Pressure-sensitive adhesives for transdermal drug delivery systems. Pharm Sci Technol Today 2:60–69
Tanaka K, Kitamura N, Naka K, Chujo Y (2008) Multi-modal 19F NMR probe using perfluorinated cubic silsesquioxane coated silica nanoparticles for monitoring enzymatic activity. Chem Commun:6176–6178
Tanaka K, Kitamura N, Chujo Y (2011) Bimodal quantitative monitoring for enzymatic activity with simultaneous signal increases in 19F NMR and fluorescence using silica nanoparticle-based molecular probes. Bioconjug Chem 22:1484–1490
Tang T, Castelletto V, Parras P, Hamley IW, King SM, Roy D, Perrier S, Hoogenboom R, Schubert US (2006) Thermo-responsive poly(methyl methacrylate)-block-poly(N-isopropylacrylamide) block copolymers synthesized by RAFT polymerization: Micellization and gelation. Macromol Chem Phys 207:1718–1726
Tang X, Tang S, Sivan V, Zhang W, Mitchell A, Kalantar-Zadeh K, Khoshmanesh K (2013) Photochemically induced motion of liquid metal marbles. Appl Phys Lett 103:174104-1–174104-4
Taylor W, Jones RAL (2010) Producing high-density highmolecular-weight polymer brushes by a “grafting to” method from a concentrated homopolymer solution. Langmuir 26:13954–13958
Taylor W, Jones RAL (2013) Protein adsorption on wellcharacterized polyethylene oxide brushes on gold: dependence on molecular weight and grafting density. Langmuir 29:6116–6122
Tekin H, Sanchez JG, Tsinman T, Langer R, Khademhosseini A (2011) Thermoresponsive platforms for tissue engineering and regenerative medicine. AICHE J 57:3249–3258
Thompson KL, Fielding LA, Mykhaylyk OO, Lane JA, Derry MJ, Armes SP (2015) Vermicious thermo-responsive Pickering emulsifiers. Chem Sci 6:4207–4214
Tomlinson MR, Cousin F, Geoghegan M (2009) Creation of dense polymer brush layers by the controlled deposition of an amphiphilic responsive comb polymer. Polymer 50:4829–4836
Toyama M, Ito T, Nukatsuka H, Ikeda M (1973) Studies on tack of pressure-sensitive adhesive tapes: on the relationship between pressure-sensitive adhesion and surface energy of adherends. J Appl Polym Sci 17:3495–3502
Treat ND, Ayres N, Boyes SG, Brittain WJ (2006) A facile route to poly(acrylic acid) brushes using atom transfer radical polymerization. Macromolecules 39:26–29
Tsarevski NV, Sumerlin BS (eds) (2013) Fundamentals of controlled/living radical polymerization. Royal Society of Chemistry, London
Tsujii Y, Ohno K, Yamamoto S, Goto A, Fukuda T (2006) Structure and properties of high-density polymer brushes prepared by surface-initiated living radical polymerization. Adv Polym Sci 197:1–45
Urban MW (ed) (2011) Handbook of stimuli-responsive materials. Wiley-VCH, Weinheim
Vogel V (1996) What do nonlinear optical techniques have to offer the biosciences? Curr Opin Colloid Interface Sci 1:257–263
von Recum HA, Okano T, Kim SW, Bernstein PS (1999) Maintenance of retinoid metabolism in human retinal pigment epithelium cell culture. Exp Eye Res 69:97–107
Wang JS, Matyjaszewski K (1995) Controlled/“living” radical polymerization. Halogen atom transfer radical polymerization promoted by a cu(I)/cu(II) redox process. Macromolecules 28:7901–7910
Wang T, Lei CH, Dalton AB, Creton C, Lin Y, Sun YP, Fernando KAS, Manea M, Asua JM, Keddie JL (2006) Waterborne, nanocomposite pressure-sensitive adhesives with high tack energy, optical transparency, and electrical conductivity. Adv Mater 18:2730–2734
Wang X, Xiao X, Wang X, Zhou J, Li L, Xu J (2007) Reversibly switchable double-responsive block copolymer brushes. Macromol Rapid Commun 28:828–833
Wang T, Long Y, Liu L, Wang X, Craig VSJ, Zhang G, Liu G (2014) Cation-specific conformational behavior of polyelectrolyte brushes: from aqueous to nonaqueous solvent. Langmuir 30:12850–12859
Webber GB, Wanless EJ, Bütün V, Armes SP, Biggs S (2002) Self-organized monolayer films of stimulus-responsive micelles. Nano Lett 2:1307–1313
Webber GB, Wanless EJ, Armes SP, Tang Y, Li Y, Biggs S (2004) Nano-anemones: stimulus-responsive copolymer-micelle surfaces. Adv Mater 16:1794–1798
Webber GB, Wanless EJ, Armes SP, Biggs S (2005a) Tunable diblock copolymer micelles–adapting behavior via subtle chemical modifications. Faraday Discuss 128:193–209
Webber GB, Wanless EJ, Armes SP, Biggs S (2005b) Tunable diblock copolymer micelles–adapting behaviour via subtle chemical modifications. Faraday Discuss 128:193–209
Wei QS, Ji J, Shen JC (2008) Synthesis of near-infrared responsive gold nanorod/PNIPAAm core/shell nanohybrids via surface initiated ATRP for smart drug delivery. Macromol Rapid Commun 29:645–650
Wei Y, Gao D, Li L, Shang S (2011) Memory effect in polymer brushes containing pendent carbazole groups. Polymer 52:1385–1390
Wei Q, Cai M, Zhou F, Liu W (2013) Dramatically tuning friction using responsive polyelectrolyte brushes. Macromolecules 46:9368–9379
Willott JD, Humphreys BA, Murdoch TJ, Edmondson S, Webber GB, Wanless EJ (2015a) Hydrophobic effects within the dynamic pH-response of polybasic tertiary amine methacrylate brushes. Phys Chem Chem Phys 17:3880–3890
Willott JD, Murdoch TJ, Humphreys BA, Edmondson S, Webber GB, Wanless EJ (2015b) Anion-specific effects on the behavior of pH-sensitive polybasic brushes. Langmuir 31:3707–3717
Wilson MD, Whitesides GM (1988) The anthranilate amide of "polyethylene carboxylic acid" shows an exceptionally large change with pH in its wettability by water. J Am Chem Soc 110:8718–8719
Woods DA, Bain CD (2014) Total internal reflection spectroscopy for studying soft matter. Soft Matter 10:1071–1096
Wu T, Gong P, Szleifer I, Vlček P, Šubr V, Genzer J (2007) Behavior of surface-anchored poly(acrylic acid) brushes with grafting density gradients on solid substrates: 1. Experiment. Macromolecules 40:8756–8764
Wu T, Zhang YF, Wang XF, Liu SY (2008) Fabrication of hybrid silica nanoparticles densely grafted with thermoresponsive poly(N-isopropylacrylamide) brushes of controlled thickness via surface-initiated atom transfer radical polymerization. Chem Mater 20:101–109
Wu B, Wang X, Yang J, Hua Z, Tian K, Kou R, Zhang J, Ye S, Luo Y, Craig VSJ, Zhang G, Liu G (2016) Reorganization of hydrogen bond network makes strong polyelectrolyte brushes pH-responsive. Sci Adv 2:e1600579
Wuelfing WP, Gross SM, Miles DT, Murray RW (1998) Nanometer gold clusters protected by surface-bound monolayers of thiolated poly(ethylene glycol) polymer electrolyte. J Am Chem Soc 120:12696–12697
Xia F, Feng L, Wang S, Sun T, Song W, Jiang W, Jiang L (2006) Dual-responsive surfaces that switch between superhydrophilicity and superhydrophobicity. Adv Mater 18:432–436
Xu FJ, Zhong SP, Yung LYL, Tong YW, Kang ET, Neoh KG (2006) Thermoresponsive comb-shaped copolymer-Si (100) hybrids for accelerated temperature-dependent cell detachment. Biomaterials 27:1236–1245
Xu LQ, Wan D, Gong HF, Neoh KG, Kang ET, Fu GD (2010) One-pot preparation of ferrocene-functionalized polymer brushes on gold substrates by combined surface-initiated atom transfer radical polymerization and “click chemistry”. Langmuir 26:15376–15382
Yakushiji T, Sakai K, Kikuchi A, Aoyagi T, Sakurai Y, Okano T (1998) Graft architectural effects on thermoresponsive wettability changes of poly(N-isopropylacrylamide)-modified surfaces. Langmuir 14:4657–4662
Yamada N, Okano T, Sakai H, Karikusa F, Sawasaki Y, Sakurai Y (1990) Thermo-responsive polymeric surfaces; control of attachment and detachment of cultured cells. Makromol Chem Rapid Commun 11:571–576
Yamago S (2009) Precision polymer synthesis by degenerative transfer controlled/living radical polymerization using organotellurium, organostibine, and organobismuthine chain-transfer agents. Chem Rev 109:5051–5068
Yang Y, Yan X, Cui Y, He Q, Li D, Wang A, Fei J, Li JJ (2008) Preparation of polymer-coated mesoporous silica nanoparticles used for cellular imaging by a “graft-from” method. Mater Chem 18:5731–5737
Yang R, Peng S, Hughes TC (2014) Multistimuli responsive organogels based on a reactive azobenzene gelator. Soft Matter 10:2188–2196
Yenice Z, Schön S, Bildirir H, Genzer J, von Klitzing R (2015) Thermoresponsive PDMAEMA brushes: effect of gold nanoparticle deposition. J Phys Chem B 119:10348–10358
Yim H, Kent MS, Satija S, Mendez S, Balamurugan SS, Balamurugan S, Lopez GP (2004) Study of the conformational change of poly(N-isopropylacrylamide)-grafted chains in water with neutron reflection: molecular weight dependence at high grafting density. J Polym Sci B Polym Phys 42:3302–3310
Yim H, Kent MS, Mendez S, Lopez GP, Satija S, Seo Y (2006) Effects of grafting density and molecular weight on the temperature-dependent conformational change of poly(N-isopropylacrylamide) grafted chains in water. Macromolecules 39:3420–3426
Yoshida M, Lahann J (2008) Smart nanomaterials. ACS Nano 2:1101–1107
You YZ, Kalebaila KK, Brock SL, Oupicky D (2008) Temperature-controlled uptake and release in PNIPAM-modified porous silica nanoparticles. Chem Mater 20:3354–3359
Yow HN, Biggs S (2013) Probing the stability of sterically stabilized polystyrene particles by centrifugal sedimentation. Soft Matter 9:10031–10041
Yu AM, Wang YJ, Barlow E, Caruso F (2005) Mesoporous silica particles as templates for preparing enzyme loaded biocompatible microcapsules. Adv Mater 17:1737–1741
Yu Q, Li X, Zhang Y, Yuan L, Zhao T, Chen H (2011) The synergistic effects of stimuli-responsive polymers with nano-structured surfaces: wettability and protein adsorption. RSC Adv 1:262–269
Yuan W, Jiang G, Wang J, Wang G, Song Y, Jiang L (2006) Temperature/light dual-responsive surface with tunable wettability created by modification with an azobenzene-containing copolymer. Macromolecules 39:1300–1303
Yusa S, Fukuda K, Yamamoto T, Iwasaki Y, Watanabe A, Akiyoshi K, Morishima Y (2007) Salt effect on the heat-induced association behavior of gold nanoparticles coated with poly(N-isopropylacrylamide) prepared via reversible addition-fragmentation chain transfer (RAFT) radical polymerization. Langmuir 23:12842–12848
Zeiser M, Freudensprung I, Hellweg T (2012) Linearly thermoresponsive core-shell microgels: towards a new class of nanoactuators. Polymer 53:6096–6101
Zhang Q, Remsen EE, Wooley KL (2000) Shell cross-linked nanoparticles containing hydrolytically degradable, crystalline core domains. J Am Chem Soc 122:3642–3651
Zhang Q, Clark CG, Wang M, Remsen EE, Wooley KL (2002a) Thermally-induced (re)shaping of Core−Shell Nanocrystalline particles. Nano Lett 2:1051–1054
Zhang Y, Kohler N, Zhang M (2002b) Surface modification of superparamagnetic magnetite nanoparticles and their intracellular uptake. Biomaterials 23:1553–1561
Zhang MM, Liu L, Zhao HY, Yang Y, Fu GQ, He BL (2006) Double-responsive polymer brushes on the surface of colloid particles. J Colloid Interface Sci 301:85–91
Zhang Q, Xia F, Sun T, Song W, Zhao T, Liu M, Jiang L (2008) Wettability switching between high hydrophilicity at low pH and high hydrophobicity at high pH on surface based on pH-responsive polymer. Chem Commun:1199–1201
Zhang L, Cha D, Wang P (2012) Remotely controllable liquid marbles. Adv Mater 24:4756–4760
Zhang Z, Morse AJ, Armes SP, Lewis AL, Geoghegan M, Leggett GJ (2013) Nanoscale contact mechanics of biocompatible polyzwitterionic brushes. Langmuir 29:10684–10692
Zhang S, Vi T, Luo K, Koberstein JT (2016) Kinetics of polymer interfacial reactions: polymer brush formation by click reactions of alkyne end-functional polymers with azide-functional substrates. Macromolecules 49:5461–5474
Zhao B, Brittain WJ (2000) Polymer brushes: surface-immobilized macromolecules. Prog Polym Sci 25:677–710
Zhou Z, Zhu S, Zhang D (2007) Grafting of thermo-responsive polymer inside mesoporous silica with large pore size using ATRP and investigation of its use in drug release. J Mater Chem 17:2428–2433
Zhou YN, Li JJ, Zhang Q, Luo ZH (2014) Light-responsive smart surface with controllable wettability and excellent stability. Langmuir 30:12236–12242
Zhu YF, Shi JL, Shen WH, Dong XP, Feng JW, Ruan ML, Li YS (2005) Stimuli-responsive controlled drug release from a hollow mesoporous silica sphere/polyelectrolyte multilayer core-shell structure. Angew Chem Int Ed 44:5083–5087
Zosel A (1992) Chapter 4. In: Satas D (ed) Advances in pressure sensitive adhesive technology, vol 1. Satas & Associates, Warwick
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer International Publishing AG, part of Springer Nature
About this chapter
Cite this chapter
Fujii, S., Wanless, E.J., Yusa, Si., Webber, G.B., Ishida, N. (2018). Stimulus-Responsive Soft Surface/Interface Toward Applications in Adhesion, Sensor and Biomaterial. In: Hozumi, A., Jiang, L., Lee, H., Shimomura, M. (eds) Stimuli-Responsive Dewetting/Wetting Smart Surfaces and Interfaces. Biologically-Inspired Systems, vol 11. Springer, Cham. https://doi.org/10.1007/978-3-319-92654-4_12
Download citation
DOI: https://doi.org/10.1007/978-3-319-92654-4_12
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-92653-7
Online ISBN: 978-3-319-92654-4
eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)